JPS5665838A - Preparation of beta-alkoxymethoxymethyl halide - Google Patents
Preparation of beta-alkoxymethoxymethyl halideInfo
- Publication number
- JPS5665838A JPS5665838A JP14173479A JP14173479A JPS5665838A JP S5665838 A JPS5665838 A JP S5665838A JP 14173479 A JP14173479 A JP 14173479A JP 14173479 A JP14173479 A JP 14173479A JP S5665838 A JPS5665838 A JP S5665838A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- expressed
- formula
- halide
- alkoxyethoxymethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
PURPOSE: To obtain the titled compound through simple operations in two stage without using a solid dehydrating agent, by the reaction of a β-alkoxyethyl alcohol with HCHO and subsequently with a halogenating agent forming no water.
CONSTITUTION: A β-alkoxyethyl alcohol expressed by formula I (R1 is lower alkyl) is lower alkyl) is reacted with formaldehyde, and the resultant compound, a β-alkoxymethyl alcohol expressed by formula II, is reacted with a halogenating agent forming no water, e.g. thionyl chloride or bromide, to give a β-alkoxyethoxymethyl halide expressed by formula III (X is halogen). After the reaction is carried out in the first stage the unreacted raw material alcohol and HCHO are eliminated by distillation, etc., and the used acid catalyst is also removed, to separate the β-alkoxyethoxymethyl alcohol.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14173479A JPS6049170B2 (en) | 1979-10-31 | 1979-10-31 | Method for producing β-alkoxyethoxymethyl halide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14173479A JPS6049170B2 (en) | 1979-10-31 | 1979-10-31 | Method for producing β-alkoxyethoxymethyl halide |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5665838A true JPS5665838A (en) | 1981-06-03 |
JPS6049170B2 JPS6049170B2 (en) | 1985-10-31 |
Family
ID=15298957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14173479A Expired JPS6049170B2 (en) | 1979-10-31 | 1979-10-31 | Method for producing β-alkoxyethoxymethyl halide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6049170B2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0679627A1 (en) * | 1994-04-28 | 1995-11-02 | Säurefabrik Schweizerhall | Process for the preparation of halogenated ethers |
JP2010504917A (en) * | 2006-09-29 | 2010-02-18 | クリスタリア プロデュトス キミコス ファーマシューティコス リミターダ | Method for producing fluoromethyl 2,2,2-trifluoro-1- (trifluoromethyl) ethyl ether |
JP2010504916A (en) * | 2006-09-29 | 2010-02-18 | クリスタリア プロデュトス キミコス ファーマシューティコス リミターダ | Method for producing chloromethyl 2,2,2-trifluoro-1- (trifluoromethyl) ethyl ether |
CN102295537A (en) * | 2010-06-25 | 2011-12-28 | 吉林师范大学 | Method for producing methoxyethyl chloromethyl ether |
-
1979
- 1979-10-31 JP JP14173479A patent/JPS6049170B2/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0679627A1 (en) * | 1994-04-28 | 1995-11-02 | Säurefabrik Schweizerhall | Process for the preparation of halogenated ethers |
JP2010504917A (en) * | 2006-09-29 | 2010-02-18 | クリスタリア プロデュトス キミコス ファーマシューティコス リミターダ | Method for producing fluoromethyl 2,2,2-trifluoro-1- (trifluoromethyl) ethyl ether |
JP2010504916A (en) * | 2006-09-29 | 2010-02-18 | クリスタリア プロデュトス キミコス ファーマシューティコス リミターダ | Method for producing chloromethyl 2,2,2-trifluoro-1- (trifluoromethyl) ethyl ether |
CN102295537A (en) * | 2010-06-25 | 2011-12-28 | 吉林师范大学 | Method for producing methoxyethyl chloromethyl ether |
Also Published As
Publication number | Publication date |
---|---|
JPS6049170B2 (en) | 1985-10-31 |
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