JPH08113701A - トコフエロールで安定化されたポリエーテルポリオール - Google Patents
トコフエロールで安定化されたポリエーテルポリオールInfo
- Publication number
- JPH08113701A JPH08113701A JP7275043A JP27504395A JPH08113701A JP H08113701 A JPH08113701 A JP H08113701A JP 7275043 A JP7275043 A JP 7275043A JP 27504395 A JP27504395 A JP 27504395A JP H08113701 A JPH08113701 A JP H08113701A
- Authority
- JP
- Japan
- Prior art keywords
- polyether polyol
- tocopherol
- stabilized
- polyether
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005862 polyol Polymers 0.000 title claims abstract description 48
- 150000003077 polyols Chemical class 0.000 title claims abstract description 48
- 239000004721 Polyphenylene oxide Substances 0.000 title claims abstract description 47
- 229920000570 polyether Polymers 0.000 title claims abstract description 47
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 title claims abstract description 22
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229930003799 tocopherol Natural products 0.000 title claims abstract description 17
- 239000011732 tocopherol Substances 0.000 title claims abstract description 17
- 235000010384 tocopherol Nutrition 0.000 title claims abstract description 13
- 229960001295 tocopherol Drugs 0.000 title claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 10
- 229920002635 polyurethane Polymers 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 7
- 235000019149 tocopherols Nutrition 0.000 claims description 4
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 claims description 4
- 230000000087 stabilizing effect Effects 0.000 claims description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 abstract description 22
- 239000003381 stabilizer Substances 0.000 abstract description 9
- 239000003963 antioxidant agent Substances 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 4
- 230000003078 antioxidant effect Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 12
- 238000004383 yellowing Methods 0.000 description 7
- 235000004835 α-tocopherol Nutrition 0.000 description 7
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
- 235000006708 antioxidants Nutrition 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 229930003427 Vitamin E Natural products 0.000 description 4
- 229940087168 alpha tocopherol Drugs 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229960000984 tocofersolan Drugs 0.000 description 4
- 235000019165 vitamin E Nutrition 0.000 description 4
- 239000011709 vitamin E Substances 0.000 description 4
- 229940046009 vitamin E Drugs 0.000 description 4
- 239000002076 α-tocopherol Substances 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 150000003772 α-tocopherols Chemical class 0.000 description 3
- WGVKWNUPNGFDFJ-DQCZWYHMSA-N β-tocopherol Chemical compound OC1=CC(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C WGVKWNUPNGFDFJ-DQCZWYHMSA-N 0.000 description 3
- 235000007680 β-tocopherol Nutrition 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000003781 β-tocopherols Chemical class 0.000 description 2
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
- FANGQVKSFHFPBY-UHFFFAOYSA-N 2-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound OC(=O)C(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 FANGQVKSFHFPBY-UHFFFAOYSA-N 0.000 description 1
- SMNGQGWPUVVORF-UHFFFAOYSA-N 3,5-ditert-butyl-4-methylphenol Chemical compound CC1=C(C(C)(C)C)C=C(O)C=C1C(C)(C)C SMNGQGWPUVVORF-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229940066595 beta tocopherol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229950000688 phenothiazine Drugs 0.000 description 1
- 150000002990 phenothiazines Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- -1 polysiloxanes Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1545—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4435474 | 1994-10-04 | ||
| DE4435474.6 | 1994-10-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH08113701A true JPH08113701A (ja) | 1996-05-07 |
Family
ID=6529936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7275043A Pending JPH08113701A (ja) | 1994-10-04 | 1995-09-29 | トコフエロールで安定化されたポリエーテルポリオール |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US5695689A (OSRAM) |
| EP (1) | EP0705872A2 (OSRAM) |
| JP (1) | JPH08113701A (OSRAM) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002053760A (ja) * | 2000-08-09 | 2002-02-19 | Asahi Glass Co Ltd | 耐候性に優れた硬化性組成物 |
| JP2007529585A (ja) * | 2004-03-18 | 2007-10-25 | ビーエーエスエフ アクチェンゲゼルシャフト | ポリエーテルアルコール、及びポリウレタン合成用のポリエーテルアルコールを製造する方法 |
| WO2021001920A1 (ja) * | 2019-07-02 | 2021-01-07 | 三菱ケミカル株式会社 | ポリアルキレンエーテルグリコール組成物及びその製造方法 |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5859280A (en) * | 1997-07-01 | 1999-01-12 | Betzdearborn Inc. | Methods for inhibiting the polymerization of vinyl monomers |
| US6613821B2 (en) * | 1998-10-09 | 2003-09-02 | Canon Kabushiki Kaisha | Cloth treating agent, cloth, textile printing process and print |
| KR20040076257A (ko) * | 2001-12-21 | 2004-08-31 | 아크조 노벨 엔.브이. | 폴리우레탄 발포체용 비-할로겐화 포스페이트 스코치 방지첨가제 |
| SE526945C2 (sv) * | 2003-04-02 | 2005-11-22 | Amcor Flexibles Europe As | Material för förpackningsändamål innehållande vitamin E för att förhindra oxidation, samt en förpackning därav och förfarande för framställning av materialet |
| US20050014637A1 (en) * | 2003-06-04 | 2005-01-20 | Duijghuisen Henricus Petrus Bernardus | Polyether polyol composition |
| WO2006113805A2 (en) * | 2005-04-19 | 2006-10-26 | R.T. Vanderbilt Company, Inc. | Topical polyurethane foam oxidative photooxidative stabilizer |
| GB2523756B (en) * | 2014-03-03 | 2017-01-11 | Addivant Switzerland Gmbh | Antioxidant compositions |
| EP3015169B1 (en) | 2014-10-28 | 2024-04-10 | The Regents Of The University Of California | Sample collection tube with curable polymer separator |
| HUE036632T2 (hu) | 2014-10-28 | 2018-07-30 | Univ California | Kompozit tömítõanyagok és plazma leválasztók vérgyûjtõ csövekhez |
| MX376468B (es) | 2016-01-21 | 2025-03-07 | Basf Se | Mezcla aditiva para estabilizar poliol y poliuretano. |
| EP3293218A1 (de) * | 2016-09-13 | 2018-03-14 | Covestro Deutschland AG | Verfahren zur erniedrigung der aldehydemissionen von polyurethanschaumstoffen |
| TWI809138B (zh) * | 2019-07-03 | 2023-07-21 | 日商三菱化學股份有限公司 | 聚伸烷基醚二醇組成物及其製造方法 |
| FR3100542B1 (fr) | 2019-09-09 | 2021-10-08 | Polybridge | composition comportant un polyol |
| US20250090668A1 (en) | 2022-01-14 | 2025-03-20 | Dow Global Technologies Llc | Glycol compositions including tocopherols |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE725926C (de) * | 1938-05-07 | 1942-10-02 | Happich Gmbh Gebr | Zweiteiliger Druckknopfunterteil, insbesondere zur Befestigung von Schonbezuegen bei Kraftfahrzeugen |
| US4021385A (en) * | 1974-12-30 | 1977-05-03 | Basf Wyandotte Corporation | Polyurethane foams resistant to discoloration |
| US4007230A (en) * | 1975-02-24 | 1977-02-08 | The Dow Chemical Company | Antioxidant composition for stabilizing polyols |
| JPS56152863A (en) * | 1980-04-28 | 1981-11-26 | Adeka Argus Chem Co Ltd | Synthetic resin composition |
| US4444676A (en) * | 1983-04-01 | 1984-04-24 | Atlantic Richfield Company | Stabilized polyoxyalkylene polyether polyols and polyurethane foams prepared therefrom |
| DE3725926A1 (de) * | 1987-08-05 | 1989-02-16 | Basf Ag | Gemisch zum stabilisieren von polyurethanen |
| DE3735577A1 (de) * | 1987-10-21 | 1989-05-03 | Basf Ag | Gemisch zum stabilisieren von polyurethanen |
| DE3842945C1 (OSRAM) * | 1988-12-21 | 1990-02-15 | Bayer Ag, 5090 Leverkusen, De | |
| GB9121575D0 (en) * | 1991-10-11 | 1991-11-27 | Sandoz Ltd | Improvements in or relating to organic compounds |
| US5218008A (en) * | 1991-11-13 | 1993-06-08 | The Dow Chemical Company | Polyethers stabilized with 6-chromanol derivatives |
| CH686306A5 (de) * | 1993-09-17 | 1996-02-29 | Ciba Geigy Ag | 3-Aryl-benzofuranone als Stabilisatoren. |
-
1995
- 1995-09-20 US US08/530,628 patent/US5695689A/en not_active Expired - Fee Related
- 1995-09-21 EP EP95114878A patent/EP0705872A2/de not_active Withdrawn
- 1995-09-29 JP JP7275043A patent/JPH08113701A/ja active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002053760A (ja) * | 2000-08-09 | 2002-02-19 | Asahi Glass Co Ltd | 耐候性に優れた硬化性組成物 |
| JP2007529585A (ja) * | 2004-03-18 | 2007-10-25 | ビーエーエスエフ アクチェンゲゼルシャフト | ポリエーテルアルコール、及びポリウレタン合成用のポリエーテルアルコールを製造する方法 |
| WO2021001920A1 (ja) * | 2019-07-02 | 2021-01-07 | 三菱ケミカル株式会社 | ポリアルキレンエーテルグリコール組成物及びその製造方法 |
| KR20220029547A (ko) * | 2019-07-02 | 2022-03-08 | 미쯔비시 케미컬 주식회사 | 폴리알킬렌에테르글리콜 조성물 및 그 제조 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0705872A3 (OSRAM) | 1996-05-08 |
| EP0705872A2 (de) | 1996-04-10 |
| US5695689A (en) | 1997-12-09 |
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