JPH06100479A - 酢酸、酢酸メチル及び無水酢酸の同時製造方法 - Google Patents

酢酸、酢酸メチル及び無水酢酸の同時製造方法

Info

Publication number
JPH06100479A
JPH06100479A JP16092793A JP16092793A JPH06100479A JP H06100479 A JPH06100479 A JP H06100479A JP 16092793 A JP16092793 A JP 16092793A JP 16092793 A JP16092793 A JP 16092793A JP H06100479 A JPH06100479 A JP H06100479A
Authority
JP
Japan
Prior art keywords
methyl acetate
acetic acid
carbon monoxide
methanol
rhodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16092793A
Other languages
English (en)
Japanese (ja)
Inventor
Sung Jin Uhm
性 鎭 嚴
Sung Hwan Han
成 煥 韓
Jun Woo Oh
俊 雨 呉
Oh Shim Joo
五 心 朱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Advanced Institute of Science and Technology KAIST
Original Assignee
Korea Advanced Institute of Science and Technology KAIST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1019920011524A external-priority patent/KR940000148A/ko
Priority claimed from KR1019920020188A external-priority patent/KR960005512B1/ko
Priority claimed from KR1019920025281A external-priority patent/KR960003797B1/ko
Application filed by Korea Advanced Institute of Science and Technology KAIST filed Critical Korea Advanced Institute of Science and Technology KAIST
Publication of JPH06100479A publication Critical patent/JPH06100479A/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/54—Preparation of carboxylic acid anhydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0231—Halogen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP16092793A 1992-06-30 1993-06-30 酢酸、酢酸メチル及び無水酢酸の同時製造方法 Pending JPH06100479A (ja)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR1019920011524A KR940000148A (ko) 1992-06-30 1992-06-30 기상 메탄올 카르보닐화 반응용 촉매 및 이를 이용한 아세트산의 개선된 제조방법
KR1019920020188A KR960005512B1 (ko) 1992-10-30 1992-10-30 메틸 아세테이트, 아세트산 및 무수 아세트산의 병산 방법
KR25281/1992 1992-12-23
KR11524/1992 1992-12-23
KR20188/1992 1992-12-23
KR1019920025281A KR960003797B1 (ko) 1992-12-23 1992-12-23 비균질계 기상 메탄올 카르보닐화 반응에 의한 아세트산의 개선된 제조 방법

Publications (1)

Publication Number Publication Date
JPH06100479A true JPH06100479A (ja) 1994-04-12

Family

ID=27348838

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16092793A Pending JPH06100479A (ja) 1992-06-30 1993-06-30 酢酸、酢酸メチル及び無水酢酸の同時製造方法

Country Status (2)

Country Link
JP (1) JPH06100479A (de)
DE (1) DE4321766C2 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008523040A (ja) * 2004-12-09 2008-07-03 ビーピー ケミカルズ リミテッド カルボニル化生成物の製造方法
CN115870007A (zh) * 2022-11-30 2023-03-31 东南大学 一种用于乙烯羰基化合成丙酸酯的复合催化剂及其使用方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960006546B1 (ko) * 1993-07-28 1996-05-17 한국과학기술연구원 초산에스테르의 제조 방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS523926A (en) * 1975-06-25 1977-01-12 Nippon Soken Inc Fuel injection device for internal combustion engine
JPS6369719A (ja) * 1986-07-31 1988-03-29 ビ−ピ−　ケミカルズ　リミテツド 金属の回収方法
JPH04257538A (ja) * 1990-10-03 1992-09-11 Bp Chem Internatl Ltd カルボン酸無水物の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2450965C2 (de) * 1974-10-26 1983-06-09 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Essigsäureanhydrid
JPS6043767B2 (ja) * 1981-06-26 1985-09-30 薫 藤元 アルコ−ルのカルボニル化用触媒
DE3323654A1 (de) * 1983-07-01 1985-01-03 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von essigsaeure und methylacetat

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS523926A (en) * 1975-06-25 1977-01-12 Nippon Soken Inc Fuel injection device for internal combustion engine
JPS6369719A (ja) * 1986-07-31 1988-03-29 ビ−ピ−　ケミカルズ　リミテツド 金属の回収方法
JPH04257538A (ja) * 1990-10-03 1992-09-11 Bp Chem Internatl Ltd カルボン酸無水物の製造方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008523040A (ja) * 2004-12-09 2008-07-03 ビーピー ケミカルズ リミテッド カルボニル化生成物の製造方法
KR101270855B1 (ko) * 2004-12-09 2013-06-05 비피 케미칼즈 리미티드 카르보닐화 생성물의 제조 방법
CN115870007A (zh) * 2022-11-30 2023-03-31 东南大学 一种用于乙烯羰基化合成丙酸酯的复合催化剂及其使用方法
CN115870007B (zh) * 2022-11-30 2024-03-15 东南大学 一种用于乙烯羰基化合成丙酸酯的复合催化剂及其使用方法

Also Published As

Publication number Publication date
DE4321766A1 (de) 1994-01-05
DE4321766C2 (de) 1996-11-28

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