JPH052336B2 - - Google Patents

Info

Publication number

JPH052336B2

JPH052336B2 JP60106653A JP10665385A JPH052336B2 JP H052336 B2 JPH052336 B2 JP H052336B2 JP 60106653 A JP60106653 A JP 60106653A JP 10665385 A JP10665385 A JP 10665385A JP H052336 B2 JPH052336 B2 JP H052336B2

Authority

JP

Japan

Prior art keywords

iron

compound

aqueous solution

solid

deodorizing

Prior art date

1985-05-18

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired - Lifetime

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• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 38
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 23
• KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
• 239000007787 solid Substances 0.000 claims description 21
• 229910052742 iron Inorganic materials 0.000 claims description 19
• 239000002245 particle Substances 0.000 claims description 18
• 150000001875 compounds Chemical class 0.000 claims description 17
• 239000000203 mixture Substances 0.000 claims description 16
• 239000011148 porous material Substances 0.000 claims description 16
• 229920002301 cellulose acetate Polymers 0.000 claims description 13
• 229960005070 ascorbic acid Drugs 0.000 claims description 11
• 235000010323 ascorbic acid Nutrition 0.000 claims description 9
• 239000011668 ascorbic acid Substances 0.000 claims description 9
• 230000021736 acetylation Effects 0.000 claims description 8
• 238000006640 acetylation reaction Methods 0.000 claims description 8
• 150000002506 iron compounds Chemical class 0.000 claims description 3
• 230000001877 deodorizing effect Effects 0.000 description 20
• 239000007864 aqueous solution Substances 0.000 description 19
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 15
• HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
• 239000003795 chemical substances by application Substances 0.000 description 9
• 238000000034 method Methods 0.000 description 7
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
• 229910021529 ammonia Inorganic materials 0.000 description 6
• 238000001035 drying Methods 0.000 description 6
• 235000019645 odor Nutrition 0.000 description 6
• 239000000243 solution Substances 0.000 description 5
• 239000007789 gas Substances 0.000 description 4
• 238000005470 impregnation Methods 0.000 description 4
• CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 3
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
• 230000000052 comparative effect Effects 0.000 description 3
• 239000007788 liquid Substances 0.000 description 3
• 239000000843 powder Substances 0.000 description 3
• CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
• 239000002211 L-ascorbic acid Substances 0.000 description 2
• 235000000069 L-ascorbic acid Nutrition 0.000 description 2
• 229910021536 Zeolite Inorganic materials 0.000 description 2
• PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
• HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
• 239000011790 ferrous sulphate Substances 0.000 description 2
• 235000003891 ferrous sulphate Nutrition 0.000 description 2
• LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
• BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
• 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
• 238000004519 manufacturing process Methods 0.000 description 2
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
• 229910052753 mercury Inorganic materials 0.000 description 2
• 150000003839 salts Chemical class 0.000 description 2
• 238000004448 titration Methods 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• 239000010457 zeolite Substances 0.000 description 2
• KRUJOKMDEHYPOP-UHFFFAOYSA-L 2-hydroxybutanedioate;iron(2+) Chemical compound [Fe+2].[O-]C(=O)C(O)CC([O-])=O KRUJOKMDEHYPOP-UHFFFAOYSA-L 0.000 description 1
• 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
• 229920001747 Cellulose diacetate Polymers 0.000 description 1
• PMVSDNDAUGGCCE-TYYBGVCCSA-L Ferrous fumarate Chemical compound [Fe+2].[O-]C(=O)\C=C\C([O-])=O PMVSDNDAUGGCCE-TYYBGVCCSA-L 0.000 description 1
• 229910021575 Iron(II) bromide Inorganic materials 0.000 description 1
• VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
• 229910002651 NO3 Inorganic materials 0.000 description 1
• NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
• 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
• 239000011230 binding agent Substances 0.000 description 1
• 239000001768 carboxy methyl cellulose Substances 0.000 description 1
• 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
• 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
• 230000001112 coagulating effect Effects 0.000 description 1
• 230000015271 coagulation Effects 0.000 description 1
• 238000005345 coagulation Methods 0.000 description 1
• 239000003245 coal Substances 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 238000000576 coating method Methods 0.000 description 1
• 230000006378 damage Effects 0.000 description 1
• 239000002781 deodorant agent Substances 0.000 description 1
• 238000004090 dissolution Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 235000010350 erythorbic acid Nutrition 0.000 description 1
• 239000004318 erythorbic acid Substances 0.000 description 1
• 229940046149 ferrous bromide Drugs 0.000 description 1
• 229960002089 ferrous chloride Drugs 0.000 description 1
• 239000011773 ferrous fumarate Substances 0.000 description 1
• 229960000225 ferrous fumarate Drugs 0.000 description 1
• 235000002332 ferrous fumarate Nutrition 0.000 description 1
• 229940076136 ferrous iodide Drugs 0.000 description 1
• 238000011049 filling Methods 0.000 description 1
• LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 1
• 239000011521 glass Substances 0.000 description 1
• 229940015043 glyoxal Drugs 0.000 description 1
• 239000008187 granular material Substances 0.000 description 1
• 238000000227 grinding Methods 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 238000002347 injection Methods 0.000 description 1
• 239000007924 injection Substances 0.000 description 1
• NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 1
• -1 iron ions Chemical class 0.000 description 1
• GYCHYNMREWYSKH-UHFFFAOYSA-L iron(ii) bromide Chemical compound [Fe+2].[Br-].[Br-] GYCHYNMREWYSKH-UHFFFAOYSA-L 0.000 description 1
• BQZGVMWPHXIKEQ-UHFFFAOYSA-L iron(ii) iodide Chemical compound [Fe+2].[I-].[I-] BQZGVMWPHXIKEQ-UHFFFAOYSA-L 0.000 description 1
• 230000001788 irregular Effects 0.000 description 1
• 229940026239 isoascorbic acid Drugs 0.000 description 1
• 230000005923 long-lasting effect Effects 0.000 description 1
• 239000002184 metal Substances 0.000 description 1
• 229910052751 metal Inorganic materials 0.000 description 1
• 238000000465 moulding Methods 0.000 description 1
• 230000009965 odorless effect Effects 0.000 description 1
• 230000035515 penetration Effects 0.000 description 1
• 230000000704 physical effect Effects 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 238000001179 sorption measurement Methods 0.000 description 1
• 239000003381 stabilizer Substances 0.000 description 1
• 238000003756 stirring Methods 0.000 description 1
• 238000003860 storage Methods 0.000 description 1
• 238000005406 washing Methods 0.000 description 1