JPS57114583A - Preparation of 2,3-epoxycyclohexan-1-ol - Google Patents

Preparation of 2,3-epoxycyclohexan-1-ol

Info

Publication number
JPS57114583A
JPS57114583A JP56000871A JP87181A JPS57114583A JP S57114583 A JPS57114583 A JP S57114583A JP 56000871 A JP56000871 A JP 56000871A JP 87181 A JP87181 A JP 87181A JP S57114583 A JPS57114583 A JP S57114583A
Authority
JP
Japan
Prior art keywords
compound
cyclohex
reaction
epoxycyclohexan
cyclohexene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP56000871A
Other languages
Japanese (ja)
Other versions
JPH0153273B2 (en
Inventor
Takao Maki
Yoshio Asahi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP56000871A priority Critical patent/JPS57114583A/en
Publication of JPS57114583A publication Critical patent/JPS57114583A/en
Publication of JPH0153273B2 publication Critical patent/JPH0153273B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To improve the selectivity of the titled compound in the liquid-phase oxidation of cyclohexene with molecular oxygen in the presence of a soluble vanadium compound catalyst, by carrying out the reaction in the presence of cyclohex-2-en-1-ol porduced as a by-product.
CONSTITUTION: 2,3-Epoxycyclohexan-1-ol is prepared by the liquid-phase oxidation of cyclohexene and cyclohex-2-en-1-ol with molecular oxygen in the presence of a soluble vanadium compound catalyst. In the above reaction, the mixture of the by-produced cyclohexeneoxide (A), cyclohex-2-en-1-one (B) and cyclohex-2-en- 1-ol (C) is, if necessary after separating the compound A, recycled to the reaction system to convert the compound C in the mixture to the objective compound. When the compounds A and B which are inert to the reaction are converted to the compound C by conventional method, and recycled to the reaction system, the yield of the objective compound can be further improved.
COPYRIGHT: (C)1982,JPO&Japio
JP56000871A 1981-01-07 1981-01-07 Preparation of 2,3-epoxycyclohexan-1-ol Granted JPS57114583A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP56000871A JPS57114583A (en) 1981-01-07 1981-01-07 Preparation of 2,3-epoxycyclohexan-1-ol

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP56000871A JPS57114583A (en) 1981-01-07 1981-01-07 Preparation of 2,3-epoxycyclohexan-1-ol

Publications (2)

Publication Number Publication Date
JPS57114583A true JPS57114583A (en) 1982-07-16
JPH0153273B2 JPH0153273B2 (en) 1989-11-13

Family

ID=11485727

Family Applications (1)

Application Number Title Priority Date Filing Date
JP56000871A Granted JPS57114583A (en) 1981-01-07 1981-01-07 Preparation of 2,3-epoxycyclohexan-1-ol

Country Status (1)

Country Link
JP (1) JPS57114583A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006328339A (en) * 2005-04-28 2006-12-07 Konica Minolta Medical & Graphic Inc Polymerizable composition, polymerization method, polymerizable ink, image forming method using the same, inkjet printer and epoxy compound

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0465862U (en) * 1990-10-16 1992-06-09

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52104493A (en) * 1976-03-01 1977-09-01 Zenichi Yoshida Liquid phase oxidation catalyst for unsaturated organic compounds
JPS5353605A (en) * 1976-10-23 1978-05-16 Air Prod & Chem Method of producing olefin oxide

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52104493A (en) * 1976-03-01 1977-09-01 Zenichi Yoshida Liquid phase oxidation catalyst for unsaturated organic compounds
JPS5353605A (en) * 1976-10-23 1978-05-16 Air Prod & Chem Method of producing olefin oxide

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006328339A (en) * 2005-04-28 2006-12-07 Konica Minolta Medical & Graphic Inc Polymerizable composition, polymerization method, polymerizable ink, image forming method using the same, inkjet printer and epoxy compound

Also Published As

Publication number Publication date
JPH0153273B2 (en) 1989-11-13

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