JPH11349701A - 不透明着色軟質樹脂シート及びその製造方法 - Google Patents
不透明着色軟質樹脂シート及びその製造方法Info
- Publication number
- JPH11349701A JPH11349701A JP10157819A JP15781998A JPH11349701A JP H11349701 A JPH11349701 A JP H11349701A JP 10157819 A JP10157819 A JP 10157819A JP 15781998 A JP15781998 A JP 15781998A JP H11349701 A JPH11349701 A JP H11349701A
- Authority
- JP
- Japan
- Prior art keywords
- resin sheet
- opaque colored
- soft resin
- colored soft
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 306
- 239000011347 resin Substances 0.000 title claims abstract description 306
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 73
- 238000001816 cooling Methods 0.000 claims abstract description 111
- 229910052751 metal Inorganic materials 0.000 claims abstract description 56
- 239000002184 metal Substances 0.000 claims abstract description 56
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 48
- 239000013013 elastic material Substances 0.000 claims abstract description 29
- 230000003746 surface roughness Effects 0.000 claims abstract description 18
- 239000004743 Polypropylene Substances 0.000 claims description 54
- 229920001155 polypropylene Polymers 0.000 claims description 53
- -1 polypropylene Polymers 0.000 claims description 53
- 229920001577 copolymer Polymers 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 25
- 239000005977 Ethylene Substances 0.000 claims description 24
- 238000003825 pressing Methods 0.000 claims description 16
- 229920005674 ethylene-propylene random copolymer Polymers 0.000 claims description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 12
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 11
- 229920005673 polypropylene based resin Polymers 0.000 claims description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 10
- 238000009835 boiling Methods 0.000 claims description 8
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 8
- 230000002093 peripheral effect Effects 0.000 claims description 8
- 238000000137 annealing Methods 0.000 claims description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 7
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 7
- 229920001684 low density polyethylene Polymers 0.000 claims description 7
- 239000004702 low-density polyethylene Substances 0.000 claims description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000498 cooling water Substances 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 230000005489 elastic deformation Effects 0.000 claims description 5
- 229920001971 elastomer Polymers 0.000 claims description 5
- 239000005062 Polybutadiene Substances 0.000 claims description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 4
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 4
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims description 4
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 claims description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 239000005042 ethylene-ethyl acrylate Substances 0.000 claims description 2
- 239000012968 metallocene catalyst Substances 0.000 claims description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 2
- 230000003287 optical effect Effects 0.000 abstract description 4
- 239000010410 layer Substances 0.000 description 58
- 230000000052 comparative effect Effects 0.000 description 33
- 239000003086 colorant Substances 0.000 description 31
- 239000002344 surface layer Substances 0.000 description 23
- 239000002994 raw material Substances 0.000 description 17
- 239000011342 resin composition Substances 0.000 description 11
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 10
- 239000004800 polyvinyl chloride Substances 0.000 description 9
- 229920000915 polyvinyl chloride Polymers 0.000 description 9
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 229920000034 Plastomer Polymers 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 229920001973 fluoroelastomer Polymers 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- GJTGYNPBJNRYKI-UHFFFAOYSA-N hex-1-ene;prop-1-ene Chemical compound CC=C.CCCCC=C GJTGYNPBJNRYKI-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10157819A JPH11349701A (ja) | 1998-06-05 | 1998-06-05 | 不透明着色軟質樹脂シート及びその製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10157819A JPH11349701A (ja) | 1998-06-05 | 1998-06-05 | 不透明着色軟質樹脂シート及びその製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11349701A true JPH11349701A (ja) | 1999-12-21 |
| JPH11349701A5 JPH11349701A5 (enExample) | 2005-09-08 |
Family
ID=15658008
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10157819A Pending JPH11349701A (ja) | 1998-06-05 | 1998-06-05 | 不透明着色軟質樹脂シート及びその製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11349701A (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002264261A (ja) * | 2001-03-14 | 2002-09-18 | Oguri Mokko Kk | 積層シート、積層体及び積層体の製造方法 |
| JP2006321990A (ja) * | 2005-04-22 | 2006-11-30 | Asahi Kasei Chemicals Corp | 容器包装用エチレン系樹脂 |
| JP2008018731A (ja) * | 2007-10-05 | 2008-01-31 | Idemitsu Unitech Co Ltd | 透明ポリプロピレンシートの製造方法および透明ポリプロピレンシート |
-
1998
- 1998-06-05 JP JP10157819A patent/JPH11349701A/ja active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002264261A (ja) * | 2001-03-14 | 2002-09-18 | Oguri Mokko Kk | 積層シート、積層体及び積層体の製造方法 |
| JP2006321990A (ja) * | 2005-04-22 | 2006-11-30 | Asahi Kasei Chemicals Corp | 容器包装用エチレン系樹脂 |
| JP2008018731A (ja) * | 2007-10-05 | 2008-01-31 | Idemitsu Unitech Co Ltd | 透明ポリプロピレンシートの製造方法および透明ポリプロピレンシート |
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