JPS58157061A - Layer-built fuel cell - Google Patents

Layer-built fuel cell

Info

Publication number
JPS58157061A
JPS58157061A JP57039908A JP3990882A JPS58157061A JP S58157061 A JPS58157061 A JP S58157061A JP 57039908 A JP57039908 A JP 57039908A JP 3990882 A JP3990882 A JP 3990882A JP S58157061 A JPS58157061 A JP S58157061A
Authority
JP
Japan
Prior art keywords
pipe
inner tube
heat exchange
heat
outer tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP57039908A
Other languages
Japanese (ja)
Inventor
Mitsuie Matsumura
光家 松村
Yoichi Mizumoto
水本 洋一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Electric Corp
Original Assignee
Mitsubishi Electric Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Electric Corp filed Critical Mitsubishi Electric Corp
Priority to JP57039908A priority Critical patent/JPS58157061A/en
Publication of JPS58157061A publication Critical patent/JPS58157061A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04067Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
    • H01M8/04074Heat exchange unit structures specially adapted for fuel cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04029Heat exchange using liquids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Fuel Cell (AREA)

Abstract

PURPOSE:To increase the homogeneity of the internal temperature distribution of a temperature regulating body by making each of heat-exchange pipes, which are attached to the temperature regulating body, to have a double-pipe structure formed by inserting an inner tube having opened ends into an outer tube having closed ends. CONSTITUTION:Heat-exchange pipes 6 are attached to a temperature regulating body 5 which is installed in the middle of a stacked body, which is formed by stacking in order a plural number of units each consisting of a fuel electrode, an electrolyte matrix, an oxidizer electrode and a gas-separating plate. Each heat-exchange pipe 6 is made by inserting an inner tube 6a having opened ends into an outer tube 6b having closed ends. Circulating water, after flowing into the inner tube 6a from a circulating-water inlet pipe 7, flows through the inner tube 6a in a given direction, reverses its direction at the end of the outer tube 6b, and flows through the outer tube 6b out into an outlet pipe 8. As a result, since circulating inflow water and circulating outflow water exchange their heat through the wall of the inner tube 6a to perform heating or cooling, the homogeneity of the temperature distribution of the regulating body 5 can be widely increased.

Description

【発明の詳細な説明】 この発明は、積J−形燃料箪池、特にその温度調節体に
関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a J-type fuel tank, and particularly to a temperature regulator thereof.

従来この種の装置として第1図に示すものがあった。図
において、(1)は上・下面にそれぞれ燃料流路と酸化
剤流路(図示せず)を有したカーボン板等から製作され
た温度調節体、(2)はこの温度調節体(1)の中に装
着されたU字形状をした熱交換配管、(3)および(4
)はこの熱交換配管(21に接続され、上記温If調節
体(1)の外部に設置した循環水入口管および循櫨水出
口管である〇 次に動作について説明する。燃料電極、電解質マトリッ
クス、酸化剤電極から構成される単電池をガス分離板を
用いて複数個積層した燃料電池において、起動時には室
温から動作温度まで加熱し。
A conventional device of this type is shown in FIG. In the figure, (1) is a temperature control body made from a carbon plate or the like, which has a fuel flow path and an oxidizer flow path (not shown) on the upper and lower surfaces, respectively, and (2) is this temperature control body (1). U-shaped heat exchange pipes installed in (3) and (4)
) are the circulating water inlet pipe and circulating water outlet pipe connected to this heat exchange pipe (21) and installed outside the temperature If controller (1). Next, the operation will be explained.Fuel electrode, electrolyte matrix In a fuel cell in which a plurality of single cells each consisting of an oxidizer electrode are stacked together using a gas separation plate, the fuel cell is heated from room temperature to operating temperature at startup.

運転時には余剰熱を除去・冷却して一定温度に維持する
必要から、温度調節体をある単電池個数ごとに挿入・設
置する構成となっている。すなわち、儂壇水入口管(3
)および循環水出口管(4)を用いて、0次形状なした
熱交換配管(2)に起動時には温水?、運転時には冷却
水を強制循環させて、温度調節体(11を加熱もしくは
冷却することにより積層形燃料電池の温度制(財)をす
る。第2図に詳細な構造を示すように、この温度調節体
(11は燃料電池本体との熱の授受を効率的に行なうた
めに、上板(1a)と下& (lb)とから成り、下板
(Ib)の内部には熱交換配管(2)を設置するU字形
状の溝部があシ、この溝部に熱交換配¥(2)を装着し
て下板(lb)との空隙には充填剤を挿入し喪後、上板
(1a)にて蕪をして一体物にした構成としている。
During operation, it is necessary to remove excess heat and cool it to maintain a constant temperature, so a temperature regulator is inserted and installed for each number of cells. That is, the Yudan water inlet pipe (3
) and the circulating water outlet pipe (4), hot water is supplied to the zero-order heat exchange piping (2) at startup. During operation, the temperature of the stacked fuel cell is controlled by forcing cooling water to circulate and heating or cooling the temperature regulator (11). The regulator (11) consists of an upper plate (1a) and a lower plate (lb) in order to efficiently transfer heat to and from the fuel cell main body, and inside the lower plate (Ib) there is a heat exchange pipe (2 ) is installed in the U-shaped groove, attach the heat exchanger (2) to this groove, insert a filler into the gap between it and the lower plate (lb), and then replace the upper plate (1a). The structure is made by turning turnips and making them into a single piece.

従来の温度調節体は以上の工うに構成されているので、
温水・冷却水等の熱線体が熱交換配管の入口から出口ま
でにおいて、温度調節体本体と直接熱交換するので、入
口部分での熱交換率が強く、出口部分でのそれが弱く、
そのため温度調節体本体の面内温度分布を一様にするの
が困難であった・この発明は上記のような従来のものの
欠点を除去するためになされたもので、熱交換配管を二
重管構造にし、内側管から外側管へ、又はその逆に流れ
るようにして、温度調節体の温度分布が一様になるよう
にしようとするものである。
Conventional temperature regulators are constructed as described above, so
Since the hot wire such as hot water and cooling water directly exchanges heat with the temperature control body from the inlet to the outlet of the heat exchange piping, the heat exchange rate is strong at the inlet and weak at the outlet.
Therefore, it was difficult to make the in-plane temperature distribution of the temperature controller body uniform. This invention was made to eliminate the drawbacks of the conventional ones as described above. It is intended to have a uniform temperature distribution in the temperature regulating body by structuring the temperature to flow from the inner tube to the outer tube or vice versa.

以下、この発明の一寮施例を図について説明する。第3
図において、(5)は上・下面にそれぞれ燃料流路と酸
化剤流路(図示せず)を有したカーボン板等から製作さ
れた温度調節体、(6)はこの温度調節体(5)の中に
装着された二重管構造をしているはぼ直管形状の熱交換
配管、(7)はこの熱交換配管(6)の内側管に接続さ
れ九循積水入口管、(8)は上記熱交換配管(6)の外
側管に接続された循環水出口管である。第4図において
、上記温度調節体(5)の構造の一例を示すが、上記温
゛度調節体(5)は上板(5a)と下板(5b)に分割
され、上板(5a)は上面には燃料流路、下板(5b)
は上板(5a)に接する面には上記熱交換配管(6)を
設置する矩形状の溝部と他面には酸化剤流路を有する構
造であり、上記熱交換配管(6)を装着して!21!1
iに充填剤を挿入後、上板(5a)と下板(5b)を装
着・一体化するものである。
Hereinafter, a dormitory embodiment of the present invention will be explained with reference to the drawings. Third
In the figure, (5) is a temperature regulator made of a carbon plate, etc., which has a fuel channel and an oxidizer channel (not shown) on the upper and lower surfaces, respectively, and (6) is this temperature regulator (5). A heat exchange pipe (7) in the shape of a straight tube with a double pipe structure installed inside the pipe, (7) is connected to the inner pipe of this heat exchange pipe (6), and a nine-circulation seismic water inlet pipe (8) is a circulating water outlet pipe connected to the outer pipe of the heat exchange pipe (6). In FIG. 4, an example of the structure of the temperature regulating body (5) is shown. The temperature regulating body (5) is divided into an upper plate (5a) and a lower plate (5b), and the upper plate (5a) There is a fuel flow path on the top surface and a bottom plate (5b).
has a structure in which the surface in contact with the upper plate (5a) has a rectangular groove in which the heat exchange piping (6) is installed, and the other surface has an oxidizing agent flow path, and the heat exchange piping (6) is installed. hand! 21!1
After inserting the filler into i, the upper plate (5a) and lower plate (5b) are attached and integrated.

次に動作について説明する。積層形燃料電池において、
温度調節体(旬をある単電池個数ごとに挿入・設置し、
あるいは単−池゛の複数個の積層体の上°下表面にも設
置し、循環水入口管(7)および循環水出口管(8)を
それぞれの主管に接続する。次いで、この循環水入口管
(7)と循環水出口管(8)とを介して、熱交換配管(
6)K起動時には温水を、運転時には冷却水を強制循環
させて、温度調節体(5)を加熱もしくは冷却する。こ
のときの循環水の流れの様子を、第5図の温度調節体の
断面図によって、詳細に説明する。循環水入口管(7)
から流入した循環水は熱交換配管(6)の内側管(6a
)を一定方向に流れ、内側管(6a)は先端部分が閉放
され、外側管(6b)は先端部分が閉じているので、熱
交換配管(6)の先端部分で流れの方向を逆転して外側
管(6b)を流れて、循環水出口管(8)から流出する
。すなわち、温度調節体(6)の中に装着された熱交換
配管〈6)の二重管部分では、循環水は内側管(6a)
から流入して外側管(6b)から流出する間に、内側管
(6a)の管壁を通して流入循環水と流出循環水とで熱
交換(自己熱交換と呼ぶ)が行なわれる。次いで、流入
循環水は、この自己熱交換の後、外側管(6b)の管壁
を通して温度調節体(5)本体と熱交換することにより
Next, the operation will be explained. In stacked fuel cells,
Temperature control body (temperature control body is inserted and installed for each number of cells,
Alternatively, it may be installed on the upper and lower surfaces of a plurality of stacked single ponds, and the circulating water inlet pipe (7) and circulating water outlet pipe (8) are connected to the respective main pipes. Next, the heat exchange piping (
6) Hot water is forcedly circulated during K startup, and cooling water is forcedly circulated during operation to heat or cool the temperature regulator (5). The flow of the circulating water at this time will be explained in detail with reference to a cross-sectional view of the temperature regulator shown in FIG. Circulating water inlet pipe (7)
The circulating water flowing in from the inner pipe (6a) of the heat exchange pipe (6)
) flows in a fixed direction, and since the inner tube (6a) has an open tip and the outer tube (6b) has a closed tip, the flow direction is reversed at the tip of the heat exchange pipe (6). The water flows through the outer pipe (6b) and flows out from the circulating water outlet pipe (8). That is, in the double pipe part of the heat exchange piping (6) installed in the temperature regulator (6), the circulating water flows through the inner pipe (6a).
Heat exchange (referred to as self-heat exchange) is carried out between the inflow circulating water and the outflow circulating water through the wall of the inner pipe (6a) while the water flows in from the inner pipe (6b) and flows out from the outer pipe (6b). Next, after this self-heat exchange, the inflow circulating water exchanges heat with the main body of the temperature regulator (5) through the tube wall of the outer tube (6b).

温度調節体(句本体ひいては積層形燃料電池本体の加熱
もしくは冷却を行なう。このように、流入する循環水は
自己熱交換をし友後、温度調節体(5)本体の加熱+シ
<は冷却をすることになるので、従来の熱交換配管(2
)のように7重管構造のものと比較すると、温度調節体
(5)本体の面内温度分布の一様性は2倍以上向上する
ことになる。tた、熱交換配管(6)は直管形状にすれ
は、温度調節体(5)本体の接着・一体化の後に熱交換
配管(6)の内側管(6a)の着脱は容易であり、保守
・点検が容易である。
The temperature regulator (5) heats or cools the main body of the stacked fuel cell. In this way, the inflowing circulating water exchanges its own heat, and after that, the temperature regulator (5) heats or cools the main body. Therefore, conventional heat exchange piping (2
), the uniformity of the in-plane temperature distribution of the main body of the temperature regulator (5) is improved by more than twice. In addition, since the heat exchange pipe (6) has a straight pipe shape, it is easy to attach and detach the inner pipe (6a) of the heat exchange pipe (6) after adhering and integrating the main body of the temperature regulator (5). Maintenance and inspection are easy.

なお、主起実施例では、熱交換配管(6)への循環水が
内側管より外側管へ流れる場合のものを示したが、外側
管より内側管へ流れて自己熱交換するものでもよい。
In the main embodiment, the circulating water to the heat exchange piping (6) flows from the inner pipe to the outer pipe, but it may flow from the outer pipe to the inner pipe for self-heat exchange.

また、熱交換配管(6)に直管形状で円管のものを示し
たが、曲管形状や角管のものでもよい。さらに、温度調
節体く5】に上板(5a)と下板(5b)を接着・一体
化するものを示したが、ちと↓シ上板と下板の一体物に
熱交換配管(6)の設置用溝部を加工して装着しても↓
い。
Further, although the heat exchange piping (6) is shown as a straight circular pipe, it may be a curved pipe or a square pipe. Furthermore, the temperature control body (5) shows the upper plate (5a) and the lower plate (5b) bonded and integrated, but the heat exchange piping (6) is attached to the integrated upper plate and lower plate. Even if you process the installation groove and install it ↓
stomach.

以上のように、この発明によれば熱交換配管を。As described above, the present invention provides heat exchange piping.

先端部分を閉じた外側管に先端部分を開放した内側管を
挿入した二重管構造にし、熱媒体が上記内側管から外側
管又は外側管から内側管へ流れるようにしたので、温度
調節体の温度分布の一様性が向上する。
A double tube structure is adopted in which an inner tube with an open tip is inserted into an outer tube with a closed tip, and the heat medium flows from the inner tube to the outer tube or from the outer tube to the inner tube. The uniformity of temperature distribution is improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来の温度調節体を透視して内部の配管を示す
斜視図、第2図は従来の温度調節体を分解して示す斜視
図、第3図はこの発明の一5*施例の要部の温度調節体
を透視して内部の配管を示す斜視図、第4図はこの発明
の一実施例の要部の温度−節体を分解して示す斜視図、
第5図はこの発明の一実施例の要部の温度調節体を示す
断面側面図である。なお、回申、同一符号は同一、又は
相当部分を示す・ (6)・・・温度調節体、(6)・・・熱交換配管、(
6a)°・・内側管、 (6b)・・・外饋管、(7)
・・・循環水入口管、(8)パ循壊水出ロ管。 代理人 葛野信− 第1図 第2図 第3図 手続補正書(自発) 特許庁長官殿 1、事件の表示    特願昭Sマー5ssos号2、
発明の名称 積層形燃料電池 3、補正をする者 代表者片山仁へ部 6、補正の対象 明細書の発明の詳細な説明の欄 6、補正の内容 明細書の第6頁第2行〜第8行の[温度調節体(6)本
体の接着・一体化の後に熱交換配管(6)の内側管(6
a)Jを[温度調節体(5)に装着して空隙に充填剤を
挿入後に熱交換配管(6)または内側管(61) Jと
訂正する。 以上
Fig. 1 is a perspective view showing the internal piping seen through a conventional temperature regulator, Fig. 2 is an exploded perspective view of the conventional temperature regulator, and Fig. 3 is a 15th embodiment of the present invention. FIG. 4 is a perspective view showing the internal piping as seen through the temperature control body of the main part of the invention; FIG.
FIG. 5 is a cross-sectional side view showing the main part of the temperature regulator according to an embodiment of the present invention. In addition, the same reference numerals indicate the same or corresponding parts (6) Temperature regulator, (6) Heat exchange piping, (
6a) °...Inner tube, (6b)...Outer feed tube, (7)
... Circulating water inlet pipe, (8) Circulating water outlet pipe. Agent Makoto Kuzuno - Figure 1 Figure 2 Figure 3 Procedural amendment (voluntary) Commissioner of the Japan Patent Office 1, Indication of case Patent application Shomar 5ssos No. 2,
Name of the invention: Stacked fuel cell 3, Representative Hitoshi Katayama of the person making the amendment, Part 6, Detailed explanation of the invention in the specification subject to the amendment, column 6, Page 6, lines 2 to 2 of the statement of contents of the amendment. Line 8 [After gluing and integrating the temperature regulator (6) body, the inner pipe (6) of the heat exchange piping (6)
a) Correct J to [heat exchange piping (6) or inner pipe (61) J after attaching to temperature regulator (5) and inserting filler into the gap. that's all

Claims (2)

【特許請求の範囲】[Claims] (1)燃料電極、電解質マトリックス、酸化剤W&及び
ガス分離板を順次複数個積層する槓+m体の中間又は表
面に温度調節体を設置させた績J−形燃料電池において
、上記温度調節体に装着された熱交換配管な、先端部分
を閉じた外側管に先端部分な開放した内側管を挿入した
二重管構造にし、熱媒体が上記内側管と外側管を流れる
ようにしたことを特徴とする積層形燃料電池。
(1) In a J-type fuel cell, a temperature control body is installed in the middle or on the surface of a shell+m structure in which a plurality of fuel electrodes, electrolyte matrix, oxidizer W&, and gas separation plates are sequentially laminated. The attached heat exchange piping has a double-tube structure in which an inner tube with an open tip is inserted into an outer tube with a closed tip and an inner tube with an open tip, so that the heat medium flows through the inner tube and the outer tube. stacked fuel cells.
(2)熱交換配管は直管形状であることを特徴とする特
許請求の範囲第1項記載の積層形燃料電池。
(2) The stacked fuel cell according to claim 1, wherein the heat exchange pipe has a straight pipe shape.
JP57039908A 1982-03-12 1982-03-12 Layer-built fuel cell Pending JPS58157061A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57039908A JPS58157061A (en) 1982-03-12 1982-03-12 Layer-built fuel cell

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57039908A JPS58157061A (en) 1982-03-12 1982-03-12 Layer-built fuel cell

Publications (1)

Publication Number Publication Date
JPS58157061A true JPS58157061A (en) 1983-09-19

Family

ID=12566050

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57039908A Pending JPS58157061A (en) 1982-03-12 1982-03-12 Layer-built fuel cell

Country Status (1)

Country Link
JP (1) JPS58157061A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0681156A1 (en) * 1994-05-07 1995-11-08 Schmidt-Bretten GmbH Heat exchanger
KR101253905B1 (en) 2010-12-28 2013-04-16 주식회사 포스코 Fuel cell stack
DE102012205750A1 (en) * 2012-04-10 2013-10-10 Continental Automotive Gmbh Cooling device i.e. cooling fin, for use in coolant distributor of cooling system for battery of e.g. electric car, has flow channel comprising inlet- and exhaust openings that are oriented in same direction of longitudinal axis
DE102011084536B4 (en) * 2011-10-14 2018-02-15 Continental Automotive Gmbh Cooling device for an electrical energy storage and energy storage device

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0681156A1 (en) * 1994-05-07 1995-11-08 Schmidt-Bretten GmbH Heat exchanger
KR101253905B1 (en) 2010-12-28 2013-04-16 주식회사 포스코 Fuel cell stack
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DE102012205750B4 (en) 2012-04-10 2020-06-25 Continental Automotive Gmbh Coolant distributor for a plurality of cooling devices, cooling system and energy storage with a cooling system

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