JP2020193329A - 防ダニ単位用量物品 - Google Patents
防ダニ単位用量物品 Download PDFInfo
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- JP2020193329A JP2020193329A JP2020086499A JP2020086499A JP2020193329A JP 2020193329 A JP2020193329 A JP 2020193329A JP 2020086499 A JP2020086499 A JP 2020086499A JP 2020086499 A JP2020086499 A JP 2020086499A JP 2020193329 A JP2020193329 A JP 2020193329A
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- laundry detergent
- detergent composition
- liquid laundry
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- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
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- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
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- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 description 1
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- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
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- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
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- Detergent Compositions (AREA)
Abstract
Description
本発明は、水溶性フィルム及び液体洗濯洗剤組成物を含む、防ダニ水溶性単位用量物品であって、液体洗濯洗剤組成物の約1%〜20%の安息香酸ベンジルを防ダニ活性物質として含む、防ダニ水溶性単位用量物品に関する。本発明による水溶性フィルム及び液体洗濯洗剤組成物について、以下により詳細に説明する。
本発明のフィルムは、水溶性又は水分散性である。水溶性フィルムの厚さは、好ましくは、約20〜約150マイクロメートル(μm)、好ましくは約35〜約125μm、更により好ましくは約50〜約110μm、最も好ましくは約76μmである。
上記水溶性フィルムによって形成された内部区画に封入された液体洗濯洗剤組成物は、当該液体洗濯洗剤組成物の総重量の約1%〜約20%の安息香酸ベンジルを含む。
本発明によれば、「非石鹸アニオン性界面活性剤」という用語は、脂肪酸又はその対応する塩(石鹸)を包含しない。好ましくは、非石鹸アニオン性界面活性剤は、直鎖アルキルベンゼンスルホネート、アルキルサルフェート、アルコキシル化アルキルサルフェート、又はこれらの混合物から選択される。
非イオン性界面活性剤は、脂肪族アルコールアルコキシレート、オキソ合成脂肪族アルコールアルコキシレート、ゲルベアルコールアルコキシレート、アルキルフェノールアルコールアルコキシレート、又はこれらの混合物から選択される。アルキル鎖は、直鎖であっても分枝状であってもよく、それぞれの出発アルコールは、天然由来であっても合成由来であってもよい。
「脂肪酸」という用語は、脂肪酸又は脂肪酸塩を包含する。脂肪酸は、好ましくは、飽和又は不飽和のいずれかである、多くの場合長い非分枝状脂肪族末端を有する、カルボン酸である。本発明に好適な脂肪酸又は脂肪酸の塩は、好ましくはナトリウム塩、好ましくはC12〜C18飽和及び/又は不飽和脂肪酸、より好ましくはC12〜C14飽和及び/又は不飽和脂肪酸、並びにアルカリ又はアルカリ土類金属の炭酸塩、最も好ましくは炭酸ナトリウムである。
本明細書で使用する硬化ヒマシ油(HCO)は、最も全般的には、液体洗濯洗剤組成物中で結晶化可能なものであるならば、任意の硬化ヒマシ油又はその誘導体であってもよい。ヒマシ油には、ヒドロキシル基を組み込むC10〜C22アルキル又はアルケニル部分を含む、グリセリド、特にトリグリセリドを含むものもある。ヒマシ油を水素化して、HCOを製造することにより、出発油中にリシノレイル部分として存在し得る二重結合を変換する。その結果、リシノレイル部分は、飽和ヒドロキシアルキル部分、例えば、ヒドロキシステアリルに変換される。本明細書におけるHCOは、トリヒドロキシステアリン、ジヒドロキシステアリン、及びこれらの混合物から選択されてもよい。HCOは、固形、溶融物及びこれらの混合物から選択されるものが挙げられるが、これらに限定されない任意の好適な出発形態で加工することができる。仕上げた洗濯洗剤製品に送達される硬化ヒマシ油の対応する百分率は、1.0%未満、典型的には約0.1%〜約0.8%であってもよい。HCOは、液体洗濯洗剤組成物の約0.01%〜約1%、又は更には約0.05%〜約0.8%の濃度で存在してもよい。
当業者には、本発明の液体洗濯洗剤組成物を製造するためのプロセスが理解されよう。当業者には、液体洗濯洗剤組成物を製造するための標準的なプロセス及び設備が理解されよう。
本発明の一態様は、布地を洗浄するプロセスであって、このプロセスは、本発明の液体洗濯洗剤組成物又は単位用量物品と水とを接触させることにより、液体洗濯洗剤組成物を少なくとも約200倍、好ましくは最大約3000倍、より好ましくは約400〜約1000倍で水に希釈して洗浄液を形成する工程と、布地を当該洗浄液と接触させる工程と、を含む。
当業者に周知の標準的な混合技法及び装置を用いて、下記のずり減粘液体洗剤配合物を調製した。安息香酸ベンジルを本発明の組成物A中に加えておき、1,2−プロパンジオールを比較用組成物Aと比較して再調整して、安息香酸ベンジル含有のための自由配合領域を実現する。硬化ヒマシ油をトリミング剤として使用して、両方の試験製品間の高剪断粘度(1000/秒)と合わせた。高剪断粘度は、液体充填動作中に生じる製品粘度に近似的である。
当業者に周知の標準的な混合技法及び装置を用いて、下記のずり減粘液体洗剤配合物を調製した。安息香酸ベンジルを本発明の組成物B中に加えておき、全ての他の配合活性物質を比較用組成物Bと比較して再調整して、安息香酸ベンジル含有のための自由配合領域を実現し、他方で、最終的な溶媒の変化を2つの試験配合物間で最低限に保つ。
Claims (15)
- 内部に液体洗濯洗剤組成物を封入する内部区画を有するパウチに形成された、水溶性ポリマーフィルムを含む、防ダニ単位用量物品であって、前記液体洗濯洗剤組成物が、1000秒−1の剪断速度及び20℃の温度で測定して、100〜900mPa・sの範囲の高剪断粘度を特徴とし、前記液体洗濯洗剤組成物は、前記液体洗濯洗剤組成物の総重量の、20%〜70%の1つ以上の非石鹸界面活性剤と、1%〜20%の安息香酸ベンジルと、を含む、防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、1000秒−1の剪断速度及び20℃の温度で測定して、150〜800mPa・s、好ましくは200〜600mPa・sの範囲の高剪断粘度を特徴とする、請求項1に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、ずり減粘特性を有する非ニュートン流体である、請求項1又は2に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の総重量の5%〜40%、好ましくは10%〜35%、より好ましくは15%〜30%の、1つ以上の非石鹸アニオン性界面活性剤を含み、好ましくは、前記1つ以上の非石鹸アニオン性界面活性剤は、直鎖アルキルベンゼンスルホネート、アルコキシル化アルキルサルフェート、及びこれらの組み合わせからなる群から選択される、請求項1〜3のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の総重量の2%〜25%、好ましくは5%〜20%、より好ましくは10%〜15%の、1つ以上の非イオン性界面活性剤を含み、好ましくは、前記1つ以上の非イオン性界面活性剤は、脂肪族アルコールアルコキシレート、オキソ合成脂肪族アルコールアルコキシレート、及びこれらの組み合わせからなる群から選択される、請求項1〜4のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の総重量の2%〜15%、好ましくは3%〜12%、より好ましくは4%〜10%の安息香酸ベンジルを含む、請求項1〜5のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、5%〜30%、好ましくは10%〜25%、より好ましくは15%〜20%の、1,2−プロパンジオール、ジプロピレングリコール、グリセロール、及びこれらの組み合わせからなる群から選択される1つ以上の溶媒を更に含む、請求項1〜6のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の3重量%〜10重量%、より好ましくは5重量%〜7重量%の脂肪酸又はその塩を更に含む、請求項1〜7のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の5重量%〜15重量%、より好ましくは6重量%〜10重量%の、アルカノールアミン、好ましくはモノエタノールアミンを更に含む、請求項1〜8のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、前記液体洗濯洗剤組成物の0.5重量%〜20重量%、より好ましくは1重量%〜15重量%、最も好ましくは5重量%〜12重量%の水を更に含む、請求項1〜9のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、ずり減粘レオロジー構造化剤を更に含み、当該構造化剤が、好ましくは硬化ヒマシ油である、請求項1〜10のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、脱イオン水中の10%希釈液として20℃で測定して、6〜10、より好ましくは6.5〜8.9、最も好ましくは7〜8のpHを有する、請求項1〜11のいずれか一項に記載の防ダニ単位用量物品。
- 前記液体洗濯洗剤組成物が、0.5秒−1の剪断速度及び20℃の温度で測定して、1000mPa・s〜10000mPa・s、好ましくは1500mPa・s〜7500mPa・s、より好ましくは2000mPa・s〜5000mPa・sの範囲の低剪断粘度を特徴とする、請求項1〜12のいずれか一項に記載の防ダニ単位用量物品。
- 前記水溶性ポリマーフィルムが、水溶性ポリビニルアルコールポリマー、水溶性ポリビニルアルコールコポリマー、又はこれらの混合物を含む、請求項1〜13のいずれか一項に記載の防ダニ単位用量物品。
- 液体糸状化を低減するとともに防ダニ効果をもたらすための、液体洗濯洗剤組成物中での1重量%〜20重量%の安息香酸ベンジルの使用であって、前記液体洗濯洗剤組成物が、1000秒−1の剪断速度及び20℃の温度で測定して、100〜900mPa・sの範囲の高剪断粘度を特徴とする、使用。
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DE102004007594A1 (de) * | 2004-02-17 | 2004-08-26 | Heinz Kiefer | Verwendung eines antiparasitären Mittels in Form einer Lösung gegen Hausstaubmilben zur Durchtränkung des Gewebes von Textilien bei Maschinen- und Handwäsche (auch zum Besprühen von Teppichen und Polster), dadurch gekennzeichnet, daß es eine Kombination von Tannins aus Quercus cortex, Ratanhiae radix und Tormentillae rhizoma enthält |
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