JPH06500125A - 有機ケイ素化合物 - Google Patents
有機ケイ素化合物Info
- Publication number
- JPH06500125A JPH06500125A JP4508889A JP50888992A JPH06500125A JP H06500125 A JPH06500125 A JP H06500125A JP 4508889 A JP4508889 A JP 4508889A JP 50888992 A JP50888992 A JP 50888992A JP H06500125 A JPH06500125 A JP H06500125A
- Authority
- JP
- Japan
- Prior art keywords
- group
- formula
- compound
- groups
- units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003961 organosilicon compounds Chemical class 0.000 title claims description 29
- 125000000217 alkyl group Chemical group 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 29
- -1 organosiloxane compound Chemical class 0.000 claims description 29
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 23
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 15
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000000126 substance Substances 0.000 claims description 11
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 8
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 229910000077 silane Inorganic materials 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 5
- 125000004122 cyclic group Chemical group 0.000 claims description 5
- 150000003377 silicon compounds Chemical class 0.000 claims description 5
- 125000005375 organosiloxane group Chemical group 0.000 claims description 4
- 230000000903 blocking effect Effects 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000011067 equilibration Methods 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 2
- 150000002894 organic compounds Chemical class 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 3
- 150000002431 hydrogen Chemical group 0.000 claims 2
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims 1
- 150000001721 carbon Chemical class 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 19
- 210000003491 skin Anatomy 0.000 description 18
- 238000006243 chemical reaction Methods 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002537 cosmetic Substances 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000035515 penetration Effects 0.000 description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 150000008282 halocarbons Chemical class 0.000 description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000004566 IR spectroscopy Methods 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 238000009395 breeding Methods 0.000 description 3
- 230000001488 breeding effect Effects 0.000 description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000000475 sunscreen effect Effects 0.000 description 3
- 239000000516 sunscreening agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 2
- RGHHSNMVTDWUBI-UHFFFAOYSA-N 4-hydroxybenzaldehyde Chemical compound OC1=CC=C(C=O)C=C1 RGHHSNMVTDWUBI-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 2
- HCPOCMMGKBZWSJ-UHFFFAOYSA-N ethyl 3-hydrazinyl-3-oxopropanoate Chemical compound CCOC(=O)CC(=O)NN HCPOCMMGKBZWSJ-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical group CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000000338 in vitro Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 150000003058 platinum compounds Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 210000000434 stratum corneum Anatomy 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- LITSBNREXIFYBV-UHFFFAOYSA-N 3-oxobutanoic acid platinum Chemical compound [Pt].CC(=O)CC(O)=O.CC(=O)CC(O)=O LITSBNREXIFYBV-UHFFFAOYSA-N 0.000 description 1
- GSSBOYWRKTVVQX-UHFFFAOYSA-N 4-prop-2-ynoxybenzaldehyde Chemical compound O=CC1=CC=C(OCC#C)C=C1 GSSBOYWRKTVVQX-UHFFFAOYSA-N 0.000 description 1
- 241000566146 Asio Species 0.000 description 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 description 1
- 241000896693 Disa Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical group CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 241000384512 Trachichthyidae Species 0.000 description 1
- 125000000218 acetic acid group Chemical class C(C)(=O)* 0.000 description 1
- 150000007513 acids Chemical group 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000005083 alkoxyalkoxy group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Chemical group 0.000 description 1
- 238000003965 capillary gas chromatography Methods 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 108010011222 cyclo(Arg-Pro) Proteins 0.000 description 1
- 230000007071 enzymatic hydrolysis Effects 0.000 description 1
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229960001679 octinoxate Drugs 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 230000037368 penetrate the skin Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011814 protection agent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 150000003256 radium compounds Chemical class 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003284 rhodium compounds Chemical class 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000037072 sun protection Effects 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/57—Compounds covalently linked to a(n inert) carrier molecule, e.g. conjugates, pro-fragrances
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Birds (AREA)
- Dermatology (AREA)
- General Chemical & Material Sciences (AREA)
- Silicon Polymers (AREA)
- Cosmetics (AREA)
- Lubricants (AREA)
Abstract
Description
Claims (19)
- 1.一般式: ▲数式、化学式、表等があります▼(i)で示される単位を少なくとも一つ有す るオルガノシロキサン化合物であって、 前記シロキサン中に存在する他の単位が、一般式:R−bSio4−b/2(i i) [上記式中、 RはC1−8アルキル又はアリール基を表し、R1は水素原子又はC1−5アル キル基であり、R2は水素原子、C1−6アルキル基又はOR1基であり、R3 はC1−5アルキル基であり、R′′は水素原子、一価C1−6炭化水素又はハ ロゲン化炭化水素基を表し、aは0、1又は2の値を有し、bは0、1、2又は 3の値を有し、nは1〜6の値を有する、但し−C(R1)=CH−(CR12 )a−O−基と2個のR2とは−CH=C[C(O)OR3]2基に対してパラ 位置と両メタ位置において芳香環に結合する] で示される単位であるオルガノシロキサン化合物。
- 2.全てのRとR′′基の少なくとも80%がメチル基である請求項1記載のオ ルガノシロキサン化合物。
- 3.各R1が水素、メチル及びエチルから選択される請求項1又は2に記載のオ ルガノシロキサン化合物。
- 4.少なくとも一つのR2基が水素であり、他の基が水素、メトキシ又はエトキ シである請求項1〜3のいずれかに記載のオルガノシロキサン化合物。
- 5.R3がメチル又はエチルである請求項1〜4のいずれかに記載のオルガノシ ロキサン化合物。
- 6.R1とR2基がそれぞれ水素である請求項1〜5のいずれかに記載のオルガ ノシロキサン化合物。
- 7.実質的に線状又は環式ジオルガノシロキサンである請求項1〜6のいずれか に記載のオルガノシロキサン化合物。
- 8.−C(R1)=CH−(CR12)a−O−基が−CH=C[C(O)OR 3]2基に対して芳香環のパラ位置を占め、両R2基が−CH=C[C(O)O R3]2基に対して芳香環のメタ位置を占める請求項1〜7のいずれかに記載の オルガノシロキサン化合物。
- 9.単位(i)数が分子中のシロキサン単位の総数の最大20%に限定される請 求項1〜8のいずれかに記載のオルガノシロキサン化合物。
- 10.単位(i)数が単位の総数の10%以下に限定される請求項1〜9のいず れかに記載のオルガノシロキサン化合物。
- 11.一般式(i)単位がオルガノシロキサン化合物の末端に存在する請求項1 〜10のいずれかに記載のオルガノシロキサン化合物。
- 12.式(i)の末端ブロッキング単位2個と、一般式(ii)単位8〜90個 とを有する請求項1〜11のいずれかに記載のオルガノシロキサン化合物。
- 13.式: ▲数式、化学式、表等があります▼(iii)[式中、R1は水素原子又はC1 −5アルキル基であり、R2は水素原子、C1−6アルキル基又はOR1基であ り、R3はC1−5アルキル基であり、nは1〜6の値を有する、但し不飽和炭 素−炭素三重結合を含む基と2個のR2基とは、 エステル含有基に対して芳香環の二つのメタ位置とパラ位置とに結合する] を有する化合物。
- 14.一般式: ▲数式、化学式、表等があります▼(vi)[式中、R、R1、R2、R3及び nは上記で定義した通りであり、Zは加水分解可能な基であり、Xは0、1又は 2の値を有する] を有するシラン。
- 15. (A)一般式: ▲数式、化学式、表等があります▼(iii)[式中、R1は水素原子又はC1 −5アルキル基であり、R2は水素原子、C1−6アルキル基又はOR1基であ り、R3はC1−5アルキル基であり、nは1〜6の値を有する、但し不飽和三 重結合を含む基と2個のR2基とは、−CH=C−[C(O)OR3]2基に対 して芳香環の二つのメタ位置とパラ位置とに結合する]で示される化合物と、 (B)一般式: O3−a/2SiHR(iv) で示される単位を少なくとも一つ有する有機ケイ素化合物であって、 化合物中に存在する他の単位が一般式:R−bSio4−b/2(ii) [上記式中、R、R′′、a及びbは上記で定義した通りである]で示される単 位である有機ケイ素化合物とを共に反応させることを含む、請求項1記載の有機 ケイ素化合物の製造方法。
- 16.化学量論的割合の(A)と(B)又はやや化学量論的に過剰な(A)が用 いられる請求項15記載の方法。
- 17.請求項14記載の加水分解可能なシランを他の加水分解可能なシランと共 に同時加水分解を受けさせるか、又は式(ii)単位を有する環式もしくは線状 ポリオルガノシロキサンと平衡化させることを含む請求項1記載の有機ケイ素化 合物の製造方法。
- 18.請求項1〜12のいずれかに記載のオルガノシロキサン化合物を含むコス メチック又は塗料組成物。
- 19.請求項1〜12のいずれかに記載のオルガノシロキサン化合物の紫外線吸 収剤としての使用。
Applications Claiming Priority (2)
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GB919110123A GB9110123D0 (en) | 1991-05-10 | 1991-05-10 | Organosilicon compounds their preparation and use |
GB91.10123.8 | 1991-05-10 |
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JPH06500125A true JPH06500125A (ja) | 1994-01-06 |
JP2854977B2 JP2854977B2 (ja) | 1999-02-10 |
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JP4508889A Expired - Lifetime JP2854977B2 (ja) | 1991-05-10 | 1992-05-07 | 有機ケイ素化合物 |
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US (2) | US5403944A (ja) |
EP (1) | EP0538431B1 (ja) |
JP (1) | JP2854977B2 (ja) |
AT (1) | ATE134635T1 (ja) |
AU (2) | AU652633B2 (ja) |
BR (1) | BR9205272A (ja) |
DE (1) | DE69208582T2 (ja) |
DK (1) | DK0538431T3 (ja) |
ES (1) | ES2084356T3 (ja) |
GB (1) | GB9110123D0 (ja) |
IL (3) | IL101811A (ja) |
SG (1) | SG49054A1 (ja) |
WO (1) | WO1992020690A1 (ja) |
ZA (1) | ZA923318B (ja) |
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- 1992-05-07 BR BR9205272A patent/BR9205272A/pt not_active IP Right Cessation
- 1992-05-07 DE DE69208582T patent/DE69208582T2/de not_active Revoked
- 1992-05-07 EP EP92909392A patent/EP0538431B1/en not_active Revoked
- 1992-05-07 SG SG1996005567A patent/SG49054A1/en unknown
- 1992-05-07 DK DK92909392.0T patent/DK0538431T3/da active
- 1992-05-07 ZA ZA923318A patent/ZA923318B/xx unknown
- 1992-05-07 ES ES92909392T patent/ES2084356T3/es not_active Expired - Lifetime
- 1992-05-07 AT AT92909392T patent/ATE134635T1/de not_active IP Right Cessation
- 1992-05-07 AU AU16771/92A patent/AU652633B2/en not_active Expired
- 1992-05-07 JP JP4508889A patent/JP2854977B2/ja not_active Expired - Lifetime
- 1992-05-08 IL IL10181192A patent/IL101811A/en not_active IP Right Cessation
- 1992-05-08 IL IL12470192A patent/IL124701A/xx not_active IP Right Cessation
-
1994
- 1994-09-21 US US08/310,020 patent/US5495039A/en not_active Expired - Lifetime
- 1994-12-01 AU AU79176/94A patent/AU687908B2/en not_active Expired
-
1998
- 1998-05-29 IL IL12470198A patent/IL124701A0/xx unknown
Also Published As
Publication number | Publication date |
---|---|
GB9110123D0 (en) | 1991-07-03 |
ZA923318B (en) | 1993-07-02 |
IL101811A (en) | 1999-06-20 |
DE69208582D1 (de) | 1996-04-04 |
AU1677192A (en) | 1992-12-30 |
IL124701A0 (en) | 1998-12-06 |
US5495039A (en) | 1996-02-27 |
DE69208582T2 (de) | 1996-10-02 |
AU652633B2 (en) | 1994-09-01 |
IL101811A0 (en) | 1992-12-30 |
EP0538431A1 (en) | 1993-04-28 |
AU687908B2 (en) | 1998-03-05 |
DK0538431T3 (da) | 1996-04-09 |
ATE134635T1 (de) | 1996-03-15 |
SG49054A1 (en) | 1998-05-18 |
BR9205272A (pt) | 1993-07-27 |
IL124701A (en) | 1999-08-17 |
WO1992020690A1 (en) | 1992-11-26 |
JP2854977B2 (ja) | 1999-02-10 |
US5403944A (en) | 1995-04-04 |
AU7917694A (en) | 1995-02-16 |
EP0538431B1 (en) | 1996-02-28 |
ES2084356T3 (es) | 1996-05-01 |
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