JPS5675443A - Novel allyl alcohol - Google Patents
Novel allyl alcoholInfo
- Publication number
- JPS5675443A JPS5675443A JP15187779A JP15187779A JPS5675443A JP S5675443 A JPS5675443 A JP S5675443A JP 15187779 A JP15187779 A JP 15187779A JP 15187779 A JP15187779 A JP 15187779A JP S5675443 A JPS5675443 A JP S5675443A
- Authority
- JP
- Japan
- Prior art keywords
- ethylenedioxy
- allyl alcohol
- bornan
- penten
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:A 2-substituted allyl alcohol of the Z-form or consisting of the Z- form as a chief component expressed by formula I (R is sec-butyl, iso-butyl, cyclopropyl, cyclohexyl, 2-phenylethyl or 2-ethylenedioxy-bornan-9-yl.
EXAMPLE: (Z)-5-(2-Ethylenedioxy-bornan-9-yl)-2-methyl-2-penten-1-ol.
USE: An intermediate for a medicine or a perfume, e.g. α-santalol.
PROCESS: For example, a 2-ethylenedioxy-9-bromobornane is reacted with Li, to prepare 9-lithio-2-ethylenedioxybornane, which is further reacted with 3,4-epoxy-3- methylbutene-1, to give (Z)-5-(2-ethylenedioxy-bornan-9-yl)-2-methyl-2-penten-1-ol expressed by formula II.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15187779A JPS5675443A (en) | 1979-11-22 | 1979-11-22 | Novel allyl alcohol |
DE8080107288T DE3068252D1 (en) | 1979-11-22 | 1980-11-21 | Process for preparing predominantly z-substituted allylic alcohols |
EP80107288A EP0029603B1 (en) | 1979-11-22 | 1980-11-21 | Process for preparing predominantly z-substituted allylic alcohols |
US07/529,730 US5004843A (en) | 1979-11-22 | 1990-05-29 | Process for producing allylic alcohols |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP15187779A JPS5675443A (en) | 1979-11-22 | 1979-11-22 | Novel allyl alcohol |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5675443A true JPS5675443A (en) | 1981-06-22 |
JPS6315277B2 JPS6315277B2 (en) | 1988-04-04 |
Family
ID=15528149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP15187779A Granted JPS5675443A (en) | 1979-11-22 | 1979-11-22 | Novel allyl alcohol |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5675443A (en) |
-
1979
- 1979-11-22 JP JP15187779A patent/JPS5675443A/en active Granted
Non-Patent Citations (1)
Title |
---|
JOURNAL OF POLYMER SCIENCE POLYMER CHEMISTRY EDITION * |
Also Published As
Publication number | Publication date |
---|---|
JPS6315277B2 (en) | 1988-04-04 |
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