JPH051060B2 - - Google Patents
Info
- Publication number
- JPH051060B2 JPH051060B2 JP59204184A JP20418484A JPH051060B2 JP H051060 B2 JPH051060 B2 JP H051060B2 JP 59204184 A JP59204184 A JP 59204184A JP 20418484 A JP20418484 A JP 20418484A JP H051060 B2 JPH051060 B2 JP H051060B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- zone
- gas
- oxygen
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 claims description 193
- 239000007789 gas Substances 0.000 claims description 104
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 46
- 229910052760 oxygen Inorganic materials 0.000 claims description 46
- 239000001301 oxygen Substances 0.000 claims description 46
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 42
- 238000011069 regeneration method Methods 0.000 claims description 42
- 229910052799 carbon Inorganic materials 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 38
- 230000008929 regeneration Effects 0.000 claims description 35
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 29
- 229910052717 sulfur Inorganic materials 0.000 claims description 29
- 239000011593 sulfur Substances 0.000 claims description 29
- 238000002485 combustion reaction Methods 0.000 claims description 16
- 239000011261 inert gas Substances 0.000 claims description 11
- 239000002244 precipitate Substances 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 8
- 150000003464 sulfur compounds Chemical class 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 238000011282 treatment Methods 0.000 claims description 7
- 238000009835 boiling Methods 0.000 claims description 4
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 4
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052815 sulfur oxide Inorganic materials 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 2
- 239000010419 fine particle Substances 0.000 claims 2
- 238000007599 discharging Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
- 230000007246 mechanism Effects 0.000 description 9
- 239000003921 oil Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 238000001704 evaporation Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 239000003546 flue gas Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 238000004231 fluid catalytic cracking Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YALHCTUQSQRCSX-UHFFFAOYSA-N sulfane sulfuric acid Chemical compound S.OS(O)(=O)=O YALHCTUQSQRCSX-UHFFFAOYSA-N 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/20—Regeneration or reactivation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S502/00—Catalyst, solid sorbent, or support therefor: product or process of making
- Y10S502/515—Specific contaminant removal
- Y10S502/517—Sulfur or sulfur compound removal
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US538316 | 1983-10-03 | ||
| US06/538,316 US4621069A (en) | 1983-10-03 | 1983-10-03 | Continuous process for catalyst regeneration by staged burnoff of carbon and sulfur compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6094145A JPS6094145A (ja) | 1985-05-27 |
| JPH051060B2 true JPH051060B2 (enExample) | 1993-01-07 |
Family
ID=24146405
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59204184A Granted JPS6094145A (ja) | 1983-10-03 | 1984-10-01 | 炭素及び硫黄化合物の段階的な燃焼除去による連続的触媒再生方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4621069A (enExample) |
| JP (1) | JPS6094145A (enExample) |
| CA (1) | CA1225075A (enExample) |
| DE (1) | DE3434337C2 (enExample) |
| GB (1) | GB2147518B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013017999A (ja) * | 2007-04-27 | 2013-01-31 | Cosmo Oil Co Ltd | 炭化水素油の水素化処理触媒の再生方法 |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8722841D0 (en) * | 1987-09-29 | 1987-11-04 | Shell Int Research | Regeneration of hydrocracking catalyst |
| JPH01127046A (ja) * | 1987-11-10 | 1989-05-19 | Masaaki Tamayama | 触媒の再生方法およびその装置 |
| JPH02298356A (ja) * | 1989-05-09 | 1990-12-10 | Sofutaade Kogyo Kk | 触媒の再生方法及びその装置 |
| US5073529A (en) * | 1989-12-20 | 1991-12-17 | Amoco Corporation | Method of regenerating a nonacidic zeolite catalyst |
| US5254513A (en) * | 1991-05-20 | 1993-10-19 | Texaco, Inc. | Method for the reactivation of spent alumina-supported hydrotreating catalysts |
| US5209840A (en) * | 1991-10-02 | 1993-05-11 | Texaco Inc. | Separation of active catalyst particles from spent catalyst particles by air elutriation |
| FR2699430B1 (fr) * | 1992-12-22 | 1995-03-17 | Eurecat Europ Retrait Catalys | Procédé de régénération d'un catalyseur de conversion d'hydrocarbures. |
| US5824619A (en) * | 1994-05-12 | 1998-10-20 | Uop | Particulate cooling process with reduced thermal channeling |
| WO1996029148A1 (en) * | 1995-03-20 | 1996-09-26 | Shell Internationale Research Maatschappij B.V. | Process for catalyst regeneration |
| US6123833A (en) * | 1998-09-22 | 2000-09-26 | Uop Llc | Method for controlling moisture in a catalyst regeneration process |
| CN1098338C (zh) * | 2000-06-12 | 2003-01-08 | 中国石油化工集团公司 | 一种加氢催化剂器外再生方法 |
| US8262753B2 (en) * | 2000-08-17 | 2012-09-11 | Bayne Carew | Apparatus for generating hydrocarbon fuel |
| US8147590B2 (en) | 2000-08-17 | 2012-04-03 | Bayne Carew | Fluid filter separator and method |
| DE10161665A1 (de) * | 2001-12-14 | 2003-06-26 | Lurgi Ag | Verfahren zur thermischen Entkokung eines Zeolith-Katalysators |
| DE10350476A1 (de) * | 2003-10-23 | 2005-05-25 | Tricat Gmbh Catalyst Service Bitterfeld | Verfahren und Vorrichtung zur Regenerierung, Aktivierung und Konservierung von Hydrotreatment-Katalysatoren |
| FR2864529B1 (fr) * | 2003-12-24 | 2006-12-15 | Valdi | Procede de preparation de sulfate de sodium |
| JP5524887B2 (ja) * | 2011-03-17 | 2014-06-18 | 株式会社神戸製鋼所 | 重質油からの水素化分解油の製造方法 |
| EP2736636B1 (en) | 2011-07-27 | 2020-01-08 | Saudi Arabian Oil Company | Method for removing sulfur compounds from gaseous hydrocarbons using catalytic compositions |
| US9186625B2 (en) * | 2012-09-21 | 2015-11-17 | Andritz, Inc. | Method and apparatus for pre-heating recirculated flue gas to a dry scrubber during periods of low temperature |
| JP6071542B2 (ja) * | 2012-12-27 | 2017-02-01 | 日揮触媒化成株式会社 | 水素化処理触媒の再生方法、再生水素化処理触媒の製造方法 |
| JP2015085307A (ja) * | 2013-11-01 | 2015-05-07 | Jx日鉱日石エネルギー株式会社 | 水素化処理用触媒の製造方法及び炭化水素油の製造方法 |
| RU2638159C1 (ru) * | 2016-10-17 | 2017-12-12 | Общество с ограниченной ответственностью ООО "Компания "Новые технологии" Республика Башкортостан | Способ окислительной регенерации катализаторов гидроочистки нефтяного сырья |
| RU2635924C1 (ru) * | 2016-11-14 | 2017-11-17 | Общество с ограниченной ответственностью "ХАММЕЛЬ" | Способ регенерации закоксованного катализатора и устройство для его реализации |
| FR3135630A1 (fr) | 2022-05-18 | 2023-11-24 | Axens | Dispositif permettant la regeneration d’un catalyseur d’hydroconversion et procedes associes |
| FR3155240A1 (fr) | 2023-11-15 | 2025-05-16 | IFP Energies Nouvelles | Procede de regeneration et de tri d’un catalyseur d’hydroconversion use pour recyclage a l’hydroconversion |
| FR3159910A1 (fr) | 2024-03-06 | 2025-09-12 | IFP Energies Nouvelles | Procede de decontamination d’un catalyseur use par extraction de contaminants metalliques |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2579834A (en) * | 1951-12-25 | Moving catalyst conveesion system | ||
| US1440194A (en) * | 1917-11-16 | 1922-12-26 | Gen Norit Company Ltd | Method of drying, burning, and recovering finely-divided material |
| US1943976A (en) * | 1931-01-16 | 1934-01-16 | George R Lewers | Process of revivifying mineral absorbents |
| US2304398A (en) * | 1940-02-08 | 1942-12-08 | Sinclair Refining Co | Catalytic cracking |
| US2457837A (en) * | 1943-05-21 | 1949-01-04 | Socony Vacuum Oil Co Inc | Multistage regeneration of a moving bed catalyst |
| US2436340A (en) * | 1943-08-13 | 1948-02-17 | Phillips Petroleum Co | Conversion of hydrocarbons using moving catalysts |
| US2723949A (en) * | 1951-10-31 | 1955-11-15 | Universal Oil Prod Co | Method and apparatus for converting a hydrocarbon oil stream in the presence of a relatively thin moving particle bed |
| US3533960A (en) * | 1967-10-06 | 1970-10-13 | Universal Oil Prod Co | Regeneration of sulfur - contaminated carbonized catalyst subsequent to sulfide scale removal from heater |
| US3764558A (en) * | 1971-06-24 | 1973-10-09 | Sun Oil Co Pennsylvania | Constant low oxygen concentration gas regeneration of refining catalysts |
| US4007131A (en) * | 1974-01-31 | 1977-02-08 | Mobil Oil Corporation | Hydroprocessing catalyst regeneration |
| US4026821A (en) * | 1976-05-10 | 1977-05-31 | Catco Venture | Catalyst regeneration |
-
1983
- 1983-10-03 US US06/538,316 patent/US4621069A/en not_active Expired - Lifetime
-
1984
- 1984-09-19 DE DE3434337A patent/DE3434337C2/de not_active Expired - Fee Related
- 1984-10-01 GB GB08424758A patent/GB2147518B/en not_active Expired
- 1984-10-01 JP JP59204184A patent/JPS6094145A/ja active Granted
- 1984-10-01 CA CA000464401A patent/CA1225075A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013017999A (ja) * | 2007-04-27 | 2013-01-31 | Cosmo Oil Co Ltd | 炭化水素油の水素化処理触媒の再生方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2147518B (en) | 1986-12-03 |
| GB8424758D0 (en) | 1984-11-07 |
| GB2147518A (en) | 1985-05-15 |
| CA1225075A (en) | 1987-08-04 |
| US4621069A (en) | 1986-11-04 |
| DE3434337A1 (de) | 1985-04-18 |
| JPS6094145A (ja) | 1985-05-27 |
| DE3434337C2 (de) | 1996-01-11 |
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