JPS5914407B2 - ゼオライトｚｓｍ−３４及びそれを使用した転化法 - Google Patents

ゼオライトｚｓｍ−３４及びそれを使用した転化法

Info

Publication number
JPS5914407B2
JPS5914407B2 JP52131637A JP13163777A JPS5914407B2 JP S5914407 B2 JPS5914407 B2 JP S5914407B2 JP 52131637 A JP52131637 A JP 52131637A JP 13163777 A JP13163777 A JP 13163777A JP S5914407 B2 JPS5914407 B2 JP S5914407B2
Authority
JP
Japan
Prior art keywords
zeolite
sio
catalyst
zsm
molar ratio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP52131637A
Other languages
English (en)
Japanese (ja)
Other versions
JPS5358499A (en
Inventor
エドウイン・ニ−ル・ギベンス
エドワ−ド・ジヨセフ・ロジンスキ−
チヤ−ルズ・ジヨセフ・プランク
メイ・コウニング・ルビン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/738,773 external-priority patent/US4079096A/en
Priority claimed from US05/738,771 external-priority patent/US4086186A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of JPS5358499A publication Critical patent/JPS5358499A/ja
Publication of JPS5914407B2 publication Critical patent/JPS5914407B2/ja
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/30—Erionite or offretite type, e.g. zeolite T
    • C01B39/305—Erionite or offretite type, e.g. zeolite T using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the eroionite or offretite type, e.g. zeolite T

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP52131637A 1976-11-04 1977-11-04 ゼオライトｚｓｍ−３４及びそれを使用した転化法 Expired JPS5914407B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US05/738,773 US4079096A (en) 1976-11-04 1976-11-04 Manufacture of light olefins
US0000SN738771 1976-11-04
US0000SN738773 1976-11-04
US05/738,771 US4086186A (en) 1976-11-04 1976-11-04 Crystalline zeolite ZSM-34 and method of preparing the same

Publications (2)

Publication Number Publication Date
JPS5358499A JPS5358499A (en) 1978-05-26
JPS5914407B2 true JPS5914407B2 (ja) 1984-04-04

Family

ID=27113414

Family Applications (1)

Application Number Title Priority Date Filing Date
JP52131637A Expired JPS5914407B2 (ja) 1976-11-04 1977-11-04 ゼオライトｚｓｍ−３４及びそれを使用した転化法

Country Status (8)

Country Link
JP (1) JPS5914407B2 (OSRAM)
AU (1) AU510040B2 (OSRAM)
DE (1) DE2749024C2 (OSRAM)
FR (1) FR2369997A1 (OSRAM)
GB (1) GB1589856A (OSRAM)
IT (1) IT1087929B (OSRAM)
NL (1) NL181921C (OSRAM)
NZ (1) NZ185397A (OSRAM)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2440914A1 (fr) * 1978-11-10 1980-06-06 Mobil Oil Corp Composition de zeolite cristalline
US4247416A (en) * 1979-02-28 1981-01-27 Mobil Oil Corporation Crystalline zeolite ZSM-25
NL7902021A (nl) * 1979-03-14 1980-09-16 Shell Int Research Werkwijze voor de bereiding van methaan en/of ethaan.
JPS577817A (en) * 1980-06-13 1982-01-16 Idemitsu Kosan Co Ltd Manufacture of crystalline zeolite
DE3134317A1 (de) * 1981-08-31 1983-03-10 Hoechst Ag, 6000 Frankfurt Boro-alumosilikate mit zeolithstruktur und verfahren zu deren herstellung
DE3136684A1 (de) * 1981-09-16 1983-04-21 Hoechst Ag, 6230 Frankfurt "gallium- und/oder indiumhaltige zeolithe und verfahren zu deren herstellung sowie ihre verwendung"
ZA828519B (en) * 1981-12-30 1984-06-27 Mobil Oil Corp Catalysts for light olefin production
DE3217322A1 (de) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt Kristalline aluminosilicat-zeolithe, verfahren zu ihrer herstellung sowie ihre verwendung
DE3217323A1 (de) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt Zirkon- und/oder hafniumhaltige zeolithe und verfahren zu ihrer herstellung sowie ihre verwendung
DE3217324A1 (de) * 1982-05-08 1983-11-10 Hoechst Ag, 6230 Frankfurt Titanhaltige zeolithe und verfahren zu ihrer herstellung sowie ihre verwendung
DK163296C (da) * 1982-10-08 1992-07-06 Tosoh Corp Fremgangsmaade til fremstilling af zeoliter
DE3240870A1 (de) * 1982-11-05 1984-05-10 Hoechst Ag, 6230 Frankfurt Titan-, zirkon- und/oder hafniumhaltige zeolithe und verfahren zu ihrer herstellung sowie ihre verwendung
US4496786A (en) * 1983-09-30 1985-01-29 Chevron Research Company Selective conversion of methanol to low molecular weight olefins over high silica SSZ-13 zeolite
FR2565575B1 (fr) * 1984-06-07 1988-08-26 Inst Francais Du Petrole Zeolite de la famille de l'offretite et procede de fabrication
US4705907A (en) * 1985-05-29 1987-11-10 Showa Shell Sekiyu Kabushiki Kaisha Production of liquid hydrocarbon from gas containing lower hydrocarbon
JP5118482B2 (ja) * 2004-04-20 2013-01-16 ユーオーピー エルエルシー Ｕｚｍ−１６：結晶性アルミノシリケートゼオライト質材料
JP5902682B2 (ja) * 2010-07-15 2016-04-13 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ＮＯｘの選択的還元用の銅含有ＺＳＭ−３４、ＯＦＦ及び／又はＥＲＩゼオライト系材料

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL238953A (OSRAM) * 1958-05-08
US3578398A (en) * 1968-04-01 1971-05-11 Mobil Oil Corp Synthetic crystalline zeolite and preparation thereof
US3699139A (en) * 1969-10-16 1972-10-17 Mobil Oil Corp Synthetic crystalline aluminosilicate
NL168194C (nl) * 1970-02-25 1982-03-16 Shell Int Research Werkwijze voor de bereiding van aluminosilicaatzeolieten.
GB1299016A (en) * 1970-06-12 1972-12-06 Bp Chem Int Ltd Hydrocarbon separation process
US3758539A (en) * 1971-03-09 1973-09-11 Air Prod & Chem Offretite synthesis from minerals
BE789628A (fr) * 1971-10-04 1973-04-03 Ici Ltd Zeolites
FR2228721A1 (en) * 1973-05-07 1974-12-06 Mobil Oil ZSM-21 synthetic crystalline aluminosilicate zeolites - for use as hydrocarbon conversion catalysts
US3947482A (en) * 1974-03-20 1976-03-30 W. R. Grace & Co. Method for producing open framework zeolites
DE2615065A1 (de) * 1976-04-07 1977-10-27 Mobil Oil Corp Synthetischer kristalliner aluminosilikatzeolith, verfahren zu dessen herstellung und verwendung desselben

Also Published As

Publication number Publication date
DE2749024C2 (de) 1987-03-26
GB1589856A (en) 1981-05-20
AU3030077A (en) 1979-05-10
NL181921C (nl) 1987-12-01
NL7712165A (nl) 1978-05-08
JPS5358499A (en) 1978-05-26
NL181921B (nl) 1987-07-01
FR2369997B1 (OSRAM) 1982-02-05
NZ185397A (en) 1979-12-11
DE2749024A1 (de) 1978-05-24
IT1087929B (it) 1985-06-04
AU510040B2 (en) 1980-06-05
FR2369997A1 (fr) 1978-06-02

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