JPH09509972A - アミノ及びフルオロ基含有シロキサンなど - Google Patents
アミノ及びフルオロ基含有シロキサンなどInfo
- Publication number
- JPH09509972A JPH09509972A JP7523017A JP52301795A JPH09509972A JP H09509972 A JPH09509972 A JP H09509972A JP 7523017 A JP7523017 A JP 7523017A JP 52301795 A JP52301795 A JP 52301795A JP H09509972 A JPH09509972 A JP H09509972A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- phenyl
- siloxane
- hydrocarbyl
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 title claims description 37
- 125000003277 amino group Chemical group 0.000 title description 2
- 125000001153 fluoro group Chemical group F* 0.000 title description 2
- 239000000839 emulsion Substances 0.000 claims abstract description 75
- -1 fluorocarbon siloxanes Chemical class 0.000 claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000000758 substrate Substances 0.000 claims abstract description 34
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 25
- 125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 13
- 125000004966 cyanoalkyl group Chemical group 0.000 claims abstract description 11
- 238000009833 condensation Methods 0.000 claims abstract description 10
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims abstract description 7
- 125000004103 aminoalkyl group Chemical group 0.000 claims abstract 3
- 239000003995 emulsifying agent Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- 125000003709 fluoroalkyl group Chemical group 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims 4
- 230000005494 condensation Effects 0.000 abstract description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 238000001556 precipitation Methods 0.000 abstract description 4
- 238000010336 energy treatment Methods 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 33
- 239000000203 mixture Substances 0.000 description 29
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 28
- 229910000077 silane Inorganic materials 0.000 description 26
- 239000003054 catalyst Substances 0.000 description 19
- 239000003921 oil Substances 0.000 description 17
- 229920001296 polysiloxane Polymers 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 239000012258 stirred mixture Substances 0.000 description 7
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000006386 neutralization reaction Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000012855 volatile organic compound Substances 0.000 description 6
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000012263 liquid product Substances 0.000 description 5
- 230000007774 longterm Effects 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 125000005372 silanol group Chemical group 0.000 description 5
- 239000004575 stone Substances 0.000 description 5
- 239000004480 active ingredient Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 4
- 150000004756 silanes Chemical class 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- 239000013011 aqueous formulation Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 2
- 241000218645 Cedrus Species 0.000 description 2
- JZUFKLXOESDKRF-UHFFFAOYSA-N Chlorothiazide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC2=C1NCNS2(=O)=O JZUFKLXOESDKRF-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 229960003237 betaine Drugs 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 239000011455 calcium-silicate brick Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000010985 leather Substances 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000004611 spectroscopical analysis Methods 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- QNVQPXNRAJFKQV-UHFFFAOYSA-N 1-fluoroethane-1,2-diol Chemical compound OCC(O)F QNVQPXNRAJFKQV-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000014653 Carica parviflora Nutrition 0.000 description 1
- 241000243321 Cnidaria Species 0.000 description 1
- 241000252233 Cyprinus carpio Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- IKXDEFIEGAVNOZ-UHFFFAOYSA-N [SiH4].[C] Chemical compound [SiH4].[C] IKXDEFIEGAVNOZ-UHFFFAOYSA-N 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/495—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
- C04B41/4961—Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/60—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
- C04B41/61—Coating or impregnation
- C04B41/62—Coating or impregnation with organic materials
- C04B41/64—Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00517—Coating or impregnation materials for masonry
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/203—Oil-proof or grease-repellant materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Silicon Polymers (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.式: [式中、 xは1〜100であり、 yはxの1〜10倍であり、 zはxの0〜5倍であり、 0〜5であり、そしてR2はC1〜C3−アルキルである)、 フルオロアルキルであり、nは1〜3であり、そしてZは-CH2-又は-O-である) 、 又は1であり、R3はH又はC1〜C3−アルキルである)、そして RcはC1〜C12−ヒドロカルビル又はハロゲン含有ヒドロカルビル、フェニル 、置換されたフェニル、又はシアノアルキルである] によって表されるポリマーフルオロカーボンシロキサンおよび対応する分岐し たポリマー構造体。 2.Rfが平均で6〜12個の炭素を有する混合ペルフルオロアルキル基であり、Z が-CH2-であり、nが1であり、mが0であり、そしてR2がエチル又はメチルで ある、請求項1に記載のポリマーフルオロカーボンシロキサン。 3.pが0であり、R1がメチル又はエチルであり、そしてR3がHである、請求項 2に記載のポリマーフルオロカーボンシロキサ ン。 4.RcがC1〜C8−アルキル、フェニル、オクチル、イソブチル又はシアノエチル である、請求項3に記載のポリマーフルオロカーボンシロキサン。 5. 式: [式中、 xは1〜100であり、 yはxの1〜10倍であり、 zはxの0〜5倍であり、 0〜5であり、そしてR2はC1〜C3−アルキルである)、 フルオロアルキルであり、nは1〜3であり、そしてZは-CH2-又は-O-である) 、 又は1であり、R3はH又はC1〜C3−アルキルである)、そして RcはC1〜C12−ヒドロカルビル又はハロゲン含有ヒドロカルビル、フェニル 、置換されたフェニル、又はシアノアルキルである] によって表される、エマルジョンの重量を基にして0.1〜40重量%のポリマー フルオロカーボンシロキサン又は対応する分岐したポリマー構造体と、前記ポリ マーフルオロカーボンシロキサンを実質的に完全に加水分解された状態に保留し そして同時に前記ポリマーフルオロカーボンシロキサンの認め得る自己縮合を抑 制す るために十分に高いHLB値の効果的な量の乳化剤と、アミノアルキルシラン(Rc) 部分を少なくとも部分的に中和してかくして反応性水性エマルジョンを生成させ るために効果的な量の酸とを含む水性エマルジョン。 6.Rfが平均で6〜12個の炭素を有する混合ペルフルオロアルキル基であり、Z が-CH2-であり、nが1であり、mが0であり、そしてR2がエチル又はメチルで ある、請求項5に記載の水性エマルジョン。 7.pが0であり、R1がメチル又はエチルであり、そしてR3がHである、請求項 6に記載の水性エマルジョン。 8.RcがC1〜C8−アルキル、フェニル、オクチル、イソブチル又はシアノエチル である、請求項7に記載の水性エマルジョン。 9.100重量部の水ごとに66.7重量部までの乳化剤を更に含む、請求項5に記載 の水性エマルジョン。 10.式: [式中、 xは1〜100であり、 yはxの1〜10倍であり、 zはxの0〜5倍であり、 0〜5であり、そしてR2はC1〜C3−アルキルである)、 フルオロアルキルであり、nは1〜3であり、そしてZは-CH2-又はO-である) 、 又は1であり、R3はH又はC1〜C3−アルキルである)、そして RcはC1〜C12−ヒドロカルビル又はハロゲン含有ヒドロカルビル、フェニル 、置換されたフェニル、又はシアノアルキルである] によって表される、エマルジョンの重量を基にして0.1〜40重量%のポリマー フルオロカーボンシロキサン又は対応する分岐したポリマー構造体と、前記ポリ マーフルオロカーボンシロキサンを実質的に完全に加水分解された状態に保留し そして同時に前記ポリマーフルオロカーボンシロキサンの認め得る自己縮合を抑 制するために十分に高いHLB値の効果的な量の乳化剤と、アミノアルキルシラン( Rc)部分を少なくとも部分的に中和してかくして反応性水性エマルジョンを生成 させるために効果的な量の酸とを含むエマルジョンを、その上に堆積させそして 乾燥させた基体から成るコートされた表面。 11.Rfが平均で6〜12個の炭素を有する混合ペルフルオロアルキル基であり、Z が-CH2-であり、nが1であり、mが0であり、そしてR2がエチル又はメチルで ある、請求項10に記載のコートされた表面。 12.pが0であり、R1がメチル又はエチルであり、そしてR3がHである、請求項 11に記載のコートされた表面。 13.RcがC1〜C8−アルキル、フェニル、オクチル、イソブチル又はシアノエチル である、請求項12に記載のコートされた表面。 14.100重量部の水ごとに66.7重量部までの乳化剤を更に含む、請求項10に記載 のコートされた表面。 15.(a)効果的な量の (i)式: Ra−Si−(OR1)3 [式中、 フルオロアルキルであり、nは1〜3であり、そしてZは-CH2-又は-O-である) 、そして 0〜5であり、そしてR2はC1〜C3−アルキルである)] の一種又はそれより多くのペルフルオロアルキルアルコキシシラン、 (ii)式: Rb−Si−(OR1)3 [式中、 又は1であり、R3はH又はC1〜C3−アルキルである)] の一種又はそれより多くの置換されたアミノアルキルアルコキシシラン、並び に必要に応じて (iii)式: Rc−Si−(OR1)3 (4) [式中、 RcはC1〜C12-ヒドロカルビル又はハロゲン含有ヒドロカルビル、フェニル、 置換されたフェニル、又はシアノアルキルである] の一種又はそれより多くの炭化水素シラン を縮合させて、式: [式中、 xは1〜100であり、 yはxの1〜10倍であり、 zはxの0〜5倍であり、 0〜5であり、そしてR2はC1〜C3-アルキルである)、 フルオロアルキルであり、nは1〜3であり、そしてZは-CH2-又は-O-である) 、 又は1であり、R3はH又はC1〜C3−アルキルである)、そして RcはC1〜C12−ヒドロカルビル又はハロゲン含有ヒドロカルビル、フェニル 、置換されたフェニル、又はシアノアルキルである] によって表されるポリマーフルオロカーボンシロキサンを製造するステップ、 並びに (b)0.1〜40重量%の前記ポリマーフルオロカーボンシロキサンを、前記ポ リマーフルオロカーボンシロキサンを実質的に完全に加水分解された状態に保留 しそして同時に前記ポリマーフルオロカーボンシロキサンの認め得る自己縮合を 抑制するために十分に高いHLB値の効果的な量の乳化剤と、アミノアルキルシラ ン(Rc)部分を少なくとも部分的に中和するために効果的な量の酸とを含む水の中 に懸濁させてかくして反応性水性エマルジョンを生成させるステップ から成るポリマーフルオロカーボンシロキサンの水性エマルジョンを製造する 方法。 16.Rfが平均で6〜12個の炭素を有する混合ペルフルオロアルキル 基であり、 Zが-CH2-でり、nが1であり、mが0であり、そしてR2がエチル又はメチルで ある、請求項15に記載の方法。 17.pが0であり、R1がメチル又はエチルであり、そしてR3がHである、請求項 16に記載の方法。 18.RcがC1〜C8−アルキル、フェニル、オクチル、イソブチル又はシアノエチル である、請求項17に記載の方法。 19.100重量部の水ごとに66.7重量部までの乳化剤を更に含む、請求項15に記載 の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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US08/205,988 | 1994-03-04 | ||
US08/205,988 US5442011A (en) | 1994-03-04 | 1994-03-04 | Polymeric fluorocarbon siloxanes, emulsions and surface coatings thereof |
PCT/US1995/002582 WO1995023830A1 (en) | 1994-03-04 | 1995-03-03 | Amino and fluoro group containing siloxanes, ... etc. |
Publications (2)
Publication Number | Publication Date |
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JPH09509972A true JPH09509972A (ja) | 1997-10-07 |
JP3597864B2 JP3597864B2 (ja) | 2004-12-08 |
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Application Number | Title | Priority Date | Filing Date |
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JP52301795A Expired - Fee Related JP3597864B2 (ja) | 1994-03-04 | 1995-03-03 | アミノ及びフルオロ基含有シロキサンなど |
Country Status (8)
Country | Link |
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US (1) | US5442011A (ja) |
EP (1) | EP0748357B1 (ja) |
JP (1) | JP3597864B2 (ja) |
KR (1) | KR100364647B1 (ja) |
AU (1) | AU693170B2 (ja) |
CA (1) | CA2182866C (ja) |
DE (1) | DE69510334T2 (ja) |
WO (1) | WO1995023830A1 (ja) |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10158522A (ja) * | 1996-12-03 | 1998-06-16 | Huels Ag | 水を基礎とするオルガノポリシロキサン含有組成物、該組成物の製造法並びに該組成物の使用法 |
JP2003534439A (ja) * | 2000-05-19 | 2003-11-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | エマルジョンおよび撥水性組成物 |
JP2003321544A (ja) * | 2002-04-30 | 2003-11-14 | Chisso Corp | 感熱応答性シラン化合物およびその製造方法ならびにこれを含む感熱応答性材料 |
JP2008514744A (ja) * | 2004-09-24 | 2008-05-08 | エボニック デグサ ゲーエムベーハー | 鉱物質及び非鉱物質基材の表面処理のための液状弗素含有組成物 |
JP2019157124A (ja) * | 2018-03-06 | 2019-09-19 | 株式会社エフコンサルタント | 水性被覆材 |
Also Published As
Publication number | Publication date |
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JP3597864B2 (ja) | 2004-12-08 |
EP0748357A1 (en) | 1996-12-18 |
DE69510334T2 (de) | 1999-11-04 |
AU693170B2 (en) | 1998-06-25 |
AU1937595A (en) | 1995-09-18 |
WO1995023830A1 (en) | 1995-09-08 |
CA2182866C (en) | 2005-07-26 |
DE69510334D1 (de) | 1999-07-22 |
US5442011A (en) | 1995-08-15 |
EP0748357B1 (en) | 1999-06-16 |
KR100364647B1 (ko) | 2003-05-09 |
CA2182866A1 (en) | 1995-09-08 |
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