JPS59136134A - 一酸化炭素吸着剤の製造法 - Google Patents
一酸化炭素吸着剤の製造法Info
- Publication number
- JPS59136134A JPS59136134A JP58011739A JP1173983A JPS59136134A JP S59136134 A JPS59136134 A JP S59136134A JP 58011739 A JP58011739 A JP 58011739A JP 1173983 A JP1173983 A JP 1173983A JP S59136134 A JPS59136134 A JP S59136134A
- Authority
- JP
- Japan
- Prior art keywords
- copper
- carbon
- carbon monoxide
- minutes
- adsorbent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 73
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 73
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000003463 adsorbent Substances 0.000 title description 66
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000007787 solid Substances 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- 150000001447 alkali salts Chemical class 0.000 claims abstract description 3
- 150000007942 carboxylates Chemical class 0.000 claims abstract 3
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 73
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 23
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 239000010949 copper Substances 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 12
- -1 Halide salts Chemical class 0.000 claims description 6
- 238000002336 sorption--desorption measurement Methods 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
- 238000001179 sorption measurement Methods 0.000 abstract description 27
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 22
- 238000003756 stirring Methods 0.000 abstract description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 17
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 14
- 230000002829 reductive effect Effects 0.000 abstract description 11
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 abstract description 10
- 239000000243 solution Substances 0.000 abstract description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 abstract description 4
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract description 3
- 235000019253 formic acid Nutrition 0.000 abstract description 3
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 abstract description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 238000003795 desorption Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 58
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 56
- 229910052757 nitrogen Inorganic materials 0.000 description 27
- 235000002597 Solanum melongena Nutrition 0.000 description 17
- 239000003153 chemical reaction reagent Substances 0.000 description 13
- 239000005751 Copper oxide Substances 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910000431 copper oxide Inorganic materials 0.000 description 9
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 9
- 239000008213 purified water Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- ODWXUNBKCRECNW-UHFFFAOYSA-M bromocopper(1+) Chemical compound Br[Cu+] ODWXUNBKCRECNW-UHFFFAOYSA-M 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 239000003610 charcoal Substances 0.000 description 4
- 229910000365 copper sulfate Inorganic materials 0.000 description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 101100227721 Rattus norvegicus Frk gene Proteins 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
- 241000257465 Echinoidea Species 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 240000002234 Allium sativum Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- ONBHUPNUUMQQMW-UHFFFAOYSA-K Cl[Cu](Cl)Cl Chemical compound Cl[Cu](Cl)Cl ONBHUPNUUMQQMW-UHFFFAOYSA-K 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229910021591 Copper(I) chloride Inorganic materials 0.000 description 1
- 229910021594 Copper(II) fluoride Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- 235000008597 Diospyros kaki Nutrition 0.000 description 1
- 241000581652 Hagenia abyssinica Species 0.000 description 1
- BIWLTUFDBVSPQH-UHFFFAOYSA-H P(=O)([O-])([O-])[O-].[Ag+2].P(=O)([O-])([O-])[O-].[Ag+2].[Ag+2] Chemical compound P(=O)([O-])([O-])[O-].[Ag+2].P(=O)([O-])([O-])[O-].[Ag+2].[Ag+2] BIWLTUFDBVSPQH-UHFFFAOYSA-H 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- OKTJSMMVPCPJKN-BJUDXGSMSA-N carbon-11 Chemical class [11C] OKTJSMMVPCPJKN-BJUDXGSMSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- FSGSLHGEFPNBBN-UHFFFAOYSA-M copper(1+);formate Chemical compound [Cu+].[O-]C=O FSGSLHGEFPNBBN-UHFFFAOYSA-M 0.000 description 1
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 description 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 description 1
- GWFAVIIMQDUCRA-UHFFFAOYSA-L copper(ii) fluoride Chemical compound [F-].[F-].[Cu+2] GWFAVIIMQDUCRA-UHFFFAOYSA-L 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- HFDWIMBEIXDNQS-UHFFFAOYSA-L copper;diformate Chemical compound [Cu+2].[O-]C=O.[O-]C=O HFDWIMBEIXDNQS-UHFFFAOYSA-L 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000004611 garlic Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58011739A JPS59136134A (ja) | 1983-01-27 | 1983-01-27 | 一酸化炭素吸着剤の製造法 |
| CA000423423A CA1226270A (en) | 1982-03-13 | 1983-03-11 | Carbon monoxide adsorbent/separating agent and method of producing same |
| DE19833308693 DE3308693A1 (de) | 1982-03-13 | 1983-03-11 | Adsorptionsmittel fuer kohlenmonoxid und verfahren zu dessen herstellung |
| GB08306759A GB2117265B (en) | 1982-03-13 | 1983-03-11 | Carbon monoxide adsorbent and method of producing the same |
| US06/475,258 US4587114A (en) | 1982-03-13 | 1983-03-14 | Method for separating carbon dioxide from mixed gas |
| FR8304146A FR2522982B1 (fr) | 1982-03-13 | 1983-03-14 | Matiere a base de carbone et de cuivre pour adsorber et separer l'oxyde de carbone et son procede de production |
| AU19958/83A AU547014B2 (en) | 1982-10-09 | 1983-10-07 | Method of producing a carbon monoxide adsorbent/separating agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58011739A JPS59136134A (ja) | 1983-01-27 | 1983-01-27 | 一酸化炭素吸着剤の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59136134A true JPS59136134A (ja) | 1984-08-04 |
| JPS6253223B2 JPS6253223B2 (enrdf_load_stackoverflow) | 1987-11-09 |
Family
ID=11786394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58011739A Granted JPS59136134A (ja) | 1982-03-13 | 1983-01-27 | 一酸化炭素吸着剤の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59136134A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6168135A (ja) * | 1984-09-11 | 1986-04-08 | Topy Ind Ltd | たばこ煙中の一酸化炭素除去剤 |
| US5922640A (en) * | 1996-02-29 | 1999-07-13 | Mitsubishi Gas Chemical Company, Inc. | Adsorbent for carbon monoxide |
| JP2005289761A (ja) * | 2004-04-02 | 2005-10-20 | Japan Pionics Co Ltd | 塩化銅（ｉ）の製造原料及び製造方法、並びにそれを用いたガスの吸着剤、吸着方法、及び回収方法 |
| JP2010269264A (ja) * | 2009-05-22 | 2010-12-02 | Kansai Coke & Chem Co Ltd | Ｃｏ吸脱着剤の製造方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447885A (en) * | 1977-09-22 | 1979-04-14 | Kureha Chem Ind Co Ltd | Ethylene absorbent and production thereof |
-
1983
- 1983-01-27 JP JP58011739A patent/JPS59136134A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5447885A (en) * | 1977-09-22 | 1979-04-14 | Kureha Chem Ind Co Ltd | Ethylene absorbent and production thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6168135A (ja) * | 1984-09-11 | 1986-04-08 | Topy Ind Ltd | たばこ煙中の一酸化炭素除去剤 |
| US5922640A (en) * | 1996-02-29 | 1999-07-13 | Mitsubishi Gas Chemical Company, Inc. | Adsorbent for carbon monoxide |
| JP2005289761A (ja) * | 2004-04-02 | 2005-10-20 | Japan Pionics Co Ltd | 塩化銅（ｉ）の製造原料及び製造方法、並びにそれを用いたガスの吸着剤、吸着方法、及び回収方法 |
| JP2010269264A (ja) * | 2009-05-22 | 2010-12-02 | Kansai Coke & Chem Co Ltd | Ｃｏ吸脱着剤の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6253223B2 (enrdf_load_stackoverflow) | 1987-11-09 |
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