JPS56164129A - Preparation of allyl alcohol - Google Patents

Preparation of allyl alcohol

Info

Publication number
JPS56164129A
JPS56164129A JP6688680A JP6688680A JPS56164129A JP S56164129 A JPS56164129 A JP S56164129A JP 6688680 A JP6688680 A JP 6688680A JP 6688680 A JP6688680 A JP 6688680A JP S56164129 A JPS56164129 A JP S56164129A
Authority
JP
Japan
Prior art keywords
expressed
formula
alkyl
reaction
allyl alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP6688680A
Other languages
Japanese (ja)
Other versions
JPS637170B2 (en
Inventor
Hideki Sakurai
Akira Hosomi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Takasago International Corp
Takasago Corp
Original Assignee
Takasago Perfumery Industry Co
Takasago Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Takasago Perfumery Industry Co, Takasago Corp filed Critical Takasago Perfumery Industry Co
Priority to JP6688680A priority Critical patent/JPS56164129A/en
Publication of JPS56164129A publication Critical patent/JPS56164129A/en
Publication of JPS637170B2 publication Critical patent/JPS637170B2/ja
Granted legal-status Critical Current

Links

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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the titled compound in high yield in one reactor, by reacting iodotrimethylsilane with an oxirane, dehydroiodinating the resultant 2-iodoalkoxytrimethylsilane, and treating the reaction product with an acid.
CONSTITUTION: Iodotrimethylsilane expressed by formula III is reacted with an oxirane expressed by formula I (R1 is H, 1W10C alkyl or alkenyl which may have a substituent taking no part in the reaction; R2 is H or 1W4C lower alkyl; R3 is 1W10C alkyl or alkenyl which may have a substituent taking no part in the reaction; the dotted line means that R1 and R3 may link to form 5W20 membered ring) to produce a 2-iodoalkoxylrmethylstlane expressed by formula IV, which is dehydroidinated with a base, e.g. 1,8-diazabicyclo[5.4.0]-undecene-7, etc. The resultant compound is then treated with an acid, to give an allyl alcohol expressed by formula II. The raw material can also be synthesized in the same reactor.
USE: A perfume, a medicine or an intermediate therefor.
COPYRIGHT: (C)1981,JPO&Japio
JP6688680A 1980-05-20 1980-05-20 Preparation of allyl alcohol Granted JPS56164129A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6688680A JPS56164129A (en) 1980-05-20 1980-05-20 Preparation of allyl alcohol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6688680A JPS56164129A (en) 1980-05-20 1980-05-20 Preparation of allyl alcohol

Publications (2)

Publication Number Publication Date
JPS56164129A true JPS56164129A (en) 1981-12-17
JPS637170B2 JPS637170B2 (en) 1988-02-15

Family

ID=13328822

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6688680A Granted JPS56164129A (en) 1980-05-20 1980-05-20 Preparation of allyl alcohol

Country Status (1)

Country Link
JP (1) JPS56164129A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4935451A (en) * 1989-09-11 1990-06-19 Syracuse University Conversion of optically active epoxy alcohols to allylic alcohols
US5087773A (en) * 1990-04-23 1992-02-11 Syracuse University Selective tellurium-mediated synthesis of optically active E- or Z-allyl alcohols from optically active epoxy alcohols
KR20000063913A (en) * 2000-08-10 2000-11-06 하현준 Process for preparing 1,2-diaminopropane alcohols from aziridines

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4935451A (en) * 1989-09-11 1990-06-19 Syracuse University Conversion of optically active epoxy alcohols to allylic alcohols
US5087773A (en) * 1990-04-23 1992-02-11 Syracuse University Selective tellurium-mediated synthesis of optically active E- or Z-allyl alcohols from optically active epoxy alcohols
KR20000063913A (en) * 2000-08-10 2000-11-06 하현준 Process for preparing 1,2-diaminopropane alcohols from aziridines

Also Published As

Publication number Publication date
JPS637170B2 (en) 1988-02-15

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