JPS57149813A - Treatment of phosphoric acid extracted solution by ion exchange - Google Patents
Treatment of phosphoric acid extracted solution by ion exchangeInfo
- Publication number
- JPS57149813A JPS57149813A JP56031252A JP3125281A JPS57149813A JP S57149813 A JPS57149813 A JP S57149813A JP 56031252 A JP56031252 A JP 56031252A JP 3125281 A JP3125281 A JP 3125281A JP S57149813 A JPS57149813 A JP S57149813A
- Authority
- JP
- Japan
- Prior art keywords
- phosphoric acid
- acid
- agent
- regenerating
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 5
- 238000005342 ion exchange Methods 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 abstract 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 6
- 229910052742 iron Inorganic materials 0.000 abstract 4
- 230000001172 regenerating effect Effects 0.000 abstract 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- 230000000873 masking effect Effects 0.000 abstract 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 2
- 239000003729 cation exchange resin Substances 0.000 abstract 2
- 150000001768 cations Chemical class 0.000 abstract 2
- -1 iron ion Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 abstract 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 abstract 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 235000006408 oxalic acid Nutrition 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000011975 tartaric acid Substances 0.000 abstract 1
- 235000002906 tartaric acid Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
Abstract
PURPOSE: To manufacture high purity phosphoric acid having an extremely low iron ion content by adding an iron masking agent to a regenerating agent for regenerating a strongly acidic cation exchange resin used to remove traces of cations from wet process phosphoric acid.
CONSTITUTION: In a method or removing traces of cations contained in an extracted soln. composed chiefly of phosphoric acid, an org. solvent and water with a strongly acidic cation exchange resin, an iron masking agent is added to a regenerating agent for the resin. As the regeneratig agent an aqueous sulfuric acid soln. with about 5W15wt% concn. is used in general. As the masking agent 1 or ≥2 kinds of compounds selected from citric acid, oxalic acid, thiocyanic acid, tartaric acid, EDTA and phosphoric acid are used by about 2W10 times the necessary theoretical amount. Thus, iron ions can be prevented from entering the product from the regenerating agent.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56031252A JPS57149813A (en) | 1981-03-06 | 1981-03-06 | Treatment of phosphoric acid extracted solution by ion exchange |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56031252A JPS57149813A (en) | 1981-03-06 | 1981-03-06 | Treatment of phosphoric acid extracted solution by ion exchange |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS57149813A true JPS57149813A (en) | 1982-09-16 |
Family
ID=12326163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56031252A Pending JPS57149813A (en) | 1981-03-06 | 1981-03-06 | Treatment of phosphoric acid extracted solution by ion exchange |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57149813A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01258749A (en) * | 1988-04-08 | 1989-10-16 | Mitsui Toatsu Chem Inc | Regenerating agent for cation exchange resin and regenerating process using said regenerating agent |
| WO2024075406A1 (en) * | 2022-10-06 | 2024-04-11 | オルガノ株式会社 | Method for producing cation exchange resin and method for refining organic acid solution |
-
1981
- 1981-03-06 JP JP56031252A patent/JPS57149813A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01258749A (en) * | 1988-04-08 | 1989-10-16 | Mitsui Toatsu Chem Inc | Regenerating agent for cation exchange resin and regenerating process using said regenerating agent |
| JPH0511494B2 (en) * | 1988-04-08 | 1993-02-15 | Mitsui Toatsu Chemicals | |
| WO2024075406A1 (en) * | 2022-10-06 | 2024-04-11 | オルガノ株式会社 | Method for producing cation exchange resin and method for refining organic acid solution |
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