JPS57102855A - Preparation of aromatic urethane - Google Patents
Preparation of aromatic urethaneInfo
- Publication number
- JPS57102855A JPS57102855A JP55180254A JP18025480A JPS57102855A JP S57102855 A JPS57102855 A JP S57102855A JP 55180254 A JP55180254 A JP 55180254A JP 18025480 A JP18025480 A JP 18025480A JP S57102855 A JPS57102855 A JP S57102855A
- Authority
- JP
- Japan
- Prior art keywords
- phenol
- aromatic
- nitro compound
- urethane
- aromatic nitro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
PURPOSE: To prepare the titled compound economically, by reacting an aromatic nitro compound and a lower a aliphatic alcohol or a phenol in liquid phase in the presence of a catalyst containing platinum-group metal with CO preparaed by specific method, and circulating and reusing the exhaust gas of the reaction.
CONSTITUTION: An aromatic nitro compound (e.g. nitrobenzene) and a lower aliphatic alcohol (e.g. methanol) or a phenol are made to react with CO in liquid phase in the presence of a catalyst containing a platinum-group metal (e.g. Pd, Rh, etc.) at 100W250°C to obtain an aromatic urethane. The amount of the alcohol or phenol is 2W400mol, pref. 5W50mol per 1mol of the nitro group of the aromatic nitro compound. The CO gas is prepared by passing a mixed gas containing CO2 and O2 through the layer of coke heated at ≥900°C. The exhaust gas obtained after the completion of the urethane-forming reaction is recycled to the above coke layer.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55180254A JPS57102855A (en) | 1980-12-19 | 1980-12-19 | Preparation of aromatic urethane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55180254A JPS57102855A (en) | 1980-12-19 | 1980-12-19 | Preparation of aromatic urethane |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS57102855A true JPS57102855A (en) | 1982-06-26 |
Family
ID=16080045
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55180254A Pending JPS57102855A (en) | 1980-12-19 | 1980-12-19 | Preparation of aromatic urethane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57102855A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4603216A (en) * | 1983-09-16 | 1986-07-29 | Catalytica Associates | Process for the preparation of urethanes |
US4629804A (en) * | 1983-09-16 | 1986-12-16 | Catalytica Associates | Process for preparation of urethanes |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55145654A (en) * | 1979-05-01 | 1980-11-13 | Mitsubishi Chem Ind Ltd | Preparation of aromatic carbamic acid ester |
JPS55147253A (en) * | 1979-05-04 | 1980-11-17 | Mitsubishi Chem Ind Ltd | Preparation of aromatic carbamic acid ester |
-
1980
- 1980-12-19 JP JP55180254A patent/JPS57102855A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55145654A (en) * | 1979-05-01 | 1980-11-13 | Mitsubishi Chem Ind Ltd | Preparation of aromatic carbamic acid ester |
JPS55147253A (en) * | 1979-05-04 | 1980-11-17 | Mitsubishi Chem Ind Ltd | Preparation of aromatic carbamic acid ester |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4603216A (en) * | 1983-09-16 | 1986-07-29 | Catalytica Associates | Process for the preparation of urethanes |
US4629804A (en) * | 1983-09-16 | 1986-12-16 | Catalytica Associates | Process for preparation of urethanes |
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