JPH0676532B2 - ゴム強化ポリビニルアルコールフィルム組成物 - Google Patents
ゴム強化ポリビニルアルコールフィルム組成物Info
- Publication number
- JPH0676532B2 JPH0676532B2 JP60063173A JP6317385A JPH0676532B2 JP H0676532 B2 JPH0676532 B2 JP H0676532B2 JP 60063173 A JP60063173 A JP 60063173A JP 6317385 A JP6317385 A JP 6317385A JP H0676532 B2 JPH0676532 B2 JP H0676532B2
- Authority
- JP
- Japan
- Prior art keywords
- polyvinyl alcohol
- film
- weight
- rubber
- polymer matrix
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims description 65
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims description 64
- 239000000203 mixture Substances 0.000 title claims description 25
- 239000010408 film Substances 0.000 claims description 75
- 229920000642 polymer Polymers 0.000 claims description 32
- 229920001971 elastomer Polymers 0.000 claims description 27
- 239000005060 rubber Substances 0.000 claims description 27
- 239000011159 matrix material Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 230000009477 glass transition Effects 0.000 claims description 13
- 239000003599 detergent Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- -1 polysiloxane Polymers 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 6
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 6
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 235000010356 sorbitol Nutrition 0.000 claims description 3
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 2
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 229930195725 Mannitol Natural products 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920002367 Polyisobutene Polymers 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 2
- 239000000594 mannitol Substances 0.000 claims description 2
- 235000010355 mannitol Nutrition 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 6
- 229920003023 plastic Polymers 0.000 claims 4
- 239000004033 plastic Substances 0.000 claims 4
- 239000007864 aqueous solution Substances 0.000 claims 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 2
- 239000004375 Dextrin Substances 0.000 claims 1
- 229920001353 Dextrin Polymers 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 235000019425 dextrin Nutrition 0.000 claims 1
- 239000004744 fabric Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 239000005033 polyvinylidene chloride Substances 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 230000000052 comparative effect Effects 0.000 description 9
- 239000004014 plasticizer Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 6
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical group OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- IDOQDZANRZQBTP-UHFFFAOYSA-N 2-[2-(2,4,4-trimethylpentan-2-yl)phenoxy]ethanol Chemical compound CC(C)(C)CC(C)(C)C1=CC=CC=C1OCCO IDOQDZANRZQBTP-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920013646 Hycar Polymers 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 229920004929 Triton X-114 Polymers 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- FZWBNHMXJMCXLU-BLAUPYHCSA-N isomaltotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O)O1 FZWBNHMXJMCXLU-BLAUPYHCSA-N 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000003763 resistance to breakage Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/595,980 US4608187A (en) | 1984-04-02 | 1984-04-02 | Rubber toughened polyvinyl alcohol film compositions |
| US595980 | 1984-04-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60248763A JPS60248763A (ja) | 1985-12-09 |
| JPH0676532B2 true JPH0676532B2 (ja) | 1994-09-28 |
Family
ID=24385509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60063173A Expired - Lifetime JPH0676532B2 (ja) | 1984-04-02 | 1985-03-27 | ゴム強化ポリビニルアルコールフィルム組成物 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4608187A (enExample) |
| EP (1) | EP0157612B1 (enExample) |
| JP (1) | JPH0676532B2 (enExample) |
| AR (1) | AR242364A1 (enExample) |
| AU (1) | AU570102B2 (enExample) |
| BR (1) | BR8501365A (enExample) |
| CA (1) | CA1249688A (enExample) |
| DE (1) | DE3570685D1 (enExample) |
| ES (4) | ES8700299A1 (enExample) |
| TR (1) | TR22291A (enExample) |
Families Citing this family (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4797221A (en) * | 1985-09-12 | 1989-01-10 | S. C. Johnson & Son, Inc. | Polymer sheet for delivering laundry care additive and laundry care product formed from same |
| EP0221651A1 (en) * | 1985-09-27 | 1987-05-13 | Kao Corporation | Water soluble polyvinyl alcohol derivative |
| GB8612706D0 (en) * | 1986-05-23 | 1986-07-02 | Unilever Plc | Sealable container |
| US5234615A (en) * | 1987-10-02 | 1993-08-10 | Ecolab Inc. | Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use |
| US5078301A (en) * | 1987-10-02 | 1992-01-07 | Ecolab Inc. | Article comprising a water soluble bag containing a multiple use amount of a pelletized functional material and methods of its use |
| US4849256A (en) * | 1988-03-11 | 1989-07-18 | The Clorox Company | Process for plasticizing polyvinyl alcohol resin |
| US4806261A (en) * | 1988-04-11 | 1989-02-21 | Colgate-Palmolive Co. | Detersive article |
| US5055215A (en) * | 1989-03-03 | 1991-10-08 | Fabritec International Corporation | Unit-dose drycleaning product and method |
| US5196132A (en) * | 1989-03-03 | 1993-03-23 | Fabritec International Corporation | Unit-dose drycleaning product |
| EP0389695A1 (en) * | 1989-03-28 | 1990-10-03 | Neste Oy | Gastight material |
| JP2860129B2 (ja) * | 1990-02-01 | 1999-02-24 | 日本合成化学工業株式会社 | 耐衝撃性の優れた成型物の製造法 |
| US5126400A (en) * | 1990-07-30 | 1992-06-30 | Dow Corning Corporation | Reinforced polyorganosiloxane elastomers |
| US5126403A (en) * | 1990-07-30 | 1992-06-30 | Dow Corning Corporation | Reinforced polyorganosiloxane elastomers |
| CA2107356C (en) | 1991-05-14 | 2002-09-17 | Elizabeth J. Gladfelter | Two part solid detergent chemical concentrate |
| JPH05329276A (ja) * | 1992-05-20 | 1993-12-14 | Mitsui & Co Ltd | 水溶性有色バルーン |
| US5349000A (en) * | 1993-02-25 | 1994-09-20 | Air Products And Chemicals, Inc. | Extrudable polyvinyl alcohol compositions containing polyester-polyether block copolymers |
| US5649326A (en) * | 1994-11-18 | 1997-07-22 | Johnson & Johnson Professional, Inc. | Flexible hydrophilic coating for orthopaedic casting gloves and method for making such gloves |
| US6673765B1 (en) | 1995-05-15 | 2004-01-06 | Ecolab Inc. | Method of making non-caustic solid cleaning compositions |
| DE69700854T2 (de) * | 1996-04-10 | 2000-05-18 | Kuraray Co., Ltd | Geformte Gegenstände aus Polyvinylalkohol |
| US6150324A (en) | 1997-01-13 | 2000-11-21 | Ecolab, Inc. | Alkaline detergent containing mixed organic and inorganic sequestrants resulting in improved soil removal |
| US6258765B1 (en) * | 1997-01-13 | 2001-07-10 | Ecolab Inc. | Binding agent for solid block functional material |
| GB9906176D0 (en) * | 1999-03-17 | 1999-05-12 | Unilever Plc | Process for producing a water soluble package |
| GB9906171D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| GB9906169D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| US6387870B1 (en) | 1999-03-29 | 2002-05-14 | Ecolab Inc. | Solid pot and pan detergent |
| EP1194523B1 (de) * | 1999-07-09 | 2005-11-30 | Henkel Kommanditgesellschaft auf Aktien | Wasch- oder reinigungsmittel-portion |
| EP1272606A1 (en) * | 2000-04-14 | 2003-01-08 | Unilever N.V. | Water soluble package and liquid contents thereof |
| US20040072709A1 (en) * | 2000-10-18 | 2004-04-15 | Ralf Wiedemann | Cleaning compositions packaged in ethoxlated polyvinylalcohol materials |
| US6638902B2 (en) | 2001-02-01 | 2003-10-28 | Ecolab Inc. | Stable solid enzyme compositions and methods employing them |
| US6492312B1 (en) | 2001-03-16 | 2002-12-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Water soluble sachet with a dishwashing enhancing particle |
| US6632291B2 (en) | 2001-03-23 | 2003-10-14 | Ecolab Inc. | Methods and compositions for cleaning, rinsing, and antimicrobial treatment of medical equipment |
| GB2414958A (en) * | 2004-06-11 | 2005-12-14 | Reckitt Benckiser Nv | A process for preparing a water soluble article. |
| US7964544B2 (en) * | 2005-10-31 | 2011-06-21 | Ecolab Usa Inc. | Cleaning composition and method for preparing a cleaning composition |
| US20070179073A1 (en) * | 2005-11-09 | 2007-08-02 | Smith Kim R | Detergent composition for removing polymerized food soils and method for cleaning polymerized food soils |
| US20070253926A1 (en) * | 2006-04-28 | 2007-11-01 | Tadrowski Tami J | Packaged cleaning composition concentrate and method and system for forming a cleaning composition |
| MX2010010246A (es) | 2008-04-07 | 2010-10-20 | Ecolab Inc | Composicion desengrasante liquida ultraconcentrada. |
| US9701931B2 (en) | 2013-09-30 | 2017-07-11 | Chemlink Laboratories, Llc | Environmentally preferred antimicrobial compositions |
| DE102016201498B4 (de) | 2016-02-01 | 2017-08-17 | Norbert Kuhl | Sauerstoffdichter lebensmittelbehälter |
| CN112334535B (zh) * | 2018-06-20 | 2023-03-28 | 株式会社可乐丽 | 聚乙烯醇膜、拉伸膜和聚乙烯醇膜的制造方法 |
| TWI838441B (zh) | 2018-12-21 | 2024-04-11 | 日商可樂麗股份有限公司 | 耐油膜、耐油基材及耐油紙 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2804395A (en) * | 1953-09-04 | 1957-08-27 | Setrak K Boyajian | Envelopes and the like with remoistenable adhesive comprising polyvinyl alcohol |
| NL266245A (enExample) * | 1960-06-22 | |||
| GB927963A (en) * | 1961-01-06 | 1963-06-06 | Kurashiki Rayon Kk | Method of preventing water-soluble films of polyvinyl alcohol derivatives from adhering and non-sticky films made thereby |
| GB1003178A (en) * | 1961-05-27 | 1965-09-02 | Kurashiki Rayon Kk | Method of manufacturing water soluble film |
| US3113674A (en) * | 1961-08-28 | 1963-12-10 | Eastman Kodak Co | Composition comprising sodium cellulose acetate sulfate and a polymer and unit package preparted therefrom |
| US3220991A (en) * | 1962-03-28 | 1965-11-30 | Monsanto Co | Heat stabilization of polyvinyl alcohol with aliphatic polycarboxylic acid |
| US3413229A (en) * | 1964-03-03 | 1968-11-26 | Mono Sol Division Baldwin Mont | Polyvinyl alcohol compositions |
| US3374195A (en) * | 1964-03-03 | 1968-03-19 | Mono Sol Division | Polyvinyl alcohol compositions containing a plasticizer mixture |
| US3409598A (en) * | 1964-06-18 | 1968-11-05 | Denki Kagaku Kogyo Kk | Process for the manufacture of water soluble polyvinyl alcohol film |
| US3366592A (en) * | 1964-06-24 | 1968-01-30 | Du Pont | Polyvinyl alcohol plasticized with 2, 2-diethyl-1, 3-propanediol |
| US3300546A (en) * | 1965-10-05 | 1967-01-24 | American Cyanamid Co | Water soluble envelope prepared from a graft polymer of alkyl acrylate on a polyvinyl alcohol/polyvinyl acetate co-polymer |
| CA813298A (en) * | 1966-07-08 | 1969-05-20 | W. Gray Frederick | Bleaching packets |
| US3505303A (en) * | 1966-12-30 | 1970-04-07 | Air Reduction | Water soluble modified polyvinyl alcohol films |
| US3563244A (en) * | 1968-03-15 | 1971-02-16 | Hajime Moribe | Condoms |
| US3632786A (en) * | 1968-11-12 | 1972-01-04 | Monsanto Co | Polyvinyl alcohol adhesive composition with high wet tack containing a boron compound and a cis 1 2 polyol compound |
| US3607812A (en) * | 1968-12-17 | 1971-09-21 | Denki Kagaku Kogyo Kk | Method of manufacturing polyvinyl alcohol films and product |
| US3892905A (en) * | 1970-08-12 | 1975-07-01 | Du Pont | Cold water soluble plastic films |
| JPS5117933A (en) * | 1974-08-05 | 1976-02-13 | Kuraray Co | Gomujobutsushitsuno suiseibunsantaino seizoho |
| JPS5117936A (en) * | 1974-08-05 | 1976-02-13 | Kuraray Co | Shisu 1*44 horiisopurengomusuiseibunsantaino seiho |
| JPS6011736B2 (ja) * | 1974-08-05 | 1985-03-27 | 株式会社クラレ | 水性分散液の製造法 |
| JPS5810438B2 (ja) * | 1975-01-31 | 1983-02-25 | ユニチカ株式会社 | ポリビニルアルコ−ルケイホツトメルトガタセツチヤクザイノ セイゾウホウホウ |
| US4155971A (en) * | 1976-08-18 | 1979-05-22 | E. I. Du Pont De Nemours And Company | Method of making water-soluble films from polyvinyl alcohol compositions |
| US4082678A (en) * | 1976-11-10 | 1978-04-04 | The Procter & Gamble Company | Fabric conditioning articles and process |
| US4115292A (en) * | 1977-04-20 | 1978-09-19 | The Procter & Gamble Company | Enzyme-containing detergent articles |
| GB1583082A (en) * | 1977-05-18 | 1981-01-21 | Unilever Ltd | Detergent products |
| US4289815A (en) * | 1978-06-26 | 1981-09-15 | Airwick Industries, Inc. | Cold water-insoluble polyvinyl alcohol pouch for the controlled release of active ingredients |
| MX151028A (es) * | 1978-11-17 | 1984-09-11 | Unilever Nv | Mejoras en bolsa insoluble pero permeable al agua que tiene una capa protectora dispersable o soluble en agua,que contiene una composicion detergente en particulas |
| JPS5831106B2 (ja) * | 1979-04-24 | 1983-07-04 | 出光興産株式会社 | 熱可塑性樹脂組成物 |
| NZ199130A (en) * | 1980-12-15 | 1985-07-31 | Colgate Palmolive Co | Water-soluble film;mixture of polyvinyl alcohol and polyacrylic acid |
| US4374035A (en) * | 1981-07-13 | 1983-02-15 | The Procter & Gamble Company | Accelerated release laundry bleach product |
| US4416791A (en) * | 1981-11-11 | 1983-11-22 | Lever Brothers Company | Packaging film and packaging of detergent compositions therewith |
| US4410441A (en) * | 1982-04-26 | 1983-10-18 | Lever Brothers Company | Product for treating fabrics in a washing machine |
-
1984
- 1984-04-02 US US06/595,980 patent/US4608187A/en not_active Expired - Lifetime
-
1985
- 1985-03-22 TR TR13977A patent/TR22291A/xx unknown
- 1985-03-26 CA CA000477486A patent/CA1249688A/en not_active Expired
- 1985-03-26 BR BR8501365A patent/BR8501365A/pt not_active IP Right Cessation
- 1985-03-27 JP JP60063173A patent/JPH0676532B2/ja not_active Expired - Lifetime
- 1985-03-27 AR AR85299900A patent/AR242364A1/es active
- 1985-03-29 EP EP85302217A patent/EP0157612B1/en not_active Expired
- 1985-03-29 DE DE8585302217T patent/DE3570685D1/de not_active Expired
- 1985-04-01 AU AU40556/85A patent/AU570102B2/en not_active Ceased
- 1985-04-02 ES ES542542A patent/ES8700299A1/es not_active Expired
- 1985-04-02 ES ES542541A patent/ES8707266A1/es not_active Expired
- 1985-04-02 ES ES551884A patent/ES8800967A1/es not_active Expired
- 1985-04-02 ES ES551883A patent/ES8704192A1/es not_active Expired
Non-Patent Citations (1)
| Title |
|---|
| 長野浩一著「ポバール」（１９８１．４．１）（株）高分子刊行会発行Ｐ．３７８〜３９４ |
Also Published As
| Publication number | Publication date |
|---|---|
| ES551884A0 (es) | 1987-12-01 |
| BR8501365A (pt) | 1985-11-19 |
| ES8800967A1 (es) | 1987-12-01 |
| TR22291A (tr) | 1987-01-02 |
| AU4055685A (en) | 1985-10-10 |
| ES551883A0 (es) | 1987-04-01 |
| ES8707266A1 (es) | 1987-07-16 |
| ES542541A0 (es) | 1987-07-16 |
| AU570102B2 (en) | 1988-03-03 |
| CA1249688A (en) | 1989-01-31 |
| ES8704192A1 (es) | 1987-04-01 |
| ES8700299A1 (es) | 1986-10-01 |
| US4608187B1 (enExample) | 1988-02-09 |
| US4608187A (en) | 1986-08-26 |
| EP0157612A3 (en) | 1986-10-01 |
| AR242364A1 (es) | 1993-03-31 |
| JPS60248763A (ja) | 1985-12-09 |
| EP0157612A2 (en) | 1985-10-09 |
| DE3570685D1 (en) | 1989-07-06 |
| EP0157612B1 (en) | 1989-05-31 |
| ES542542A0 (es) | 1986-10-01 |
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