JPS57102832A - Preparation of cyclopentenolones - Google Patents
Preparation of cyclopentenolonesInfo
- Publication number
- JPS57102832A JPS57102832A JP55178326A JP17832680A JPS57102832A JP S57102832 A JPS57102832 A JP S57102832A JP 55178326 A JP55178326 A JP 55178326A JP 17832680 A JP17832680 A JP 17832680A JP S57102832 A JPS57102832 A JP S57102832A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- acid
- pref
- aqueous solvent
- formulai
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Abstract
PURPOSE: To prepare the titled compound useful as an alcohol component of a useful pesticide, directly, in one step, in high yield, by heating a furancarbinol compound in water or in an aqueous solvent containing a small amount of organic solvent.
CONSTITUTION: The furancarbinol compound of formulaI(R1 is ≤6C cycloalkenyl group) is heated in an aqueous solvent in the presence or absence of pref. a metal salt such as magnesium chloride as a catalyst and/or a surface active agent, at pref. 20W200°C, esp. 80W180°C to obtain the compound of formula II. The pH of the reaction mixture is adjusted to 3W8 with an acid such as inorganic acid, e.g. sulfuric acid or organic acid, e.g. acetic acid, and a base such as an alkali metal, e.g. sodium. The amount of the aqueous solvent is 0.5W 100pts.wt. pref. 5W80pts.wt. per 1pt. of the compound of formulaI.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55178326A JPS57102832A (en) | 1980-12-16 | 1980-12-16 | Preparation of cyclopentenolones |
US06/324,135 US4398043A (en) | 1980-12-10 | 1981-11-23 | Process for preparing cyclopentenolones |
EP81110282A EP0053842B1 (en) | 1980-12-10 | 1981-12-09 | Process for preparing cyclopentenolones |
DE8181110282T DE3165126D1 (en) | 1980-12-10 | 1981-12-09 | Process for preparing cyclopentenolones |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55178326A JPS57102832A (en) | 1980-12-16 | 1980-12-16 | Preparation of cyclopentenolones |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57102832A true JPS57102832A (en) | 1982-06-26 |
JPS6254418B2 JPS6254418B2 (en) | 1987-11-14 |
Family
ID=16046524
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55178326A Granted JPS57102832A (en) | 1980-12-10 | 1980-12-16 | Preparation of cyclopentenolones |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57102832A (en) |
-
1980
- 1980-12-16 JP JP55178326A patent/JPS57102832A/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6254418B2 (en) | 1987-11-14 |
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