JPS57102855A - Preparation of aromatic urethane - Google Patents

Preparation of aromatic urethane

Info

Publication number
JPS57102855A
JPS57102855A JP55180254A JP18025480A JPS57102855A JP S57102855 A JPS57102855 A JP S57102855A JP 55180254 A JP55180254 A JP 55180254A JP 18025480 A JP18025480 A JP 18025480A JP S57102855 A JPS57102855 A JP S57102855A
Authority
JP
Japan
Prior art keywords
phenol
aromatic
nitro compound
urethane
aromatic nitro
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP55180254A
Other languages
Japanese (ja)
Inventor
Tsutomu Takeuchi
Mineo Nishi
Kunio Kagoya
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP55180254A priority Critical patent/JPS57102855A/en
Publication of JPS57102855A publication Critical patent/JPS57102855A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To prepare the titled compound economically, by reacting an aromatic nitro compound and a lower a aliphatic alcohol or a phenol in liquid phase in the presence of a catalyst containing platinum-group metal with CO preparaed by specific method, and circulating and reusing the exhaust gas of the reaction.
CONSTITUTION: An aromatic nitro compound (e.g. nitrobenzene) and a lower aliphatic alcohol (e.g. methanol) or a phenol are made to react with CO in liquid phase in the presence of a catalyst containing a platinum-group metal (e.g. Pd, Rh, etc.) at 100W250°C to obtain an aromatic urethane. The amount of the alcohol or phenol is 2W400mol, pref. 5W50mol per 1mol of the nitro group of the aromatic nitro compound. The CO gas is prepared by passing a mixed gas containing CO2 and O2 through the layer of coke heated at ≥900°C. The exhaust gas obtained after the completion of the urethane-forming reaction is recycled to the above coke layer.
COPYRIGHT: (C)1982,JPO&Japio
JP55180254A 1980-12-19 1980-12-19 Preparation of aromatic urethane Pending JPS57102855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55180254A JPS57102855A (en) 1980-12-19 1980-12-19 Preparation of aromatic urethane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55180254A JPS57102855A (en) 1980-12-19 1980-12-19 Preparation of aromatic urethane

Publications (1)

Publication Number Publication Date
JPS57102855A true JPS57102855A (en) 1982-06-26

Family

ID=16080045

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55180254A Pending JPS57102855A (en) 1980-12-19 1980-12-19 Preparation of aromatic urethane

Country Status (1)

Country Link
JP (1) JPS57102855A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4603216A (en) * 1983-09-16 1986-07-29 Catalytica Associates Process for the preparation of urethanes
US4629804A (en) * 1983-09-16 1986-12-16 Catalytica Associates Process for preparation of urethanes

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55145654A (en) * 1979-05-01 1980-11-13 Mitsubishi Chem Ind Ltd Preparation of aromatic carbamic acid ester
JPS55147253A (en) * 1979-05-04 1980-11-17 Mitsubishi Chem Ind Ltd Preparation of aromatic carbamic acid ester

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55145654A (en) * 1979-05-01 1980-11-13 Mitsubishi Chem Ind Ltd Preparation of aromatic carbamic acid ester
JPS55147253A (en) * 1979-05-04 1980-11-17 Mitsubishi Chem Ind Ltd Preparation of aromatic carbamic acid ester

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4603216A (en) * 1983-09-16 1986-07-29 Catalytica Associates Process for the preparation of urethanes
US4629804A (en) * 1983-09-16 1986-12-16 Catalytica Associates Process for preparation of urethanes

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