JPS5455537A - Preparation of dinitrobiphenyl ethers - Google Patents
Preparation of dinitrobiphenyl ethersInfo
- Publication number
- JPS5455537A JPS5455537A JP11860377A JP11860377A JPS5455537A JP S5455537 A JPS5455537 A JP S5455537A JP 11860377 A JP11860377 A JP 11860377A JP 11860377 A JP11860377 A JP 11860377A JP S5455537 A JPS5455537 A JP S5455537A
- Authority
- JP
- Japan
- Prior art keywords
- dinitrobiphenyl
- ethers
- halonitrobenzenes
- hydrogencarbonates
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the title compounds useful as raw materials for medicines, pesticides, synthetic resins, etc., by reacting halonitrobenzenes only with alkali metal carbonates or hydrogencarbonates in the presence of nitrous ions in a polar aprotic solvent.
CONSTITUTION: Halonitrobenzenes, e.g. p-chloronitrobenzene, etc. of formula I: (X is halogen; Y1 and Y2 are H, alkyl, alkoxy, or carboxyl groups; n is 1 or 2, at least one of the nitro groups is at the o- or p-position to X) are reacted with alkali metal carbonates, e.g. sodium carbonate, etc., or hydrogencarbonates in the presence of nitrous ions, e.g. sodium nitrite, etc., in an amount of 0.005W0.5 mole per mole of the starting materials in a polar aprotic solvent, e.g. dimethyl sulfoxide, etc. to give dinitrobiphenyl ethers, e.g. bis(4-nitrophenyl)ether, etc. of formula II.
EFFECT: Expensive K salts are unnecessary
COPYRIGHT: (C)1979,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11860377A JPS5455537A (en) | 1977-10-04 | 1977-10-04 | Preparation of dinitrobiphenyl ethers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11860377A JPS5455537A (en) | 1977-10-04 | 1977-10-04 | Preparation of dinitrobiphenyl ethers |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5455537A true JPS5455537A (en) | 1979-05-02 |
JPS5748058B2 JPS5748058B2 (en) | 1982-10-14 |
Family
ID=14740647
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11860377A Granted JPS5455537A (en) | 1977-10-04 | 1977-10-04 | Preparation of dinitrobiphenyl ethers |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5455537A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007324894A (en) * | 2006-05-31 | 2007-12-13 | Japan Radio Co Ltd | Tone signal detection circuit for radio equipment |
-
1977
- 1977-10-04 JP JP11860377A patent/JPS5455537A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007324894A (en) * | 2006-05-31 | 2007-12-13 | Japan Radio Co Ltd | Tone signal detection circuit for radio equipment |
Also Published As
Publication number | Publication date |
---|---|
JPS5748058B2 (en) | 1982-10-14 |
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