JPS5677280A - Iron porphyrin complex of proximal base type - Google Patents

Iron porphyrin complex of proximal base type

Info

Publication number
JPS5677280A
JPS5677280A JP16208180A JP16208180A JPS5677280A JP S5677280 A JPS5677280 A JP S5677280A JP 16208180 A JP16208180 A JP 16208180A JP 16208180 A JP16208180 A JP 16208180A JP S5677280 A JPS5677280 A JP S5677280A
Authority
JP
Japan
Prior art keywords
formula
added
solution
compound
aami
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16208180A
Other languages
Japanese (ja)
Other versions
JPS5810388B2 (en
Inventor
Hiroyuki Nishide
Manabu Kaneda
Yuichi Ono
Hidetoshi Tsuchida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP55162081A priority Critical patent/JPS5810388B2/en
Publication of JPS5677280A publication Critical patent/JPS5677280A/en
Publication of JPS5810388B2 publication Critical patent/JPS5810388B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

NEW MATERIAL:A compound shown by the formula I [P is an iron prophyrin complex having a porphyrin ring shown by the formula II, wherein iron (II) is coordinated in the center; X is H, 1W20C alkyl, or alkali metal; R is methyl or ethyl; n is 4W6]
USE: A gas absorbent. Useful for removing a very small amount of CO, NO, and O2 from a gas or useful as a cocatalyst in a catalytic reaction, etc.
PROCESS: Potassium phthalimide is reacted with an alkylene bromide and 2-methylimidazole successively to give a compound (AAMI) shown by the formula III. A compound shown by the formula IV (the circle sign is porphine; X' is alkyl) and triethylamine are dissolved in CH2Cl2, ethyl chloroformate is added to the solution at -10°C, and AAMI is added to the solution, or the compound show by the formula IV is dissolved in CH2Cl2, N,N'-dicyclohexylcarbodiimide is added to the solution at 0°C, and AAMI is added to the solution, so that the reaction is carried out to give a compound shown by the formula V, which is dissolved in DMF and reacted with FeCl2.nH2O in a gas flow under reflux to give a compound shown by the formula I.
COPYRIGHT: (C)1981,JPO&Japio
JP55162081A 1980-11-19 1980-11-19 Proximal base type iron porphyrin complex Expired JPS5810388B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55162081A JPS5810388B2 (en) 1980-11-19 1980-11-19 Proximal base type iron porphyrin complex

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55162081A JPS5810388B2 (en) 1980-11-19 1980-11-19 Proximal base type iron porphyrin complex

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP12563079A Division JPS5648244A (en) 1979-09-29 1979-09-29 Gas adsorbent

Publications (2)

Publication Number Publication Date
JPS5677280A true JPS5677280A (en) 1981-06-25
JPS5810388B2 JPS5810388B2 (en) 1983-02-25

Family

ID=15747717

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55162081A Expired JPS5810388B2 (en) 1980-11-19 1980-11-19 Proximal base type iron porphyrin complex

Country Status (1)

Country Link
JP (1) JPS5810388B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4977177A (en) * 1985-04-30 1990-12-11 Nippon Petrochemicals Company, Ltd. Tetrapyrrole polyaminomonocarboxylic acid therapeutic agents
CN101905114A (en) * 2010-08-07 2010-12-08 太原市恒远化工环保科技有限公司 High purification method of industrial tail gas containing oxynitride

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4977177A (en) * 1985-04-30 1990-12-11 Nippon Petrochemicals Company, Ltd. Tetrapyrrole polyaminomonocarboxylic acid therapeutic agents
CN101905114A (en) * 2010-08-07 2010-12-08 太原市恒远化工环保科技有限公司 High purification method of industrial tail gas containing oxynitride

Also Published As

Publication number Publication date
JPS5810388B2 (en) 1983-02-25

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