JPH0581680B2 - - Google Patents
Info
- Publication number
- JPH0581680B2 JPH0581680B2 JP61079620A JP7962086A JPH0581680B2 JP H0581680 B2 JPH0581680 B2 JP H0581680B2 JP 61079620 A JP61079620 A JP 61079620A JP 7962086 A JP7962086 A JP 7962086A JP H0581680 B2 JPH0581680 B2 JP H0581680B2
- Authority
- JP
- Japan
- Prior art keywords
- plating
- alloy plating
- zincate
- plating bath
- additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000007747 plating Methods 0.000 claims description 52
- 239000000654 additive Substances 0.000 claims description 17
- 239000002184 metal Chemical class 0.000 claims description 16
- 229910052751 metal Chemical class 0.000 claims description 16
- 230000000996 additive effect Effects 0.000 claims description 15
- 229920000768 polyamine Polymers 0.000 claims description 13
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 12
- 229920001281 polyalkylene Polymers 0.000 claims description 11
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000008139 complexing agent Substances 0.000 claims description 6
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 239000000956 alloy Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 6
- -1 NaOH Chemical class 0.000 description 5
- 229920002873 Polyethylenimine Polymers 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 229910007567 Zn-Ni Inorganic materials 0.000 description 4
- 229910007614 Zn—Ni Inorganic materials 0.000 description 4
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 239000002168 alkylating agent Substances 0.000 description 3
- 229940100198 alkylating agent Drugs 0.000 description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- BUAXCDYBNXEWEB-UHFFFAOYSA-N 2-(chloromethyl)oxirane;n-methylmethanamine Chemical compound CNC.ClCC1CO1 BUAXCDYBNXEWEB-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229910000640 Fe alloy Inorganic materials 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 2
- 241000080590 Niso Species 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005246 galvanizing Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- ZRSNZINYAWTAHE-UHFFFAOYSA-N p-methoxybenzaldehyde Chemical compound COC1=CC=C(C=O)C=C1 ZRSNZINYAWTAHE-UHFFFAOYSA-N 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 description 2
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 description 2
- 235000012141 vanillin Nutrition 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 description 1
- SDKQKTMVNUGBPR-UHFFFAOYSA-N 2-(chloromethyl)oxirane;1h-imidazole Chemical compound C1=CNC=N1.ClCC1CO1 SDKQKTMVNUGBPR-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229910018661 Ni(OH) Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- 229940001468 citrate Drugs 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- SATCULPHIDQDRE-UHFFFAOYSA-N piperonal Chemical compound O=CC1=CC=C2OCOC2=C1 SATCULPHIDQDRE-UHFFFAOYSA-N 0.000 description 1
- 229920000333 poly(propyleneimine) Polymers 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Electroplating And Plating Baths Therefor (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7962086A JPS62238387A (ja) | 1986-04-07 | 1986-04-07 | ジンケ−ト型亜鉛合金めつき浴 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7962086A JPS62238387A (ja) | 1986-04-07 | 1986-04-07 | ジンケ−ト型亜鉛合金めつき浴 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62238387A JPS62238387A (ja) | 1987-10-19 |
| JPH0581680B2 true JPH0581680B2 (zh) | 1993-11-15 |
Family
ID=13695103
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7962086A Granted JPS62238387A (ja) | 1986-04-07 | 1986-04-07 | ジンケ−ト型亜鉛合金めつき浴 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62238387A (zh) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62240788A (ja) * | 1986-04-14 | 1987-10-21 | Deitsupusoole Kk | 亜鉛−ニツケル合金用めつき浴 |
| JPH02141596A (ja) * | 1988-11-21 | 1990-05-30 | Yuken Kogyo Kk | ジンケート型亜鉛合金メッキ浴 |
| JP4570738B2 (ja) * | 1999-08-05 | 2010-10-27 | 日本表面化学株式会社 | 電気亜鉛めっき浴及びめっき方法 |
| JP5219011B2 (ja) | 1999-11-10 | 2013-06-26 | 日本表面化学株式会社 | 表面処理液、表面処理剤及び表面処理方法 |
| EP4074867A1 (en) | 2019-12-11 | 2022-10-19 | Yuken Industry Co., Ltd. | Alkaline zinc-iron plating bath |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5380334A (en) * | 1976-12-24 | 1978-07-15 | Basf Ag | Zinc electroplating bath |
-
1986
- 1986-04-07 JP JP7962086A patent/JPS62238387A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5380334A (en) * | 1976-12-24 | 1978-07-15 | Basf Ag | Zinc electroplating bath |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS62238387A (ja) | 1987-10-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4263363B2 (ja) | 亜鉛被膜または亜鉛合金被膜のめっき堆積のためのシアン化物を含まない水性アルカリ浴 | |
| US4488942A (en) | Zinc and zinc alloy electroplating bath and process | |
| CA2159268C (en) | Alkaline zinc and zinc alloy electroplating baths and processes | |
| US4134802A (en) | Electrolyte and method for electrodepositing bright metal deposits | |
| US4889602A (en) | Electroplating bath and method for forming zinc-nickel alloy coating | |
| KR101502804B1 (ko) | Ｐｄ 및 Ｐｄ-Ｎｉ 전해질 욕조 | |
| US4877496A (en) | Zinc-nickel alloy plating solution | |
| JPH06287791A (ja) | シアン化物を含まない１価金属のメッキ溶液 | |
| US5552031A (en) | Palladium alloy plating compositions | |
| US5169514A (en) | Plating compositions and processes | |
| US3864222A (en) | Baths for Electrodeposition of Gold and Gold Alloys and Method Therefore | |
| EP1075553B1 (en) | Zinc and zinc alloy electroplating additives and electroplating methods | |
| JPS6056085A (ja) | 亜鉛／鉄合金めつき浴及び方法 | |
| US4278514A (en) | Bright palladium electrodeposition solution | |
| JPH0319308B2 (zh) | ||
| EP2350355A1 (en) | Zinc alloy electroplating baths and processes | |
| CA1077429A (en) | Bath and process for the electrodeposition of a palladium-nickel alloy | |
| JP3171117B2 (ja) | ニッケル、コバルト又はニッケル・コバルト合金とリンとの合金めっき浴及びめっき方法 | |
| US5582709A (en) | Zinc-cobalt alloy-plating alkaline bath and plating method using the same | |
| JPH0581680B2 (zh) | ||
| US5194140A (en) | Electroplating composition and process | |
| JP2769614B2 (ja) | 亜鉛−ニツケル合金用めつき浴 | |
| EP0225422A1 (en) | Alkaline baths and methods for electrodeposition of palladium and palladium alloys | |
| WO2003006360A2 (en) | Brightener for zinc-nickel plating bath | |
| US4134804A (en) | Cyanide-free zinc plating bath and process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |