JPH0453586B2 - - Google Patents
Info
- Publication number
- JPH0453586B2 JPH0453586B2 JP59093920A JP9392084A JPH0453586B2 JP H0453586 B2 JPH0453586 B2 JP H0453586B2 JP 59093920 A JP59093920 A JP 59093920A JP 9392084 A JP9392084 A JP 9392084A JP H0453586 B2 JPH0453586 B2 JP H0453586B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- catalyst according
- proportion
- pores
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 45
- 239000003054 catalyst Substances 0.000 claims description 43
- 239000011148 porous material Substances 0.000 claims description 27
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 17
- 239000000243 solution Substances 0.000 claims description 16
- 238000003786 synthesis reaction Methods 0.000 claims description 15
- 238000001556 precipitation Methods 0.000 claims description 14
- 239000000126 substance Substances 0.000 claims description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 8
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- 239000005751 Copper oxide Substances 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910000431 copper oxide Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000011787 zinc oxide Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- GFCDJPPBUCXJSC-UHFFFAOYSA-N [O-2].[Zn+2].[Cu]=O Chemical compound [O-2].[Zn+2].[Cu]=O GFCDJPPBUCXJSC-UHFFFAOYSA-N 0.000 claims description 4
- 239000001099 ammonium carbonate Substances 0.000 claims description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 2
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 235000012501 ammonium carbonate Nutrition 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000012452 mother liquor Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 239000012018 catalyst precursor Substances 0.000 description 9
- 238000009826 distribution Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 3
- 238000004438 BET method Methods 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910017089 AlO(OH) Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical group [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- VODBHXZOIQDDST-UHFFFAOYSA-N copper zinc oxygen(2-) Chemical compound [O--].[O--].[Cu++].[Zn++] VODBHXZOIQDDST-UHFFFAOYSA-N 0.000 description 1
- ZDSXDABMPSGVRA-UHFFFAOYSA-N copper zinc tetranitrate Chemical compound [Cu++].[Zn++].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O ZDSXDABMPSGVRA-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011777 magnesium Chemical group 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Chemical group 0.000 description 1
- 239000011572 manganese Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3317725A DE3317725A1 (de) | 1983-05-16 | 1983-05-16 | Katalysator fuer die methanolsynthese |
| DE3317725.2 | 1983-05-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59222232A JPS59222232A (ja) | 1984-12-13 |
| JPH0453586B2 true JPH0453586B2 (it) | 1992-08-27 |
Family
ID=6199062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59093920A Granted JPS59222232A (ja) | 1983-05-16 | 1984-05-12 | メタノ−ル合成用の触媒 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4535071A (it) |
| EP (1) | EP0125689B2 (it) |
| JP (1) | JPS59222232A (it) |
| CA (1) | CA1213264A (it) |
| DD (1) | DD251085A5 (it) |
| DE (2) | DE3317725A1 (it) |
| DK (1) | DK241384A (it) |
| FI (1) | FI841968A (it) |
| NO (1) | NO841975L (it) |
| ZA (1) | ZA843695B (it) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3403492A1 (de) * | 1984-02-02 | 1985-08-08 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur herstellung einer mischung aus methanol und hoeheren alkoholen |
| DE3403491A1 (de) * | 1984-02-02 | 1985-08-14 | Süd-Chemie AG, 8000 München | Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen |
| US4801574A (en) * | 1987-12-02 | 1989-01-31 | Air Products And Chemicals, Inc. | In-situ activation of CuO/ZnO/Al2 O3 catalysts in the liquid phase |
| JP2773183B2 (ja) * | 1989-02-09 | 1998-07-09 | 三菱瓦斯化学株式会社 | メタノール合成触媒前駆体の製造法 |
| US5622907A (en) * | 1989-04-28 | 1997-04-22 | Electric Power Research Institute, Inc. | Post-reducing treatment of alcohol synthesis catalysts with carbon dioxide |
| US5155086A (en) * | 1989-09-12 | 1992-10-13 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process of using said catalyst |
| US5345005A (en) * | 1989-09-12 | 1994-09-06 | Engelhard Corporation | Hydrogenation catalyst, process for preparing and process of using said catalyst |
| US5134108A (en) * | 1991-05-22 | 1992-07-28 | Engelhard Corporation | Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof |
| DE4127318A1 (de) * | 1991-08-17 | 1993-02-18 | Hoechst Ag | Kupfer-zinkoxid-aluminiumoxid enthaltende katalysatoren |
| DE4206750A1 (de) † | 1992-03-04 | 1993-09-09 | Hoechst Ag | Verfahren zur herstellung von alkoholen oder aminen |
| DE4244273A1 (de) * | 1992-12-28 | 1994-06-30 | Hoechst Ag | Kupferkatalysator |
| EP0868943B1 (en) * | 1997-03-31 | 2002-10-30 | Director-General Of The Agency Of Industrial Science And Technology | Copper, zinc and aluminium based catalyst for methanol synthesis and reforming |
| DE10160486A1 (de) * | 2001-12-08 | 2003-06-12 | Sued Chemie Ag | Katalysator für die Methanolsynthese |
| DE10207443A1 (de) | 2002-02-22 | 2003-09-04 | Bayer Ag | Verfahren und Katalysator zur Herstellung von Alkoholen |
| US20030191200A1 (en) * | 2002-04-08 | 2003-10-09 | Jianhua Yao | Synthesis gas conversion and novel catalysts for same |
| DE102005020630A1 (de) * | 2005-05-03 | 2006-11-23 | Süd-Chemie AG | Herstellung von Cu/Zn/Al-Katalysatoren über den Formiatweg |
| DE102005035762A1 (de) * | 2005-07-29 | 2007-02-01 | Süd-Chemie AG | Hochporöse Schichten aus MOF-Materialien und Verfahren zur Herstellung derartiger Schichten |
| DE102005037893A1 (de) * | 2005-08-10 | 2007-02-15 | Süd-Chemie AG | Verfahren zur Herstellung hochaktiver Metall/Metalloxid-Katalysatoren |
| GB0620793D0 (en) * | 2006-10-20 | 2006-11-29 | Johnson Matthey Plc | Process |
| CN101332433B (zh) * | 2007-06-27 | 2011-07-20 | 中国石油化工股份有限公司 | 一种催化裂化催化剂及其制备和应用方法 |
| US20090149324A1 (en) * | 2007-12-05 | 2009-06-11 | Basf Catalysts Llc | Low temperature water gas shift catalyst |
| JP5145022B2 (ja) * | 2007-12-19 | 2013-02-13 | 三菱重工業株式会社 | ペレット状メタノール合成触媒及びその製造方法、メタノール合成方法及びその装置 |
| GB0910364D0 (en) * | 2009-06-17 | 2009-07-29 | Johnson Matthey Plc | Carbon oxides conversion process |
| GB0910366D0 (en) | 2009-06-17 | 2009-07-29 | Johnson Matthey Plc | Methanol synthesis process |
| EP2357037A1 (de) | 2010-02-17 | 2011-08-17 | LANXESS Deutschland GmbH | Verfahren zur Herstellung von mechanisch stabilen Katalysatorformkörpern |
| DE102010021792B4 (de) | 2010-05-27 | 2022-03-31 | Clariant Produkte (Deutschland) Gmbh | Katalysatoren und Verfahren zu deren Herstellung |
| US8778833B2 (en) | 2010-11-11 | 2014-07-15 | Basf Corporation | Copper-zirconia catalyst and method of use and manufacture |
| DE102011086451A1 (de) | 2011-11-16 | 2013-05-16 | Süd-Chemie Ip Gmbh & Co. Kg | Methanolsynthesekatalysator auf basis von kupfer, zink und aluminium |
| US9295978B2 (en) | 2012-02-15 | 2016-03-29 | Basf Corporation | Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas |
| DE102013225724A1 (de) | 2013-12-12 | 2015-06-18 | Evonik Industries Ag | Reinigung flüssiger Kohlenwasserstoffströme mittels kupferhaltiger Sorptionsmittel |
| JP2015163594A (ja) * | 2014-02-28 | 2015-09-10 | 積水化学工業株式会社 | 酸素化物の製造方法 |
| DE102014004391A1 (de) | 2014-03-26 | 2015-10-15 | Clariant International Ltd. | Verfahren zur Herstellung von Katalysatoren mit erhöhter Festigkeit und verringertem Volumenschwund |
| EP3023131A1 (de) | 2014-11-18 | 2016-05-25 | Evonik Degussa GmbH | Zweistufige Feinentschwefelung von Olefingemischen |
| SG10201604013RA (en) | 2015-05-28 | 2016-12-29 | Evonik Degussa Gmbh | Hydrogen-assisted adsorption of sulphur compounds from olefin mixtures |
| EP3305404A1 (en) | 2016-10-10 | 2018-04-11 | National Petrochemical Company | Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution |
| DE102016225171A1 (de) | 2016-12-15 | 2018-06-21 | Clariant International Ltd | Tablettierter Katalysator für die Methanolsynthese mit erhöhter mechanischer Stabilität |
| CN108568300B (zh) * | 2017-03-08 | 2020-11-24 | 中国石油化工股份有限公司 | 一种铜锌铝催化剂及其制备方法 |
| CN110935478B (zh) * | 2018-09-25 | 2022-07-12 | 中国石油化工股份有限公司 | 合成甲醇催化剂的制备方法 |
| CN110935455B (zh) * | 2018-09-25 | 2022-07-08 | 中国石油化工股份有限公司 | 一种铜锌催化剂的制法 |
| CN110935490B (zh) * | 2018-09-25 | 2022-03-08 | 中国石油化工股份有限公司 | 一种铜锌催化剂及其制备方法 |
| CN110935457B (zh) * | 2018-09-25 | 2022-03-08 | 中国石油化工股份有限公司 | 一种铜锌催化剂的制备方法 |
| GB201905293D0 (en) * | 2019-04-15 | 2019-05-29 | Johnson Matthey Plc | Copper-containing catalysts |
| CN111167518A (zh) * | 2020-01-06 | 2020-05-19 | 上海应用技术大学 | 一种二氧化碳加氢合成甲醇催化剂CuZn/UiO-66及其制备方法 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4917391A (it) * | 1972-04-20 | 1974-02-15 | ||
| JPS4942240A (it) * | 1972-03-06 | 1974-04-20 | ||
| JPS5144715A (ja) * | 1974-10-16 | 1976-04-16 | Hitachi Ltd | Kyukikanetsusochi |
| JPS5562030A (en) * | 1978-10-26 | 1980-05-10 | Basf Ag | Manufacture of methanol |
| JPS55106543A (en) * | 1979-02-10 | 1980-08-15 | Mitsubishi Gas Chem Co Inc | Preparation of catalyst for synthesizing methanol |
| JPS5670836A (en) * | 1979-11-12 | 1981-06-13 | Mitsubishi Gas Chem Co Inc | Preparation of methanol synthesis catalyst |
| JPS57130547A (en) * | 1981-02-06 | 1982-08-13 | Mitsubishi Gas Chem Co Inc | Catalyst for methanol synthesis |
| JPS5867352A (ja) * | 1981-07-22 | 1983-04-21 | エレクトリツク・パワ−・リサ−チ・インスチテユ−ト・インコ−ポレ−テツド | メタノ−ル合成触媒 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3407030A (en) * | 1962-12-31 | 1968-10-22 | Monsanto Co | Method of catalytically treating gases |
| US3388972A (en) * | 1966-12-14 | 1968-06-18 | Catalysts & Chemicals Inc | Low temperature shift reaction catalysts and methods for their preparation |
| GB1296212A (it) * | 1969-03-04 | 1972-11-15 | ||
| US3661806A (en) * | 1970-01-05 | 1972-05-09 | Grace W R & Co | Exhaust gas oxidation catalyst and process |
| US3790505A (en) * | 1971-05-04 | 1974-02-05 | Catalysts & Chem Inc | Low temperature methanol synthesis catalyst |
| US4279781A (en) * | 1979-10-09 | 1981-07-21 | United Catalysts Inc. | Catalyst for the synthesis of methanol |
| NO146046L (it) * | 1980-03-28 |
-
1983
- 1983-05-16 DE DE3317725A patent/DE3317725A1/de not_active Withdrawn
-
1984
- 1984-05-10 CA CA000454028A patent/CA1213264A/en not_active Expired
- 1984-05-12 JP JP59093920A patent/JPS59222232A/ja active Granted
- 1984-05-15 DD DD84263040A patent/DD251085A5/de not_active IP Right Cessation
- 1984-05-16 ZA ZA843695A patent/ZA843695B/xx unknown
- 1984-05-16 NO NO841975A patent/NO841975L/no unknown
- 1984-05-16 EP EP84105513A patent/EP0125689B2/de not_active Expired
- 1984-05-16 DE DE8484105513T patent/DE3464208D1/de not_active Expired
- 1984-05-16 US US06/610,745 patent/US4535071A/en not_active Expired - Lifetime
- 1984-05-16 DK DK241384A patent/DK241384A/da not_active Application Discontinuation
- 1984-05-16 FI FI841968A patent/FI841968A/fi not_active Application Discontinuation
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4942240A (it) * | 1972-03-06 | 1974-04-20 | ||
| JPS4917391A (it) * | 1972-04-20 | 1974-02-15 | ||
| JPS5144715A (ja) * | 1974-10-16 | 1976-04-16 | Hitachi Ltd | Kyukikanetsusochi |
| JPS5562030A (en) * | 1978-10-26 | 1980-05-10 | Basf Ag | Manufacture of methanol |
| JPS55106543A (en) * | 1979-02-10 | 1980-08-15 | Mitsubishi Gas Chem Co Inc | Preparation of catalyst for synthesizing methanol |
| JPS5670836A (en) * | 1979-11-12 | 1981-06-13 | Mitsubishi Gas Chem Co Inc | Preparation of methanol synthesis catalyst |
| JPS57130547A (en) * | 1981-02-06 | 1982-08-13 | Mitsubishi Gas Chem Co Inc | Catalyst for methanol synthesis |
| JPS5867352A (ja) * | 1981-07-22 | 1983-04-21 | エレクトリツク・パワ−・リサ−チ・インスチテユ−ト・インコ−ポレ−テツド | メタノ−ル合成触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| ZA843695B (en) | 1984-12-24 |
| FI841968A (fi) | 1984-11-17 |
| DE3317725A1 (de) | 1984-11-22 |
| DK241384A (da) | 1984-11-17 |
| CA1213264A (en) | 1986-10-28 |
| FI841968A0 (fi) | 1984-05-16 |
| EP0125689A2 (de) | 1984-11-21 |
| JPS59222232A (ja) | 1984-12-13 |
| NO841975L (no) | 1984-11-19 |
| EP0125689B1 (de) | 1987-06-16 |
| EP0125689A3 (en) | 1985-05-15 |
| DE3464208D1 (en) | 1987-07-23 |
| US4535071A (en) | 1985-08-13 |
| DK241384D0 (da) | 1984-05-16 |
| EP0125689B2 (de) | 1989-10-18 |
| DD251085A5 (de) | 1987-11-04 |
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