JPS5978980A - 金属基体表面とセラミツク素材との接合構造 - Google Patents

金属基体表面とセラミツク素材との接合構造

Info

Publication number
JPS5978980A
JPS5978980A JP57185882A JP18588282A JPS5978980A JP S5978980 A JPS5978980 A JP S5978980A JP 57185882 A JP57185882 A JP 57185882A JP 18588282 A JP18588282 A JP 18588282A JP S5978980 A JPS5978980 A JP S5978980A
Authority
JP
Japan
Prior art keywords
ceramic
metal substrate
fitting
substrate surface
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP57185882A
Other languages
English (en)
Other versions
JPS6111907B2 (ja
Inventor
秀雄 劉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Usui Kokusai Sangyo Kaisha Ltd
Original Assignee
Usui Kokusai Sangyo Kaisha Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Usui Kokusai Sangyo Kaisha Ltd filed Critical Usui Kokusai Sangyo Kaisha Ltd
Priority to JP57185882A priority Critical patent/JPS5978980A/ja
Priority to GB08326147A priority patent/GB2128919B/en
Priority to FR8315972A priority patent/FR2534902B1/fr
Priority to DE3337364A priority patent/DE3337364C2/de
Priority to US06/542,105 priority patent/US4523554A/en
Publication of JPS5978980A publication Critical patent/JPS5978980A/ja
Publication of JPS6111907B2 publication Critical patent/JPS6111907B2/ja
Granted legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F7/00—Casings, e.g. crankcases or frames
    • F02F7/0085—Materials for constructing engines or their parts
    • F02F7/0087—Ceramic materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/025—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of glass or ceramic material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04—Ceramic interlayers
    • C04B2237/06—Oxidic interlayers
    • C04B2237/062—Oxidic interlayers based on silica or silicates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04—Ceramic interlayers
    • C04B2237/06—Oxidic interlayers
    • C04B2237/068—Oxidic interlayers based on refractory oxides, e.g. zirconia
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/04—Ceramic interlayers
    • C04B2237/09—Ceramic interlayers wherein the active component for bonding is not the largest fraction of the interlayer
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/34—Oxidic
    • C04B2237/343—Alumina or aluminates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/34—Oxidic
    • C04B2237/345—Refractory metal oxides
    • C04B2237/348—Zirconia, hafnia, zirconates or hafnates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/36—Non-oxidic
    • C04B2237/365—Silicon carbide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/36—Non-oxidic
    • C04B2237/368—Silicon nitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40—Metallic
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/61—Joining two substrates of which at least one is porous by infiltrating the porous substrate with a liquid, such as a molten metal, causing bonding of the two substrates, e.g. joining two porous carbon substrates by infiltrating with molten silicon
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/64—Forming laminates or joined articles comprising grooves or cuts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/72—Forming laminates or joined articles comprising at least two interlayers directly next to each other
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/76—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc
    • C04B2237/765—Forming laminates or joined articles comprising at least one member in the form other than a sheet or disc, e.g. two tubes or a tube and a sheet or disc at least one member being a tube
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00—Metals
    • F05C2201/04—Heavy metals
    • F05C2201/0403—Refractory metals, e.g. V, W
    • F05C2201/0406—Chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Ceramic Products (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Laminated Bodies (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 本発明は金属基体の表面とセラミック素材嵌着重合して
なる接合構造に関するものである。
従来のこの種接合構造としては、第６図に例示するよう
に、例えば内燃機関におけるピストンライナーの開発試
用の楡上品にみるように、金属製円筒基体α１）の内周
面とに別体のＡｔ２ｏｓ系、Ｚｒ０ｇ系、８１５Ｎ、系
或いはｓｉｃ系等からなる円筒のセラミック部材（１２
１を焼嵌め等の手段によシ嵌着重合して構成している。
しかし、単に相互の周面での焼嵌め構造では、絶へず高
温度条件下での使用状態に伴い円筒基体０１）とセラミ
ック部材０″７ＪとＫ、２等相互の熱膨張係数の極度の
差異に起因して、しばしば嵌着重合部に緩みを招く傾向
となし、強いてはセラミック部材０２側にルを生せしめ
る問題を有した。又同時に之等焼嵌め構造に伴い相互単
体時の寸法精度並びに処理条件に可成シの加工上の煩わ
しさを招き、概して生産性の低下をみる等の問題を有し
た。
本発明はかかる問題を解決するためになされたものであ
って、その要旨は、特にセラミック部材側の嵌着重合面
に形成した特定な組成による緻密なセラミックの含浸層
と、それぞれの接合面の少なくとも一方に設けた嵌着重
合面での浸透溝との相乗効果によって相互の結合力を増
大せしめた接台構造にある。
以下、この発明の一実施例を第１図〜第５回に基づいて
説明する。（１）は内燃機関のピストンライナーとして
の金属基体、（２）は金属基体（１）の内側表面に嵌着
重合して固定してなるｄ、０．系、ＺｒＯ２糸、３１１
ＩＮ、系或いはＳｉＣ系等からなる円筒のセラミック素
材にして、２等相互のなす金属基体（１）側の嵌着重合
面（げもしくはセラミック素材（２）側の嵌着重合面（
９，Ｙの少なくとも一方に設けた略々全長に亘る複数の
浸透溝（３）、　（３）’、Ｉ：＜＋“・・・をもって
嵌着重合してなるものである。（４）及び（５）は斯る
嵌着重合した状麺、目をもって１％にセラミック素材（
２）側の重合面（２白１Ｉｌｌと外表面（２）′’側と
の之等面附近に沿って形成したＣｒ２０１　単体もしく
はＳｉｎｇ　＋　Ｃｒ２Ｏ３及びＡｔ５Ｏ，からなる組
成を有した加熱焼成に伴って化学結合されてなる緻密な
セラミックの含浸層である。
上記セラミックの含浸層（４１、（５）の形成に際して
は、可溶性クローム化合物の濃水溶液（例えばＨ２Ｃｒ
Ｏ４）に酸化クローム（ｃｒＱｏ３）　４１体もしくは
珪石（ｓｈｏ２）、酸化クローム（ｃｒ２ｏ３）及び溶
融アルミナ（α−ｍ、ｏ３）からなる混合微粉末を添加
して充分に攪拌混合した液中に前記嵌着重合した状態を
もって浸漬せしめ、浸透溝ｆ３）　、　（３Ｙ、（３）
／’・・・部からの浸透による重合面（２ト側と外表面
（２）”とにそれぞれ含浸せしめ、次で４００℃前後の
加熱処理を施すことＫよって２等加熱焼成に伴い微粒子
相互及び金属基体（１）の嵌着重合面（ＩＹに介在する
クローム酸化物による各組成物との化学結合した緻密な
セラミックの含浸層（４１、（５）をそれぞれ形成して
なるものである。
本発明は上記のごとく、浸透ｍ　（：（）、　（：（）
’、（３）“・・・を有して嵌着重合した状態をもって
、単に前記液への浸漬とその後の倣温度での加熱処理と
によって簡易にセラミック素材（２）側の重合面（２ト
側と外表面（２）側との之等面附近にセラミックの含浸
１ｎ（４）　、　（５）を形成することとなシ、特にＣ
ｒ２Ｏ３と且つ浸透溝（３）。
（ζ（＋’　、　（３）″・・・との相乗効果によシ嵌
着重合部での金属基体（１１表面とのなす結合力を著し
く増大する結果となるため、面温度条件下での２等嵌着
重合部での緩みの憂いがなく、又浸漬に伴う緻密性の優
つた含浸層（４）　、　（５１を形成する結果となり、
同時にセラミック素材（２）側の重合面（２ト側と外表
面（２）”（１１！ｌとの之等面附近に沿って設けた内
部を多孔質の状態のま＼をもってなす含浸効果によって
断熱性の劣化を殆んどみることなく構成し得る効果を有
するものである。
なお、浸透溝ｒ３１　、　Ｉ：（Ｙ、（３）″・・・と
しては螺旋状或いは傾斜、網状等その他種々の形状をも
って設けても。
本発明の要旨を異にするものでないことは勿論のことで
ある。
【図面の簡単な説明】
第１図は本発明の一実施例を示すもので、金桟基体表面
とセラミック素材との嵌着重合構造をピストンライナー
に適応したピストンライナーの平面図、第２図は第１図
Ｉ−Ｉ線の断面図、第３図は第１図釦線へ部の拡大図、
第４図は同上他の実施例を示す拡大図、第５図は第２図
鎖線Ｂ部の拡大図、第６図は従来の接合構造の一例を示
す拡大図である。 １′°・°金属基体側の嵌着重合面、２・・・セラミッ
ク素１Ｍ’、　２’・・・セラミック素材側の嵌着重合
面、２′・・・外表面、３　、３’、　３”・・・浸透
溝、４．訃・・重合面側と外表面側とでのセラミックの
含浸層 特許出願人　臼井国際産業株式会社 茅１図 Ａ 亭２図 第３図 埠４［！！！］ 第５図 埠６ＷＩ

Claims (1)

    【特許請求の範囲】
  1. 金属基体の表面に、別体からなるセラミック部材を嵌着
    重合してなる接合構造に？いて、それぞれの嵌着重合面
    （＋）’　、　（２１’の少なくとも一方に設けた略々
    全長に亘る複数の浸透溝（３）　、　（３１’、　（３
    Ｙ’・・・を有して相互に嵌着重合せしめるとともに、
    セラミック素材（２）の重合面（２）′側と外表面（２
    Ｙ′側の各面付近に沿ってＣｒ２Ｏ！！単体もしくは５
    ｉＯｐ＋　Ｃｒ１２０３及びＡｔ２ｏｆ１からなる組成
    を有した加熱焼成に伴って化学結合された緻密なセラミ
    ックの含浸層（４）　、　（５）を形成することを特徴
    とする金属基体表面とセラミック部材との接合構造。
JP57185882A 1982-10-22 1982-10-22 金属基体表面とセラミツク素材との接合構造 Granted JPS5978980A (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP57185882A JPS5978980A (ja) 1982-10-22 1982-10-22 金属基体表面とセラミツク素材との接合構造
GB08326147A GB2128919B (en) 1982-10-22 1983-09-29 Joining ceramic to metal
FR8315972A FR2534902B1 (fr) 1982-10-22 1983-10-07 Assemblage de metal et de ceramique
DE3337364A DE3337364C2 (de) 1982-10-22 1983-10-14 Verfahren zur Herstellung eines Verbundbauteils aus Metall und Keramik
US06/542,105 US4523554A (en) 1982-10-22 1983-10-14 Metal and ceramic assembly

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57185882A JPS5978980A (ja) 1982-10-22 1982-10-22 金属基体表面とセラミツク素材との接合構造

Publications (2)

Publication Number Publication Date
JPS5978980A true JPS5978980A (ja) 1984-05-08
JPS6111907B2 JPS6111907B2 (ja) 1986-04-05

Family

ID=16178524

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57185882A Granted JPS5978980A (ja) 1982-10-22 1982-10-22 金属基体表面とセラミツク素材との接合構造

Country Status (5)

Country Link
US (1) US4523554A (ja)
JP (1) JPS5978980A (ja)
DE (1) DE3337364C2 (ja)
FR (1) FR2534902B1 (ja)
GB (1) GB2128919B (ja)

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GB2128919A (en) 1984-05-10
FR2534902B1 (fr) 1987-01-16
JPS6111907B2 (ja) 1986-04-05
DE3337364C2 (de) 1987-02-05
GB2128919B (en) 1986-02-12
US4523554A (en) 1985-06-18
GB8326147D0 (en) 1983-11-02
FR2534902A1 (fr) 1984-04-27
DE3337364A1 (de) 1984-04-26

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