JPS57209836A - Compound expressed by tmgacoo4 and having hexagonal layered structure and preparation thereof - Google Patents
Compound expressed by tmgacoo4 and having hexagonal layered structure and preparation thereofInfo
- Publication number
- JPS57209836A JPS57209836A JP56094663A JP9466381A JPS57209836A JP S57209836 A JPS57209836 A JP S57209836A JP 56094663 A JP56094663 A JP 56094663A JP 9466381 A JP9466381 A JP 9466381A JP S57209836 A JPS57209836 A JP S57209836A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- heating
- layered structure
- decomposable
- hexagonal layered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Hard Magnetic Materials (AREA)
- Soft Magnetic Materials (AREA)
Abstract
PURPOSE: A novel compound consisting of a compound oxide of Tm, Ga and Co, expressed by TmGaCoO4, and having the hexagonal layered structure.
CONSTITUTION: Tm, Tm2O3 or a compound decomposable into Tm2O3 by heating is mixed with Ga, Ga2O3 or a compound decomposable into Ga2O3 by heating and Co, CoO or a compound decomposable into CoO by heating. The respective particle diameters thereof are preferably ≤about 10μm. The atomic ratio of Tm/Ga/Co is 1:1:1. The resultant mixture is then heated at 1,000°C or above in the air, an oxidizing atmosphere or such a reducing atmosphere as not to reduce Ga and Co from the trivalent and bivalent ionic states. After the completion of the reaction, the reaction mixture is guenched to 0°C or quickly taken out to the air and give the aimed LuGaCoO4 compound. The compound assumes a black color and is found to have the crystal structure by the powder X-ray diffractometry and the same type as the well-known YFe2O4.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56094663A JPS6041621B2 (en) | 1981-06-19 | 1981-06-19 | Compound having hexagonal layered structure represented by TmGaCoO↓4 and method for producing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP56094663A JPS6041621B2 (en) | 1981-06-19 | 1981-06-19 | Compound having hexagonal layered structure represented by TmGaCoO↓4 and method for producing the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57209836A true JPS57209836A (en) | 1982-12-23 |
JPS6041621B2 JPS6041621B2 (en) | 1985-09-18 |
Family
ID=14116485
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56094663A Expired JPS6041621B2 (en) | 1981-06-19 | 1981-06-19 | Compound having hexagonal layered structure represented by TmGaCoO↓4 and method for producing the same |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6041621B2 (en) |
-
1981
- 1981-06-19 JP JP56094663A patent/JPS6041621B2/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
JPS6041621B2 (en) | 1985-09-18 |
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