JPS56158740A - Preparation of dinitrodiphenyl ethers - Google Patents
Preparation of dinitrodiphenyl ethersInfo
- Publication number
- JPS56158740A JPS56158740A JP6170780A JP6170780A JPS56158740A JP S56158740 A JPS56158740 A JP S56158740A JP 6170780 A JP6170780 A JP 6170780A JP 6170780 A JP6170780 A JP 6170780A JP S56158740 A JPS56158740 A JP S56158740A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- compound
- halonitrobenzene
- carbonate
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain easily the titled compound useful as a raw material for preparing a drug, agricultural chemical, synthetic resin, etc., by reacting a halonitrobenzene with a compound of an alkali metal in the presence of nitric ion in a polar organic solvent.
CONSTITUTION: A halonitrobenzene (e.g., parachloronitrobenzene, etc.) shown by the formula I (X is halogen; Y1 and Y2 are H, alkyl, alkoxy, etc.; n is 1 or 2; at least one of nitro groups is located at ortho- or paraposition based on X) is reacted with a compound of an alkali metal (e.g., NaOH, KOH, Li OH, etc.) [with the proviso that carbonate and hydrogen-carbonate are omitted] in a polar organic solvent (e.g., DMF, DMS, dioxane, etc.) in the presence of nitric ion, to give the titled compound shown by the formula II. Paradinitrobenzene, etc. is used as the nitric ion and its amount is 0.001mol ≤ to <1 mole based on 1mol of the compound shown by the formula I.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6170780A JPS56158740A (en) | 1980-05-12 | 1980-05-12 | Preparation of dinitrodiphenyl ethers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6170780A JPS56158740A (en) | 1980-05-12 | 1980-05-12 | Preparation of dinitrodiphenyl ethers |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS56158740A true JPS56158740A (en) | 1981-12-07 |
Family
ID=13178965
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6170780A Pending JPS56158740A (en) | 1980-05-12 | 1980-05-12 | Preparation of dinitrodiphenyl ethers |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56158740A (en) |
-
1980
- 1980-05-12 JP JP6170780A patent/JPS56158740A/en active Pending
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