JPS59155930A - Forming method of minute pattern - Google Patents

Forming method of minute pattern

Info

Publication number
JPS59155930A
JPS59155930A JP58031213A JP3121383A JPS59155930A JP S59155930 A JPS59155930 A JP S59155930A JP 58031213 A JP58031213 A JP 58031213A JP 3121383 A JP3121383 A JP 3121383A JP S59155930 A JPS59155930 A JP S59155930A
Authority
JP
Japan
Prior art keywords
layer
layers
photosensitive film
lift
semiconductor substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP58031213A
Other languages
Japanese (ja)
Inventor
Wataru Wakamiya
若宮 亙
Hideaki Itakura
秀明 板倉
Kenji Takayama
健司 高山
Kyusaku Nishioka
西岡 久作
Masahiro Hatanaka
畑中 正宏
Masayuki Nakajima
真之 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP58031213A priority Critical patent/JPS59155930A/en
Publication of JPS59155930A publication Critical patent/JPS59155930A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/09Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
    • G03F7/095Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers having more than one photosensitive layer

Abstract

PURPOSE:To obtain a reversely inclined layer of a minute pattern fitted to a lift-off through one-time ultraviolet beam irradiation without generating an excessive boundary layer by laminating and forming a photosensitive film as a first layer and a photosensitive film as a second layer, a kind thereof is the same as the film but a gamma value and sensitivity thereof differ, on a semiconductor substrate and beam-transferring and developing the surface. CONSTITUTION:A first positive type resist layer 12 photosensitized to far ultraviolet beams is applied on a semiconductor substrate 11 as a photosensitive film as a first layer, and a second positive type resist layer 13, a kind thereof is the same as the layer 12 but a gamma value and sensitivity thereof are lower, is laminated and applied onto the layer 12. A solvent contained in these layers is evaporated at a proper temperature, ultraviolet beams 15 are irradiated through mask patterns 14, and resists in exposed sections are removed through development. Accordingly, development advances up to the layer 12 from the layer 13 while intruding to the inside of the layer 12, and reversely inclined layers effective for a lift-off are obtained, thus preventing the generation of an excessive boundary layer between the layers 12 and 13.

Description

【発明の詳細な説明】 〔発明の技術分野〕 この発明は半導体装置の製造工程における微細パターン
の形成方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Technical Field of the Invention] The present invention relates to a method for forming fine patterns in the manufacturing process of semiconductor devices.

〔従来技術〕[Prior art]

従来のこの種の微細パターン形成方法の一例を第1図な
いし第3図に示す。すなわち、まず第1図に示すように
、半導体基板(1)上に商品名PMMKなどの遠紫外光
に感光する第1のレジスト層(2)を塗布し、適当な温
度でその溶媒を蒸発させたのち、続いてその上に商品名
AZ1350Jなどの紫外光に感光する第2のレジスト
層(3)を塗布し、同様に適当な温度でその溶媒を蒸発
させ、かつこれにマスクパターン(4)を介して紫外光
(5)を照射し、現像して露光部のレジストを除去する
。こ\で各レジスト層(2) 、 (3)に前記のよう
にP MMK オ!びAZ1350Jを使用した場合、
これら両層の境界部には不溶解層(6)が形成されるの
で、第2図に示すように、この不溶解層(6)の露出部
をO,プラズマ(7)などによシ除去した上で、こ\に
遠紫外光(8)を照射し、現像することによって、第3
図に示すように、第1のレジスト層(2)が残された第
2のレジスト層(3)の下部にまで喰い込んで現像され
、リフトオフに適当な逆傾斜層を得られるのである。
An example of a conventional method for forming fine patterns of this kind is shown in FIGS. 1 to 3. That is, as shown in Fig. 1, first, a first resist layer (2) sensitive to far ultraviolet light such as PMMK (trade name) is coated on a semiconductor substrate (1), and the solvent is evaporated at an appropriate temperature. Thereafter, a second resist layer (3) sensitive to ultraviolet light such as product name AZ1350J is applied thereon, the solvent is similarly evaporated at an appropriate temperature, and a mask pattern (4) is applied thereto. UV light (5) is irradiated through the resist film, and the resist in the exposed area is removed by development. Now apply PMMK to each resist layer (2) and (3) as described above. When using AZ1350J,
An insoluble layer (6) is formed at the boundary between these two layers, so as shown in Figure 2, the exposed part of this insoluble layer (6) is removed using O, plasma (7), etc. Then, by irradiating this with far ultraviolet light (8) and developing it, the third
As shown in the figure, the first resist layer (2) digs into the lower part of the remaining second resist layer (3) and is developed, resulting in a reversely sloped layer suitable for lift-off.

しかし乍らこの従来方法においては、2度に亘って紫外
光、遠紫外光を照射する必要があるほか第1および第2
のレジストの組み合わせによっては、不溶解層が形成さ
れることになって、この不溶解層を除去するために別の
工程を追加しなければならないなどの不都合があった。
However, in this conventional method, it is necessary to irradiate ultraviolet light and far ultraviolet light twice, and also to irradiate the first and second
Depending on the combination of resists, an indissolved layer may be formed, resulting in the inconvenience that another process must be added to remove this insoluble layer.

〔発明の概要〕[Summary of the invention]

この発明は従来のこのような欠点に鑑み、第1および第
2のレジスト層として、特性の異なる同種のレジストを
重ねて塗布することによシ、余分な境界層を形成させず
に、しかも1度の紫外光照射によって、リフトオフに有
効な逆傾斜層を得られるようにしたものである。
In view of the above-mentioned drawbacks of the conventional resists, the present invention has been developed by overlapping the same type of resists with different characteristics as the first and second resist layers, thereby eliminating the formation of an extra boundary layer and making it possible to It is possible to obtain a reversely sloped layer that is effective for lift-off by irradiating UV light at a high temperature.

〔発明の実施例〕[Embodiments of the invention]

以下、この発明方法の一実施゛例につき、第4図および
第5図を参照して詳細に説明する。
Hereinafter, one embodiment of the method of this invention will be described in detail with reference to FIGS. 4 and 5.

第4図のように、まず半導体基板(11)上に第1層の
感光性被膜として、AZ系などのポジ形の第1のレジス
ト層翰を塗布し、適当な温度でその溶媒を蒸発させたの
ち、続いてその上に第2層の感光性被膜として、前記第
1のレジスト層σ2と同種ではあるが、これよシもγ値
が低くて低感度、すなわち特性の異なるポジ形の第2の
レジスト層α騰を塗布し、同様に適当な温度でその溶媒
を蒸発させ、かつこれにマスクパターン(14)を介し
て紫外光(15+を照射し、現像して露光部のレジスト
を除去する。
As shown in Fig. 4, first, a first positive resist layer such as AZ type is applied as the first photosensitive film on the semiconductor substrate (11), and the solvent is evaporated at an appropriate temperature. After that, a second layer of photosensitive coating is applied thereon, which is of the same type as the first resist layer σ2, but also has a lower γ value and lower sensitivity, that is, a positive resist layer with different characteristics. 2. Apply a resist layer α, evaporate the solvent at an appropriate temperature, irradiate it with ultraviolet light (15+) through a mask pattern (14), develop it, and remove the resist in the exposed area. do.

この操作によシ第1のレジスト層(1つは第2のレジス
ト層α謙よセもそのγ値ならびに感度が高いだめに、現
像は第2のレジスト層←りから第1のレジスト層(12
にまで、しかもその内側に喰い込んで進み、第5図のよ
うにリフトオフに有効な逆傾斜層が得られるのでアシ、
このときこれらの第1および第2のレジスト層(J2)
 、 (13間には、両層が同種であるために余分な境
界層が形成されることはない。
Due to this operation, the first resist layer (one is the second resist layer), and since its γ value and sensitivity are high, development is performed from the second resist layer ← to the first resist layer ( 12
As it penetrates into the inside of the layer, as shown in Figure 5, a reverse slope layer that is effective for lift-off is obtained.
At this time, these first and second resist layers (J2)
, (13, since both layers are of the same type, no extra boundary layer is formed.

なお前記実施例では、感光性被膜としてAZ系のポジ形
レジストについて述べたが、他のレジストの場合にあっ
ても同様の作用効果が得られることは勿論である。
In the above embodiments, an AZ-based positive resist was used as the photosensitive film, but it goes without saying that similar effects can be obtained with other resists.

〔発明の効果〕〔Effect of the invention〕

以上詳述したようにこの発明方法によれば、第1層およ
び第2層に特性の異なる同種の感光性被膜を用いたので
、両層間に不必要な境界層が形成されず、しかも1度の
露光、現像によってリフトオフに適した逆傾斜層を得る
ことができ、従って微細パターン形成のだめの工程数の
減少が可能となり、ひいてはパターン精度を向上し得る
などの特長がある。
As detailed above, according to the method of the present invention, since the same type of photosensitive coatings with different characteristics are used for the first layer and the second layer, an unnecessary boundary layer is not formed between the two layers, and moreover, By exposure and development, a reversely sloped layer suitable for lift-off can be obtained, and therefore, the number of steps required for forming fine patterns can be reduced, and pattern accuracy can be improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図ないし第3図は従来例による微細ノくターンの形
成方法を工程順に示すそれぞれ断面図、第4図および第
5図はこの発明の一実施例による微細パターンの形成方
法を工程順に示すそれぞれ断面図である。 αυ・・・・半導体基板、(12・・・ど第1のレジス
ト層(第1層感光性被膜) 、(13・・・・第2のレ
ジスト層(第2層感光性被膜)、Q→・・・どマスクパ
ターン、叫・・・・紫外光。 代 理 人    葛  野  信  −口乙Z  η
=2  区、14
1 to 3 are cross-sectional views showing a conventional method for forming a fine pattern in order of process, and FIGS. 4 and 5 show a method for forming a fine pattern according to an embodiment of the present invention in order of process. Each is a sectional view. αυ... Semiconductor substrate, (12... First resist layer (first layer photosensitive coating), (13... Second resist layer (second layer photosensitive coating), Q→ ...Mask pattern, shouting...ultraviolet light. Agent Shin Kuzuno - KuchiotsuZ η
=2 Ward, 14

Claims (1)

【特許請求の範囲】[Claims] 半導体基板上に第1層の感光性被膜を形成したのち、そ
の上にこの第1層の感光性被膜と同種で、かつγ値、感
度などの特性の異なる第2層の感光性被膜を形成させ、
ついでこれにパターンを光転写、現像することを特徴と
する微細パターンの形成方法。
After forming a first layer of photosensitive coating on a semiconductor substrate, a second layer of photosensitive coating is formed thereon, which is the same type as the first layer of photosensitive coating but has different characteristics such as γ value and sensitivity. let me,
A method for forming a fine pattern, which is characterized in that the pattern is then phototransferred and developed.
JP58031213A 1983-02-25 1983-02-25 Forming method of minute pattern Pending JPS59155930A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58031213A JPS59155930A (en) 1983-02-25 1983-02-25 Forming method of minute pattern

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58031213A JPS59155930A (en) 1983-02-25 1983-02-25 Forming method of minute pattern

Publications (1)

Publication Number Publication Date
JPS59155930A true JPS59155930A (en) 1984-09-05

Family

ID=12325149

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58031213A Pending JPS59155930A (en) 1983-02-25 1983-02-25 Forming method of minute pattern

Country Status (1)

Country Link
JP (1) JPS59155930A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4738910A (en) * 1985-06-12 1988-04-19 Hitachi, Ltd. Method of applying a resist
WO2005124459A1 (en) * 2004-06-22 2005-12-29 Nagase Chemtex Corporation Organic film composition and method for forming resist pattern
CN105938302A (en) * 2016-07-05 2016-09-14 深圳市华星光电技术有限公司 Method for improving lift-off efficiency of peripheral region of liquid crystal display panel

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4738910A (en) * 1985-06-12 1988-04-19 Hitachi, Ltd. Method of applying a resist
WO2005124459A1 (en) * 2004-06-22 2005-12-29 Nagase Chemtex Corporation Organic film composition and method for forming resist pattern
CN105938302A (en) * 2016-07-05 2016-09-14 深圳市华星光电技术有限公司 Method for improving lift-off efficiency of peripheral region of liquid crystal display panel

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