JPS5785375A - Alkali metallic salt of 5-carboxyorotic acid - Google Patents
Alkali metallic salt of 5-carboxyorotic acidInfo
- Publication number
- JPS5785375A JPS5785375A JP55161384A JP16138480A JPS5785375A JP S5785375 A JPS5785375 A JP S5785375A JP 55161384 A JP55161384 A JP 55161384A JP 16138480 A JP16138480 A JP 16138480A JP S5785375 A JPS5785375 A JP S5785375A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- expressed
- reacted
- alkyl
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
NEW MATERIAL:A compound expressed by formulaI[Me is alkali metal; R1 is 1W4C alkyl, allyl, cyclohexyl, benzyl or formula VII (R2 is 1W4C alkyl, 1W4C alkoxyl or halogen; n is 0,1,2 or 3)].
EXAMPLE: Potassium 5-carboxy-1-(n-butyl)orotate.
USE: An agricultural chemical, medicine or an intermediate therefor.
PROCESS: A cyanoformic ester of formula II (R3 is 1W4C alkyl) is reacted with a malonic diester expressed by formula III (R4 and R5 are the same as R3) in the presence of a titanium halide, etc. at -10W100°C, and the reaction product is then treated with water, etc. to afford a compound expressed by formula IV, which is then reacted with an isocyanate expressed by the formula R1NCO in the presence of a quaternary ammonium fluoride, etc. at 20W100°C to give a hydantoin derivative expressed by formula VI. The resultant compound is reacted with an alkali hydroxide in a solvent, e.g. water, at room temperature. A mineral acid is then added thereto to give the compound expressed by formulaI.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55161384A JPS5785375A (en) | 1980-11-18 | 1980-11-18 | Alkali metallic salt of 5-carboxyorotic acid |
US06/319,793 US4400508A (en) | 1980-11-18 | 1981-11-09 | Orotic acid derivatives |
DE8181109628T DE3170766D1 (en) | 1980-11-18 | 1981-11-11 | Orotic acid derivatives and their use as agricultural chemicals |
EP81109628A EP0052341B1 (en) | 1980-11-18 | 1981-11-11 | Orotic acid derivatives and their use as agricultural chemicals |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55161384A JPS5785375A (en) | 1980-11-18 | 1980-11-18 | Alkali metallic salt of 5-carboxyorotic acid |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5785375A true JPS5785375A (en) | 1982-05-28 |
JPS6132311B2 JPS6132311B2 (en) | 1986-07-25 |
Family
ID=15734059
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55161384A Granted JPS5785375A (en) | 1980-11-18 | 1980-11-18 | Alkali metallic salt of 5-carboxyorotic acid |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5785375A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6083315A (en) * | 1996-12-20 | 2000-07-04 | Seiko Epson Corporation | Agglomerated pigment, process for producing the same, aqueous pigment dispersion, and water-based ink composition |
-
1980
- 1980-11-18 JP JP55161384A patent/JPS5785375A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6083315A (en) * | 1996-12-20 | 2000-07-04 | Seiko Epson Corporation | Agglomerated pigment, process for producing the same, aqueous pigment dispersion, and water-based ink composition |
Also Published As
Publication number | Publication date |
---|---|
JPS6132311B2 (en) | 1986-07-25 |
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