JPH04502271A - 廃ガスから窒素酸化物を除去する触媒の製造方法 - Google Patents
廃ガスから窒素酸化物を除去する触媒の製造方法Info
- Publication number
- JPH04502271A JPH04502271A JP2501021A JP50102190A JPH04502271A JP H04502271 A JPH04502271 A JP H04502271A JP 2501021 A JP2501021 A JP 2501021A JP 50102190 A JP50102190 A JP 50102190A JP H04502271 A JPH04502271 A JP H04502271A
- Authority
- JP
- Japan
- Prior art keywords
- halogen
- carbon
- gas
- nitrogen oxides
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims description 27
- 239000003054 catalyst Substances 0.000 title claims description 17
- 239000002912 waste gas Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 27
- 150000002367 halogens Chemical class 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 150000002366 halogen compounds Chemical class 0.000 claims description 14
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 7
- -1 bromine compound Chemical class 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims 1
- 239000000571 coke Substances 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 8
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- CAMXVZOXBADHNJ-UHFFFAOYSA-N ammonium nitrite Chemical compound [NH4+].[O-]N=O CAMXVZOXBADHNJ-UHFFFAOYSA-N 0.000 description 3
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000257465 Echinoidea Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3842526.2 | 1988-12-17 | ||
| DE3842526A DE3842526A1 (de) | 1988-12-17 | 1988-12-17 | Verfahren zur herstellung eines katalysators zur entfernung von stickstoffoxiden aus abgasen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04502271A true JPH04502271A (ja) | 1992-04-23 |
Family
ID=6369396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2501021A Pending JPH04502271A (ja) | 1988-12-17 | 1989-12-14 | 廃ガスから窒素酸化物を除去する触媒の製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5179058A (enExample) |
| EP (1) | EP0448585B1 (enExample) |
| JP (1) | JPH04502271A (enExample) |
| AT (1) | ATE81475T1 (enExample) |
| DE (2) | DE3842526A1 (enExample) |
| WO (1) | WO1990006803A1 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4125913C1 (enExample) * | 1991-08-05 | 1993-01-07 | Bergwerksverband Gmbh, 4300 Essen, De | |
| US5372619A (en) * | 1992-10-14 | 1994-12-13 | Ucar Carbon Technology Corporation | Method for storing methane using a halogenating agent treated activated carbon |
| KR100215276B1 (ko) * | 1995-03-30 | 1999-08-16 | 쓰치야 히로오 | 다공성 탄소재, 그 제조방법 및 그 용도 |
| US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
| KR100991761B1 (ko) * | 2002-05-06 | 2010-11-03 | 알베마를 코포레이션 | 흡착제 및 연소기체로부터 수은을 제거하는 방법 |
| US8617492B2 (en) * | 2008-01-08 | 2013-12-31 | Carbonxt Group Limited | System and method for making low volatile carboneaceous matter with supercritical CO2 |
| US8628707B2 (en) * | 2008-01-08 | 2014-01-14 | Carbonxt Group Limited | System and method for making carbon foam anodes |
| US20090172998A1 (en) * | 2008-01-08 | 2009-07-09 | Carbonxt Group Limited | System and method for refining carbonaceous material |
| UA109399C2 (uk) | 2009-04-01 | 2015-08-25 | Термічно активоване вугілля, стійке до самозапалювання | |
| EP2531276A4 (en) * | 2010-02-04 | 2014-07-02 | Ada Es Inc | METHOD AND SYSTEM FOR CONTROLLING MERCURY EMISSIONS IN COAL-DRIVEN HEATING METHODS |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| EP2545334B8 (en) | 2010-03-10 | 2018-09-19 | ADA-ES, Inc. | Process for dilute phase injection of dry alkaline materials into a gas |
| US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
| BR112013004469A2 (pt) | 2010-08-30 | 2016-06-07 | Albemarle Corp | carvão ativado sorvente para remover mercúrio de emissões produzidas durante combustão de combustível, aditivo não halogenado e processo par aumentar a estabilidade térmica de carvão ativado |
| CN103201029B (zh) | 2010-08-30 | 2016-08-17 | 阿尔比马尔公司 | 用于从燃料燃烧过程中产生的排放物中除去汞的改进的溴化的吸附剂 |
| US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
| US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
| US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
| US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
| US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
| US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
| CN110523265A (zh) * | 2018-05-24 | 2019-12-03 | 中国石油化工股份有限公司 | 一种氮氧化物消除方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1989108A (en) * | 1933-05-22 | 1935-01-29 | Jacque C Morrell | Process of producing nonstructural activated carbon |
| JPS477687B1 (enExample) * | 1967-01-13 | 1972-03-04 | ||
| US3662523A (en) * | 1970-12-15 | 1972-05-16 | American Optical Corp | Adsorbents for removal of mercury vapor from air or gas |
| US3961020A (en) * | 1972-10-09 | 1976-06-01 | Hitachi, Ltd. | Process for removing sulfur oxides and nitrogen oxides from flue gases using halogen-impregnated actuated carbon with simultaneous injection of ammonia |
| GB1460240A (en) * | 1974-11-12 | 1976-12-31 | Exxon Research Engineering Co | Lewis acid-fluorine compounds of carbon |
| US3962133A (en) * | 1974-12-12 | 1976-06-08 | Mobil Oil Corporation | Graphite intercalation |
| US4031185A (en) * | 1975-02-03 | 1977-06-21 | Hitachi, Ltd. | Process for making nitrogen oxides contained in flue gas harmless |
| DE3715526A1 (de) * | 1987-05-09 | 1988-11-17 | Bergwerksverband Gmbh | Verfahren zur entfernung von quecksilber aus gasen |
-
1988
- 1988-12-17 DE DE3842526A patent/DE3842526A1/de active Granted
-
1989
- 1989-12-14 JP JP2501021A patent/JPH04502271A/ja active Pending
- 1989-12-14 DE DE9090900190T patent/DE58902470D1/de not_active Expired - Fee Related
- 1989-12-14 WO PCT/EP1989/001537 patent/WO1990006803A1/de not_active Ceased
- 1989-12-14 AT AT90900190T patent/ATE81475T1/de active
- 1989-12-14 EP EP90900190A patent/EP0448585B1/de not_active Expired - Lifetime
-
1991
- 1991-05-30 US US07/707,571 patent/US5179058A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3842526C2 (enExample) | 1992-05-21 |
| US5179058A (en) | 1993-01-12 |
| DE3842526A1 (de) | 1990-06-21 |
| ATE81475T1 (de) | 1992-10-15 |
| DE58902470D1 (de) | 1992-11-19 |
| EP0448585B1 (de) | 1992-10-14 |
| WO1990006803A1 (de) | 1990-06-28 |
| EP0448585A1 (de) | 1991-10-02 |
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