JPS59139676A - Manufacture of semiconductor integrated circuit - Google Patents

Manufacture of semiconductor integrated circuit

Info

Publication number
JPS59139676A
JPS59139676A JP1298483A JP1298483A JPS59139676A JP S59139676 A JPS59139676 A JP S59139676A JP 1298483 A JP1298483 A JP 1298483A JP 1298483 A JP1298483 A JP 1298483A JP S59139676 A JPS59139676 A JP S59139676A
Authority
JP
Japan
Prior art keywords
layer
oxide film
gate oxide
integrated circuit
semiconductor integrated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1298483A
Other languages
Japanese (ja)
Inventor
Hiroshi Matsui
宏 松井
Tadashi Mori
森 規
Kazuyuki Honda
本多 一行
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oki Electric Industry Co Ltd
Original Assignee
Oki Electric Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oki Electric Industry Co Ltd filed Critical Oki Electric Industry Co Ltd
Priority to JP1298483A priority Critical patent/JPS59139676A/en
Publication of JPS59139676A publication Critical patent/JPS59139676A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate

Abstract

PURPOSE:To enable to form a second layer gate oxide film is which an outward diffusion does not arise by a method wherein, in case a gate oxide film of the second layer is formed, an oxide film is formed at low temperatures as the first step thereof and the prescribed gate oxide film thickness is obtained at high temperatures as the second step thereof. CONSTITUTION:A first layer gate oxide film 4 is formed by patterning using a first layer polycrystalline Si 5 containing high-concentration P as the mask. Then, when a second layer gate oxide film 6 is manufactured, the second layer gate oxide film 6 of 30-150Angstrom is formed, as the first step thereof, at low temperatures of 600-800 deg.C at which the outward diffusion of P does not arise. In the second gate oxidation process of the second step, 500Angstrom is formed at the usual high-temperature oxidation temperatures, 800-1,200 deg.C. A second layer polycrystalline Si 7 is formed and a gate pattern formation is performed using the second layer Si 7 as the etching mask. Since the manufacture of the oxide film 6 is performed at low temperatures at the early stage thereof, a phenomenon of outward diffusion does not arise, even though high-concentration P impurities are contained in the first layer polycrystalline Si 5 and in the back face thereof.

Description

【発明の詳細な説明】 (技術分野) この発明は安定したトランジスタ特性金谷易に得ること
のできる半導体集積回路の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Technical Field) The present invention relates to a method of manufacturing a semiconductor integrated circuit that can easily obtain stable transistor characteristics.

(従来技術) 従来の半導体集積回路の製造方法をFAMO8型集積回
結集積回路法を例にして第1図に示す。まず、第1図(
a)に示すように、P型基板1にLOCO8用S i 
、N、膜2のパターンを形成し、フィールド酸化膜3を
形成する。なお、この第1図(a)における100はメ
モリセル領域200は周辺トランジスタ領域を示す。
(Prior Art) A conventional method for manufacturing a semiconductor integrated circuit is shown in FIG. 1 using the FAMO8 type integrated circuit method as an example. First, Figure 1 (
As shown in a), Si for LOCO8 is placed on the P-type substrate 1.
, N, pattern the film 2, and form the field oxide film 3. Note that 100 in FIG. 1(a) indicates the memory cell area 200 and the peripheral transistor area.

次に、第1図(b)に示すように、5isN4膜2を除
去した後第1層ζ−ト酸化膜4、第1層ポリSi5を全
面形成する。次に、第1層ポリSi5の抵抗を下げるた
めにPを比較的高濃度に拡散させる。
Next, as shown in FIG. 1(b), after removing the 5isN4 film 2, a first layer ζ-oxide film 4 and a first layer poly-Si 5 are formed on the entire surface. Next, P is diffused at a relatively high concentration in order to lower the resistance of the first layer poly-Si5.

次に、第1図(c)に示すように、周辺トランジスタ領
域200の第1層ポリSi5をホトリソ・エツチングに
よシ除去する。
Next, as shown in FIG. 1(c), the first layer poly-Si 5 in the peripheral transistor region 200 is removed by photolithography and etching.

次に、第1図(dJに示すように、900〜1200℃
の酸素雰囲気でケ゛−ト眩化暎6を形成し、続いて第2
層ポリSi7を形成する。
Next, as shown in Figure 1 (dJ),
A cathode 6 is formed in an oxygen atmosphere, followed by a second one.
A layer polySi7 is formed.

次に、第1図(e)に示すように、ホトリソ・エツチン
グによシ、メモリセル領域100と周辺トランジスタ領
域200にケ°−ドパターンを形成する。
Next, as shown in FIG. 1(e), a cade pattern is formed in the memory cell region 100 and the peripheral transistor region 200 by photolithography and etching.

しかる後、第1図(f)に示すように、ソース・ドレイ
ン拡散領域8を形成し、中間絶縁膜としてPSG膜9ヘ
コンタクト領域10をあけ、さらにA/配装llを形成
する。
Thereafter, as shown in FIG. 1(f), a source/drain diffusion region 8 is formed, a contact region 10 is opened to the PSG film 9 as an intermediate insulating film, and an A/wiring 11 is further formed.

しかし、上述の従来の半導体集積回路の製造方法には以
下のような欠点が廟った。すなわち、第1図(d)の工
程においてケ°−ト酸化膜6を形成する際、第1層ポリ
Si5の中に含まれる不純物であるPが外方拡散を起こ
し、周辺トランジスタ領域200に拡散されるため、周
辺トランジスタのしきい値電圧が不安定となる欠点が有
った。
However, the conventional semiconductor integrated circuit manufacturing method described above has the following drawbacks. That is, when forming the keto oxide film 6 in the step shown in FIG. Therefore, there was a drawback that the threshold voltage of the peripheral transistors became unstable.

上記外方拡散を防ぐ手段として、第1層ポリSi5の中
のP鑓度を下ける方法が有効であるが、これは新たに以
下のような欠点が生ずる。
As a means to prevent the above-mentioned outward diffusion, it is effective to lower the P content in the first poly-Si layer 5, but this new drawback arises as follows.

(1)第1層ポリSi5の抵抗が高くなる。(1) The resistance of the first layer poly-Si5 increases.

(2) 第1層才li5と第1層ポリSi5間に介在す
る酸化膜のリーク1流が多くなるので、70−チイング
ケ゛−ト型EPROMの電荷保持特性が劣化する。
(2) Since the amount of leakage from the oxide film interposed between the first layer Si5 and the first layer polySi5 increases, the charge retention characteristics of the 70-channel gate type EPROM deteriorate.

(発明の目的9 この発明は、上記従来の欠点を除去するためにな式れた
もので、第1層才すSiに篩磯度不純物を含んでいても
、外方拡散が起こらない第2ケ゛−ト酸化を形成するこ
とができ、第2層ポリSi構造の1vt OS型集積回
路の製造方法に通用できる半導体集積回路の製造方法を
提供することを目的とする。
(Objective of the Invention 9) The present invention was developed to eliminate the above-mentioned drawbacks of the conventional technology. It is an object of the present invention to provide a method for manufacturing a semiconductor integrated circuit that can form a gate oxide and is applicable to a method for manufacturing a 1vt OS type integrated circuit having a second layer poly-Si structure.

(発明の構成) この発明の半導体集積回路の製造方法は、2層ボIJS
i構造を有する半導体集積回路の製造方法において、第
2層目のケ゛−ト酸化膜を形成する場合に第Iステップ
として600〜800℃で30〜150Aの酸化膜を形
成し、第2ステツプとして800〜1200℃で乃1定
のゲート酸化膜厚を得るようにしたものである。
(Structure of the Invention) The method for manufacturing a semiconductor integrated circuit of the present invention includes a two-layered IJS
In a method for manufacturing a semiconductor integrated circuit having an i-structure, when forming a second layer of a gate oxide film, an oxide film of 30 to 150 A is formed at 600 to 800°C as an I step, and as a second step. A constant gate oxide film thickness is obtained at 800 to 1200°C.

(実施例) 以下、この発明の半導体集イltM路の製造方法の実釉
例について、第1図(aJ〜躬11刊(f)を後月4し
て説明する。この発明の場合、第11図(a)でボした
工程の佐、第1図(1)Jで示した半導体を形成する。
(Example) Hereinafter, an actual glaze example of the method for manufacturing a semiconductor assembly of the present invention will be explained with reference to FIGS. After the step omitted in FIG. 11(a), the semiconductor shown in FIG. 1(1)J is formed.

次に、f、:J濃度のPをボッ7×1020G−3含ん
だ41層ポリSi5 (4300A )をマスクにして
第1層ケ゛−ト改化g4(8ooλ)をパターン形j’
mする。
Next, using a 41-layer poly-Si5 (4300A) containing 7 x 1020G-3 holes of P with a density of f,:J as a mask, the first layer gate modified g4 (8ooλ) is formed into a pattern j'
m.

次に、第1図(d)に下す第2増ケ゛−ト1紋化ノ換6
の製造に際し第1ステツプとして600〜800℃のP
の外方拡散が起こらない低温で30〜150Xの第2 
/*り°−ト敵化BIA6を形成する。
Next, the second expansion case 1 pattern conversion 6 shown in FIG.
P at 600-800℃ as the first step in the production of
30-150X at a low temperature where outward diffusion of
/* Form a remote enemy BIA6.

次に、第2ステツプの第2ケ゛−ト咳化工程を通常の高
温酸化(800〜120OA )で500X形成する。
Next, in the second step, the second case is formed by conventional high temperature oxidation (800 to 120 OA) at 500X.

続いて、第1図(d)に示すように、従来方法と同様に
、第2層ポlJ’si7を3600 A形成し、第2層
ポリSi7をエツチングマスクにしてケ゛−ドパターン
形成を行う(ケ゛−ト長ば3μ) 次に、第1図(fJに示すようにソース・ドレイン拡散
領域8をAsインンラテーション法で仮・a閉さ0.5
μ程度に形成し、中間絶縁膜として、PSG膜9を5o
ooAデボし、このPSG膜9にボンタクト領域10を
あけ、1μ程度のAA配がWllのパターンを形成する
Subsequently, as shown in FIG. 1(d), similarly to the conventional method, a second layer of polyJ'si7 is formed with a thickness of 3600 Å, and a cade pattern is formed using the second layer of polySi7 as an etching mask. (The gate length is 3μ.) Next, as shown in FIG.
The PSG film 9 is formed to have a thickness of approximately
ooA is debossed, a bond area 10 is opened in this PSG film 9, and an AA pattern of about 1 μm forms a Wll pattern.

以上、説明したように、第1の実施例では、裁2層ケ゛
−ト眩化農6の初期を600〜800℃の低温で行うた
め、第1虐ボ1Jsi5内および表面に尚枳度のP不純
物を含んでいても外方拡故現株が起こらない。その効果
として、 (1ン  第1層ポリシリコンの抵抗を低減させること
が可能であるっ (2]  第2層ケ゛−ト酸化領域に非コントロールの
不純物が入らないので、トランジスタ特性が安定し、バ
ラツキが小さくなる。
As explained above, in the first embodiment, since the initial stage of the cutting two-layer case dazzling process 6 is carried out at a low temperature of 600 to 800°C, the inside and surface of the first processing chamber 1Jsi5 are coated with a high degree of glare. Even if it contains P impurities, outward spread does not occur. As a result, (1) it is possible to reduce the resistance of the first layer polysilicon; (2) the transistor characteristics are stabilized because uncontrolled impurities do not enter the second layer gate oxide region; Variations become smaller.

(3)  ボIJSi層1d]膜として電気的膜質の良
好なP濃度6〜8×1020d3が使用できる。
(3) IJSi layer 1d] A film having a P concentration of 6 to 8×10 20 d3 with good electrical film quality can be used.

などの利点がある。There are advantages such as

具体的な効果例として、第2図(100Iffウェーハ
でのしきい値電圧vT分布比較を示すもので、特性aは
従来の製造方法の場合で、付任すはこの発明の製造方法
の場合である)の実験例を説明する。第1の実施例にお
いて、第1層ボ!J Si 54300人中のPの不純
9勿は7 X 102’ crt:3、第2層ケ゛−ト
畝化膜は従来方法の場合1ooo℃で500人、この発
明方法の場合第1スデツプ700℃で50X、第2ステ
ップ1000℃でトータル500A形成した。
As a specific example of the effect, FIG. 2 (shows a comparison of threshold voltage vT distributions on a 100Iff wafer), where characteristic a is for the conventional manufacturing method, and characteristics a are for the manufacturing method of the present invention. ) will be explained below. In the first embodiment, the first layer Bo! J Si 54,300 P impurity 9 of course 7 x 102' crt: 3, the second layer Kate ribbed film is 500 people at 100°C in the case of the conventional method, the first step is 700°C in the case of the inventive method A total of 500A was formed at 50X and 1000°C in the second step.

この第2図の特性aに示すように従来方法ではウェーハ
の周辺側でPの外方拡散によシしきい値電圧■・1・が
低下しているのに比べて、特性すのように、この発明方
法はウェーハ内のvTのバラツキが非常に小さくなるこ
とを確認している。
As shown in characteristic a in Fig. 2, in the conventional method, the threshold voltage 1. , it has been confirmed that the method of this invention greatly reduces the variation in vT within a wafer.

(発明の効果) 以上のように、この発明の半専体集積回路の製造方法に
よれ(#:f%第2層目のケ゛−ト収化膜を形成する際
に、第1ステツプとして、600〜800℃で30〜1
50人の酸化膜を形成した後、第2ステツプとして80
0〜1200℃でハ1定の膜厚余得るようにしたので、
第1)vIホリSiK尚纜度不純物を含んでいても外方
拡散の起こらない第2ケ゛−トハ化を形成することが可
能である。これにともない、第2層ポリS目N造の+v
i OS型集抗回路の製造方法に進用することができる
オリ点を南する。
(Effects of the Invention) As described above, according to the method for manufacturing a semi-dedicated integrated circuit of the present invention (#:f%), as a first step, 30-1 at 600-800℃
After forming an oxide film of 50 people, the second step is to form an oxide film of 80 people.
Since we made it possible to obtain a certain amount of film thickness between 0 and 1200℃,
1) VII Hole SiK It is possible to form a second crystal layer in which no out-diffusion occurs even if it contains high-grade impurities. Along with this, +v of the second layer poly S mesh N structure
We will find the starting point that can be applied to the manufacturing method of iOS type resistor collector circuit.

【図面の簡単な説明】[Brief explanation of drawings]

第1凶(a)ないし第1図(f)はそれぞれ従来および
この発明の半得体集積回路の製造方法の工程説明図、第
2図は従来およびこの発明の半専俸集槓回路の製造方法
で得られた100nウエーハでのしきい値電圧vT分布
比較を示す図である。 1・・・P型基板、2・・・5isN+膜、3・・・フ
ィールド敗化膜、4・・・第1層ケ゛−1ば化膜、5・
・・第1層ポリ5i16・・・第2層ケ゛−ト酸化膜、
7・・・第2JtiポリS1%8・・・ソース・ドレイ
ン拡散領域、9・・・PSGM、10・・コンタクト鎖
酸、11・・・Al配勝。 特許出願人 沖電気工業昧式会社 レー“」
1 (a) to 1 (f) are process explanatory diagrams of the conventional method of manufacturing a semi-integrated integrated circuit and the present invention, respectively, and FIG. 2 is a process explanatory diagram of the conventional method of manufacturing a semi-integrated integrated circuit and the present invention. FIG. 3 is a diagram showing a comparison of threshold voltage vT distributions on 100n wafers obtained in FIG. DESCRIPTION OF SYMBOLS 1... P-type substrate, 2... 5isN+ film, 3... Field decomposition film, 4... First layer case-1 base film, 5...
...First layer poly 5i16...Second layer Kate oxide film,
7... 2nd Jti poly S1% 8... source/drain diffusion region, 9... PSGM, 10... contact chain acid, 11... Al distribution. Patent applicant: Oki Electric Industry Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] 2層多結晶シリコン構造を有するM OS型シリコン半
導体集積回路の製造方法において、第2層目のP−)1
1化膜を形成する場合、第1ステツプとして600〜8
00℃で30〜150久の酸化膜を形成し、さらに第2
ステツプとして800〜1200℃でWr定のy−トy
化膜厚を得る工程を含むことを特徴とする半導体集積回
路の製造方法。
In a method for manufacturing an MOS type silicon semiconductor integrated circuit having a two-layer polycrystalline silicon structure, the second layer P-)1
When forming a monolayer, the first step is 600 to 8
An oxide film is formed for 30 to 150 years at 00°C, and then a second
Y-toy with Wr constant at 800-1200℃ as a step
1. A method for manufacturing a semiconductor integrated circuit, comprising a step of obtaining a film thickness.
JP1298483A 1983-01-31 1983-01-31 Manufacture of semiconductor integrated circuit Pending JPS59139676A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1298483A JPS59139676A (en) 1983-01-31 1983-01-31 Manufacture of semiconductor integrated circuit

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1298483A JPS59139676A (en) 1983-01-31 1983-01-31 Manufacture of semiconductor integrated circuit

Publications (1)

Publication Number Publication Date
JPS59139676A true JPS59139676A (en) 1984-08-10

Family

ID=11820466

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1298483A Pending JPS59139676A (en) 1983-01-31 1983-01-31 Manufacture of semiconductor integrated circuit

Country Status (1)

Country Link
JP (1) JPS59139676A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62219625A (en) * 1986-03-20 1987-09-26 Seiko Instr & Electronics Ltd Manufacture of semiconductor device
WO2001020654A1 (en) * 1999-09-14 2001-03-22 Infineon Technologies North America Corp. Process for improving the thickness uniformity of a thin oxide layer in semiconductor wafer fabrication

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62219625A (en) * 1986-03-20 1987-09-26 Seiko Instr & Electronics Ltd Manufacture of semiconductor device
WO2001020654A1 (en) * 1999-09-14 2001-03-22 Infineon Technologies North America Corp. Process for improving the thickness uniformity of a thin oxide layer in semiconductor wafer fabrication
US6537926B1 (en) 1999-09-14 2003-03-25 Infineon Technologies, Ag Process for improving the thickness uniformity of a thin oxide layer in semiconductor wafer fabrication

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