JPS5647406A - Production of immobilized crown compound - Google Patents

Production of immobilized crown compound

Info

Publication number
JPS5647406A
JPS5647406A JP12502779A JP12502779A JPS5647406A JP S5647406 A JPS5647406 A JP S5647406A JP 12502779 A JP12502779 A JP 12502779A JP 12502779 A JP12502779 A JP 12502779A JP S5647406 A JPS5647406 A JP S5647406A
Authority
JP
Japan
Prior art keywords
chloromethylated
integer
amino group
formula
produce
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12502779A
Other languages
Japanese (ja)
Inventor
Tetsuyoshi Suzuki
Hidekazu Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP12502779A priority Critical patent/JPS5647406A/en
Publication of JPS5647406A publication Critical patent/JPS5647406A/en
Pending legal-status Critical Current

Links

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  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PURPOSE:A specific crown ether bearing an amino group is made to react with a chloromethylated and crosslinked polystyrene to produce the titled compound that is used as an interphase transferring catalyst, metal capturing agent or separator because of its readily recoverably properties and no toxicity in high efficiency. CONSTITUTION:The reaction of (A) a crown ether bearing an amino group of formula I (l is integer of 1-7) or formula II (m, n are 0 or integer of 1-6) such as aminobenzo-15-crown-5, with (B) a chloromethylated and crosslinked polystyrene is conducted in a solvent such as dimethylformamide in a nitrogen atmosphere at room temperature to 150 deg.C to produce the objective compound. The preferred amount of component A is 1-10 times equivalents of the chlorine atoms in component B. By using this resin, both of sodium and potassium salts are separated from a mixed aqueous solution containing them.
JP12502779A 1979-09-28 1979-09-28 Production of immobilized crown compound Pending JPS5647406A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP12502779A JPS5647406A (en) 1979-09-28 1979-09-28 Production of immobilized crown compound

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12502779A JPS5647406A (en) 1979-09-28 1979-09-28 Production of immobilized crown compound

Publications (1)

Publication Number Publication Date
JPS5647406A true JPS5647406A (en) 1981-04-30

Family

ID=14900027

Family Applications (1)

Application Number Title Priority Date Filing Date
JP12502779A Pending JPS5647406A (en) 1979-09-28 1979-09-28 Production of immobilized crown compound

Country Status (1)

Country Link
JP (1) JPS5647406A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0320489A (en) * 1989-06-19 1991-01-29 Chlorine Eng Corp Ltd Production of tetraalkylammonium hydroxide
WO2014019501A1 (en) * 2012-08-03 2014-02-06 天津工业大学 Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof
JP2017520667A (en) * 2014-04-03 2017-07-27 ユニヴェルシテ パリ−スュッドＵｎｉｖｅｒｓｉｔｅ Ｐａｒｉｓ−Ｓｕｄ A novel complex for the separation of cations.
CN117225476A (en) * 2023-11-15 2023-12-15 山东华夏神舟新材料有限公司 Supported metal catalyst and preparation and regeneration methods and application thereof
US11993827B2 (en) 2018-07-06 2024-05-28 Moselle Technologies, Llc Methods and compositions for recovery of lithium from liquid solutions with nanoparticles

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0320489A (en) * 1989-06-19 1991-01-29 Chlorine Eng Corp Ltd Production of tetraalkylammonium hydroxide
WO2014019501A1 (en) * 2012-08-03 2014-02-06 天津工业大学 Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof
KR20150058153A (en) * 2012-08-03 2015-05-28 티엔진 폴리테크닉 유니버시티 Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof
US9988466B2 (en) 2012-08-03 2018-06-05 Tianjin Polytechnic University Benzocrown ether graft polymer with lithium isotopic separation effect and preparation method thereof
JP2017520667A (en) * 2014-04-03 2017-07-27 ユニヴェルシテ パリ−スュッドＵｎｉｖｅｒｓｉｔｅ Ｐａｒｉｓ−Ｓｕｄ A novel complex for the separation of cations.
US11993827B2 (en) 2018-07-06 2024-05-28 Moselle Technologies, Llc Methods and compositions for recovery of lithium from liquid solutions with nanoparticles
CN117225476A (en) * 2023-11-15 2023-12-15 山东华夏神舟新材料有限公司 Supported metal catalyst and preparation and regeneration methods and application thereof
CN117225476B (en) * 2023-11-15 2024-02-20 山东华夏神舟新材料有限公司 Supported metal catalyst and preparation and regeneration methods and application thereof

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