JPS56133237A - Preparation of glycolic acid and alkoxyacetic acid or ester thereof - Google Patents

Preparation of glycolic acid and alkoxyacetic acid or ester thereof

Info

Publication number
JPS56133237A
JPS56133237A JP3587280A JP3587280A JPS56133237A JP S56133237 A JPS56133237 A JP S56133237A JP 3587280 A JP3587280 A JP 3587280A JP 3587280 A JP3587280 A JP 3587280A JP S56133237 A JPS56133237 A JP S56133237A
Authority
JP
Japan
Prior art keywords
ester
acid
alkoxyacetic
glycolic
alcoholysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3587280A
Other languages
Japanese (ja)
Other versions
JPS6356211B2 (en
Inventor
Hirosuke Wada
Akio Baba
Noboru Wada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP3587280A priority Critical patent/JPS56133237A/en
Priority to DE19813107518 priority patent/DE3107518A1/en
Publication of JPS56133237A publication Critical patent/JPS56133237A/en
Publication of JPS6356211B2 publication Critical patent/JPS6356211B2/ja
Granted legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE: To obtain the titled compounds in high yield, by subjecting the reaction product prepared by reacting formaldehyde with a formic ester and CO in the preesnce of a strong acidic catalyst to the hydrolysis or alcoholysis to decompose the condensed dimer.
CONSTITUTION: A reaction product obtained by reacting formaldehyde wit a formic ester and CO in the presence of a strong acidic catalyst, e.g. strongly acidic cationic resin, mainly a compound of formula I (R is 1W10C alkyl) to formula VI, is hydrolyzed or alcoholized to give glycolic acid or an alkoxyacetic acid or an ester thereof. The condensed dimers expressed by the formulas IVWVI are converted into a glycolic ester, alkoxyacetic ester or alkoxyacetic acid by the hydrolysis or alcoholysis. High-boiling substances other than the dimers are almost decomposed and converted into the compounds expressed by formulas IWIII.
COPYRIGHT: (C)1981,JPO&Japio
JP3587280A 1980-02-29 1980-03-21 Preparation of glycolic acid and alkoxyacetic acid or ester thereof Granted JPS56133237A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP3587280A JPS56133237A (en) 1980-03-21 1980-03-21 Preparation of glycolic acid and alkoxyacetic acid or ester thereof
DE19813107518 DE3107518A1 (en) 1980-02-29 1981-02-27 Process for the preparation of esters and ethers of glycolic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3587280A JPS56133237A (en) 1980-03-21 1980-03-21 Preparation of glycolic acid and alkoxyacetic acid or ester thereof

Publications (2)

Publication Number Publication Date
JPS56133237A true JPS56133237A (en) 1981-10-19
JPS6356211B2 JPS6356211B2 (en) 1988-11-07

Family

ID=12454079

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3587280A Granted JPS56133237A (en) 1980-02-29 1980-03-21 Preparation of glycolic acid and alkoxyacetic acid or ester thereof

Country Status (1)

Country Link
JP (1) JPS56133237A (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0088529A2 (en) * 1982-03-08 1983-09-14 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing alkoxyacetic esters
CN1064040C (en) * 1997-09-29 2001-04-04 中国科学院成都有机化学研究所 Method and catalyst of synthesis of methyl glycolate
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
JP2015517992A (en) * 2012-03-27 2015-06-25 イーストマン ケミカル カンパニー Method for collecting and recycling acid catalyst
US10329230B2 (en) 2010-08-18 2019-06-25 Eastman Chemical Company Process for the separation and purification of a mixed diol stream

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0088529A2 (en) * 1982-03-08 1983-09-14 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing alkoxyacetic esters
EP0088529A3 (en) * 1982-03-08 1984-03-21 Toa Nenryo Kogyo Kabushiki Kaisha Process for producing alkoxyacetic esters
CN1064040C (en) * 1997-09-29 2001-04-04 中国科学院成都有机化学研究所 Method and catalyst of synthesis of methyl glycolate
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8779214B2 (en) 2010-08-18 2014-07-15 Eastman Chemical Company Methods for recovery and recycle of ruthenium homogenous catalysts
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US10329230B2 (en) 2010-08-18 2019-06-25 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
JP2015517992A (en) * 2012-03-27 2015-06-25 イーストマン ケミカル カンパニー Method for collecting and recycling acid catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration

Also Published As

Publication number Publication date
JPS6356211B2 (en) 1988-11-07

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