JPS59137849A - 接触燃焼式の可燃性ガス検知素子の製法 - Google Patents
接触燃焼式の可燃性ガス検知素子の製法Info
- Publication number
- JPS59137849A JPS59137849A JP1056983A JP1056983A JPS59137849A JP S59137849 A JPS59137849 A JP S59137849A JP 1056983 A JP1056983 A JP 1056983A JP 1056983 A JP1056983 A JP 1056983A JP S59137849 A JPS59137849 A JP S59137849A
- Authority
- JP
- Japan
- Prior art keywords
- chloride
- catalyst
- carrier
- methane
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001514 detection method Methods 0.000 title description 10
- 238000004519 manufacturing process Methods 0.000 title description 6
- 238000007084 catalytic combustion reaction Methods 0.000 title 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 24
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 9
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 238000005342 ion exchange Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000011230 binding agent Substances 0.000 claims abstract description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 3
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 21
- 229910000510 noble metal Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- FOSZYDNAURUMOT-UHFFFAOYSA-J azane;platinum(4+);tetrachloride Chemical compound N.N.N.N.[Cl-].[Cl-].[Cl-].[Cl-].[Pt+4] FOSZYDNAURUMOT-UHFFFAOYSA-J 0.000 claims description 3
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 30
- 239000007789 gas Substances 0.000 abstract description 22
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract description 18
- 230000010718 Oxidation Activity Effects 0.000 abstract description 11
- 229910052763 palladium Inorganic materials 0.000 abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 6
- 239000001257 hydrogen Substances 0.000 abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 5
- 229930195734 saturated hydrocarbon Natural products 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000005470 impregnation Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- -1 chlorine ions Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 101100536546 Caenorhabditis elegans tcl-2 gene Chemical class 0.000 description 1
- 241000256011 Sphingidae Species 0.000 description 1
- NOWPEMKUZKNSGG-UHFFFAOYSA-N azane;platinum(2+) Chemical compound N.N.N.N.[Pt+2] NOWPEMKUZKNSGG-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical group [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 description 1
- 229910003445 palladium oxide Inorganic materials 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/14—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature
- G01N27/16—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of an electrically-heated body in dependence upon change of temperature caused by burning or catalytic oxidation of surrounding material to be tested, e.g. of gas
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1056983A JPS59137849A (ja) | 1983-01-27 | 1983-01-27 | 接触燃焼式の可燃性ガス検知素子の製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1056983A JPS59137849A (ja) | 1983-01-27 | 1983-01-27 | 接触燃焼式の可燃性ガス検知素子の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59137849A true JPS59137849A (ja) | 1984-08-08 |
| JPH0361138B2 JPH0361138B2 (enrdf_load_stackoverflow) | 1991-09-18 |
Family
ID=11753869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1056983A Granted JPS59137849A (ja) | 1983-01-27 | 1983-01-27 | 接触燃焼式の可燃性ガス検知素子の製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59137849A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005098405A1 (ja) | 2004-03-30 | 2005-10-20 | Citizen Watch Co., Ltd. | ガスセンサ用ヒータコイル、ガスセンサ用検知素子、接触燃焼式ガスセンサおよび接触燃焼式ガスセンサの製造方法 |
| JP2018040814A (ja) * | 2017-12-13 | 2018-03-15 | 矢崎エナジーシステム株式会社 | ガス検知素子、及び、接触燃焼式ガスセンサ |
-
1983
- 1983-01-27 JP JP1056983A patent/JPS59137849A/ja active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005098405A1 (ja) | 2004-03-30 | 2005-10-20 | Citizen Watch Co., Ltd. | ガスセンサ用ヒータコイル、ガスセンサ用検知素子、接触燃焼式ガスセンサおよび接触燃焼式ガスセンサの製造方法 |
| US7713480B2 (en) | 2004-03-30 | 2010-05-11 | Citizen Holdings Co., Ltd. | Heater coil for gas sensor, detection element for gas sensor, contact combustion type gas sensor, and method for manufacturing contact combustion type gas sensor |
| JP4688794B2 (ja) * | 2004-03-30 | 2011-05-25 | シチズンホールディングス株式会社 | ガスセンサ用ヒータコイル、ガスセンサ用検知素子、接触燃焼式ガスセンサおよび接触燃焼式ガスセンサの製造方法 |
| US8246913B2 (en) | 2004-03-30 | 2012-08-21 | Citizen Holdings Co., Ltd. | Heater coil for gas sensor, detecting element for gas sensor, catalytic combustion gas sensor, and manufacturing method of catalytic combustion gas sensor |
| US8257656B2 (en) | 2004-03-30 | 2012-09-04 | Citizen Holdings Co., Ltd. | Heater coil for gas sensor, detecting element for gas sensor, catalytic combustion gas sensor, and manufacturing method of catalytic combustion gas sensor |
| JP2018040814A (ja) * | 2017-12-13 | 2018-03-15 | 矢崎エナジーシステム株式会社 | ガス検知素子、及び、接触燃焼式ガスセンサ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0361138B2 (enrdf_load_stackoverflow) | 1991-09-18 |
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