JPS56127384A - Cation picket fence-type tetraphenylporphyrine and gas adsorbent - Google Patents
Cation picket fence-type tetraphenylporphyrine and gas adsorbentInfo
- Publication number
- JPS56127384A JPS56127384A JP3010580A JP3010580A JPS56127384A JP S56127384 A JPS56127384 A JP S56127384A JP 3010580 A JP3010580 A JP 3010580A JP 3010580 A JP3010580 A JP 3010580A JP S56127384 A JPS56127384 A JP S56127384A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- tetraphenylporphyrine
- cation
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Gas Separation By Absorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
NEW MATERIAL:A cation picket fence-type tetraphenylporphyrine of formula I [R are groups of formula II (R' is methyl or ethyl) all of which are in the same side of the plane containing the porphyrine ring], or its complex having a ligand coordinated to the axial coordination site at the other side of the above plane.
EXAMPLE: FeIP - [ NHCOCH2N⊕(CH3)3Br⊖ ]4Br (IP is tetraphenylporphyrine ring).
USE: Gas adsorbent capable of reversibly adsorbing and desorbing O, CO, etc. in water at room temperature. Also it can be used as an oxygen carrier cocatalyst for oxygen addition reaction and for a fuel cell, or raw material of artificial blood.
PROCESS: Reaction of a compound of formula (R')2NH with bromoacetic acid gives the compound of formula III, which is made to react with triethylamine, etc. to afford the compound of formula IV. The product is treated with FeBr2, and the resulting compound of formula V is converted to the titled compound of formula I by the reaction with R'Br.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55030105A JPS5834478B2 (en) | 1980-03-10 | 1980-03-10 | Cationic fence type iron tetraphenylporphyrin and gas adsorbent |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP55030105A JPS5834478B2 (en) | 1980-03-10 | 1980-03-10 | Cationic fence type iron tetraphenylporphyrin and gas adsorbent |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56127384A true JPS56127384A (en) | 1981-10-06 |
JPS5834478B2 JPS5834478B2 (en) | 1983-07-27 |
Family
ID=12294491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP55030105A Expired JPS5834478B2 (en) | 1980-03-10 | 1980-03-10 | Cationic fence type iron tetraphenylporphyrin and gas adsorbent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5834478B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4800188A (en) * | 1987-03-20 | 1989-01-24 | Hoechst Celanese Corp. | Method for supporting metalloporphyrins on polybenzimidazole porous articles |
US6444337B1 (en) | 2000-09-26 | 2002-09-03 | Energetics, Inc. | Fuel cell with low cathodic polarization and high power density |
KR101117633B1 (en) * | 2004-06-30 | 2012-02-29 | 삼성에스디아이 주식회사 | Carbon monoxide adsorbent for fuel cell, carbon monoxide remover for fuel cell, fuel cell system, and removal method using the carbon monoxide adsorbent |
WO2013042695A1 (en) * | 2011-09-21 | 2013-03-28 | 国立大学法人岡山大学 | Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester. |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03113588U (en) * | 1990-03-08 | 1991-11-20 | ||
ES2382651T3 (en) | 2001-10-05 | 2012-06-12 | Kao Corporation | Aqueous solutions of high concentration of N, N-dialkylglycine and process for the production thereof |
-
1980
- 1980-03-10 JP JP55030105A patent/JPS5834478B2/en not_active Expired
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4800188A (en) * | 1987-03-20 | 1989-01-24 | Hoechst Celanese Corp. | Method for supporting metalloporphyrins on polybenzimidazole porous articles |
US6444337B1 (en) | 2000-09-26 | 2002-09-03 | Energetics, Inc. | Fuel cell with low cathodic polarization and high power density |
KR101117633B1 (en) * | 2004-06-30 | 2012-02-29 | 삼성에스디아이 주식회사 | Carbon monoxide adsorbent for fuel cell, carbon monoxide remover for fuel cell, fuel cell system, and removal method using the carbon monoxide adsorbent |
WO2013042695A1 (en) * | 2011-09-21 | 2013-03-28 | 国立大学法人岡山大学 | Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester. |
CN103987714A (en) * | 2011-09-21 | 2014-08-13 | 国立大学法人冈山大学 | Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester. |
JPWO2013042695A1 (en) * | 2011-09-21 | 2015-03-26 | 国立大学法人 岡山大学 | Metal porphyrin complex, method for producing the same, carbon dioxide fixing catalyst comprising the same, and method for producing cyclic carbonate |
US9211534B2 (en) | 2011-09-21 | 2015-12-15 | National University Corporation Okayama University | Metalloporphyrin complex, manufacturing process therefor and carbon dioxide fixation catalyst therefrom, as well as process for manufacturing cyclic carbonate |
EP2759546A4 (en) * | 2011-09-21 | 2016-10-19 | Univ Okayama Nat Univ Corp | Metal porphyrin complex, method for producing same, carbon dioxide immobilization catalyst comprising same, and method for producing cyclic carbonic acid ester. |
Also Published As
Publication number | Publication date |
---|---|
JPS5834478B2 (en) | 1983-07-27 |
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