JPH0468335B2 - - Google Patents
Info
- Publication number
- JPH0468335B2 JPH0468335B2 JP4682286A JP4682286A JPH0468335B2 JP H0468335 B2 JPH0468335 B2 JP H0468335B2 JP 4682286 A JP4682286 A JP 4682286A JP 4682286 A JP4682286 A JP 4682286A JP H0468335 B2 JPH0468335 B2 JP H0468335B2
- Authority
- JP
- Japan
- Prior art keywords
- plasticizer
- solid
- heat
- present
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004014 plasticizer Substances 0.000 claims description 40
- 229920000642 polymer Polymers 0.000 claims description 16
- -1 dicarboxylic acid ester compound Chemical class 0.000 claims description 13
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 8
- 125000003118 aryl group Chemical group 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000001188 haloalkyl group Chemical group 0.000 claims description 2
- 239000007787 solid Substances 0.000 description 37
- 230000001070 adhesive effect Effects 0.000 description 31
- 239000000853 adhesive Substances 0.000 description 26
- 239000000203 mixture Substances 0.000 description 15
- 239000007788 liquid Substances 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 6
- 230000000903 blocking effect Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 6
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- VOWAEIGWURALJQ-UHFFFAOYSA-N Dicyclohexyl phthalate Chemical compound C=1C=CC=C(C(=O)OC2CCCCC2)C=1C(=O)OC1CCCCC1 VOWAEIGWURALJQ-UHFFFAOYSA-N 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- DWNAQMUDCDVSLT-UHFFFAOYSA-N diphenyl phthalate Chemical compound C=1C=CC=C(C(=O)OC=2C=CC=CC=2)C=1C(=O)OC1=CC=CC=C1 DWNAQMUDCDVSLT-UHFFFAOYSA-N 0.000 description 4
- 239000010419 fine particle Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- QXGJCWSBOZXWOV-UHFFFAOYSA-N 3,4-dihydroxyphthalic acid Chemical class OC(=O)C1=CC=C(O)C(O)=C1C(O)=O QXGJCWSBOZXWOV-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- LVTPRIAGCBEGPW-UHFFFAOYSA-N (2-benzoyloxyphenyl) benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1=CC=CC=C1OC(=O)C1=CC=CC=C1 LVTPRIAGCBEGPW-UHFFFAOYSA-N 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- KCXZNSGUUQJJTR-UHFFFAOYSA-N Di-n-hexyl phthalate Chemical compound CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCC KCXZNSGUUQJJTR-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- VNGOYPQMJFJDLV-UHFFFAOYSA-N dimethyl benzene-1,3-dicarboxylate Chemical compound COC(=O)C1=CC=CC(C(=O)OC)=C1 VNGOYPQMJFJDLV-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 150000003505 terpenes Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- RJHSCCZVRVXSEF-UHFFFAOYSA-N (2-hydroxyphenyl) benzoate Chemical compound OC1=CC=CC=C1OC(=O)C1=CC=CC=C1 RJHSCCZVRVXSEF-UHFFFAOYSA-N 0.000 description 1
- XFDQLDNQZFOAFK-UHFFFAOYSA-N 2-benzoyloxyethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOC(=O)C1=CC=CC=C1 XFDQLDNQZFOAFK-UHFFFAOYSA-N 0.000 description 1
- LUNMJRJMSXZSLC-UHFFFAOYSA-N 2-cyclopropylethanol Chemical compound OCCC1CC1 LUNMJRJMSXZSLC-UHFFFAOYSA-N 0.000 description 1
- FEPZCOXDXJXVEL-UHFFFAOYSA-N 2-methoxyethyl octadecanoate urea Chemical compound NC(N)=O.CCCCCCCCCCCCCCCCCC(=O)OCCOC FEPZCOXDXJXVEL-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZIJKGAXBCRWEOL-SAXBRCJISA-N Sucrose octaacetate Chemical compound CC(=O)O[C@H]1[C@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1 ZIJKGAXBCRWEOL-SAXBRCJISA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- JVVXZOOGOGPDRZ-SLFFLAALSA-N [(1R,4aS,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,9,10,10a-hexahydrophenanthren-1-yl]methanamine Chemical compound NC[C@]1(C)CCC[C@]2(C)C3=CC=C(C(C)C)C=C3CC[C@H]21 JVVXZOOGOGPDRZ-SLFFLAALSA-N 0.000 description 1
- 239000001344 [(2S,3S,4R,5R)-4-acetyloxy-2,5-bis(acetyloxymethyl)-2-[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxolan-3-yl] acetate Substances 0.000 description 1
- PJLLCGNQPWXWGL-UHFFFAOYSA-N [3-benzoyloxy-2-(benzoyloxymethyl)-2-methylpropyl] benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC(COC(=O)C=1C=CC=CC=1)(C)COC(=O)C1=CC=CC=C1 PJLLCGNQPWXWGL-UHFFFAOYSA-N 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- MRTVEHHKUKXEOC-UHFFFAOYSA-N benzene-1,2-diol;benzoic acid Chemical compound OC1=CC=CC=C1O.OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 MRTVEHHKUKXEOC-UHFFFAOYSA-N 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- RVOJTCZRIKWHDX-UHFFFAOYSA-N cyclohexanecarbonyl chloride Chemical compound ClC(=O)C1CCCCC1 RVOJTCZRIKWHDX-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- DVAIYSZTXVOUQZ-UHFFFAOYSA-N diucifon Chemical compound N1C(=O)NC(=O)C(S(=O)(=O)NC=2C=CC(=CC=2)S(=O)(=O)C=2C=CC(NS(=O)(=O)C=3C(NC(=O)NC=3C)=O)=CC=2)=C1C DVAIYSZTXVOUQZ-UHFFFAOYSA-N 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 210000004905 finger nail Anatomy 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- DKYVVNLWACXMDW-UHFFFAOYSA-N n-cyclohexyl-4-methylbenzenesulfonamide Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC1CCCCC1 DKYVVNLWACXMDW-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920001490 poly(butyl methacrylate) polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920006249 styrenic copolymer Polymers 0.000 description 1
- 229940013883 sucrose octaacetate Drugs 0.000 description 1
- SYDJVRWZOWPNNO-UHFFFAOYSA-N sucrose-benzoate Natural products OCC1OC(OC2(COC(=O)c3ccccc3)OC(CO)C(O)C2O)C(O)C(O)C1O SYDJVRWZOWPNNO-UHFFFAOYSA-N 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- CBKMOPGKNJBDFA-UHFFFAOYSA-N tricyclohexyl 2-hydroxypropane-1,2,3-tricarboxylate Chemical compound C1CCCCC1OC(=O)CC(C(=O)OC1CCCCC1)(O)CC(=O)OC1CCCCC1 CBKMOPGKNJBDFA-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4682286A JPS62205140A (ja) | 1986-03-03 | 1986-03-03 | 重合体用可塑剤 |
US07/021,393 US4745026A (en) | 1986-03-03 | 1987-03-03 | Thermal delayed tack sheets |
US07/174,517 US4833023A (en) | 1986-03-03 | 1988-03-28 | Thermal delayed tack sheets |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4682286A JPS62205140A (ja) | 1986-03-03 | 1986-03-03 | 重合体用可塑剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62205140A JPS62205140A (ja) | 1987-09-09 |
JPH0468335B2 true JPH0468335B2 (fr) | 1992-11-02 |
Family
ID=12758025
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4682286A Granted JPS62205140A (ja) | 1986-03-03 | 1986-03-03 | 重合体用可塑剤 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS62205140A (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5969210B2 (ja) * | 2008-12-31 | 2016-08-17 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 強化されたプロ触媒組成物及びプロセス |
JP7255063B2 (ja) * | 2019-06-07 | 2023-04-11 | 三井化学株式会社 | エステル化合物、エステル化合物の製造方法、熱可塑性樹脂用可塑剤、及び熱可塑性樹脂組成物 |
-
1986
- 1986-03-03 JP JP4682286A patent/JPS62205140A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS62205140A (ja) | 1987-09-09 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4745026A (en) | Thermal delayed tack sheets | |
JPH0987609A (ja) | ディレードタック粘着剤組成物 | |
JPH0756017B2 (ja) | 感圧接着剤 | |
JPH05148467A (ja) | 酢酸ビニル/エチレン/アクリレート共重合体水性エマルジヨンを含む粘着性の感圧接着剤組成物 | |
JP3204768B2 (ja) | アクリル系感圧接着剤組成物及び両面テープ | |
JP2000103969A (ja) | 熱可塑性樹脂組成物、感熱性粘着剤及び感熱性粘着シート | |
KR101367710B1 (ko) | 하이브리드 에멀션 점착제 | |
JPS6221835B2 (fr) | ||
JP2698078B2 (ja) | 感熱性粘着組成物および感熱性粘着シート | |
JPH0468335B2 (fr) | ||
JPH06100848A (ja) | 感熱性ディレードタック型粘着剤および感熱性粘着シート | |
JPH073239A (ja) | ディレードタック型粘着剤および粘着シート | |
JP2732526B2 (ja) | 感熱性粘着組成物および感熱性粘着シート | |
JPH01207372A (ja) | 熱活性遅延型粘着剤組成物および熱活性遅延型粘着シート | |
JP2000053874A (ja) | 熱可塑性樹脂組成物、水性組成物、感熱性粘着剤及び感熱性粘着シ―ト | |
JPS63275685A (ja) | 水性粘着剤組成物 | |
JP2914029B2 (ja) | 感熱性ディレードタック型粘着剤 | |
JPH0629398B2 (ja) | 感熱性粘着組成物およびそれを用いて得られた感熱性粘着シ−ト | |
JPS62212482A (ja) | サ−マルタツク組成物 | |
JP3018868B2 (ja) | 高速ラベラー用感熱性粘着シート | |
JP4457490B2 (ja) | ディレードタック型粘着剤組成物及び粘着ラベル | |
JPS62252439A (ja) | 可塑剤 | |
JP4086502B2 (ja) | 水系感熱性粘着剤組成物、感熱性粘着シート及び感熱性粘着シートの製造方法 | |
JP3497878B2 (ja) | 感熱性粘着シート | |
JPS62240334A (ja) | 可塑剤 |