JPS60118624A - 結晶サイズのそろつた高シリカモルデナイトの製造法 - Google Patents
結晶サイズのそろつた高シリカモルデナイトの製造法Info
- Publication number
- JPS60118624A JPS60118624A JP22367783A JP22367783A JPS60118624A JP S60118624 A JPS60118624 A JP S60118624A JP 22367783 A JP22367783 A JP 22367783A JP 22367783 A JP22367783 A JP 22367783A JP S60118624 A JPS60118624 A JP S60118624A
- Authority
- JP
- Japan
- Prior art keywords
- source
- sio2
- mixture
- mordenite
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000013078 crystal Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229910052680 mordenite Inorganic materials 0.000 title abstract description 28
- 239000000377 silicon dioxide Substances 0.000 title abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 32
- 229910001868 water Inorganic materials 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 11
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 11
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 11
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 9
- 238000010335 hydrothermal treatment Methods 0.000 abstract description 9
- 239000011734 sodium Substances 0.000 abstract description 9
- 235000019353 potassium silicate Nutrition 0.000 abstract description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052593 corundum Inorganic materials 0.000 abstract description 7
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 7
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 7
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 6
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 abstract description 5
- 229910001388 sodium aluminate Inorganic materials 0.000 abstract description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001948 sodium oxide Inorganic materials 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000010457 zeolite Substances 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 229910001415 sodium ion Inorganic materials 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- -1 ammonium ions Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002447 crystallographic data Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22367783A JPS60118624A (ja) | 1983-11-28 | 1983-11-28 | 結晶サイズのそろつた高シリカモルデナイトの製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22367783A JPS60118624A (ja) | 1983-11-28 | 1983-11-28 | 結晶サイズのそろつた高シリカモルデナイトの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60118624A true JPS60118624A (ja) | 1985-06-26 |
| JPH0343208B2 JPH0343208B2 (enrdf_load_stackoverflow) | 1991-07-01 |
Family
ID=16801914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22367783A Granted JPS60118624A (ja) | 1983-11-28 | 1983-11-28 | 結晶サイズのそろつた高シリカモルデナイトの製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60118624A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01305811A (ja) * | 1988-06-01 | 1989-12-11 | Babcock Hitachi Kk | ハイシリカモルデナイト型ゼオライトの製造方法 |
| WO1998038131A1 (de) * | 1997-02-27 | 1998-09-03 | Süd-Chemie AG | VERFAHREN ZUR HERSTELLUNG VON ZEOLITHEN MIT EINEM HOHEN Si/Al-ATOMVERHÄLTNIS |
| JP2006187961A (ja) * | 2005-01-06 | 2006-07-20 | Gifu Plast Ind Co Ltd | 組み立て箱のインモールド成形による成形法 |
-
1983
- 1983-11-28 JP JP22367783A patent/JPS60118624A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01305811A (ja) * | 1988-06-01 | 1989-12-11 | Babcock Hitachi Kk | ハイシリカモルデナイト型ゼオライトの製造方法 |
| WO1998038131A1 (de) * | 1997-02-27 | 1998-09-03 | Süd-Chemie AG | VERFAHREN ZUR HERSTELLUNG VON ZEOLITHEN MIT EINEM HOHEN Si/Al-ATOMVERHÄLTNIS |
| US6645461B1 (en) | 1997-02-27 | 2003-11-11 | Sud-Chemie Ag | Process for production of zeolites with high Si/Al atomic ratio |
| JP2006187961A (ja) * | 2005-01-06 | 2006-07-20 | Gifu Plast Ind Co Ltd | 組み立て箱のインモールド成形による成形法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0343208B2 (enrdf_load_stackoverflow) | 1991-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10029247B2 (en) | Chabazite-type zeolite and process for producing the same | |
| JP2004083375A (ja) | Ｄｄｒ型ゼオライトの製造方法 | |
| CN104321280A (zh) | β型沸石及其制造方法 | |
| JP2012505148A (ja) | 分子篩ｓｓｚ−８２組成物およびその合成 | |
| JP6267712B2 (ja) | 選択触媒還元における触媒として使用するための、長期酸強度を有するアルミナシリケートゼオライト型材料及びその作製方法 | |
| CN108217684A (zh) | 一种促进Beta分子筛合成的方法 | |
| WO2014013969A1 (ja) | Ｍａｚ型ゼオライトの製造方法 | |
| JP6485666B1 (ja) | 非晶質アルミノケイ酸塩粒子粉末及びその製造方法 | |
| Saleh et al. | A comparative study of Y zeolite catalysts derived from natural and commercial silica: Synthesis, characterization, and catalytic performance | |
| Abid et al. | Preparation of LTA, HS and FAU/EMT intergrowth zeolites from aluminum scraps and industrial metasilicate | |
| CN116789149A (zh) | 一种zsm-48分子筛及其制备方法和应用 | |
| JPS60118624A (ja) | 結晶サイズのそろつた高シリカモルデナイトの製造法 | |
| KR20200045111A (ko) | 제올라이트 pst-29 및 그 제조방법, 이를 이용한 이산화탄소의 선택적 분리 및 메틸아민의 제조 | |
| JP2017178745A (ja) | アーモンド状の形状を有するｚｓｍ−５型ゼオライトおよびその製造方法 | |
| CN109911913A (zh) | 制备bea型分子筛的方法及bea型分子筛 | |
| CN104117388A (zh) | 一种sapo-11/zsm-5混合分子筛催化剂及其制备和应用 | |
| JP5820526B2 (ja) | ゲルマノケイ酸塩ｓｓｚ−７５ | |
| JPS5983927A (ja) | 新規結晶性アルミノシリケ−トゼオライトおよびその製造方法 | |
| Wu et al. | Effect of surfactant/silica and hydrothermal time on the specific surface area of mesoporous materials from coal-measure kaolin | |
| CN112808296A (zh) | 一种含y型分子筛的催化剂及其制备方法 | |
| JP2564581B2 (ja) | 高シリカ含有量ゼオライトの製法 | |
| JP7676194B2 (ja) | 充填密度が高いフォージャサイト型ゼオライトの製造方法 | |
| CN111099626A (zh) | Itq-43分子筛的合成方法及其合成的itq-43分子筛 | |
| JP2019178049A (ja) | ペンタシル型ゼオライト及びその製造方法 | |
| JPS6117417A (ja) | 結晶性アルミノシリケ−トゼオライトおよびその製造方法 |