JPS56127384A - Cation picket fence-type tetraphenylporphyrine and gas adsorbent - Google Patents

Cation picket fence-type tetraphenylporphyrine and gas adsorbent

Info

Publication number
JPS56127384A
JPS56127384A JP3010580A JP3010580A JPS56127384A JP S56127384 A JPS56127384 A JP S56127384A JP 3010580 A JP3010580 A JP 3010580A JP 3010580 A JP3010580 A JP 3010580A JP S56127384 A JPS56127384 A JP S56127384A
Authority
JP
Japan
Prior art keywords
formula
compound
tetraphenylporphyrine
cation
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3010580A
Other languages
Japanese (ja)
Other versions
JPS5834478B2 (en
Inventor
Junko Shigehara
Yoshiki Sato
Hidetoshi Tsuchida
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP55030105A priority Critical patent/JPS5834478B2/en
Publication of JPS56127384A publication Critical patent/JPS56127384A/en
Publication of JPS5834478B2 publication Critical patent/JPS5834478B2/en
Expired legal-status Critical Current

Links

Landscapes

  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Gas Separation By Absorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

NEW MATERIAL:A cation picket fence-type tetraphenylporphyrine of formula I [R are groups of formula II (R' is methyl or ethyl) all of which are in the same side of the plane containing the porphyrine ring], or its complex having a ligand coordinated to the axial coordination site at the other side of the above plane.
EXAMPLE: FeIP - [ NHCOCH2N⊕(CH3)3Br⊖ ]4Br (IP is tetraphenylporphyrine ring).
USE: Gas adsorbent capable of reversibly adsorbing and desorbing O, CO, etc. in water at room temperature. Also it can be used as an oxygen carrier cocatalyst for oxygen addition reaction and for a fuel cell, or raw material of artificial blood.
PROCESS: Reaction of a compound of formula (R')2NH with bromoacetic acid gives the compound of formula III, which is made to react with triethylamine, etc. to afford the compound of formula IV. The product is treated with FeBr2, and the resulting compound of formula V is converted to the titled compound of formula I by the reaction with R'Br.
COPYRIGHT: (C)1981,JPO&Japio
JP55030105A 1980-03-10 1980-03-10 Cationic fence type iron tetraphenylporphyrin and gas adsorbent Expired JPS5834478B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP55030105A JPS5834478B2 (en) 1980-03-10 1980-03-10 Cationic fence type iron tetraphenylporphyrin and gas adsorbent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP55030105A JPS5834478B2 (en) 1980-03-10 1980-03-10 Cationic fence type iron tetraphenylporphyrin and gas adsorbent

Publications (2)

Publication Number Publication Date
JPS56127384A true JPS56127384A (en) 1981-10-06
JPS5834478B2 JPS5834478B2 (en) 1983-07-27

Family

ID=12294491

Family Applications (1)

Application Number Title Priority Date Filing Date
JP55030105A Expired JPS5834478B2 (en) 1980-03-10 1980-03-10 Cationic fence type iron tetraphenylporphyrin and gas adsorbent

Country Status (1)

Country Link
JP (1) JPS5834478B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4800188A (en) * 1987-03-20 1989-01-24 Hoechst Celanese Corp. Method for supporting metalloporphyrins on polybenzimidazole porous articles
US6444337B1 (en) 2000-09-26 2002-09-03 Energetics, Inc. Fuel cell with low cathodic polarization and high power density
KR101117633B1 (en) * 2004-06-30 2012-02-29 삼성에스디아이 주식회사 Carbon monoxide adsorbent for fuel cell, carbon monoxide remover for fuel cell, fuel cell system, and removal method using the carbon monoxide adsorbent
WO2013042695A1 (en) * 2011-09-21 2013-03-28 国立大学法人岡山大学 Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester.

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03113588U (en) * 1990-03-08 1991-11-20
ES2382651T3 (en) 2001-10-05 2012-06-12 Kao Corporation Aqueous solutions of high concentration of N, N-dialkylglycine and process for the production thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4800188A (en) * 1987-03-20 1989-01-24 Hoechst Celanese Corp. Method for supporting metalloporphyrins on polybenzimidazole porous articles
US6444337B1 (en) 2000-09-26 2002-09-03 Energetics, Inc. Fuel cell with low cathodic polarization and high power density
KR101117633B1 (en) * 2004-06-30 2012-02-29 삼성에스디아이 주식회사 Carbon monoxide adsorbent for fuel cell, carbon monoxide remover for fuel cell, fuel cell system, and removal method using the carbon monoxide adsorbent
WO2013042695A1 (en) * 2011-09-21 2013-03-28 国立大学法人岡山大学 Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester.
CN103987714A (en) * 2011-09-21 2014-08-13 国立大学法人冈山大学 Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester.
JPWO2013042695A1 (en) * 2011-09-21 2015-03-26 国立大学法人 岡山大学 Metal porphyrin complex, method for producing the same, carbon dioxide fixing catalyst comprising the same, and method for producing cyclic carbonate
US9211534B2 (en) 2011-09-21 2015-12-15 National University Corporation Okayama University Metalloporphyrin complex, manufacturing process therefor and carbon dioxide fixation catalyst therefrom, as well as process for manufacturing cyclic carbonate
EP2759546A4 (en) * 2011-09-21 2016-10-19 Univ Okayama Nat Univ Corp Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester.

Also Published As

Publication number Publication date
JPS5834478B2 (en) 1983-07-27

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