JPS596253A - 耐熱・耐衝撃性樹脂組成物 - Google Patents
耐熱・耐衝撃性樹脂組成物Info
- Publication number
- JPS596253A JPS596253A JP11520882A JP11520882A JPS596253A JP S596253 A JPS596253 A JP S596253A JP 11520882 A JP11520882 A JP 11520882A JP 11520882 A JP11520882 A JP 11520882A JP S596253 A JPS596253 A JP S596253A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- rubber
- resin
- weight
- polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims description 13
- 229920005989 resin Polymers 0.000 claims abstract description 45
- 239000011347 resin Substances 0.000 claims abstract description 45
- 229920001971 elastomer Polymers 0.000 claims abstract description 44
- 239000000203 mixture Substances 0.000 claims abstract description 20
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 20
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 20
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims abstract 4
- 239000005060 rubber Substances 0.000 claims description 40
- -1 aromatic vinyl compound Chemical class 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 150000008064 anhydrides Chemical class 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 4
- 150000001993 dienes Chemical class 0.000 claims description 3
- 230000002787 reinforcement Effects 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 39
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000005062 Polybutadiene Substances 0.000 abstract description 2
- 229920002857 polybutadiene Polymers 0.000 abstract description 2
- 229920001897 terpolymer Polymers 0.000 abstract description 2
- 150000002825 nitriles Chemical class 0.000 abstract 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 230000000704 physical effect Effects 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 150000001991 dicarboxylic acids Chemical class 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000000465 moulding Methods 0.000 description 8
- 239000002131 composite material Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000012662 bulk polymerization Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000012760 heat stabilizer Substances 0.000 description 5
- 238000004898 kneading Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- 125000004018 acid anhydride group Chemical group 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- MQCPOLNSJCWPGT-UHFFFAOYSA-N 2,2'-Bisphenol F Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1O MQCPOLNSJCWPGT-UHFFFAOYSA-N 0.000 description 1
- OMNYXCUDBQKCMU-UHFFFAOYSA-N 2,4-dichloro-1-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C(Cl)=C1 OMNYXCUDBQKCMU-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 229920006310 Asahi-Kasei Polymers 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241000282375 Herpestidae Species 0.000 description 1
- 101000699781 Homo sapiens Retrotransposon Gag-like protein 4 Proteins 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 102100029131 Retrotransposon Gag-like protein 4 Human genes 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- VUKHQPGJNTXTPY-UHFFFAOYSA-N but-2-enylbenzene Chemical compound CC=CCC1=CC=CC=C1 VUKHQPGJNTXTPY-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical class OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000002464 physical blending Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11520882A JPS596253A (ja) | 1982-07-02 | 1982-07-02 | 耐熱・耐衝撃性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11520882A JPS596253A (ja) | 1982-07-02 | 1982-07-02 | 耐熱・耐衝撃性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS596253A true JPS596253A (ja) | 1984-01-13 |
| JPS6212944B2 JPS6212944B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-03-23 |
Family
ID=14657032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11520882A Granted JPS596253A (ja) | 1982-07-02 | 1982-07-02 | 耐熱・耐衝撃性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS596253A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60199055A (ja) * | 1984-03-23 | 1985-10-08 | Daicel Chem Ind Ltd | ポリカ−ボネ−ト系樹脂組成物 |
| EP0933396A3 (en) * | 1998-01-28 | 1999-12-15 | General Electric Company | Flame retardant polycarbonate resin/abs graft copolymer blends |
| US8573007B2 (en) | 2009-08-17 | 2013-11-05 | Asahi Glass Company, Limited | Process for producing molten glass, glass-melting furnace, process for producing glass products and apparatus for producing glass products |
-
1982
- 1982-07-02 JP JP11520882A patent/JPS596253A/ja active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60199055A (ja) * | 1984-03-23 | 1985-10-08 | Daicel Chem Ind Ltd | ポリカ−ボネ−ト系樹脂組成物 |
| EP0933396A3 (en) * | 1998-01-28 | 1999-12-15 | General Electric Company | Flame retardant polycarbonate resin/abs graft copolymer blends |
| US8573007B2 (en) | 2009-08-17 | 2013-11-05 | Asahi Glass Company, Limited | Process for producing molten glass, glass-melting furnace, process for producing glass products and apparatus for producing glass products |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6212944B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1987-03-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3966842A (en) | Thermoplastic molding compositions of rubber-reinforced styrene/maleic anhydride resins and polycarbonate resins | |
| WO1999006457A1 (fr) | Particules de copolymeres greffes et compositions de resines thermoplastiques | |
| JPS636110B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| US3641212A (en) | High impact strength styrene-maleic anhydride compositions | |
| EP3827035B1 (en) | Polyacrylate graft rubber copolymer and impact modified thermoplastic molding composition | |
| JPS596253A (ja) | 耐熱・耐衝撃性樹脂組成物 | |
| JPH0320348A (ja) | 高度の耐老化性を有する重合体混合物 | |
| JPH02185554A (ja) | ポリマーアロイ | |
| JPH02115206A (ja) | 透明熱可塑性成形用組成物の製造に適したグラフト重合体 | |
| CN100572410C (zh) | 一种用于pvc软质片材的abs树脂的制备方法 | |
| WO2021014736A1 (ja) | ポリジメチルシロキサンガム混合物、および、それを添加したポリジメチルシロキサンガム含有熱可塑性樹脂組成物 | |
| JP3662617B2 (ja) | 熱可塑性樹脂組成物 | |
| US4518742A (en) | Thermoplastic resin composition having toughness and high heat distortion resistance | |
| JPS60120734A (ja) | 透明な耐熱耐衝撃性樹脂組成物 | |
| US3607978A (en) | Nitrile polymeric blends | |
| JPS63162750A (ja) | 熱可塑性樹脂組成物 | |
| JPS62240352A (ja) | 芳香族ポリカ−ボネ−ト樹脂組成物 | |
| JPS6328087B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPS6324608B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPS6056742B2 (ja) | 樹脂組成物 | |
| JPS5946532B2 (ja) | 難燃性の樹脂組成物 | |
| JP3107607B2 (ja) | 熱可塑性樹脂組成物 | |
| JPS6239650A (ja) | 難燃性樹脂組成物 | |
| JPS6129982B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | ||
| JPH10168131A (ja) | 熱安定性の良好な共重合体の製造方法 |