JPH0579977B2 - - Google Patents

Info

Publication number

JPH0579977B2

JPH0579977B2 JP61132473A JP13247386A JPH0579977B2 JP H0579977 B2 JPH0579977 B2 JP H0579977B2 JP 61132473 A JP61132473 A JP 61132473A JP 13247386 A JP13247386 A JP 13247386A JP H0579977 B2 JPH0579977 B2 JP H0579977B2

Authority

JP

Japan

Prior art keywords

group

acid

silver

layer

heat

Prior art date

1986-06-07

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

Links

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• -1 silver halide Chemical class 0.000 claims description 151
• 239000002253 acid Substances 0.000 claims description 96
• 239000000463 material Substances 0.000 claims description 94
• 229910052709 silver Inorganic materials 0.000 claims description 87
• 239000004332 silver Substances 0.000 claims description 87
• 239000000126 substance Substances 0.000 claims description 66
• 239000003094 microcapsule Substances 0.000 claims description 58
• 239000002243 precursor Substances 0.000 claims description 51
• 239000011230 binding agent Substances 0.000 claims description 24
• 239000003638 chemical reducing agent Substances 0.000 claims description 21
• 239000011162 core material Substances 0.000 claims description 20
• 239000010410 layer Substances 0.000 description 164
• 150000001875 compounds Chemical class 0.000 description 77
• 239000000975 dye Substances 0.000 description 74
• 238000000034 method Methods 0.000 description 58
• 108010010803 Gelatin Proteins 0.000 description 47
• 229920000159 gelatin Polymers 0.000 description 47
• 235000019322 gelatine Nutrition 0.000 description 47
• 235000011852 gelatine desserts Nutrition 0.000 description 47
• 239000008273 gelatin Substances 0.000 description 45
• 229920000642 polymer Polymers 0.000 description 42
• 239000000839 emulsion Substances 0.000 description 40
• 238000011161 development Methods 0.000 description 31
• 239000011241 protective layer Substances 0.000 description 31
• 239000000243 solution Substances 0.000 description 27
• 239000006185 dispersion Substances 0.000 description 25
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
• 238000002360 preparation method Methods 0.000 description 24
• 125000000217 alkyl group Chemical group 0.000 description 23
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 22
• 239000003795 chemical substances by application Substances 0.000 description 22
• 239000002904 solvent Substances 0.000 description 22
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 20
• 125000001424 substituent group Chemical group 0.000 description 19
• 239000007864 aqueous solution Substances 0.000 description 18
• 150000007513 acids Chemical class 0.000 description 17
• 239000000203 mixture Substances 0.000 description 17
• 239000002245 particle Substances 0.000 description 17
• 229920001577 copolymer Polymers 0.000 description 16
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
• 125000003118 aryl group Chemical group 0.000 description 15
• 239000011248 coating agent Substances 0.000 description 15
• 238000000576 coating method Methods 0.000 description 15
• 239000004848 polyfunctional curative Substances 0.000 description 15
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
• 125000000623 heterocyclic group Chemical group 0.000 description 14
• 229920000036 polyvinylpyrrolidone Polymers 0.000 description 14
• 239000001267 polyvinylpyrrolidone Substances 0.000 description 14
• 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 14
• GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 14
• 150000003378 silver Chemical class 0.000 description 13
• 239000004372 Polyvinyl alcohol Substances 0.000 description 12
• 125000004432 carbon atom Chemical group C* 0.000 description 12
• 239000000178 monomer Substances 0.000 description 12
• 229920002451 polyvinyl alcohol Polymers 0.000 description 12
• 239000006224 matting agent Substances 0.000 description 11
• 239000000123 paper Substances 0.000 description 11
• 238000010438 heat treatment Methods 0.000 description 10
• 150000007524 organic acids Chemical class 0.000 description 10
• 229920001223 polyethylene glycol Polymers 0.000 description 10
• 239000007787 solid Substances 0.000 description 10
• 238000003860 storage Methods 0.000 description 10
• 239000002202 Polyethylene glycol Substances 0.000 description 9
• 239000004094 surface-active agent Substances 0.000 description 9
• 238000012546 transfer Methods 0.000 description 9
• PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
• 238000006243 chemical reaction Methods 0.000 description 8
• 125000000753 cycloalkyl group Chemical group 0.000 description 8
• 125000004435 hydrogen atom Chemical group [H]* 0.000 description 8
• RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 8
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
• 239000000049 pigment Substances 0.000 description 8
• 238000011160 research Methods 0.000 description 8
• WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 7
• 239000000654 additive Substances 0.000 description 7
• 125000003545 alkoxy group Chemical group 0.000 description 7
• 238000005859 coupling reaction Methods 0.000 description 7
• 230000006870 function Effects 0.000 description 7
• 229920000139 polyethylene terephthalate Polymers 0.000 description 7
• 239000005020 polyethylene terephthalate Substances 0.000 description 7
• ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 7
• 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 7
• 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
• 229920002554 vinyl polymer Polymers 0.000 description 7
• SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• 239000002585 base Substances 0.000 description 6
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
• 230000008878 coupling Effects 0.000 description 6
• 238000010168 coupling process Methods 0.000 description 6
• 238000009826 distribution Methods 0.000 description 6
• 150000002148 esters Chemical class 0.000 description 6
• 235000019589 hardness Nutrition 0.000 description 6
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
• 238000004519 manufacturing process Methods 0.000 description 6
• 150000002894 organic compounds Chemical class 0.000 description 6
• 230000036961 partial effect Effects 0.000 description 6
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 6
• NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 5
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 5
• 206010070834 Sensitisation Diseases 0.000 description 5
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
• 230000002378 acidificating effect Effects 0.000 description 5
• 125000004429 atom Chemical group 0.000 description 5
• 238000009835 boiling Methods 0.000 description 5
• CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 5
• 239000008119 colloidal silica Substances 0.000 description 5
• 239000000470 constituent Substances 0.000 description 5
• 235000014113 dietary fatty acids Nutrition 0.000 description 5
• 239000012153 distilled water Substances 0.000 description 5
• 239000000194 fatty acid Substances 0.000 description 5
• 229930195729 fatty acid Natural products 0.000 description 5
• 125000005843 halogen group Chemical group 0.000 description 5
• 229910052751 metal Chemical group 0.000 description 5
• 239000002184 metal Chemical group 0.000 description 5
• 125000001624 naphthyl group Chemical group 0.000 description 5
• 229910052757 nitrogen Inorganic materials 0.000 description 5
• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 5
• 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
• 229920000515 polycarbonate Polymers 0.000 description 5
• 239000004417 polycarbonate Substances 0.000 description 5
• 238000006116 polymerization reaction Methods 0.000 description 5
• 229920005989 resin Polymers 0.000 description 5
• 239000011347 resin Substances 0.000 description 5
• 230000035945 sensitivity Effects 0.000 description 5
• 230000008313 sensitization Effects 0.000 description 5
• 230000001235 sensitizing effect Effects 0.000 description 5
• 229940124530 sulfonamide Drugs 0.000 description 5
• QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 4
• KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
• SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
• JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 4
• DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 4
• JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
• 238000012695 Interfacial polymerization Methods 0.000 description 4
• UHBGYFCCKRAEHA-UHFFFAOYSA-N P-toluamide Chemical compound CC1=CC=C(C(N)=O)C=C1 UHBGYFCCKRAEHA-UHFFFAOYSA-N 0.000 description 4
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
• 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
• JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
• 229910021612 Silver iodide Inorganic materials 0.000 description 4
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
• XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
• 125000002947 alkylene group Chemical group 0.000 description 4
• 125000003277 amino group Chemical group 0.000 description 4
• 239000002216 antistatic agent Substances 0.000 description 4
• KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
• 239000004327 boric acid Substances 0.000 description 4
• 239000004202 carbamide Substances 0.000 description 4
• 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 4
• 229920002301 cellulose acetate Polymers 0.000 description 4
• 239000000084 colloidal system Substances 0.000 description 4
• 125000004093 cyano group Chemical group *C#N 0.000 description 4
• 230000006866 deterioration Effects 0.000 description 4
• 230000000694 effects Effects 0.000 description 4
• 238000010894 electron beam technology Methods 0.000 description 4
• NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
• QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
• 239000004816 latex Substances 0.000 description 4
• 229920000126 latex Polymers 0.000 description 4
• 239000007788 liquid Substances 0.000 description 4
• 239000000693 micelle Substances 0.000 description 4
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 4
• 239000003921 oil Substances 0.000 description 4
• 125000000962 organic group Chemical group 0.000 description 4
• PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
• 239000004926 polymethyl methacrylate Substances 0.000 description 4
• 238000006722 reduction reaction Methods 0.000 description 4
• 239000011342 resin composition Substances 0.000 description 4
• 150000003839 salts Chemical class 0.000 description 4
• 239000004576 sand Substances 0.000 description 4
• 229940045105 silver iodide Drugs 0.000 description 4
• 239000002356 single layer Substances 0.000 description 4
• 239000003381 stabilizer Substances 0.000 description 4
• 238000003756 stirring Methods 0.000 description 4
• 150000003456 sulfonamides Chemical class 0.000 description 4
• 150000003512 tertiary amines Chemical class 0.000 description 4
• 238000012360 testing method Methods 0.000 description 4
• 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 3
• WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 3
• WVKWKEWFTVEVCF-UHFFFAOYSA-N 2h-benzotriazole-4-sulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC2=NNN=C12 WVKWKEWFTVEVCF-UHFFFAOYSA-N 0.000 description 3
• IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 3
• PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
• QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
• CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
• 229910019142 PO4 Inorganic materials 0.000 description 3
• 239000004793 Polystyrene Substances 0.000 description 3
• 229910021607 Silver chloride Inorganic materials 0.000 description 3
• XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
• 239000012190 activator Substances 0.000 description 3
• 125000004423 acyloxy group Chemical group 0.000 description 3
• 125000001931 aliphatic group Chemical group 0.000 description 3
• 125000003342 alkenyl group Chemical group 0.000 description 3
• 125000004390 alkyl sulfonyl group Chemical group 0.000 description 3
• 150000001408 amides Chemical class 0.000 description 3
• 150000001412 amines Chemical class 0.000 description 3
• 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 3
• 125000004391 aryl sulfonyl group Chemical group 0.000 description 3
• 125000004104 aryloxy group Chemical group 0.000 description 3
• QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
• 229910001864 baryta Inorganic materials 0.000 description 3
• 150000001565 benzotriazoles Chemical class 0.000 description 3
• 239000011247 coating layer Substances 0.000 description 3
• 239000013078 crystal Substances 0.000 description 3
• 230000003247 decreasing effect Effects 0.000 description 3
• MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
• 238000009792 diffusion process Methods 0.000 description 3
• 239000010419 fine particle Substances 0.000 description 3
• 125000001841 imino group Chemical class [H]N=* 0.000 description 3
• 238000002844 melting Methods 0.000 description 3
• 230000008018 melting Effects 0.000 description 3
• 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 3
• 239000003960 organic solvent Substances 0.000 description 3
• 235000021317 phosphate Nutrition 0.000 description 3
• 229920002223 polystyrene Polymers 0.000 description 3
• 239000004800 polyvinyl chloride Substances 0.000 description 3
• 229920000915 polyvinyl chloride Polymers 0.000 description 3
• 229920006316 polyvinylpyrrolidine Polymers 0.000 description 3
• NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
• JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 3
• 230000009467 reduction Effects 0.000 description 3
• HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
• 229910001961 silver nitrate Inorganic materials 0.000 description 3
• 125000005504 styryl group Chemical group 0.000 description 3
• 150000005846 sugar alcohols Polymers 0.000 description 3
• 125000004964 sulfoalkyl group Chemical group 0.000 description 3
• OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
• VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
• 239000001993 wax Substances 0.000 description 3
• QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 2
• LUBJCRLGQSPQNN-UHFFFAOYSA-N 1-Phenylurea Chemical compound NC(=O)NC1=CC=CC=C1 LUBJCRLGQSPQNN-UHFFFAOYSA-N 0.000 description 2
• SGWZVZZVXOJRAQ-UHFFFAOYSA-N 2,6-Dimethyl-1,4-benzenediol Chemical compound CC1=CC(O)=CC(C)=C1O SGWZVZZVXOJRAQ-UHFFFAOYSA-N 0.000 description 2
• OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
• JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
• JWAZRIHNYRIHIV-UHFFFAOYSA-N 2-naphthol Chemical compound C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 2
• LRUDIIUSNGCQKF-UHFFFAOYSA-N 5-methyl-1H-benzotriazole Chemical compound C1=C(C)C=CC2=NNN=C21 LRUDIIUSNGCQKF-UHFFFAOYSA-N 0.000 description 2
• 244000215068 Acacia senegal Species 0.000 description 2
• 229920000178 Acrylic resin Polymers 0.000 description 2
• 239000004925 Acrylic resin Substances 0.000 description 2
• PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
• KXDAEFPNCMNJSK-UHFFFAOYSA-N Benzamide Chemical compound NC(=O)C1=CC=CC=C1 KXDAEFPNCMNJSK-UHFFFAOYSA-N 0.000 description 2
• LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
• VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
• 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
• ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
• 239000001856 Ethyl cellulose Substances 0.000 description 2
• VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
• 229920000084 Gum arabic Polymers 0.000 description 2
• OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
• CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
• BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
• PCLIMKBDDGJMGD-UHFFFAOYSA-N N-bromosuccinimide Chemical compound BrN1C(=O)CCC1=O PCLIMKBDDGJMGD-UHFFFAOYSA-N 0.000 description 2
• JRNVZBWKYDBUCA-UHFFFAOYSA-N N-chlorosuccinimide Chemical compound ClN1C(=O)CCC1=O JRNVZBWKYDBUCA-UHFFFAOYSA-N 0.000 description 2
• LQZMLBORDGWNPD-UHFFFAOYSA-N N-iodosuccinimide Chemical compound IN1C(=O)CCC1=O LQZMLBORDGWNPD-UHFFFAOYSA-N 0.000 description 2
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