JPS55124730A - Preparation of dihydroxydiphenylmethane - Google Patents

Preparation of dihydroxydiphenylmethane

Info

Publication number
JPS55124730A
JPS55124730A JP3219179A JP3219179A JPS55124730A JP S55124730 A JPS55124730 A JP S55124730A JP 3219179 A JP3219179 A JP 3219179A JP 3219179 A JP3219179 A JP 3219179A JP S55124730 A JPS55124730 A JP S55124730A
Authority
JP
Japan
Prior art keywords
dihydroxydiphenylmethane
phenol
title compound
excessive
oxalic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP3219179A
Other languages
Japanese (ja)
Inventor
Yoshio Umemura
Shunichi Hamamoto
Motojiro Aoi
Yoshikazu Goto
Hiroshi Hoshiide
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ube Corp
Original Assignee
Ube Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ube Industries Ltd filed Critical Ube Industries Ltd
Priority to JP3219179A priority Critical patent/JPS55124730A/en
Publication of JPS55124730A publication Critical patent/JPS55124730A/en
Pending legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PURPOSE: To obtain the title compound suitable for a raw material for an epoxy resin, having a specific composition, in high yield, by the reaction of phenol with HCHO in a specific ratio in the presence of oxalic acid in an inert atmosphere, and then by removing the excessive phenol through distillation.
CONSTITUTION: Phenol (P) is reacted with formaldehyde (F) in the molar ratio range of F to P of 0.02W0.04:1, in the presence of oxalic acid in an amount of 0.01W5wt% based on P, in an inert atmosphere, at 50W110°C, and the excessive P is distilled out of the reaction product to obtain the title compound containing 10W 25wt% of 2,2'-dihydroxydiphenylmethane, 40W60wt% of 2,4-dihydroxydiphenylmethane, and 25W40wt% of 4,4'-dihydroxydiphenylmethane, in high yield, with controlled contents unreacted P and high-degree condensate.
COPYRIGHT: (C)1980,JPO&Japio
JP3219179A 1979-03-22 1979-03-22 Preparation of dihydroxydiphenylmethane Pending JPS55124730A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP3219179A JPS55124730A (en) 1979-03-22 1979-03-22 Preparation of dihydroxydiphenylmethane

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP3219179A JPS55124730A (en) 1979-03-22 1979-03-22 Preparation of dihydroxydiphenylmethane

Publications (1)

Publication Number Publication Date
JPS55124730A true JPS55124730A (en) 1980-09-26

Family

ID=12352001

Family Applications (1)

Application Number Title Priority Date Filing Date
JP3219179A Pending JPS55124730A (en) 1979-03-22 1979-03-22 Preparation of dihydroxydiphenylmethane

Country Status (1)

Country Link
JP (1) JPS55124730A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0436254A (en) * 1990-05-31 1992-02-06 Mitsui Toatsu Chem Inc Production of dehydroxydiphenylmethane
JPH06128183A (en) * 1992-02-27 1994-05-10 Mitsui Toatsu Chem Inc Method for simultaneous production of bisphenol f and novolak type phenolic resin
JPH06211715A (en) * 1993-01-22 1994-08-02 Mitsui Toatsu Chem Inc Production of bisphenol f
EP0557999A3 (en) * 1992-02-27 1995-09-06 Mitsui Toatsu Chemicals Method for simultaneous preparation of bisphenol f and novolak phenol resins
JPH07330647A (en) * 1994-06-07 1995-12-19 Nippon Steel Chem Co Ltd Production of bisphenol compound
JPH08120038A (en) * 1994-10-24 1996-05-14 Honshu Chem Ind Co Ltd Liquid phenol novolak resin and its production
JPH08311141A (en) * 1995-05-19 1996-11-26 Kishimoto Akira Resol type phenolic resin and coating therefrom
US5739186A (en) * 1994-10-07 1998-04-14 Shell Oil Company Epoxy resin composition for semiconductor encapsulation
JP2011068760A (en) * 2009-09-25 2011-04-07 Dic Corp Method for producing bisphenol f in combination with novolak-type phenol resin
CN102516035A (en) * 2011-12-19 2012-06-27 胶州市精细化工有限公司 Preparation method of bisphenol F
JP2018177660A (en) * 2017-04-06 2018-11-15 エヌ・イーケムキャット株式会社 Phenol derivative selective methylation method
JP2021031428A (en) * 2019-08-22 2021-03-01 株式会社日本触媒 Method for Producing Ether Bond-Containing Compound

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5281848A (en) * 1975-12-26 1977-07-08 Chugoku Seiki Winch automatic hydraulic control wire shifter

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5281848A (en) * 1975-12-26 1977-07-08 Chugoku Seiki Winch automatic hydraulic control wire shifter

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0436254A (en) * 1990-05-31 1992-02-06 Mitsui Toatsu Chem Inc Production of dehydroxydiphenylmethane
JPH06128183A (en) * 1992-02-27 1994-05-10 Mitsui Toatsu Chem Inc Method for simultaneous production of bisphenol f and novolak type phenolic resin
EP0557999A3 (en) * 1992-02-27 1995-09-06 Mitsui Toatsu Chemicals Method for simultaneous preparation of bisphenol f and novolak phenol resins
JPH06211715A (en) * 1993-01-22 1994-08-02 Mitsui Toatsu Chem Inc Production of bisphenol f
JPH07330647A (en) * 1994-06-07 1995-12-19 Nippon Steel Chem Co Ltd Production of bisphenol compound
US5739186A (en) * 1994-10-07 1998-04-14 Shell Oil Company Epoxy resin composition for semiconductor encapsulation
JPH08120038A (en) * 1994-10-24 1996-05-14 Honshu Chem Ind Co Ltd Liquid phenol novolak resin and its production
JPH08311141A (en) * 1995-05-19 1996-11-26 Kishimoto Akira Resol type phenolic resin and coating therefrom
JP2011068760A (en) * 2009-09-25 2011-04-07 Dic Corp Method for producing bisphenol f in combination with novolak-type phenol resin
CN102516035A (en) * 2011-12-19 2012-06-27 胶州市精细化工有限公司 Preparation method of bisphenol F
JP2018177660A (en) * 2017-04-06 2018-11-15 エヌ・イーケムキャット株式会社 Phenol derivative selective methylation method
JP2021031428A (en) * 2019-08-22 2021-03-01 株式会社日本触媒 Method for Producing Ether Bond-Containing Compound

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