JPH0512355B2 - - Google Patents
Info
- Publication number
- JPH0512355B2 JPH0512355B2 JP61293075A JP29307586A JPH0512355B2 JP H0512355 B2 JPH0512355 B2 JP H0512355B2 JP 61293075 A JP61293075 A JP 61293075A JP 29307586 A JP29307586 A JP 29307586A JP H0512355 B2 JPH0512355 B2 JP H0512355B2
- Authority
- JP
- Japan
- Prior art keywords
- bis
- dimethylbiphenyl
- ruthenium
- complex
- diphenylphosphino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- GTBPUYSGSDIIMM-UHFFFAOYSA-N phosphane;ruthenium Chemical compound P.[Ru] GTBPUYSGSDIIMM-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61293075A JPS63145291A (ja) | 1986-12-09 | 1986-12-09 | ルテニウム−ホスフイン錯体 |
DE8787310762T DE3784226T2 (de) | 1986-12-09 | 1987-12-08 | Ruthenium-phosphin-komplexe. |
EP87310762A EP0271311B1 (en) | 1986-12-09 | 1987-12-08 | Ruthenium-phosphine complexes |
US07/130,577 US4766225A (en) | 1986-12-09 | 1987-12-09 | Ruthenium-phosphine complex |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61293075A JPS63145291A (ja) | 1986-12-09 | 1986-12-09 | ルテニウム−ホスフイン錯体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63145291A JPS63145291A (ja) | 1988-06-17 |
JPH0512355B2 true JPH0512355B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-02-17 |
Family
ID=17790124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61293075A Granted JPS63145291A (ja) | 1986-12-09 | 1986-12-09 | ルテニウム−ホスフイン錯体 |
Country Status (4)
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE59009670D1 (de) * | 1989-05-18 | 1995-10-26 | Hoffmann La Roche | Phosphorverbindungen. |
US5198561A (en) * | 1989-06-22 | 1993-03-30 | Monsanto Company | Ruthenium-BINAP asymmetric hydrogenation catalyst |
US5202474A (en) * | 1989-06-22 | 1993-04-13 | Monsanto Company | Asymmetric catalytic hydrogenation of α-arylpropenoic acids |
US5233084A (en) * | 1989-06-22 | 1993-08-03 | Monsanto Company | Method for preparing α-arylpropionic acids |
FR2651152B1 (fr) * | 1989-08-23 | 1991-11-29 | Elf Aquitaine | Perfectionnement a la preparation de catalyseurs chiraux a base de complexes du ruthenium et du phosphore. |
FR2671079B1 (fr) * | 1990-12-28 | 1994-06-03 | Elf Aquitaine | Procede d'hydrogenation de composes organiques et catalyseurs au ruthenium pour sa realisation. |
US5144050A (en) * | 1991-10-01 | 1992-09-01 | Monsanto Company | Ruthenium(II)-BINAP diketonate complexes |
US5412109A (en) * | 1992-07-16 | 1995-05-02 | Takasago International Corporation | Process for preparing optically active 4-methyl-2-oxetanone |
JP3310056B2 (ja) * | 1992-07-16 | 2002-07-29 | 高砂香料工業株式会社 | 光学活性4−メチル−2−オキセタノンの製造方法 |
EP0592881B1 (en) | 1992-10-05 | 1998-05-20 | Takasago International Corporation | Process for producing optically active gamma-hydroxyketones |
US5556998A (en) * | 1994-09-14 | 1996-09-17 | Takasago International Corporation | Transition metal complex, process for the preparation of the same, and asymmetric hydrogenation catalyst comprising the same |
DE19516968A1 (de) * | 1995-05-12 | 1996-11-14 | Basf Ag | Optisch aktive Phosphine, deren Herstellung, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
DE19548399A1 (de) * | 1995-12-22 | 1997-06-26 | Basf Ag | Rutheniumkomplexe mit einem chiralen, zweizähnigen Phosphinoxazolin-Liganden zur enantioselektiven Transferhydrierung von prochiralen Ketonen |
US6096920A (en) * | 1997-01-08 | 2000-08-01 | Albemarle Corporation | Preparation of carboxylic compounds and their derivatives |
US5792886A (en) * | 1997-01-08 | 1998-08-11 | Albemarle Corporation | Production of racemic 2-(6-methoxy-2-naphthyl) propionic acid of precursors thereof |
US6080888A (en) * | 1997-01-08 | 2000-06-27 | Albemarle Corporation | Preparation of olefinic compounds and carboxylic derivatives thereof |
DE19725796A1 (de) * | 1997-06-18 | 1998-12-24 | Basf Ag | Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
DE19725643A1 (de) * | 1997-06-18 | 1998-12-24 | Basf Ag | Optisch aktive Diphosphinliganden |
DE19824121A1 (de) | 1998-05-29 | 1999-12-02 | Basf Ag | Herstellung optisch aktiver Phospholane, deren Metallkomplexe und Anwendung in der asymmetrischen Synthese |
US6184415B1 (en) | 1999-11-01 | 2001-02-06 | Albemarle Corporation | Production of chiral non-racemic 2-halopropionic acid or salt thereof |
JP4534469B2 (ja) * | 2003-11-28 | 2010-09-01 | Jsr株式会社 | 金属ヒドリド錯体の製造方法 |
ES2709759T3 (es) * | 2010-05-21 | 2019-04-17 | Firmenich & Cie | Complejos a base de rutenio |
JP5897827B2 (ja) | 2010-06-25 | 2016-03-30 | サンドビック サーマル プロセス,インコーポレイティド | 加熱エレメント・コイルの支持構造 |
JP2023530856A (ja) * | 2020-06-19 | 2023-07-20 | ディーエスエム アイピー アセッツ ビー.ブイ. | 特定のα,β-不飽和カルボキシレートを製造するための改善されたプロセス |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1326012A (en) * | 1969-07-14 | 1973-08-08 | Johnson Matthey Co Ltd | Catalyst compositions |
DK350283A (da) * | 1982-08-27 | 1984-02-28 | Hoffmann La Roche | Fremgangsmaade til fremstilling af optisk aktive forbindelser |
JPS60199898A (ja) * | 1984-03-22 | 1985-10-09 | Takasago Corp | ロジウム−ホスフイン錯体 |
JPS6163690A (ja) * | 1984-09-04 | 1986-04-01 | Takasago Corp | ルテニウム−ホスフイン錯体 |
-
1986
- 1986-12-09 JP JP61293075A patent/JPS63145291A/ja active Granted
-
1987
- 1987-12-08 EP EP87310762A patent/EP0271311B1/en not_active Expired - Lifetime
- 1987-12-08 DE DE8787310762T patent/DE3784226T2/de not_active Expired - Fee Related
- 1987-12-09 US US07/130,577 patent/US4766225A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE3784226D1 (de) | 1993-03-25 |
EP0271311B1 (en) | 1993-02-17 |
DE3784226T2 (de) | 1993-06-24 |
EP0271311A3 (en) | 1990-07-04 |
JPS63145291A (ja) | 1988-06-17 |
US4766225A (en) | 1988-08-23 |
EP0271311A2 (en) | 1988-06-15 |
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