JPS5742660A - Preparation of formamide - Google Patents
Preparation of formamideInfo
- Publication number
- JPS5742660A JPS5742660A JP55116454A JP11645480A JPS5742660A JP S5742660 A JPS5742660 A JP S5742660A JP 55116454 A JP55116454 A JP 55116454A JP 11645480 A JP11645480 A JP 11645480A JP S5742660 A JPS5742660 A JP S5742660A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- formamide
- alkyl
- hydrogen
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To use an easily treatable catalyst repeatedly and to obtain a formamide in high yield, by reacting ammonia with an amine, diamine and carbon monoxide in a liquid phase in the presence of hydrogen and a catalyst of a platinum group metal.
CONSTITUTION: Ammonia is reacted with an amine shown by the formula I (R1 is H or 1W10C alkyl; R2 is 1W10C alkyl), a diamine shown by the formula II (R3 is 1W10C alkylene) and carbon monoxide in a liquid phase in the presence of hydrogen and a catalyst, e.g., a platinum group metal such as ruthenium, rhodium, their oxides, hydroxides, inorganic salts, e.g., chloridies, sulfates, nitrates, etc. at 50W 300°C to give a formamide. The catalyst is used in a concentration of preferably 1×10-4W1mol/l.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55116454A JPS5742660A (en) | 1980-08-26 | 1980-08-26 | Preparation of formamide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55116454A JPS5742660A (en) | 1980-08-26 | 1980-08-26 | Preparation of formamide |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS5742660A true JPS5742660A (en) | 1982-03-10 |
Family
ID=14687510
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55116454A Pending JPS5742660A (en) | 1980-08-26 | 1980-08-26 | Preparation of formamide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5742660A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4558157A (en) * | 1984-06-05 | 1985-12-10 | Air Products And Chemicals, Inc. | Synthesis of dimethylformamide |
JPS62255456A (en) * | 1986-04-30 | 1987-11-07 | Idemitsu Petrochem Co Ltd | Production of diethylformamide |
EP2274277A4 (en) * | 2008-04-16 | 2012-02-01 | Univ Cape Town | A process for the production of nitrogen or phosphorus containing compounds from synthesis gas |
CN105272868A (en) * | 2014-07-22 | 2016-01-27 | 中国科学院大连化学物理研究所 | Method for preparation of formamide through carbonylation |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5356608A (en) * | 1976-11-01 | 1978-05-23 | Mitsubishi Gas Chem Co Inc | Preparation of dimethylformaide |
JPS549216A (en) * | 1977-06-22 | 1979-01-24 | Mitsubishi Gas Chem Co Inc | Preparation of dimethylformamide |
-
1980
- 1980-08-26 JP JP55116454A patent/JPS5742660A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5356608A (en) * | 1976-11-01 | 1978-05-23 | Mitsubishi Gas Chem Co Inc | Preparation of dimethylformaide |
JPS549216A (en) * | 1977-06-22 | 1979-01-24 | Mitsubishi Gas Chem Co Inc | Preparation of dimethylformamide |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4558157A (en) * | 1984-06-05 | 1985-12-10 | Air Products And Chemicals, Inc. | Synthesis of dimethylformamide |
JPS62255456A (en) * | 1986-04-30 | 1987-11-07 | Idemitsu Petrochem Co Ltd | Production of diethylformamide |
JPH0529215B2 (en) * | 1986-04-30 | 1993-04-28 | Idemitsu Petrochemical Co | |
EP2274277A4 (en) * | 2008-04-16 | 2012-02-01 | Univ Cape Town | A process for the production of nitrogen or phosphorus containing compounds from synthesis gas |
US8513463B2 (en) | 2008-04-16 | 2013-08-20 | The University Of Cape Town | Process for the production of nitrogen or phosphorus containing compounds from synthesis gas |
CN105272868A (en) * | 2014-07-22 | 2016-01-27 | 中国科学院大连化学物理研究所 | Method for preparation of formamide through carbonylation |
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