JPH08505472A - 溶融金属分析用センサー - Google Patents
溶融金属分析用センサーInfo
- Publication number
- JPH08505472A JPH08505472A JP6515824A JP51582494A JPH08505472A JP H08505472 A JPH08505472 A JP H08505472A JP 6515824 A JP6515824 A JP 6515824A JP 51582494 A JP51582494 A JP 51582494A JP H08505472 A JPH08505472 A JP H08505472A
- Authority
- JP
- Japan
- Prior art keywords
- sensor
- alumina
- molten metal
- zirconia
- strontium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 30
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims abstract description 20
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 15
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 15
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011573 trace mineral Substances 0.000 claims abstract description 4
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 4
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 3
- 239000000956 alloy Substances 0.000 claims abstract description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 31
- 229910052717 sulfur Inorganic materials 0.000 claims description 28
- 239000011593 sulfur Substances 0.000 claims description 28
- 230000000694 effects Effects 0.000 claims description 20
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 14
- 239000012925 reference material Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 9
- 229910002804 graphite Inorganic materials 0.000 claims description 7
- 239000010439 graphite Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 3
- 239000002001 electrolyte material Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- -1 sulfur ions Chemical class 0.000 claims 1
- 230000035939 shock Effects 0.000 abstract description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 239000003792 electrolyte Substances 0.000 description 17
- 229910000831 Steel Inorganic materials 0.000 description 14
- 239000010959 steel Substances 0.000 description 14
- 239000000523 sample Substances 0.000 description 13
- 229910052742 iron Inorganic materials 0.000 description 10
- 239000000843 powder Substances 0.000 description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 239000000155 melt Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229910000805 Pig iron Inorganic materials 0.000 description 4
- 239000011195 cermet Substances 0.000 description 4
- 239000011819 refractory material Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 229910001427 strontium ion Inorganic materials 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- ZEGFMFQPWDMMEP-UHFFFAOYSA-N strontium;sulfide Chemical compound [S-2].[Sr+2] ZEGFMFQPWDMMEP-UHFFFAOYSA-N 0.000 description 2
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- JFBZPFYRPYOZCQ-UHFFFAOYSA-N [Li].[Al] Chemical compound [Li].[Al] JFBZPFYRPYOZCQ-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910021525 ceramic electrolyte Inorganic materials 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical group [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910002076 stabilized zirconia Inorganic materials 0.000 description 1
- 150000003437 strontium Chemical class 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/41—Oxygen pumping cells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/411—Cells and probes with solid electrolytes for investigating or analysing of liquid metals
- G01N27/4112—Composition or fabrication of the solid electrolyte
- G01N27/4114—Composition or fabrication of the solid electrolyte for detection of gases other than oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Pathology (AREA)
- Electrochemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Immunology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Investigating Or Analyzing Materials By The Use Of Ultrasonic Waves (AREA)
- Investigating Or Analyzing Materials Using Thermal Means (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB939300435A GB9300435D0 (en) | 1993-01-12 | 1993-01-12 | Sensors for the analysis of molten metals |
| GB9300435.6 | 1993-01-12 | ||
| PCT/GB1994/000045 WO1994016318A1 (en) | 1993-01-12 | 1994-01-11 | Sensors for the analysis of molten metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08505472A true JPH08505472A (ja) | 1996-06-11 |
Family
ID=10728549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6515824A Pending JPH08505472A (ja) | 1993-01-12 | 1994-01-11 | 溶融金属分析用センサー |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5656143A (enExample) |
| EP (1) | EP0679252B1 (enExample) |
| JP (1) | JPH08505472A (enExample) |
| KR (1) | KR960700452A (enExample) |
| CN (1) | CN1117762A (enExample) |
| AT (1) | ATE153760T1 (enExample) |
| AU (1) | AU670356B2 (enExample) |
| BR (1) | BR9406416A (enExample) |
| CA (1) | CA2153691A1 (enExample) |
| DE (2) | DE679252T1 (enExample) |
| GB (1) | GB9300435D0 (enExample) |
| TW (1) | TW307825B (enExample) |
| WO (1) | WO1994016318A1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006308587A (ja) * | 2005-04-26 | 2006-11-09 | Heraeus Electro-Nite Internatl Nv | 浸漬測定プローブ、特にドロップイン型の測定プローブ |
| JP2015187577A (ja) * | 2014-03-27 | 2015-10-29 | 新日鐵住金株式会社 | 溶融金属中の硫黄測定センサー |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10045939B4 (de) * | 2000-09-16 | 2016-05-04 | Caterpillar Inc. | Sensor zur Bestimmung der Konzentration von Schwefelverbindungen in einer Flüssigkeit |
| GB0107724D0 (en) * | 2001-03-28 | 2001-05-16 | Foseco Int | Electrochemical sensor |
| CN100344967C (zh) * | 2004-12-08 | 2007-10-24 | 东北大学 | 一种定硫探头及制作其辅助电极的方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5797441A (en) * | 1980-12-10 | 1982-06-17 | Kobe Steel Ltd | Rapid measuring method for quantity of sulfur |
| JPS57160657U (enExample) * | 1981-03-27 | 1982-10-08 | ||
| JPS6360152A (ja) * | 1986-09-01 | 1988-03-16 | 株式会社日立製作所 | β−アルミナ系固体電解質 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1470558A (en) * | 1974-07-03 | 1977-04-14 | Nat Res Dev | Method and apparatus for detecting elements |
| IT7528805A1 (it) * | 1975-10-30 | 1977-04-30 | Soc It Resine S I R S P A | Dispositivo per la determinazione della concentrazione del sodio nelle amalgame sodio-mercurio |
| GB1603496A (en) * | 1978-05-16 | 1981-11-25 | Atomic Energy Authority Uk | Measuring devices and apparatus |
| US4406754A (en) * | 1980-03-28 | 1983-09-27 | Kabushiki Kaisha Kobe Seiko Sho | Method and probe for the rapid determination of sulfur level |
| US4868142A (en) * | 1987-12-16 | 1989-09-19 | Stemcor Corporation | Method of manufacturing a molten metal-resistant ceramic fiber composition |
| US4882032A (en) * | 1988-06-27 | 1989-11-21 | General Motors Corporation | Hydrogen probe |
| US5112456A (en) * | 1989-12-12 | 1992-05-12 | Trustees Of The University Of Pennsylvania | Electrochemical sensors and methods for their use |
| JPH04320956A (ja) * | 1991-04-20 | 1992-11-11 | Kurosaki Refract Co Ltd | βアルミナとジルコニア固体電解質よりなる結合型ガスセンサー |
| US5228245A (en) * | 1992-03-10 | 1993-07-20 | W. R. Grace & Co.-Conn. | Non-machining surface strengthening of transformation toughened materials |
-
1993
- 1993-01-12 GB GB939300435A patent/GB9300435D0/en active Pending
-
1994
- 1994-01-11 AU AU58369/94A patent/AU670356B2/en not_active Ceased
- 1994-01-11 DE DE0679252T patent/DE679252T1/de active Pending
- 1994-01-11 BR BR9406416A patent/BR9406416A/pt not_active Application Discontinuation
- 1994-01-11 AT AT94904230T patent/ATE153760T1/de not_active IP Right Cessation
- 1994-01-11 JP JP6515824A patent/JPH08505472A/ja active Pending
- 1994-01-11 KR KR1019950702878A patent/KR960700452A/ko not_active Ceased
- 1994-01-11 US US08/464,858 patent/US5656143A/en not_active Expired - Fee Related
- 1994-01-11 CN CN94191158A patent/CN1117762A/zh active Pending
- 1994-01-11 DE DE69403442T patent/DE69403442D1/de not_active Expired - Lifetime
- 1994-01-11 CA CA002153691A patent/CA2153691A1/en not_active Abandoned
- 1994-01-11 EP EP94904230A patent/EP0679252B1/en not_active Expired - Lifetime
- 1994-01-11 WO PCT/GB1994/000045 patent/WO1994016318A1/en not_active Ceased
- 1994-02-01 TW TW083100832A patent/TW307825B/zh active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5797441A (en) * | 1980-12-10 | 1982-06-17 | Kobe Steel Ltd | Rapid measuring method for quantity of sulfur |
| JPS57160657U (enExample) * | 1981-03-27 | 1982-10-08 | ||
| JPS6360152A (ja) * | 1986-09-01 | 1988-03-16 | 株式会社日立製作所 | β−アルミナ系固体電解質 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006308587A (ja) * | 2005-04-26 | 2006-11-09 | Heraeus Electro-Nite Internatl Nv | 浸漬測定プローブ、特にドロップイン型の測定プローブ |
| JP2015187577A (ja) * | 2014-03-27 | 2015-10-29 | 新日鐵住金株式会社 | 溶融金属中の硫黄測定センサー |
Also Published As
| Publication number | Publication date |
|---|---|
| DE679252T1 (de) | 1996-09-19 |
| KR960700452A (ko) | 1996-01-20 |
| AU5836994A (en) | 1994-08-15 |
| DE69403442D1 (de) | 1997-07-03 |
| ATE153760T1 (de) | 1997-06-15 |
| CN1117762A (zh) | 1996-02-28 |
| CA2153691A1 (en) | 1994-07-21 |
| TW307825B (enExample) | 1997-06-11 |
| GB9300435D0 (en) | 1993-03-03 |
| WO1994016318A1 (en) | 1994-07-21 |
| EP0679252B1 (en) | 1997-05-28 |
| US5656143A (en) | 1997-08-12 |
| BR9406416A (pt) | 1995-12-19 |
| AU670356B2 (en) | 1996-07-11 |
| EP0679252A1 (en) | 1995-11-02 |
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