JPS5827823B2 - オルガノシロキサン重合体含有組成物 - Google Patents
オルガノシロキサン重合体含有組成物Info
- Publication number
- JPS5827823B2 JPS5827823B2 JP55105815A JP10581580A JPS5827823B2 JP S5827823 B2 JPS5827823 B2 JP S5827823B2 JP 55105815 A JP55105815 A JP 55105815A JP 10581580 A JP10581580 A JP 10581580A JP S5827823 B2 JPS5827823 B2 JP S5827823B2
- Authority
- JP
- Japan
- Prior art keywords
- mercapto
- functional
- group
- weight
- siloxane units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 117
- 125000005375 organosiloxane group Chemical group 0.000 title claims description 20
- 229920000642 polymer Polymers 0.000 title description 13
- -1 siloxane units Chemical group 0.000 claims description 84
- 125000003396 thiol group Chemical group [H]S* 0.000 claims description 62
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 27
- 229910052760 oxygen Inorganic materials 0.000 claims description 27
- 239000001301 oxygen Substances 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 24
- 239000000945 filler Substances 0.000 claims description 17
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims 2
- 239000003292 glue Substances 0.000 claims 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 27
- 238000000034 method Methods 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 239000000565 sealant Substances 0.000 description 22
- 229920001971 elastomer Polymers 0.000 description 17
- 239000000806 elastomer Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 13
- 125000004122 cyclic group Chemical group 0.000 description 12
- 238000001723 curing Methods 0.000 description 11
- 239000011541 reaction mixture Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000000499 gel Substances 0.000 description 10
- 239000004205 dimethyl polysiloxane Substances 0.000 description 9
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- 239000012763 reinforcing filler Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 239000006227 byproduct Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 125000005358 mercaptoalkyl group Chemical group 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- ILZSSCVGGYJLOG-UHFFFAOYSA-N cobaltocene Chemical compound [Co+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 ILZSSCVGGYJLOG-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 229920001002 functional polymer Polymers 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 230000036558 skin tension Effects 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 1
- HBFCKUCCFLNUHJ-UHFFFAOYSA-N 3-dimethoxysilylpropane-1-thiol Chemical compound CO[SiH](OC)CCCS HBFCKUCCFLNUHJ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 241000206761 Bacillariophyta Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 244000201986 Cassia tora Species 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- JOBBTVPTPXRUBP-UHFFFAOYSA-N [3-(3-sulfanylpropanoyloxy)-2,2-bis(3-sulfanylpropanoyloxymethyl)propyl] 3-sulfanylpropanoate Chemical compound SCCC(=O)OCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS JOBBTVPTPXRUBP-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 238000006664 bond formation reaction Methods 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000004965 chloroalkyl group Chemical group 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- UCJHMXXKIKBHQP-UHFFFAOYSA-N dichloro-(3-chloropropyl)-methylsilane Chemical compound C[Si](Cl)(Cl)CCCCl UCJHMXXKIKBHQP-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000012765 fibrous filler Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000013008 moisture curing Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000001367 organochlorosilanes Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- NCAIGTHBQTXTLR-UHFFFAOYSA-N phentermine hydrochloride Chemical compound [Cl-].CC(C)([NH3+])CC1=CC=CC=C1 NCAIGTHBQTXTLR-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1018—Macromolecular compounds having one or more carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
- C08G75/14—Polysulfides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Sealing Material Composition (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/063,017 US4239674A (en) | 1979-08-02 | 1979-08-02 | Oxygen-curable mercaptoorganosiloxane compositions catalyzed by cobaltocene compounds and method of forming higher molecular weight products therefrom |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5624424A JPS5624424A (en) | 1981-03-09 |
| JPS5827823B2 true JPS5827823B2 (ja) | 1983-06-11 |
Family
ID=22046363
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55105815A Expired JPS5827823B2 (ja) | 1979-08-02 | 1980-07-31 | オルガノシロキサン重合体含有組成物 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4239674A (cg-RX-API-DMAC10.html) |
| JP (1) | JPS5827823B2 (cg-RX-API-DMAC10.html) |
| AT (1) | AT380261B (cg-RX-API-DMAC10.html) |
| AU (1) | AU532248B2 (cg-RX-API-DMAC10.html) |
| BE (1) | BE884597A (cg-RX-API-DMAC10.html) |
| BR (1) | BR8004856A (cg-RX-API-DMAC10.html) |
| CA (1) | CA1138592A (cg-RX-API-DMAC10.html) |
| CH (2) | CH646987A5 (cg-RX-API-DMAC10.html) |
| DE (1) | DE3028781C2 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2463165A1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB2055113B (cg-RX-API-DMAC10.html) |
| IT (1) | IT1132222B (cg-RX-API-DMAC10.html) |
| NL (1) | NL8004416A (cg-RX-API-DMAC10.html) |
| SE (1) | SE445114B (cg-RX-API-DMAC10.html) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4292422A (en) * | 1979-12-03 | 1981-09-29 | Dow Corning Corporation | Oxygen-curable mercapto-functional organosilicon-organic compound compositions catalyzed by metal carbonyl compounds and method of forming higher molecular weight products therefrom |
| US4526954A (en) * | 1983-12-28 | 1985-07-02 | Union Carbide Corporation | Organosiloxane polymers and compositions containing same curable upon exposure to gaseous oxygen |
| US4572918A (en) * | 1984-10-26 | 1986-02-25 | Dow Corning Corporation | Foamable polyorganosiloxane compositions |
| JPS6244902A (ja) * | 1985-08-21 | 1987-02-26 | 鈴木総業株式会社 | 導電ゲル材 |
| US4830688A (en) * | 1987-11-19 | 1989-05-16 | Minnesota Mining And Manufacturing Company | Moisture resistant splice assembly |
| US4906719A (en) * | 1988-11-28 | 1990-03-06 | Dow Corning Corporation | Silicone sealants having reduced color |
| US5032460A (en) * | 1989-08-14 | 1991-07-16 | Minnesota Mining And Manufacturing Company | Method of making vinyl-silicone copolymers using mercapto functional silicone chain-transfer agents and release coatings made therewith |
| TW216432B (cg-RX-API-DMAC10.html) * | 1992-01-10 | 1993-11-21 | Shinetsu Chem Ind Co | |
| US5994456A (en) * | 1998-04-09 | 1999-11-30 | Dow Corning Corporation | Compositions comprising mercapto-functional organosilicon compounds |
| GB0817578D0 (en) | 2008-09-25 | 2008-11-05 | 3M Innovative Properties Co | Method for treating wheel rims and composition for use therein |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2466963A (en) * | 1945-06-16 | 1949-04-12 | Thiokol Corp | Polysulfide polymer |
| US2868751A (en) * | 1956-01-18 | 1959-01-13 | Union Carbide Corp | Method of curing silicone water repellents with cyclopentadienyl transition element catalysts and aqueous compositions of same |
| US3445419A (en) * | 1966-01-21 | 1969-05-20 | Dow Corning | Room temperature vulcanizable silicones |
| US4066603A (en) * | 1976-03-03 | 1978-01-03 | Dow Corning Corporation | Sulfur containing silicone elastomer and method of preparation |
| US4070328A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Mercaptoorganopolysiloxanes cured to elastomers with peroxides and nitrogen compounds |
| US4070329A (en) * | 1977-01-03 | 1978-01-24 | Dow Corning Corporation | Siloxane elastomer prepared from mercaptoorg anopolysiloxanes |
| US4133939A (en) * | 1977-12-16 | 1979-01-09 | Dow Corning Corporation | Method for applying a silicone release coating and coated article therefrom |
-
1979
- 1979-08-02 US US06/063,017 patent/US4239674A/en not_active Expired - Lifetime
-
1980
- 1980-07-08 CA CA000355675A patent/CA1138592A/en not_active Expired
- 1980-07-23 IT IT23621/80A patent/IT1132222B/it active
- 1980-07-24 AT AT0382780A patent/AT380261B/de not_active IP Right Cessation
- 1980-07-29 DE DE3028781A patent/DE3028781C2/de not_active Expired
- 1980-07-31 AU AU60962/80A patent/AU532248B2/en not_active Ceased
- 1980-07-31 CH CH585480A patent/CH646987A5/de not_active IP Right Cessation
- 1980-07-31 JP JP55105815A patent/JPS5827823B2/ja not_active Expired
- 1980-08-01 FR FR8017066A patent/FR2463165A1/fr active Granted
- 1980-08-01 BR BR8004856A patent/BR8004856A/pt unknown
- 1980-08-01 GB GB8025180A patent/GB2055113B/en not_active Expired
- 1980-08-01 BE BE0/201620A patent/BE884597A/fr not_active IP Right Cessation
- 1980-08-01 NL NL8004416A patent/NL8004416A/nl not_active Application Discontinuation
- 1980-08-01 SE SE8005504A patent/SE445114B/sv not_active IP Right Cessation
-
1983
- 1983-12-07 CH CH655683A patent/CH646444A5/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU6096280A (en) | 1981-02-05 |
| AT380261B (de) | 1986-05-12 |
| BR8004856A (pt) | 1981-02-10 |
| IT8023621A0 (it) | 1980-07-23 |
| CH646444A5 (de) | 1984-11-30 |
| SE8005504L (sv) | 1981-03-20 |
| CH646987A5 (de) | 1984-12-28 |
| BE884597A (fr) | 1981-02-02 |
| DE3028781A1 (de) | 1981-02-05 |
| FR2463165B1 (cg-RX-API-DMAC10.html) | 1983-04-01 |
| ATA382780A (de) | 1985-09-15 |
| US4239674A (en) | 1980-12-16 |
| GB2055113B (en) | 1983-05-18 |
| FR2463165A1 (fr) | 1981-02-20 |
| CA1138592A (en) | 1982-12-28 |
| SE445114B (sv) | 1986-06-02 |
| IT1132222B (it) | 1986-06-25 |
| AU532248B2 (en) | 1983-09-22 |
| NL8004416A (nl) | 1981-02-04 |
| DE3028781C2 (de) | 1985-08-14 |
| GB2055113A (en) | 1981-02-25 |
| JPS5624424A (en) | 1981-03-09 |
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