JPH11202549A - トナーおよび画像形成方法 - Google Patents
トナーおよび画像形成方法Info
- Publication number
- JPH11202549A JPH11202549A JP33105397A JP33105397A JPH11202549A JP H11202549 A JPH11202549 A JP H11202549A JP 33105397 A JP33105397 A JP 33105397A JP 33105397 A JP33105397 A JP 33105397A JP H11202549 A JPH11202549 A JP H11202549A
- Authority
- JP
- Japan
- Prior art keywords
- toner
- curable
- toner binder
- binder
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 92
- 239000011230 binding agent Substances 0.000 claims abstract description 103
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 28
- 239000003086 colorant Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 17
- 238000003860 storage Methods 0.000 claims abstract description 17
- 229920001225 polyester resin Polymers 0.000 claims abstract description 11
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical group C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004645 polyester resin Substances 0.000 claims abstract description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 10
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 10
- 229920001567 vinyl ester resin Chemical group 0.000 claims abstract description 7
- 239000001043 yellow dye Substances 0.000 claims abstract 2
- 239000001052 yellow pigment Substances 0.000 claims abstract 2
- 238000001723 curing Methods 0.000 claims description 20
- 125000000524 functional group Chemical group 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 239000007870 radical polymerization initiator Substances 0.000 claims description 10
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
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- 239000000463 material Substances 0.000 claims description 5
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- 229940123973 Oxygen scavenger Drugs 0.000 claims description 4
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- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical group C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 2
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- -1 acryl functional groups Chemical group 0.000 abstract description 35
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- 239000000178 monomer Substances 0.000 description 22
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- 238000011156 evaluation Methods 0.000 description 11
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- 238000004519 manufacturing process Methods 0.000 description 11
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 239000003999 initiator Substances 0.000 description 9
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- 150000003077 polyols Chemical class 0.000 description 8
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
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- 239000007787 solid Substances 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- WPSWDCBWMRJJED-UHFFFAOYSA-N 4-[2-(4-hydroxyphenyl)propan-2-yl]phenol;oxirane Chemical compound C1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 WPSWDCBWMRJJED-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000005056 polyisocyanate Substances 0.000 description 6
- 229920001228 polyisocyanate Polymers 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 229930185605 Bisphenol Natural products 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 125000002947 alkylene group Chemical group 0.000 description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 5
- 229920005792 styrene-acrylic resin Polymers 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000001476 alcoholic effect Effects 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
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- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- 239000008096 xylene Substances 0.000 description 4
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 3
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- 239000002981 blocking agent Substances 0.000 description 3
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- 229910052739 hydrogen Inorganic materials 0.000 description 3
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
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- DMBUODUULYCPAK-UHFFFAOYSA-N 1,3-bis(docosanoyloxy)propan-2-yl docosanoate Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCCCCCC DMBUODUULYCPAK-UHFFFAOYSA-N 0.000 description 2
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- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- OKYDCMQQLGECPI-UHFFFAOYSA-N thiopyrylium Chemical class C1=CC=[S+]C=C1 OKYDCMQQLGECPI-UHFFFAOYSA-N 0.000 description 1
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- UCCYOMWTNBHGGY-UHFFFAOYSA-N trioctadecyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCCCCCCCCCCCC)C(C(=O)OCCCCCCCCCCCCCCCCCC)=C1 UCCYOMWTNBHGGY-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Developing Agents For Electrophotography (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33105397A JPH11202549A (ja) | 1996-11-15 | 1997-11-14 | トナーおよび画像形成方法 |
Applications Claiming Priority (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32110996 | 1996-11-15 | ||
| JP2592397 | 1997-01-24 | ||
| JP2592497 | 1997-01-24 | ||
| JP9-25923 | 1997-11-13 | ||
| JP8-321109 | 1997-11-13 | ||
| JP9-331111 | 1997-11-13 | ||
| JP9-25924 | 1997-11-13 | ||
| JP33111197 | 1997-11-13 | ||
| JP33105397A JPH11202549A (ja) | 1996-11-15 | 1997-11-14 | トナーおよび画像形成方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH11202549A true JPH11202549A (ja) | 1999-07-30 |
| JPH11202549A5 JPH11202549A5 (https=) | 2005-07-14 |
Family
ID=27520786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33105397A Pending JPH11202549A (ja) | 1996-11-15 | 1997-11-14 | トナーおよび画像形成方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH11202549A (https=) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007156463A (ja) * | 2005-11-30 | 2007-06-21 | Xerox Corp | トナー組成物および方法 |
| JP2011100129A (ja) * | 2009-11-03 | 2011-05-19 | Xerox Corp | ケミカルトナー組成物および転写印刷方法 |
| JP2015094948A (ja) * | 2013-11-11 | 2015-05-18 | ゼロックス コーポレイションＸｅｒｏｘ Ｃｏｒｐｏｒａｔｉｏｎ | 結晶性芳香族エーテルを含む超低融点トナー |
| JP2016218392A (ja) * | 2015-05-26 | 2016-12-22 | 花王株式会社 | 電子写真用トナー |
| WO2017171099A1 (ja) * | 2016-03-31 | 2017-10-05 | キヤノン株式会社 | 画像形成装置 |
| US10429761B2 (en) | 2016-03-31 | 2019-10-01 | Canon Kabushiki Kaisha | Image forming apparatus using ultraviolet and infrared radiation |
-
1997
- 1997-11-14 JP JP33105397A patent/JPH11202549A/ja active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007156463A (ja) * | 2005-11-30 | 2007-06-21 | Xerox Corp | トナー組成物および方法 |
| JP2011100129A (ja) * | 2009-11-03 | 2011-05-19 | Xerox Corp | ケミカルトナー組成物および転写印刷方法 |
| JP2015094948A (ja) * | 2013-11-11 | 2015-05-18 | ゼロックス コーポレイションＸｅｒｏｘ Ｃｏｒｐｏｒａｔｉｏｎ | 結晶性芳香族エーテルを含む超低融点トナー |
| JP2016218392A (ja) * | 2015-05-26 | 2016-12-22 | 花王株式会社 | 電子写真用トナー |
| WO2017171099A1 (ja) * | 2016-03-31 | 2017-10-05 | キヤノン株式会社 | 画像形成装置 |
| US10429761B2 (en) | 2016-03-31 | 2019-10-01 | Canon Kabushiki Kaisha | Image forming apparatus using ultraviolet and infrared radiation |
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