JPH0444813B2 - - Google Patents
Info
- Publication number
- JPH0444813B2 JPH0444813B2 JP62217317A JP21731787A JPH0444813B2 JP H0444813 B2 JPH0444813 B2 JP H0444813B2 JP 62217317 A JP62217317 A JP 62217317A JP 21731787 A JP21731787 A JP 21731787A JP H0444813 B2 JPH0444813 B2 JP H0444813B2
- Authority
- JP
- Japan
- Prior art keywords
- light
- liquid crystal
- cell
- amount
- irradiated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000004973 liquid crystal related substance Substances 0.000 claims description 67
- 150000001875 compounds Chemical class 0.000 claims description 45
- 239000000758 substrate Substances 0.000 claims description 33
- 230000008859 change Effects 0.000 claims description 31
- 230000002441 reversible effect Effects 0.000 claims description 20
- 230000003287 optical effect Effects 0.000 claims description 15
- 239000002052 molecular layer Substances 0.000 claims description 10
- 210000004027 cell Anatomy 0.000 description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 22
- 239000010410 layer Substances 0.000 description 20
- 239000010453 quartz Substances 0.000 description 19
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 18
- 239000011521 glass Substances 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- -1 acylindigo Chemical compound 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- DMLAVOWQYNRWNQ-UHFFFAOYSA-N azobenzene Chemical compound C1=CC=CC=C1N=NC1=CC=CC=C1 DMLAVOWQYNRWNQ-UHFFFAOYSA-N 0.000 description 9
- 230000009471 action Effects 0.000 description 8
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 6
- YWILTCMUUXDNMA-UHFFFAOYSA-N 4-[(4-hexylphenyl)diazenyl]phenol Chemical compound CCCCCCc1ccc(cc1)N=Nc1ccc(O)cc1 YWILTCMUUXDNMA-UHFFFAOYSA-N 0.000 description 5
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- OKHIGGWUISQLMG-UHFFFAOYSA-N 3-diethoxysilylpropan-1-amine Chemical compound CCO[SiH](OCC)CCCN OKHIGGWUISQLMG-UHFFFAOYSA-N 0.000 description 3
- QOSSAOTZNIDXMA-UHFFFAOYSA-N Dicylcohexylcarbodiimide Chemical compound C1CCCCC1N=C=NC1CCCCC1 QOSSAOTZNIDXMA-UHFFFAOYSA-N 0.000 description 3
- 239000004988 Nematic liquid crystal Substances 0.000 description 3
- 239000004990 Smectic liquid crystal Substances 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical group 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SWDDLRSGGCWDPH-UHFFFAOYSA-N 4-triethoxysilylbutan-1-amine Chemical compound CCO[Si](OCC)(OCC)CCCCN SWDDLRSGGCWDPH-UHFFFAOYSA-N 0.000 description 2
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 210000002858 crystal cell Anatomy 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 229940097275 indigo Drugs 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OKUULHCPDNUVEV-UHFFFAOYSA-N oxan-2-yl 6-bromohexanoate Chemical compound BrCCCCCC(=O)OC1CCCCO1 OKUULHCPDNUVEV-UHFFFAOYSA-N 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 2
- 238000007699 photoisomerization reaction Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 2
- 238000006884 silylation reaction Methods 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000011043 treated quartz Substances 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- LIYUHAATNVIJCX-UHFFFAOYSA-N 2-[4-[(4-hexylphenyl)diazenyl]phenoxy]propanenitrile Chemical compound C1=CC(CCCCCC)=CC=C1N=NC1=CC=C(OC(C)C#N)C=C1 LIYUHAATNVIJCX-UHFFFAOYSA-N 0.000 description 1
- HVTQDSGGHBWVTR-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-phenylmethoxypyrazol-1-yl]-1-morpholin-4-ylethanone Chemical compound C(C1=CC=CC=C1)OC1=NN(C=C1C=1C=NC(=NC=1)NC1CC2=CC=CC=C2C1)CC(=O)N1CCOCC1 HVTQDSGGHBWVTR-UHFFFAOYSA-N 0.000 description 1
- UVOKEWIIBKIDIY-UHFFFAOYSA-N 2-phenyldiazenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1N=NC1=CC=CC=C1 UVOKEWIIBKIDIY-UHFFFAOYSA-N 0.000 description 1
- RXYQBEUFWLEHES-UHFFFAOYSA-N 2-phenyldiazenylbenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1N=NC1=CC=CC=C1 RXYQBEUFWLEHES-UHFFFAOYSA-N 0.000 description 1
- PEXGTUZWTLMFID-UHFFFAOYSA-N 2-phenyldiazenylphenol Chemical compound OC1=CC=CC=C1N=NC1=CC=CC=C1 PEXGTUZWTLMFID-UHFFFAOYSA-N 0.000 description 1
- ONJRTQUWKRDCTA-UHFFFAOYSA-N 2h-thiochromene Chemical compound C1=CC=C2C=CCSC2=C1 ONJRTQUWKRDCTA-UHFFFAOYSA-N 0.000 description 1
- HXLAEGYMDGUSBD-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propan-1-amine Chemical compound CCO[Si](C)(OCC)CCCN HXLAEGYMDGUSBD-UHFFFAOYSA-N 0.000 description 1
- CSQPODPWWMOTIY-UHFFFAOYSA-N 4-(4-octylphenyl)benzonitrile Chemical group C1=CC(CCCCCCCC)=CC=C1C1=CC=C(C#N)C=C1 CSQPODPWWMOTIY-UHFFFAOYSA-N 0.000 description 1
- BEYOBVMPDRKTNR-BUHFOSPRSA-N 4-Hydroxyazobenzene Chemical compound C1=CC(O)=CC=C1\N=N\C1=CC=CC=C1 BEYOBVMPDRKTNR-BUHFOSPRSA-N 0.000 description 1
- PLPWYNVDCPPLMM-UHFFFAOYSA-N 4-[(4-methylphenyl)diazenyl]phenol Chemical compound C1=CC(C)=CC=C1N=NC1=CC=C(O)C=C1 PLPWYNVDCPPLMM-UHFFFAOYSA-N 0.000 description 1
- KWYKRCFXFADWBK-UHFFFAOYSA-N 4-[(4-octylphenyl)diazenyl]phenol Chemical compound CCCCCCCCc1ccc(cc1)N=Nc1ccc(O)cc1 KWYKRCFXFADWBK-UHFFFAOYSA-N 0.000 description 1
- YQHDQYPKFWETPO-UHFFFAOYSA-N 4-[methoxy(dimethyl)silyl]butan-1-amine Chemical compound CO[Si](C)(C)CCCCN YQHDQYPKFWETPO-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- IHXAGVNFEFTRBD-UHFFFAOYSA-N C1=CC=C(C=C1)N=NC2=CC=CC=C2[Si](Cl)(Cl)Cl Chemical compound C1=CC=C(C=C1)N=NC2=CC=CC=C2[Si](Cl)(Cl)Cl IHXAGVNFEFTRBD-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical group C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009435 amidation Effects 0.000 description 1
- 238000007112 amidation reaction Methods 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- AFNPFLDWLMEASV-UHFFFAOYSA-N butyl-diethoxy-methylsilane Chemical compound CCCC[Si](C)(OCC)OCC AFNPFLDWLMEASV-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- MNNLUFVMZSSCJT-UHFFFAOYSA-N chembl1969613 Chemical compound C1=CC(O)=CC=C1N=NC1=CC=C(Cl)C=C1 MNNLUFVMZSSCJT-UHFFFAOYSA-N 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical group 0.000 description 1
- VEUUMBGHMNQHGO-UHFFFAOYSA-N ethyl chloroacetate Chemical compound CCOC(=O)CCl VEUUMBGHMNQHGO-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N malonic acid group Chemical group C(CC(=O)O)(=O)O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 230000003446 memory effect Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002825 nitriles Chemical group 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- OPYYWWIJPHKUDZ-UHFFFAOYSA-N phenyl cyclohexanecarboxylate Chemical compound C1CCCCC1C(=O)OC1=CC=CC=C1 OPYYWWIJPHKUDZ-UHFFFAOYSA-N 0.000 description 1
- CFPZIPBSJIMBDE-UHFFFAOYSA-N phenyl-(2-triethoxysilylphenyl)diazene Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1N=NC1=CC=CC=C1 CFPZIPBSJIMBDE-UHFFFAOYSA-N 0.000 description 1
- 238000006349 photocyclization reaction Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000010898 silica gel chromatography Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical compound S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Liquid Crystal (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
ç£æ¥äžã®å©çšåé
æ¬çºæã¯ãå
ã«ãã液æ¶ã®é
åå€åãå©çšãã
æ°èŠãªå èšé²çŽ åã«é¢ãããã®ã§ãããããã«è©³
ããããã°ãæ¬çºæã¯å ã«ããå¯éçã«æ§é å€å
ãèµ·ãååç©ã®äœçšã«ããã液æ¶å±€ã®é åå€åã
çãããããããå©çšããŠæ å ±ãäžæçåã¯æ°žä¹
çã«èšé²ããçŽ åã«é¢ãããã®ã§ããã
æ°èŠãªå èšé²çŽ åã«é¢ãããã®ã§ãããããã«è©³
ããããã°ãæ¬çºæã¯å ã«ããå¯éçã«æ§é å€å
ãèµ·ãååç©ã®äœçšã«ããã液æ¶å±€ã®é åå€åã
çãããããããå©çšããŠæ å ±ãäžæçåã¯æ°žä¹
çã«èšé²ããçŽ åã«é¢ãããã®ã§ããã
åŸæ¥ã®æè¡
液æ¶ãçšããèšé²çŽ åãšããŠã¯ãæ
å ±ãé»æ°ç
ãªäœçšãå©çšããŠè²¯èµãããã®ãšãå ã®äœçšãå©
çšããŠè²¯èµãããã®ãšãç¥ãããŠãããåè ã¯äž»
ãšããŠè¡šç€ºçšã«å©çšãããŠããã
ãªäœçšãå©çšããŠè²¯èµãããã®ãšãå ã®äœçšãå©
çšããŠè²¯èµãããã®ãšãç¥ãããŠãããåè ã¯äž»
ãšããŠè¡šç€ºçšã«å©çšãããŠããã
ãšããã§ãé»æ°çãªäœçšãå©çšããŠæ
å ±ãæžã
蟌ã液æ¶è¡šç€ºã¯ãé»åã®äŸçµŠãåæ¢ãããšæ å ±ã
æ¶å€±ããããããããæ°žä¹ çã«ä¿åããã«ã¯ãç¹
å¥ã®å·¥å€«ãå ããªããã°ãªããªããããŸããã¿ãŒ
ã³åãããé»æ¥µãçšãããã解åæ§ãäœãé«å®¹é
ã®èšé²çŽ åãšããŠã¯äžé©åœã§ããã
蟌ã液æ¶è¡šç€ºã¯ãé»åã®äŸçµŠãåæ¢ãããšæ å ±ã
æ¶å€±ããããããããæ°žä¹ çã«ä¿åããã«ã¯ãç¹
å¥ã®å·¥å€«ãå ããªããã°ãªããªããããŸããã¿ãŒ
ã³åãããé»æ¥µãçšãããã解åæ§ãäœãé«å®¹é
ã®èšé²çŽ åãšããŠã¯äžé©åœã§ããã
ä»æ¹ãå
ã®äœçšãå©çšããŠæ
å ±ã貯èµãããã®
ã«ã¯ãã¬ãŒã¶ããŒã ã®ãããªé«èŒåºŠã®å ãçºãã
ç±ãå©çšããŠããã®ç±ã«ãã液æ¶ã®çžå€åãçã
ããã圢åŒã®ãã®ãšãããããã液æ¶äžã«å ååŠ
çã«æ§é ãå€åããååç©ãå ããŠãããããã
ä»ããŠå ã®äœçšã§çžå€åããã圢åŒã®ãã®ãšãã
ãã
ã«ã¯ãã¬ãŒã¶ããŒã ã®ãããªé«èŒåºŠã®å ãçºãã
ç±ãå©çšããŠããã®ç±ã«ãã液æ¶ã®çžå€åãçã
ããã圢åŒã®ãã®ãšãããããã液æ¶äžã«å ååŠ
çã«æ§é ãå€åããååç©ãå ããŠãããããã
ä»ããŠå ã®äœçšã§çžå€åããã圢åŒã®ãã®ãšãã
ãã
ãã®ã¬ãŒã¶ããŒã ãªã©ã®ç±ãå©çšãã圢åŒã®ã
ã®ã¯é«å¯åºŠå èšé²ã«å¿çšå¯èœã§ãããããããèš
é²ã«éå®ãããããããã®å©çšç¯å²ãå¶éããã
ã®ãå ããªãããŸãå ååŠçã«æ§é ãå€åããå
åç©ãæ··åããå ã®äœçšã§çžå€åããã圢åŒã®ã
ã®ã¯ãæ å ±ãå ¥åããæåã®éã¯ãåªãã解åæ§
ã瀺ããã液æ¶ãæµåãããããæéã®çµéãšãš
ãã«èãã解åæ§ãäœäžããåŸåããããäŸã
ã°ããããã€ãã¯æ¶²æ¶ã«ãã©ã«ãªã¢ãŸãã³ãŒã³ã
溶解ããŠåŸãããããã¯ãããã¯ãªã³ã¬ã¹ããªã
ã¯æ¶²æ¶ã¯ã玫å€ç·ã®äœçšã§ã¢ã€ãœããããã¯çžã«
å€åãããããå©çšããŠæ å ±ãèšé²ããããšãã§
ããããæéã®çµéãšãšãã«æ¶²æ¶ãæµåããèšé²
åãäžæ確ã«ãªãïŒ1986幎æ¥æ¬ååŠäŒç¬¬52æ¥å£å¹Ž
äŒè¬æŒäºçš¿éåç §ïŒã
ã®ã¯é«å¯åºŠå èšé²ã«å¿çšå¯èœã§ãããããããèš
é²ã«éå®ãããããããã®å©çšç¯å²ãå¶éããã
ã®ãå ããªãããŸãå ååŠçã«æ§é ãå€åããå
åç©ãæ··åããå ã®äœçšã§çžå€åããã圢åŒã®ã
ã®ã¯ãæ å ±ãå ¥åããæåã®éã¯ãåªãã解åæ§
ã瀺ããã液æ¶ãæµåãããããæéã®çµéãšãš
ãã«èãã解åæ§ãäœäžããåŸåããããäŸã
ã°ããããã€ãã¯æ¶²æ¶ã«ãã©ã«ãªã¢ãŸãã³ãŒã³ã
溶解ããŠåŸãããããã¯ãããã¯ãªã³ã¬ã¹ããªã
ã¯æ¶²æ¶ã¯ã玫å€ç·ã®äœçšã§ã¢ã€ãœããããã¯çžã«
å€åãããããå©çšããŠæ å ±ãèšé²ããããšãã§
ããããæéã®çµéãšãšãã«æ¶²æ¶ãæµåããèšé²
åãäžæ確ã«ãªãïŒ1986幎æ¥æ¬ååŠäŒç¬¬52æ¥å£å¹Ž
äŒè¬æŒäºçš¿éåç §ïŒã
çºæã解決ããããšããåé¡ç¹
æ¬çºæã¯ãå
ã«ãã液æ¶ã®é
åå€åãå©çšããŠ
æ å ±ãèšé²ãããã®ã§ãã€ãŠãããããã®æµåæ§
ã«èµ·å ãã解åæ§ã®çµæçäœäžããããããªãå
èšé²çŽ åãæäŸããããšãç®çãšããŠãªãããã
ã®ã§ããã
æ å ±ãèšé²ãããã®ã§ãã€ãŠãããããã®æµåæ§
ã«èµ·å ãã解åæ§ã®çµæçäœäžããããããªãå
èšé²çŽ åãæäŸããããšãç®çãšããŠãªãããã
ã®ã§ããã
åé¡ç¹ã解決ããããã®æ段
æ¬çºæè
ãã¯ãå
ã«ãã液æ¶ã®é
åå€åãå©çš
ããå èšé²çŽ åãéçºããããã«ãéæç 究ãé
ããçµæãåºæ¿äžã«ãå ãå ã«ããå¯éçã«æ§é
å€åãèµ·ãååç©ã®ååå±€ãèšããã®ååå±€ã®äž
ã«æ¶²æ¶å±€ãèšããã°ãå ã«ããå¯éçã«å€åãã
ååç©ã®ïŒçš®ã®æ§é ã«å¿ããŠæ¶²æ¶ãå¯éçã«å¹³è¡
é ååã¯åçŽé åããããšããã®æ¶²æ¶å±€ã®é åã¯
äžèšååç©ã®ïŒäžå以äžã®ååã®éãªãã§ãã€ãŠ
ãè¿ éã«äŒéãããããšããããã€ãŠå ã®ç¶æ ã
å€åããªãéã液æ¶çžã¯å€åããé·æéã«ããã€
ãŠç¶æ ãä¿æãããããšãèŠåºãããã®ç¥èŠã«åº
ã¥ããŠæ¬çºæããªãã«è³ã€ãã
ããå èšé²çŽ åãéçºããããã«ãéæç 究ãé
ããçµæãåºæ¿äžã«ãå ãå ã«ããå¯éçã«æ§é
å€åãèµ·ãååç©ã®ååå±€ãèšããã®ååå±€ã®äž
ã«æ¶²æ¶å±€ãèšããã°ãå ã«ããå¯éçã«å€åãã
ååç©ã®ïŒçš®ã®æ§é ã«å¿ããŠæ¶²æ¶ãå¯éçã«å¹³è¡
é ååã¯åçŽé åããããšããã®æ¶²æ¶å±€ã®é åã¯
äžèšååç©ã®ïŒäžå以äžã®ååã®éãªãã§ãã€ãŠ
ãè¿ éã«äŒéãããããšããããã€ãŠå ã®ç¶æ ã
å€åããªãéã液æ¶çžã¯å€åããé·æéã«ããã€
ãŠç¶æ ãä¿æãããããšãèŠåºãããã®ç¥èŠã«åº
ã¥ããŠæ¬çºæããªãã«è³ã€ãã
ããªãã¡ãæ¬çºæã¯éæåºæ¿äžã«ãå
ã«ããå¯
éçã«æ§é å€åãèµ·ãååç©ã®ååå±€ãä»ããŠæ¶²
æ¶å±€ãèšããŠãªãå èšé²çŽ åãæäŸãããã®ã§ã
ãã
éçã«æ§é å€åãèµ·ãååç©ã®ååå±€ãä»ããŠæ¶²
æ¶å±€ãèšããŠãªãå èšé²çŽ åãæäŸãããã®ã§ã
ãã
æ¬çºæã«ãããéæåºæ¿ãšããŠã¯ãæ®éã®ã·ãª
ã«ã¬ã©ã¹ã硬質ã¬ã©ã¹ãç³è±ãåçš®ãã©ã¹ããã¯
ãªã©ã®ã·ãŒããããã¯ãã®è¡šé¢ã«ãé žåã±ã€çŽ ã
é žåã¹ãºãé žåã€ã³ãžãŠã ãé žåã¢ã«ãããŠã ã
é žåãã¿ã³ãé žåã¯ãã ãé žåäºéãªã©ã®éå±é ž
åç©ãçªåã±ã€çŽ ãçåã±ã€ãœçŽ ãªã©ã®è¢«èŠãæ
ãããã®ãçšããããã
ã«ã¬ã©ã¹ã硬質ã¬ã©ã¹ãç³è±ãåçš®ãã©ã¹ããã¯
ãªã©ã®ã·ãŒããããã¯ãã®è¡šé¢ã«ãé žåã±ã€çŽ ã
é žåã¹ãºãé žåã€ã³ãžãŠã ãé žåã¢ã«ãããŠã ã
é žåãã¿ã³ãé žåã¯ãã ãé žåäºéãªã©ã®éå±é ž
åç©ãçªåã±ã€çŽ ãçåã±ã€ãœçŽ ãªã©ã®è¢«èŠãæ
ãããã®ãçšããããã
éåžžã液æ¶ã¯ïŒæã®åºæ¿ã®éã«å
ãŠãããããµ
ã³ãã€ããæ§é äœãšããŠçšããããããæ¬çºæã«
ãããŠã¯ããã®ïŒæã®åºæ¿ã®ãã¡ã®å°ãªããšãäž
æ¹ãéæåºæ¿ã§ããã°ãããä»æ¹ã¯é ãéãã¢ã«
ãããŠã ãçœéãªã©ã®éå±ã®ã·ãŒãåã¯ãããã®
éå±ã§è¢«èŠããã·ãŒãã«ããããšãã§ããããã
ãã®åºæ¿ã¯éåžž0.01ãïŒmmã®åã¿ã®è¡šé¢å¹³æ»ãªã·
ãŒããšããŠçšããããã
ã³ãã€ããæ§é äœãšããŠçšããããããæ¬çºæã«
ãããŠã¯ããã®ïŒæã®åºæ¿ã®ãã¡ã®å°ãªããšãäž
æ¹ãéæåºæ¿ã§ããã°ãããä»æ¹ã¯é ãéãã¢ã«
ãããŠã ãçœéãªã©ã®éå±ã®ã·ãŒãåã¯ãããã®
éå±ã§è¢«èŠããã·ãŒãã«ããããšãã§ããããã
ãã®åºæ¿ã¯éåžž0.01ãïŒmmã®åã¿ã®è¡šé¢å¹³æ»ãªã·
ãŒããšããŠçšããããã
æ¬çºæã«ãããŠã¯ãäžèšã®åºæ¿äžã«å
ã«ããå¯
éçã«æ§é å€åãèµ·ãååç©ã®ååå±€ãèšããã
ãšãå¿ èŠã§ãããããã®ååç©ãšããŠã¯ãããã¯
ãããã¯ååç©ãæãæ®éã«çšããããã
éçã«æ§é å€åãèµ·ãååç©ã®ååå±€ãèšããã
ãšãå¿ èŠã§ãããããã®ååç©ãšããŠã¯ãããã¯
ãããã¯ååç©ãæãæ®éã«çšããããã
ãã®ããã¯ãããã¯ååç©ãšã¯ãå
ã®äœçšã§æ§
é å€åãçãããã®å ã«å¯ŸããæåäŸãã°è²èª¿ã
å€åããååç©ã§ãã€ãŠããããŸã§ççŽ âççŽ
éãççŽ âçªçŽ éãçªçŽ âçªçŽ éã®äžé£œåäºéçµ
åã®å 幟äœç°æ§ååå¿ãåå䟡å ç°æ§ååå¿ãã
ãããªãã€ãã¯ãªå ééç°åå¿ãå éç°åå¿ãå
äºå€ç°æ§ååå¿ãªã©ãå©çšããå€çš®å€æ§ã®ååç©
ãç¥ãããŠãããäŸãã°ãŠã€ãªãŒã€ã³ã¿ãŒãµã€ãš
ã³ã¹ç€Ÿçºè¡ããžãŒããšã€ãããã©ãŠã³ç·šãããã
ã¯ãããºã ãïŒ1971幎ïŒåç §ãããã®ãããªååç©
ã®ãã¡ãå 幟äœç°æ§åã«åºã¥ãããã¯ãããã¯å
åç©ã®äŸãšããŠã¯ãã¢ãŸãã³ãŒã³ãã€ã³ãžãŽãã¢
ã·ã«ã€ã³ãžãŽãããªã€ã³ãžãŽãã»ã¬ãã€ã³ãžãŽã
ããªãããã€ã³ãžãŽãããã€ã³ãžãŽãããããªã€
ã³ãžãŽãã¢ãŸã¡ãã³ãªã©ããããããªãã€ãã¯ãª
å ééç°åå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸ
ãšããŠã¯ãã€ã³ããªãã¹ãããã³ãŸãã©ã³ãã€ã³
ããªãã¹ããããããªããµãžã³ããã³ãŸãã¢ãŸãª
ãã¹ãããã³ãŸãã©ã³ãã€ã³ããªãã¹ãããã³ãŸ
ããªãã©ã³ãã¹ããã€ã³ããªãžã³ãªã©ããå éç°
åå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸãšããŠ
ã¯ãã¹ãã«ãã³ããã«ã®ããªã©ããŸãå äºå€ç°æ§
ååå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸãšããŠ
ã¯ããµãªããªãã³ã¢ãã«ãïœâããããã·ã¢ãŸã
ã³ãŒã³ãïœâããããã³ãžã«ãªã©ãããããåºæ¬
éªšæ Œãšããååç©ãæããããšãã§ããã
é å€åãçãããã®å ã«å¯ŸããæåäŸãã°è²èª¿ã
å€åããååç©ã§ãã€ãŠããããŸã§ççŽ âççŽ
éãççŽ âçªçŽ éãçªçŽ âçªçŽ éã®äžé£œåäºéçµ
åã®å 幟äœç°æ§ååå¿ãåå䟡å ç°æ§ååå¿ãã
ãããªãã€ãã¯ãªå ééç°åå¿ãå éç°åå¿ãå
äºå€ç°æ§ååå¿ãªã©ãå©çšããå€çš®å€æ§ã®ååç©
ãç¥ãããŠãããäŸãã°ãŠã€ãªãŒã€ã³ã¿ãŒãµã€ãš
ã³ã¹ç€Ÿçºè¡ããžãŒããšã€ãããã©ãŠã³ç·šãããã
ã¯ãããºã ãïŒ1971幎ïŒåç §ãããã®ãããªååç©
ã®ãã¡ãå 幟äœç°æ§åã«åºã¥ãããã¯ãããã¯å
åç©ã®äŸãšããŠã¯ãã¢ãŸãã³ãŒã³ãã€ã³ãžãŽãã¢
ã·ã«ã€ã³ãžãŽãããªã€ã³ãžãŽãã»ã¬ãã€ã³ãžãŽã
ããªãããã€ã³ãžãŽãããã€ã³ãžãŽãããããªã€
ã³ãžãŽãã¢ãŸã¡ãã³ãªã©ããããããªãã€ãã¯ãª
å ééç°åå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸ
ãšããŠã¯ãã€ã³ããªãã¹ãããã³ãŸãã©ã³ãã€ã³
ããªãã¹ããããããªããµãžã³ããã³ãŸãã¢ãŸãª
ãã¹ãããã³ãŸãã©ã³ãã€ã³ããªãã¹ãããã³ãŸ
ããªãã©ã³ãã¹ããã€ã³ããªãžã³ãªã©ããå éç°
åå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸãšããŠ
ã¯ãã¹ãã«ãã³ããã«ã®ããªã©ããŸãå äºå€ç°æ§
ååå¿ã«åºã¥ãããã¯ãããã¯ååç©ã®äŸãšããŠ
ã¯ããµãªããªãã³ã¢ãã«ãïœâããããã·ã¢ãŸã
ã³ãŒã³ãïœâããããã³ãžã«ãªã©ãããããåºæ¬
éªšæ Œãšããååç©ãæããããšãã§ããã
æ¬çºæã«ãããŠããã®ãããªããã¯ãããã¯å
åç©ã®ååå±€ãåºæ¿äžã«èšããã«ã¯ã液æ¶ã®åçŽ
é åã«éåžžçšããããŠããæ¹æ³ãäŸãã°åºæ¿ãè¡š
é¢æŽ»æ§åºãæããããã¯ãããã¯ååç©ã«ããåŠ
çããæ¹æ³ãå°ãªããšãïŒåã®ããã²ã³åååã¯
ã¢ã«ã³ãã·åºã§çœ®æãããã·ãªã«åºããã€ããã¯
ãããã¯ååç©ã§åŠçããæ¹æ³ãåºäœè¡šé¢ãã¢ã
ãåºããã€ã·ãªã«åå€ã§åŠçããã®ã¡ãã«ã«ãã
ã·ã«åºããã€ããã¯ãããã¯ååç©ãçµåããæ¹
æ³ãªã©ã«ãã€ãŠè¡ãããšãã§ããããžãšã€ãã³ã°
ããŒïŒJ.CognavdïŒèããã¢ã¬ããŠã©ãŒã»ã¯ãªã¹
ã¿ã«ãºã»ã¢ã³ãã»ãªãããã»ã¯ãªã¹ã¿ã«ãº
ïŒMolecular Crystals and Liquid CrystalsïŒãã
ãµããªã¡ã³ãïŒïŒ1982幎ïŒåã³æŸæ¬æ£äžãè§ç°åž
è¯èã液æ¶ã®ææ°æè¡ããïŒ1983幎ïŒåç §ãã
åç©ã®ååå±€ãåºæ¿äžã«èšããã«ã¯ã液æ¶ã®åçŽ
é åã«éåžžçšããããŠããæ¹æ³ãäŸãã°åºæ¿ãè¡š
é¢æŽ»æ§åºãæããããã¯ãããã¯ååç©ã«ããåŠ
çããæ¹æ³ãå°ãªããšãïŒåã®ããã²ã³åååã¯
ã¢ã«ã³ãã·åºã§çœ®æãããã·ãªã«åºããã€ããã¯
ãããã¯ååç©ã§åŠçããæ¹æ³ãåºäœè¡šé¢ãã¢ã
ãåºããã€ã·ãªã«åå€ã§åŠçããã®ã¡ãã«ã«ãã
ã·ã«åºããã€ããã¯ãããã¯ååç©ãçµåããæ¹
æ³ãªã©ã«ãã€ãŠè¡ãããšãã§ããããžãšã€ãã³ã°
ããŒïŒJ.CognavdïŒèããã¢ã¬ããŠã©ãŒã»ã¯ãªã¹
ã¿ã«ãºã»ã¢ã³ãã»ãªãããã»ã¯ãªã¹ã¿ã«ãº
ïŒMolecular Crystals and Liquid CrystalsïŒãã
ãµããªã¡ã³ãïŒïŒ1982幎ïŒåã³æŸæ¬æ£äžãè§ç°åž
è¯èã液æ¶ã®ææ°æè¡ããïŒ1983幎ïŒåç §ãã
åèšã®è¡šé¢æŽ»æ§åºããã€ããã¯ãããã¯ååç©
ã®è¡šé¢æŽ»æ§åºã®äŸãšããŠã¯ãã«ã«ãã³é žæ®åºãã
ãã³é žæ®åºãã¢ã«ãã«ã¢ã«ãããŠã å¡©æ®åºãã¢ã«
ãã«ããªãžããŠã å¡©æ®åºãã¢ã«ãã«ãããªããŠã
å¡©æ®åºãã¢ã«ããã·ã©ãã¯ãããŠã é¯äœæ®åºããš
ã¹ãã«æ®åºããããªã«æ®åºãå°¿çŽ æ®åºãã¢ãã³æ®
åºãã¢ã«ã³ãŒã«æ®åºãããšããŒã«æ®åºããã¿ã€ã³
æ®åºãªã©ãæããããšãã§ããããã®ãããªè¡šé¢
掻æ§åºããã€ããã¯ãããã¯ååç©ãåºæ¿è¡šé¢ã«
æœãã«ã¯ããããçŽæ¥åºæ¿è¡šé¢ã«å¡åžããããã
ããã¯ãããã液æ¶ç©è³ªã«æº¶è§£ããŠäœ¿çšããã°ã
ããåŸè ã®å Žåãè¡šé¢æŽ»æ§åºããã€ããã¯ããã
ã¯ååç©ã®æ·»å éã¯ã液æ¶ã®ééåœã0.01ã5.0
ééïŒ ã奜ãŸããã¯0.5ã3.0ééïŒ ã®ç¯å²ã§ã
ãã
ã®è¡šé¢æŽ»æ§åºã®äŸãšããŠã¯ãã«ã«ãã³é žæ®åºãã
ãã³é žæ®åºãã¢ã«ãã«ã¢ã«ãããŠã å¡©æ®åºãã¢ã«
ãã«ããªãžããŠã å¡©æ®åºãã¢ã«ãã«ãããªããŠã
å¡©æ®åºãã¢ã«ããã·ã©ãã¯ãããŠã é¯äœæ®åºããš
ã¹ãã«æ®åºããããªã«æ®åºãå°¿çŽ æ®åºãã¢ãã³æ®
åºãã¢ã«ã³ãŒã«æ®åºãããšããŒã«æ®åºããã¿ã€ã³
æ®åºãªã©ãæããããšãã§ããããã®ãããªè¡šé¢
掻æ§åºããã€ããã¯ãããã¯ååç©ãåºæ¿è¡šé¢ã«
æœãã«ã¯ããããçŽæ¥åºæ¿è¡šé¢ã«å¡åžããããã
ããã¯ãããã液æ¶ç©è³ªã«æº¶è§£ããŠäœ¿çšããã°ã
ããåŸè ã®å Žåãè¡šé¢æŽ»æ§åºããã€ããã¯ããã
ã¯ååç©ã®æ·»å éã¯ã液æ¶ã®ééåœã0.01ã5.0
ééïŒ ã奜ãŸããã¯0.5ã3.0ééïŒ ã®ç¯å²ã§ã
ãã
åèšããå°ãªããšãïŒåã®ããã²ã³åååã¯ã¢
ã«ã³ãã·åºã§çœ®æãããã·ãªã«åºããã€ããã¯ã
ããã¯ååç©ãšããŠã¯ãäŸãã°ããªãšããã·ã·ãª
ã«ã¢ãŸãã³ãŒã³ãã¢ãã¯ãããžãšããã·ã·ãªã«ã¢
ãŸãã³ãŒã³ãããªã¯ããã·ãªã«ã¢ãŸãã³ãŒã³ãã
ãªãšããã·ã·ãªã«ã€ã³ãžãŽãããªãšããã·ã·ãªã«
ã€ã³ããªãã¹ãããã³ãŸãã©ã³ãªã©ãããããã
ãã®ååç©ã«ããåŠçã¯ã0.1ã10ïŒ ã奜ãŸãã
ã¯0.5ãïŒïŒ ã®ç¯å²ã®æ¿åºŠã®æº¶æ¶²ãšããŠãåºæ¿è¡š
é¢ã«å¡åžãããããããã¯ãã®æº¶æ¶²äžã«åºæ¿ã浞
ããããããšã«ãã€ãŠè¡ãããããã®éã®æº¶åªãš
ããŠã¯ãæ°Žãé ¢é žããã«ãšã³ãã¢ã»ãã³ããžã¡ã
ã«ãã«ã ã¢ãããªã©ã奜é©ã§ããããŸããåŠçæ
éãšããŠã¯ãïŒç§ãªããïŒæéãéåžžã¯30ç§ãªã
ã10åéãèŠããããã®æ¹æ³ã«ãããŠã¯ãã·ãªã«
åå€ã«ããåºæ¿è¡šé¢ã®åŠçã䜵çšããããšã«ã
ããããã«çµååãåäžãããããšãã§ããã
ã«ã³ãã·åºã§çœ®æãããã·ãªã«åºããã€ããã¯ã
ããã¯ååç©ãšããŠã¯ãäŸãã°ããªãšããã·ã·ãª
ã«ã¢ãŸãã³ãŒã³ãã¢ãã¯ãããžãšããã·ã·ãªã«ã¢
ãŸãã³ãŒã³ãããªã¯ããã·ãªã«ã¢ãŸãã³ãŒã³ãã
ãªãšããã·ã·ãªã«ã€ã³ãžãŽãããªãšããã·ã·ãªã«
ã€ã³ããªãã¹ãããã³ãŸãã©ã³ãªã©ãããããã
ãã®ååç©ã«ããåŠçã¯ã0.1ã10ïŒ ã奜ãŸãã
ã¯0.5ãïŒïŒ ã®ç¯å²ã®æ¿åºŠã®æº¶æ¶²ãšããŠãåºæ¿è¡š
é¢ã«å¡åžãããããããã¯ãã®æº¶æ¶²äžã«åºæ¿ã浞
ããããããšã«ãã€ãŠè¡ãããããã®éã®æº¶åªãš
ããŠã¯ãæ°Žãé ¢é žããã«ãšã³ãã¢ã»ãã³ããžã¡ã
ã«ãã«ã ã¢ãããªã©ã奜é©ã§ããããŸããåŠçæ
éãšããŠã¯ãïŒç§ãªããïŒæéãéåžžã¯30ç§ãªã
ã10åéãèŠããããã®æ¹æ³ã«ãããŠã¯ãã·ãªã«
åå€ã«ããåºæ¿è¡šé¢ã®åŠçã䜵çšããããšã«ã
ããããã«çµååãåäžãããããšãã§ããã
次ã«ãåºæ¿è¡šé¢ãã¢ããåºããã€ã·ãªã«åå€ã§
åŠçããã®ã¡ãã«ã«ããã·ã«åºããã€ããã¯ãã
ãã¯ååç©ã§åŠçããå Žåã«çšããã·ãªã«åå€ãš
ããŠã¯ãäŸãã°ã¢ãããããã«ããªãšããã·ã·ã©
ã³ãã¢ãããããã«ãžãšããã·ã·ã©ã³ãã¢ããã
ãã«ã¡ãã«ãžãšããã·ã·ã©ã³ãã¢ããããã«ããª
ãšããã·ã·ã©ã³ãªã©ãããããããã®ã·ãªã«åå€
ã«ããåŠçã¯ãããã0.1ã10ïŒ ã奜ãŸããã¯0.5
ãïŒïŒ ã®ç¯å²ã®æ¿åºŠã®æº¶æ¶²ãšããŠããã®æº¶æ¶²ãåº
æ¿è¡šé¢ã«å¡åžãããããããã¯ãã®æº¶æ¶²äžã«æµžã
ãããããšã«ãã€ãŠè¡ãããããã®éã®æº¶åªãšã
ãŠã¯ãæ°Žããšã¿ããŒã«ãé ¢é žããã«ãšã³ãã¢ã»ã
ã³ããžã¡ãã«ãã«ã ã¢ãããªã©ã奜é©ã§ãããåŠ
çæéã¯éåžžæ°ç§ãªããæ°10åã®ç¯å²å ã§ããã
åŠçããã®ã¡ãã«ã«ããã·ã«åºããã€ããã¯ãã
ãã¯ååç©ã§åŠçããå Žåã«çšããã·ãªã«åå€ãš
ããŠã¯ãäŸãã°ã¢ãããããã«ããªãšããã·ã·ã©
ã³ãã¢ãããããã«ãžãšããã·ã·ã©ã³ãã¢ããã
ãã«ã¡ãã«ãžãšããã·ã·ã©ã³ãã¢ããããã«ããª
ãšããã·ã·ã©ã³ãªã©ãããããããã®ã·ãªã«åå€
ã«ããåŠçã¯ãããã0.1ã10ïŒ ã奜ãŸããã¯0.5
ãïŒïŒ ã®ç¯å²ã®æ¿åºŠã®æº¶æ¶²ãšããŠããã®æº¶æ¶²ãåº
æ¿è¡šé¢ã«å¡åžãããããããã¯ãã®æº¶æ¶²äžã«æµžã
ãããããšã«ãã€ãŠè¡ãããããã®éã®æº¶åªãšã
ãŠã¯ãæ°Žããšã¿ããŒã«ãé ¢é žããã«ãšã³ãã¢ã»ã
ã³ããžã¡ãã«ãã«ã ã¢ãããªã©ã奜é©ã§ãããåŠ
çæéã¯éåžžæ°ç§ãªããæ°10åã®ç¯å²å ã§ããã
ãã®ã·ãªã«åå€ã«ããåŠçããåŸãã·ãªã«åå€
ã®ã¢ããåºã«å¯Ÿããã«ã«ããã·ã«åºããã€ããã¯
ãããã¯ååç©ãåžžæ³ã«åŸã€ãŠåå¿ãããã¢ãã
çµåã圢æãããããã®ããã«ããŠãåºæ¿è¡šé¢äž
ã«ããã¯ãããã¯ååç©ãååŠçã«çµåãããã
ãšãã§ããã
ã®ã¢ããåºã«å¯Ÿããã«ã«ããã·ã«åºããã€ããã¯
ãããã¯ååç©ãåžžæ³ã«åŸã€ãŠåå¿ãããã¢ãã
çµåã圢æãããããã®ããã«ããŠãåºæ¿è¡šé¢äž
ã«ããã¯ãããã¯ååç©ãååŠçã«çµåãããã
ãšãã§ããã
åºæ¿è¡šé¢äžã«çµåããããå
ã«ããå¯éçã«æ§
é å€åãèµ·ãååç©ã¯ãåååå±€ã圢æãããã
ãã§ååã«ãã®æ©èœãçºæ®ãããããææãªãã°
ïŒååå±€åã¯ãã以äžã®å±€ã«ããããšãã§ããã
é å€åãèµ·ãååç©ã¯ãåååå±€ã圢æãããã
ãã§ååã«ãã®æ©èœãçºæ®ãããããææãªãã°
ïŒååå±€åã¯ãã以äžã®å±€ã«ããããšãã§ããã
次ã«ãå
ã«ããå¯éçã«æ§é å€åãèµ·ãååç©
ã®ååå±€äžã«èšãã液æ¶å±€ã®æ¶²æ¶ãšããŠã¯ãåŸæ¥
ç¥ãããŠãããããã€ãã¯ç³»ãã¹ã¡ãã€ãã¯ç³»å
ã³ã³ã¬ã¹ããªãã¯ç³»ã®æ¶²æ¶ç©è³ªã®äžããä»»æã®ã
ã®ãéžã¶ããšãã§ããããã¹ã¡ã¯ãã€ãã¯ç³»æ¶²æ¶
ç©è³ªã®å Žåã¯ããã枩床ã§ãããã€ãã¯æ¶²æ¶çžã
ãšããã®ãéžã¶å¿ èŠãããã
ã®ååå±€äžã«èšãã液æ¶å±€ã®æ¶²æ¶ãšããŠã¯ãåŸæ¥
ç¥ãããŠãããããã€ãã¯ç³»ãã¹ã¡ãã€ãã¯ç³»å
ã³ã³ã¬ã¹ããªãã¯ç³»ã®æ¶²æ¶ç©è³ªã®äžããä»»æã®ã
ã®ãéžã¶ããšãã§ããããã¹ã¡ã¯ãã€ãã¯ç³»æ¶²æ¶
ç©è³ªã®å Žåã¯ããã枩床ã§ãããã€ãã¯æ¶²æ¶çžã
ãšããã®ãéžã¶å¿ èŠãããã
ãã®ãããªæ¶²æ¶ç©è³ªã¯ãäŸãã°ãšãŒã»ãã®ã³
ïŒA.BequinïŒä»èããã¢ã¬ããŠã©ãŒã»ã¯ãªã¹ã¿ã«
ãºã»ã¢ã³ãã»ãªãããã»ã¯ãªã¹ã¿ã«ãº
ïŒMolecular Crystals and Liquid CrystalsïŒãã
第115å·»ã第ïŒããŒãžã«èšèŒãããŠãããããã
ã®æ¶²æ¶ç©è³ªã¯ãåç¬ã§çšããŠããããããŸãïŒçš®
以äžæ··åããŠçšããŠãããã
ïŒA.BequinïŒä»èããã¢ã¬ããŠã©ãŒã»ã¯ãªã¹ã¿ã«
ãºã»ã¢ã³ãã»ãªãããã»ã¯ãªã¹ã¿ã«ãº
ïŒMolecular Crystals and Liquid CrystalsïŒãã
第115å·»ã第ïŒããŒãžã«èšèŒãããŠãããããã
ã®æ¶²æ¶ç©è³ªã¯ãåç¬ã§çšããŠããããããŸãïŒçš®
以äžæ··åããŠçšããŠãããã
ãã®å Žåã枩床äŸåæ§ã®ãã液æ¶ç©è³ªäŸãã°å®€
æž©ã«ãããŠã¯ãå ãç §å°ããŠãæ§é å€åãèµ·ããª
ããããã枩床以äžã«å ç±ãããšå ç §å°ã«ããæ§
é å€åãèµ·ã液æ¶ç©è³ªãçšããã°ãæä¹ çãªèšé²
ãåŸãããšãã§ããã
æž©ã«ãããŠã¯ãå ãç §å°ããŠãæ§é å€åãèµ·ããª
ããããã枩床以äžã«å ç±ãããšå ç §å°ã«ããæ§
é å€åãèµ·ã液æ¶ç©è³ªãçšããã°ãæä¹ çãªèšé²
ãåŸãããšãã§ããã
次ã«æ·»ä»å³é¢ã«ããæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ããã
ããã
第ïŒå³ã¯æ¬çºæã®åºæ¬æ§é ã瀺ãæé¢å³ã§éæ
åºæ¿ïŒã®äžã«ãå ã«ããå¯éçãªæ§é å€åãèµ·ã
ååç©ã®ååå±€ïŒãä»ããŠæ¶²æ¶å±€ïŒãèšããããŠ
ãããéåžžã¯ã液æ¶å±€ãåºå®ãããã€éžæ£ãé²ã
ããã«ããã®äžãããã«åºæ¿ã§è¢«èŠããŠãããã
ã®åºæ¿ã¯éæã§ãã€ãŠãäžéæã§ãã€ãŠããã
ãããŸããã®è¡šé¢ããå ã«ããå¯éçãªæ§é å€å
ãèµ·ãååç©ã®ååå±€ã§è¢«èŠãããã®ãçšããã
ãšãã§ãããã液æ¶ãè¡šé¢ã«å¹³è¡ã«é åããäœçš
ããã€ãã¢ãžãã¢ã¹é åå±€ã§è¢«èŠãããã®ãçšã
ãããšãã§ããã
åºæ¿ïŒã®äžã«ãå ã«ããå¯éçãªæ§é å€åãèµ·ã
ååç©ã®ååå±€ïŒãä»ããŠæ¶²æ¶å±€ïŒãèšããããŠ
ãããéåžžã¯ã液æ¶å±€ãåºå®ãããã€éžæ£ãé²ã
ããã«ããã®äžãããã«åºæ¿ã§è¢«èŠããŠãããã
ã®åºæ¿ã¯éæã§ãã€ãŠãäžéæã§ãã€ãŠããã
ãããŸããã®è¡šé¢ããå ã«ããå¯éçãªæ§é å€å
ãèµ·ãååç©ã®ååå±€ã§è¢«èŠãããã®ãçšããã
ãšãã§ãããã液æ¶ãè¡šé¢ã«å¹³è¡ã«é åããäœçš
ããã€ãã¢ãžãã¢ã¹é åå±€ã§è¢«èŠãããã®ãçšã
ãããšãã§ããã
第ïŒå³ã¯ãæ¬çºæã®å¥œé©ãªå®æœæ
æ§ã®äŸã瀺ã
æé¢å³ã§ãã€ãŠãããã¯è¡šé¢äžã«ããã¯ãããã¯
ååç©ã®åååå±€ïŒãæããïŒæã®åºæ¿ïŒã®é
ã«ã液æ¶çžãæŸãã ãµã³ãã€ããæ§é ãæããŠã
ãã
æé¢å³ã§ãã€ãŠãããã¯è¡šé¢äžã«ããã¯ãããã¯
ååç©ã®åååå±€ïŒãæããïŒæã®åºæ¿ïŒã®é
ã«ã液æ¶çžãæŸãã ãµã³ãã€ããæ§é ãæããŠã
ãã
ãããŠããã®å³ã®ã¯å
ç
§å°åãã¯å
ç
§å°åŸ
ã®ç¶æ ã瀺ããå ç §å°åã¯ãããã¯ãããã¯åå
ç©ã®åååå±€ã®äœçšã«ããã液æ¶çžã«ãããŠã液
æ¶ã¯åºæ¿é¢ã«åçŽã®æ¹åïŒãã¡ãªããããã¯ïŒã«
èŠåæ£ããé åããŠããïŒïŒã次ã«ãã®å èšé²
çŽ åã®äžéšïŒ¡ã«å ãç §å°ãããšãããã¯ãããã¯
ååç©ãæ§é å€åãèµ·ãããããã®éšåã«ããã
åèšããåçŽé åãç Žå£ãã液æ¶ã¯è¡šé¢ã«å¯Ÿãå¹³
è¡ïŒãã¢ãžãã¢ã¹ïŒã®é åããšãããã®ããã«å
ã«ãã€ãŠæ§é ãå€åããåŸã®ããã¯ãããã¯åå
ç©åååå±€ã«ãããŠã¯ã液æ¶ã®é·è»žãè¡šé¢ã«å¯Ÿã
ãŠå¹³è¡ã«é åãããšããäºå®ã¯ãæ¬çºæè ã«ãã
ã¯ãããŠèŠåºããããã®ã§ããã
ã®ç¶æ ã瀺ããå ç §å°åã¯ãããã¯ãããã¯åå
ç©ã®åååå±€ã®äœçšã«ããã液æ¶çžã«ãããŠã液
æ¶ã¯åºæ¿é¢ã«åçŽã®æ¹åïŒãã¡ãªããããã¯ïŒã«
èŠåæ£ããé åããŠããïŒïŒã次ã«ãã®å èšé²
çŽ åã®äžéšïŒ¡ã«å ãç §å°ãããšãããã¯ãããã¯
ååç©ãæ§é å€åãèµ·ãããããã®éšåã«ããã
åèšããåçŽé åãç Žå£ãã液æ¶ã¯è¡šé¢ã«å¯Ÿãå¹³
è¡ïŒãã¢ãžãã¢ã¹ïŒã®é åããšãããã®ããã«å
ã«ãã€ãŠæ§é ãå€åããåŸã®ããã¯ãããã¯åå
ç©åååå±€ã«ãããŠã¯ã液æ¶ã®é·è»žãè¡šé¢ã«å¯Ÿã
ãŠå¹³è¡ã«é åãããšããäºå®ã¯ãæ¬çºæè ã«ãã
ã¯ãããŠèŠåºããããã®ã§ããã
ãããã€ãŠãäŸãã°çŽäº€ãã³ã«äžèŠ³å¯ãããšã
å ç §å°ãããªãéšåã¯å ãéããªãããå ç §å°
ããéšåã¯å ãéãã®ã§ãä»»æã®æ³¢é·ã®åå ã
çšããã°å ã®ééçã«ããå æ å ±ã®èªã¿åããè¡
ãããšãã§ããã
å ç §å°ãããªãéšåã¯å ãéããªãããå ç §å°
ããéšåã¯å ãéãã®ã§ãä»»æã®æ³¢é·ã®åå ã
çšããã°å ã®ééçã«ããå æ å ±ã®èªã¿åããè¡
ãããšãã§ããã
次ã«ç¬¬ïŒå³ã¯ã第ïŒå³ã®å Žåãšã¯å¥ã®å®æœæ
æ§
ã®äŸã§ãããïŒæã®åºæ¿ã®ãã¡ã®äžæ¹ã«ãã¢ãžã
ã¢ã¹é åå±€ïŒãèšããããŠããäŸã§ããããã®ã
ã¢ãžãã¢ã¹é åå±€ã¯ãåºæ¿è¡šé¢ãããªããã«ã¢ã«
ã³ãŒã«ãããªã€ããæš¹èãããªãªãã·ãšãã¬ã³ãª
ã©ã§ã©ãã³ã°åŠçãããããããã¯SiO2ã®ãã
ãªé žåç©ãæãæ¹åããèžçããããšã«ããèšã
ãããšãã§ããããã®äŸã«ãããŠã¯ãããã¯ãã
ãã¯ååç©åååå±€åŽã«ãããŠã¯ã第ïŒå³ã«ç€º
ãããã«æ¶²æ¶ã¯åºæ¿è¡šé¢ã«åçŽã®æ¹åã«é åããŠ
ããããã¢ãžãã¢ã¹é åå±€åŽã§ã¯åºæ¿ãšå¹³è¡ã®æ¹
åã«é åããæ§é ããšã€ãŠããããããŠãããã«
å ç §å°ãããšããã®ç §å°ãããéšåã«ãããŠã¯
液æ¶ã¯ããã¯ãããã¯ååç©åååå±€é¢ã«å¹³è¡ã«
é åããã®ã§ãå šäœããã¢ãžãã¢ã¹é åç¶æ ãšãª
ããåèšãšåæ§ã«ããŠåå ã«ããå æ å ±ãèªã¿åº
ãããšãã§ããã
ã®äŸã§ãããïŒæã®åºæ¿ã®ãã¡ã®äžæ¹ã«ãã¢ãžã
ã¢ã¹é åå±€ïŒãèšããããŠããäŸã§ããããã®ã
ã¢ãžãã¢ã¹é åå±€ã¯ãåºæ¿è¡šé¢ãããªããã«ã¢ã«
ã³ãŒã«ãããªã€ããæš¹èãããªãªãã·ãšãã¬ã³ãª
ã©ã§ã©ãã³ã°åŠçãããããããã¯SiO2ã®ãã
ãªé žåç©ãæãæ¹åããèžçããããšã«ããèšã
ãããšãã§ããããã®äŸã«ãããŠã¯ãããã¯ãã
ãã¯ååç©åååå±€åŽã«ãããŠã¯ã第ïŒå³ã«ç€º
ãããã«æ¶²æ¶ã¯åºæ¿è¡šé¢ã«åçŽã®æ¹åã«é åããŠ
ããããã¢ãžãã¢ã¹é åå±€åŽã§ã¯åºæ¿ãšå¹³è¡ã®æ¹
åã«é åããæ§é ããšã€ãŠããããããŠãããã«
å ç §å°ãããšããã®ç §å°ãããéšåã«ãããŠã¯
液æ¶ã¯ããã¯ãããã¯ååç©åååå±€é¢ã«å¹³è¡ã«
é åããã®ã§ãå šäœããã¢ãžãã¢ã¹é åç¶æ ãšãª
ããåèšãšåæ§ã«ããŠåå ã«ããå æ å ±ãèªã¿åº
ãããšãã§ããã
æ¬çºæã®å
èšé²çŽ åã«ãããŠããã€ããèšé²ã
ãæ å ±ãæ¶å»ãããå Žåã¯ãèšé²æã«äœ¿çšããå
ãšæ³¢é·ã®ç°ãªãå ãç §å°ããŠãããã¯ãããã¯å
åç©ã®æ§é ãå ã«æ»ãããšã«ããè¡ãããšãã§ã
ãã
ãæ å ±ãæ¶å»ãããå Žåã¯ãèšé²æã«äœ¿çšããå
ãšæ³¢é·ã®ç°ãªãå ãç §å°ããŠãããã¯ãããã¯å
åç©ã®æ§é ãå ã«æ»ãããšã«ããè¡ãããšãã§ã
ãã
çºæã®å¹æ
æ¬çºæã®å
èšé²çŽ åã¯ãåŸæ¥ã®ããã¯ãããã¯
ææã«ããæ å ±èšé²ã®æ¬ ç¹ãäŸãã°ãã€ããèšé²
ãããæ å ±ããèªã¿åãã®ç¹°ãè¿ãã«ããåŸã ã«
æ¶å€±ãããšããæ¬ ç¹ã瀺ããªããšããå©ç¹ããã
äžã«ã液æ¶ã®é åãããã¯ãããã¯åååå±€ã«ã
ã€ãŠåŸããããã®ã§ãæµåæ§ããã€æ¶²æ¶ã«ãã解
åæ§ã¯ãåŸæ¥ã®ããã¯ãããã¯ååç©ã液æ¶ã«å
ãããã®ãçšããå Žåãããã¯ããã«åªããŠã
ãããŸããæ¬çºæã®å èšé²çŽ åã¯ãå¯éçãªå æ
å ±è²¯èµã«çšããããã ãã§ãªããå ã¢ãã¬ã¹åã®
衚瀺ã«ã奜é©ã«çšããããšãã§ããã
ææã«ããæ å ±èšé²ã®æ¬ ç¹ãäŸãã°ãã€ããèšé²
ãããæ å ±ããèªã¿åãã®ç¹°ãè¿ãã«ããåŸã ã«
æ¶å€±ãããšããæ¬ ç¹ã瀺ããªããšããå©ç¹ããã
äžã«ã液æ¶ã®é åãããã¯ãããã¯åååå±€ã«ã
ã€ãŠåŸããããã®ã§ãæµåæ§ããã€æ¶²æ¶ã«ãã解
åæ§ã¯ãåŸæ¥ã®ããã¯ãããã¯ååç©ã液æ¶ã«å
ãããã®ãçšããå Žåãããã¯ããã«åªããŠã
ãããŸããæ¬çºæã®å èšé²çŽ åã¯ãå¯éçãªå æ
å ±è²¯èµã«çšããããã ãã§ãªããå ã¢ãã¬ã¹åã®
衚瀺ã«ã奜é©ã«çšããããšãã§ããã
å®æœäŸ
次ã«å®æœäŸã«ããæ¬çºæãããã«è©³çŽ°ã«èª¬æã
ãã
ãã
å®æœäŸ ïŒ
4â²âããã·ã«âïŒâããããã·ã¢ãŸãã³ãŒã³(1)
ïŒïœïŒ3.73Ã10-3moïŒããããªãŠã ã¡ãã©ãŒ
ãã§ãããªãŠã å¡©ã«ããã®ã¡ãããã«ïŒâããã©
ããããã©ãã«ïŒâããã¢ããããšãŒã1.03ïœ
ïŒ3.69Ã10-3moïŒåã³ãžã¡ãã«ã¢ã»ãã¢ããïŒ
mlãå ãã100âã§73æéå ç±ãããåå¿çµäºåŸ
æ°Žãå ãã宀枩ãŸã§æŸå·ããŠæåºããé»è²çµæ¶ã
ãéããŠéããããããé ¢é žãšãã«ã§æœåºããç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥åŸãæžå§äžã§æº¶åªãçå»ã
ããæ®çåããããµã³ãšãã³ãŒã³ãšã®æ··åç©ãã
åçµæ¶ããŠïŒïœïŒâïŒïŒâããã·ã«ããšãã«ã¢ãŸïŒ
âããšããã·ïœâãããµã³é žïŒïœãåŸãããã®ã«
ã«ãã³é ž200ïœïœïŒ5.05Ã10-4moïŒãå¡©åããª
ãã«ïŒmlã«å ããïŒæéå ç±éæµåŸéå°ã®å¡©åã
ãªãã«ãçå»ãã也ç¥ãšãŒãã«ïŒmlåã³ããªãšã
ã«ã¢ãã³0.15ïœïŒ1.485Ã10-3moïŒãå ããã
ãã®æ··åç©ã«æ°·å·äžãããªãšããã·ã¢ããããã
ã«ã·ã©ã³0.11ïœïŒ4.98Ã10-4moïŒã®ä¹Ÿç¥ãšãŒã
ã«æº¶æ¶²ïŒmlã滎äžããïŒæéãããŸããã®ã¡ãçª
çŽ é°å²æ°äžã§ãéããå¡©ãé€ããåŸãæžå§äžå®€æž©
ã§æº¶åªãçå»ãããé»è²ã¯ãã¯ã¹ç¶ã®ïŒ®âïŒïŒâ
ããªãšããã·ã·ãªã«ãããã«ïŒâïŒâïœïŒâïŒïŒâ
ããã·ã«ããšãã«ã¢ãŸïŒããšããã·ïœãããµã³é ž
ã¢ãã213ïœïœãåŸãã
ïŒïœïŒ3.73Ã10-3moïŒããããªãŠã ã¡ãã©ãŒ
ãã§ãããªãŠã å¡©ã«ããã®ã¡ãããã«ïŒâããã©
ããããã©ãã«ïŒâããã¢ããããšãŒã1.03ïœ
ïŒ3.69Ã10-3moïŒåã³ãžã¡ãã«ã¢ã»ãã¢ããïŒ
mlãå ãã100âã§73æéå ç±ãããåå¿çµäºåŸ
æ°Žãå ãã宀枩ãŸã§æŸå·ããŠæåºããé»è²çµæ¶ã
ãéããŠéããããããé ¢é žãšãã«ã§æœåºããç¡«
é žãã°ãã·ãŠã ã§ä¹Ÿç¥åŸãæžå§äžã§æº¶åªãçå»ã
ããæ®çåããããµã³ãšãã³ãŒã³ãšã®æ··åç©ãã
åçµæ¶ããŠïŒïœïŒâïŒïŒâããã·ã«ããšãã«ã¢ãŸïŒ
âããšããã·ïœâãããµã³é žïŒïœãåŸãããã®ã«
ã«ãã³é ž200ïœïœïŒ5.05Ã10-4moïŒãå¡©åããª
ãã«ïŒmlã«å ããïŒæéå ç±éæµåŸéå°ã®å¡©åã
ãªãã«ãçå»ãã也ç¥ãšãŒãã«ïŒmlåã³ããªãšã
ã«ã¢ãã³0.15ïœïŒ1.485Ã10-3moïŒãå ããã
ãã®æ··åç©ã«æ°·å·äžãããªãšããã·ã¢ããããã
ã«ã·ã©ã³0.11ïœïŒ4.98Ã10-4moïŒã®ä¹Ÿç¥ãšãŒã
ã«æº¶æ¶²ïŒmlã滎äžããïŒæéãããŸããã®ã¡ãçª
çŽ é°å²æ°äžã§ãéããå¡©ãé€ããåŸãæžå§äžå®€æž©
ã§æº¶åªãçå»ãããé»è²ã¯ãã¯ã¹ç¶ã®ïŒ®âïŒïŒâ
ããªãšããã·ã·ãªã«ãããã«ïŒâïŒâïœïŒâïŒïŒâ
ããã·ã«ããšãã«ã¢ãŸïŒããšããã·ïœãããµã³é ž
ã¢ãã213ïœïœãåŸãã
ãã®ããªãšããã·ã·ãªã«ã¢ãŸãã³ãŒã³ã®0.4wt
ïŒ ãšã¿ããŒã«æº¶æ¶²ã«æž æŸãªç³è±æ¿ã10å浞ãã
ãã颚也ããŠãã100âã§10å也ç¥ãããããã
ïŒåéå¡©åã¡ãã¬ã³äžã§è¶ é³æ³¢æŽæµãã100âã§
10åé也ç¥ããããã®ç³è±æ¿ã®äž¡é¢ãã¢ãŸãã³ãŒ
ã³ã§ä¿®é£ŸãããŠãããããã®348.5nmã§ã®åžå 床
ã¯0.0316ã§ãããå®éã«ã¯ç¡è²éæã§ãã€ãã
ïŒ ãšã¿ããŒã«æº¶æ¶²ã«æž æŸãªç³è±æ¿ã10å浞ãã
ãã颚也ããŠãã100âã§10å也ç¥ãããããã
ïŒåéå¡©åã¡ãã¬ã³äžã§è¶ é³æ³¢æŽæµãã100âã§
10åé也ç¥ããããã®ç³è±æ¿ã®äž¡é¢ãã¢ãŸãã³ãŒ
ã³ã§ä¿®é£ŸãããŠãããããã®348.5nmã§ã®åžå 床
ã¯0.0316ã§ãããå®éã«ã¯ç¡è²éæã§ãã€ãã
ãã®ããã«ããŠåŠçããç³è±æ¿ïŒæã§8ÎŒã®ã¬
ã©ã¹ãããã¹ããŒãµãå«ãã·ã¯ããããµã³ã«ã«ã
ã³é žããšãã«ãšã¹ãã«ç³»æ··å液æ¶ïŒïŒ«â17ââ
73âïŒïŒãæŸã¿èŸŒã¿ããšããã·æš¹èã§å°ããŠãµã³
ãã€ããã»ã«ãäœæããããã®ç¡è²éæã®ã»ã«ã
çŽäº€ãã³ã«éã«çœ®ããHeâNeã¬ãŒã¶ã§ééå é
ãã¢ãã¿ãŒããã玫å€ç·ç §å°åã®ã»ã«ã¯çŽäº€ãã³
ã¹äžã§ééå éã¯ãŒãã§ããããã¡ãªããããã¯
液æ¶é åããŠããããšãåããããã«365nmã®çŽ«
å€ç·ãç §å°ãããšãã¢ãŸãã³ãŒã³ããã©ã³ã¹ãã
ã·ã¹ãžå ç°æ§åããã«ã€ããŠééå éã¯å¢å ã
ãã次ã«ã440nm以äžã®å¯èŠå ãç §å°ãããšãã
ã©ã³ã¹ãžã®ç°æ§åãèµ·ãã«ã€ããŠééå éã¯åã³
æžå°ããããã®ééå éã¯ã玫å€ç·ãšå¯èŠå ã®äº€
äºç §å°ã«å¿ããŠå¯éçã«å€åããããŸããåãã»
ã«ã«ãã¬ãéããŠçŽ«å€ç·ãç §å°ãããšãããçŽäº€
ãã³ã«ã§æçãªç»åãèªããããããã®ç»åã¯ã»
ã«ã«å§åãå ããŠæ¶²æ¶ãæµåãããŠãä¹±ããäºã¯
ãªãã€ãã
ã©ã¹ãããã¹ããŒãµãå«ãã·ã¯ããããµã³ã«ã«ã
ã³é žããšãã«ãšã¹ãã«ç³»æ··å液æ¶ïŒïŒ«â17ââ
73âïŒïŒãæŸã¿èŸŒã¿ããšããã·æš¹èã§å°ããŠãµã³
ãã€ããã»ã«ãäœæããããã®ç¡è²éæã®ã»ã«ã
çŽäº€ãã³ã«éã«çœ®ããHeâNeã¬ãŒã¶ã§ééå é
ãã¢ãã¿ãŒããã玫å€ç·ç §å°åã®ã»ã«ã¯çŽäº€ãã³
ã¹äžã§ééå éã¯ãŒãã§ããããã¡ãªããããã¯
液æ¶é åããŠããããšãåããããã«365nmã®çŽ«
å€ç·ãç §å°ãããšãã¢ãŸãã³ãŒã³ããã©ã³ã¹ãã
ã·ã¹ãžå ç°æ§åããã«ã€ããŠééå éã¯å¢å ã
ãã次ã«ã440nm以äžã®å¯èŠå ãç §å°ãããšãã
ã©ã³ã¹ãžã®ç°æ§åãèµ·ãã«ã€ããŠééå éã¯åã³
æžå°ããããã®ééå éã¯ã玫å€ç·ãšå¯èŠå ã®äº€
äºç §å°ã«å¿ããŠå¯éçã«å€åããããŸããåãã»
ã«ã«ãã¬ãéããŠçŽ«å€ç·ãç §å°ãããšãããçŽäº€
ãã³ã«ã§æçãªç»åãèªããããããã®ç»åã¯ã»
ã«ã«å§åãå ããŠæ¶²æ¶ãæµåãããŠãä¹±ããäºã¯
ãªãã€ãã
å®æœäŸ ïŒ
å®æœäŸïŒã§åŸãããªãšããã·ã·ãªã«ã¢ãŸãã³ãŒ
ã³ãšã¢ãããããã«ããªãšããã·ã·ã©ã³ãšãïŒïŒ
ïŒã®ééæ¯ã§æ··åãããã®0.4wtïŒ ãšã¿ããŒã«æº¶
液ã§ç³è±æ¿ãå®æœäŸïŒãšåæ§ã«ããŠåŠçããåŸã
ãã®ïŒæã®ç³è±æ¿ã§8ÎŒã®æ··å液æ¶ã®ãµã³ãã€ã
ãã»ã«ãæ§æããããã®ã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã
亀äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãª
ééå éå€åãèªããããã
ã³ãšã¢ãããããã«ããªãšããã·ã·ã©ã³ãšãïŒïŒ
ïŒã®ééæ¯ã§æ··åãããã®0.4wtïŒ ãšã¿ããŒã«æº¶
液ã§ç³è±æ¿ãå®æœäŸïŒãšåæ§ã«ããŠåŠçããåŸã
ãã®ïŒæã®ç³è±æ¿ã§8ÎŒã®æ··å液æ¶ã®ãµã³ãã€ã
ãã»ã«ãæ§æããããã®ã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã
亀äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãª
ééå éå€åãèªããããã
å®æœäŸ ïŒ
å®æœäŸïŒã§åŸãã¢ãŸãã³ãŒã³åŠçããç³è±æ¿ãš
ããªããã«ã¢ã«ã³ãŒã«å¡åžããŠã©ãã³ã°åŠçãã
ç³è±æ¿ãšã§8ÎŒã®æ··å液æ¶ã®ãµã³ãã€ããã»ã«ã
æ§æãããããã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ã
ããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éã®å€
åãèªããããã
ããªããã«ã¢ã«ã³ãŒã«å¡åžããŠã©ãã³ã°åŠçãã
ç³è±æ¿ãšã§8ÎŒã®æ··å液æ¶ã®ãµã³ãã€ããã»ã«ã
æ§æãããããã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ã
ããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éã®å€
åãèªããããã
å®æœäŸ ïŒ
å®æœäŸïŒã«ããã4â²âããã·ã«âïŒâãããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«ïŒâããããã·ã¢ãŸã
ã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«åå€ã補é ãã
ç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··å液æ¶ããµã³
ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°
ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€
åãèªããããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«ïŒâããããã·ã¢ãŸã
ã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«åå€ã補é ãã
ç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··å液æ¶ããµã³
ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°
ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€
åãèªããããã
å®æœäŸ ïŒ
å®æœäŸïŒã«ããã4â²âããã·ã«âïŒâãããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã¡ãã«âïŒâãã
ããã·ã¢ãŸãã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«å
å€ã補é ããç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··
å液æ¶ããµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå
ã亀äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éç
ãªééå éå€åãèªããããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã¡ãã«âïŒâãã
ããã·ã¢ãŸãã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«å
å€ã補é ããç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··
å液æ¶ããµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå
ã亀äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éç
ãªééå éå€åãèªããããã
å®æœäŸ ïŒ
å®æœäŸïŒã«ããã4â²âããã·ã«âïŒâãããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã·ã¯ãããã·ã«ã¢
ãŸãã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«åå€ã補é
ããç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··å液æ¶ã
ãµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«
ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå
éå€åãèªããããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã·ã¯ãããã·ã«ã¢
ãŸãã³ãŒã³ãçšããŠåæ§ã«ããŠã·ãªã«åå€ã補é
ããç³è±æ¿ãåŠçããããã®ç³è±æ¿ã§æ··å液æ¶ã
ãµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«
ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå
éå€åãèªããããã
å®æœäŸ ïŒ
å®æœäŸïŒã«ããã4â²âããã·ã«âïŒâãããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âãªã¯ãã«âïŒâã
ãããã·ã¢ãŸãã³ãŒã³ãçšããŠè£œé ããã·ãªã«å
å€ã§åŠçããç³è±æ¿ã§æ··å液æ¶ããµã³ãã€ããã
ãã»ã«ãæ§æãããšããã玫å€ç·ãšå¯èŠå ã®äº€äº
ç §å°ã«ããééå éã¯å¯éçã«å€åããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âãªã¯ãã«âïŒâã
ãããã·ã¢ãŸãã³ãŒã³ãçšããŠè£œé ããã·ãªã«å
å€ã§åŠçããç³è±æ¿ã§æ··å液æ¶ããµã³ãã€ããã
ãã»ã«ãæ§æãããšããã玫å€ç·ãšå¯èŠå ã®äº€äº
ç §å°ã«ããééå éã¯å¯éçã«å€åããã
å®æœäŸ ïŒ
å®æœäŸïŒã«ããã4â²âããã·ã«âïŒâãããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã¯ããâïŒâãã
ããã·ã¢ãŸãã³ãŒã³ãçšããŠè£œé ããã·ãªã«åå€
ã§åŠçããç³è±æ¿ã§æ··å液æ¶ããµã³ãã€ããããŠ
ã»ã«ãæ§æãããšããã玫å€ç·ãšå¯èŠå ã®äº€äºç §
å°ã«ããééå éã¯å¯éçã«å€åããã
ã·ã¢ãŸãã³ãŒã³ã®ä»£ããã«4â²âã¯ããâïŒâãã
ããã·ã¢ãŸãã³ãŒã³ãçšããŠè£œé ããã·ãªã«åå€
ã§åŠçããç³è±æ¿ã§æ··å液æ¶ããµã³ãã€ããããŠ
ã»ã«ãæ§æãããšããã玫å€ç·ãšå¯èŠå ã®äº€äºç §
å°ã«ããééå éã¯å¯éçã«å€åããã
å®æœäŸ ïŒ
å
¬ç¥ã®æ¹æ³ã«ãããç³è±æ¿ãã¢ãããããã«ã
ãªãšããã·ã·ã©ã³ã®ãšã¿ããŒã«æº¶æ¶²ã§åŠçããã¢
ããåç³è±ã調補ãããå®æœäŸïŒã§åŸãã¢ãŸãã³
ãŒã³ã«ã«ãã³é žã¯ããªããå¡©åã¡ãã¬ã³ã«æº¶è§£
ãããã®æº¶æ¶²ã«ã¢ããåç³è±æ¿ã浞ããããŠãã
ããªãšãã«ã¢ãã³ãå ãã宀枩ã§ïŒæéæŸçœ®ã
ãããã®ç³è±æ¿ãå¡©åã¡ãã¬ã³ããšã¿ããŒã«ã§æŽ
æµãã100âã§10åé也ç¥ããã玫å€å¯èŠåå å
床èšã«ããã¢ãŸãã³ãŒã³åºãçµåããŠããããšã
確èªãããããã®ã¢ãŸãã³ãŒã³ã§ä¿®é£Ÿãããç³è±
æ¿ã§æ§æãããæ··å液æ¶ã»ã«ã¯ã玫å€ç·ãšå¯èŠå
ã®äº€äºç §å°ã«ããééå éãå¯éçã«å€åããã
ãªãšããã·ã·ã©ã³ã®ãšã¿ããŒã«æº¶æ¶²ã§åŠçããã¢
ããåç³è±ã調補ãããå®æœäŸïŒã§åŸãã¢ãŸãã³
ãŒã³ã«ã«ãã³é žã¯ããªããå¡©åã¡ãã¬ã³ã«æº¶è§£
ãããã®æº¶æ¶²ã«ã¢ããåç³è±æ¿ã浞ããããŠãã
ããªãšãã«ã¢ãã³ãå ãã宀枩ã§ïŒæéæŸçœ®ã
ãããã®ç³è±æ¿ãå¡©åã¡ãã¬ã³ããšã¿ããŒã«ã§æŽ
æµãã100âã§10åé也ç¥ããã玫å€å¯èŠåå å
床èšã«ããã¢ãŸãã³ãŒã³åºãçµåããŠããããšã
確èªãããããã®ã¢ãŸãã³ãŒã³ã§ä¿®é£Ÿãããç³è±
æ¿ã§æ§æãããæ··å液æ¶ã»ã«ã¯ã玫å€ç·ãšå¯èŠå
ã®äº€äºç §å°ã«ããééå éãå¯éçã«å€åããã
å®æœäŸ 10
4â²âããã·ã«âïŒâããããã·ã¢ãŸãã³ãŒã³
0.4ïœãšè§Šåªéã®ããªã¡ãã«ãã³ãžã«ã¢ã³ã¢ããŠ
ã ããããã·ãããã³ãŒã³ïŒmlã«æº¶è§£ããããã«
ã¢ã¯ãªã«ãããªã«ïŒmlããã€ããå ããã22æé
å ç±ããåŸæº¶åªãæžå§ã§çå»ããæ®çåããã³ãŒ
ã³ã§æœåºããã次ãã§ã·ãªã«ã²ã«ã«ã©ã ã¯ããã
ã«ãã粟補ããïŒâïœïŒâïŒïŒâããã·ã«ããšãã«
ã¢ãŸïŒâããšããã·ïœâãããã³ãããªã«0.25ïœã
åŸãããããå¡©é žãå«ãé ¢é žã§å æ°Žå解ãã察å¿
ããã«ã«ãã³é žãåŸãããããå¡©åããªãã«ã§é ž
å¡©åç©ã«å€ããããã§å®æœäŸïŒãšåæ§ã«ããŠã¢ã
ãåç³è±æ¿ãåŠçããããã®åžåã¹ãã¯ãã«ãã
ã¢ãŸãã³ãŒã³ãçµåããŠããããšã確èªãããã
ãã®ç³è±æ¿ã§æ§æããæ··å液æ¶ã»ã«ã¯ã玫å€ç·ãš
å¯èŠå ã®äº€äºç §å°ã«ããééå éãå¯éçã«å€å
ãããã
0.4ïœãšè§Šåªéã®ããªã¡ãã«ãã³ãžã«ã¢ã³ã¢ããŠ
ã ããããã·ãããã³ãŒã³ïŒmlã«æº¶è§£ããããã«
ã¢ã¯ãªã«ãããªã«ïŒmlããã€ããå ããã22æé
å ç±ããåŸæº¶åªãæžå§ã§çå»ããæ®çåããã³ãŒ
ã³ã§æœåºããã次ãã§ã·ãªã«ã²ã«ã«ã©ã ã¯ããã
ã«ãã粟補ããïŒâïœïŒâïŒïŒâããã·ã«ããšãã«
ã¢ãŸïŒâããšããã·ïœâãããã³ãããªã«0.25ïœã
åŸãããããå¡©é žãå«ãé ¢é žã§å æ°Žå解ãã察å¿
ããã«ã«ãã³é žãåŸãããããå¡©åããªãã«ã§é ž
å¡©åç©ã«å€ããããã§å®æœäŸïŒãšåæ§ã«ããŠã¢ã
ãåç³è±æ¿ãåŠçããããã®åžåã¹ãã¯ãã«ãã
ã¢ãŸãã³ãŒã³ãçµåããŠããããšã確èªãããã
ãã®ç³è±æ¿ã§æ§æããæ··å液æ¶ã»ã«ã¯ã玫å€ç·ãš
å¯èŠå ã®äº€äºç §å°ã«ããééå éãå¯éçã«å€å
ãããã
å®æœäŸ 11
å®æœäŸïŒã§èª¿è£œããã¢ãŸãã³ãŒã³ã§ä¿®é£Ÿããç³
è±æ¿ã§å®€æž©ã§ã¹ã¡ã¯ãã€ãã¯æ¶²æ¶çžã§ããïŒâãª
ã¯ãã«â4â²âã·ã¢ããããšãã«ïŒïŒ«â21ââ33
ââ40âïŒïŒã®ãµã³ãã€ããã»ã«ïŒã»ã«å8ÎŒïŒ
ãæ§æããã宀枩ïŒçŽ20âïŒã§çŽ«å€ç·ãç §å°ããŠ
ã液æ¶ã®çžå€åã¯å šãèªããããªãã€ãããã»ã«
ã35âã«å æž©ããŠãã玫å€ç·ãç §å°ãããšããã
çŽäº€ãã³ã«äžã§ééå éã®å€åãèªãããããã
ã®ã»ã«ã«ãã¬ãéããŠ35âã§çŽ«å€ç·ãç §å°ããŠåŸ
ãç»åã¯ã宀枩ã§ïŒã±æéå®å®ã«ååšãããã»ã«
ã«å¯èŠå ãç §å°ããŠããã®ç»åã¯æ¶å€±ããããšã
ãªãã€ãããã®ããšãããã¹ã¡ã¯ãã€ãã¯æ¶²æ¶ã«
ããã¡ã¢ãªå¹æãèªããããã
è±æ¿ã§å®€æž©ã§ã¹ã¡ã¯ãã€ãã¯æ¶²æ¶çžã§ããïŒâãª
ã¯ãã«â4â²âã·ã¢ããããšãã«ïŒïŒ«â21ââ33
ââ40âïŒïŒã®ãµã³ãã€ããã»ã«ïŒã»ã«å8ÎŒïŒ
ãæ§æããã宀枩ïŒçŽ20âïŒã§çŽ«å€ç·ãç §å°ããŠ
ã液æ¶ã®çžå€åã¯å šãèªããããªãã€ãããã»ã«
ã35âã«å æž©ããŠãã玫å€ç·ãç §å°ãããšããã
çŽäº€ãã³ã«äžã§ééå éã®å€åãèªãããããã
ã®ã»ã«ã«ãã¬ãéããŠ35âã§çŽ«å€ç·ãç §å°ããŠåŸ
ãç»åã¯ã宀枩ã§ïŒã±æéå®å®ã«ååšãããã»ã«
ã«å¯èŠå ãç §å°ããŠããã®ç»åã¯æ¶å€±ããããšã
ãªãã€ãããã®ããšãããã¹ã¡ã¯ãã€ãã¯æ¶²æ¶ã«
ããã¡ã¢ãªå¹æãèªããããã
å®æœäŸ 12
å®æœäŸïŒã§åŸãã¢ãŸãã³ãŒã³ã«ã«ãã³é
žãæ··å
液æ¶ã«0.5ééïŒ ã§æº¶è§£ããããã12ÎŒã®ã¬ã©ã¹ã¹
ããŒãµãŒãçšããŠïŒæã®ã¬ã©ã¹æ¿ã§æŸã¿ãã»ã«ã
æ§æãããšãããçŽäº€ãã³ã«äžã§ã¯ééå éã¯ãŒ
ãã§ããããã¡ãªããããã¯é åããŠããäºãå
ãã€ãããã®ã»ã«ã«ãã¬åè¶ãã«çŽ«å€ç·ãç §å°ã
ããšãããçŽäº€ãã³ã«äžã§ç»åã芳å¯ããããã
ãã«å¯èŠå ãç §å°ããçµæãç»åã¯çŽã¡ã«æ¶å€±ã
ãã
液æ¶ã«0.5ééïŒ ã§æº¶è§£ããããã12ÎŒã®ã¬ã©ã¹ã¹
ããŒãµãŒãçšããŠïŒæã®ã¬ã©ã¹æ¿ã§æŸã¿ãã»ã«ã
æ§æãããšãããçŽäº€ãã³ã«äžã§ã¯ééå éã¯ãŒ
ãã§ããããã¡ãªããããã¯é åããŠããäºãå
ãã€ãããã®ã»ã«ã«ãã¬åè¶ãã«çŽ«å€ç·ãç §å°ã
ããšãããçŽäº€ãã³ã«äžã§ç»åã芳å¯ããããã
ãã«å¯èŠå ãç §å°ããçµæãç»åã¯çŽã¡ã«æ¶å€±ã
ãã
å®æœäŸ 13
å®æœäŸïŒã®ïŒâããã©ããããã©ãã«âïŒâã
ãã¢ãããµããšãŒãã®ä»£ããã«ïŒâããã©ããã
ãã©ãã«âïŒâããã¢ãã¿ããšãŒããçšããŠåæ§
ã«ããŠã·ãªã«åå€ã補é ãã¬ã©ã¹æ¿ãåŠçããã
ãã®ã¬ã©ã¹æ¿ã§å®æœäŸïŒã§çšããæ··å液æ¶ããµã³
ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°
ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€
åãèªããããã
ãã¢ãããµããšãŒãã®ä»£ããã«ïŒâããã©ããã
ãã©ãã«âïŒâããã¢ãã¿ããšãŒããçšããŠåæ§
ã«ããŠã·ãªã«åå€ã補é ãã¬ã©ã¹æ¿ãåŠçããã
ãã®ã¬ã©ã¹æ¿ã§å®æœäŸïŒã§çšããæ··å液æ¶ããµã³
ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°
ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€
åãèªããããã
å®æœäŸ 14
å®æœäŸïŒã®ïŒâããã©ããããã©ãã«âïŒâã
ãã¢ãããµããšãŒãã®ä»£ããã«ã¯ããé ¢é žãšãã«
ãçšããŠïŒâïœïŒâïŒïŒâããã·ã«ããšãã«ã¢ãŸïŒ
ããšããã·ïœé ¢é žãšãã«ãåæãå æ°Žå解åŸãå
æ§ã«ããŠã·ãªã«åå€ã補é ããã¬ã©ã¹æ¿ãåŠçã
ãããã®åžåã¹ãã¯ãã«ããã¢ãŸãã³ãŒã³ãçµå
ããŠããäºã確èªãããããã®ã¬ã©ã¹æ¿ã§æ··å液
æ¶ããµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀
äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªé
éå éå€åãèªããããã
ãã¢ãããµããšãŒãã®ä»£ããã«ã¯ããé ¢é žãšãã«
ãçšããŠïŒâïœïŒâïŒïŒâããã·ã«ããšãã«ã¢ãŸïŒ
ããšããã·ïœé ¢é žãšãã«ãåæãå æ°Žå解åŸãå
æ§ã«ããŠã·ãªã«åå€ã補é ããã¬ã©ã¹æ¿ãåŠçã
ãããã®åžåã¹ãã¯ãã«ããã¢ãŸãã³ãŒã³ãçµå
ããŠããäºã確èªãããããã®ã¬ã©ã¹æ¿ã§æ··å液
æ¶ããµã³ãã€ããããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀
äºã«ç §å°ãããšãããçŽäº€ãã³ã«äžã§å¯éçãªé
éå éå€åãèªããããã
å®æœäŸ 15
å®æœäŸïŒã®ããªãšããã·ã¢ãããããã«ã·ã©ã³
ã®ä»£ããã«ãïŒâã¢ãããããã«ã¡ãã«ãžãšãã
ã·ã·ã©ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·
ã«ã«ã«ããžã€ãããçšããŠã¢ããåãè¡ãªãããš
ã§ã·ãªã«åå€ã補é ãããåæ§ã«ããŠã¬ã©ã¹æ¿ã
åŠçãããã®ã¬ã©ã¹æ¿ã§æ··å液æ¶ããµã³ãã€ãã
ã»ã«ã«ããããã¡ãªããããã¯é åããšã€ãŠãã
ãã®ã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ãããšã
ããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€åãèªã
ãããã
ã®ä»£ããã«ãïŒâã¢ãããããã«ã¡ãã«ãžãšãã
ã·ã·ã©ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·
ã«ã«ã«ããžã€ãããçšããŠã¢ããåãè¡ãªãããš
ã§ã·ãªã«åå€ã補é ãããåæ§ã«ããŠã¬ã©ã¹æ¿ã
åŠçãããã®ã¬ã©ã¹æ¿ã§æ··å液æ¶ããµã³ãã€ãã
ã»ã«ã«ããããã¡ãªããããã¯é åããšã€ãŠãã
ãã®ã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ãããšã
ããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€åãèªã
ãããã
å®æœäŸ 16
å®æœäŸïŒã®ããªãšããã·ã¢ãããããã«ã·ã©ã³
ã®ä»£ããã«ãïŒâã¢ããããã«ããªãšããã·ã·ã©
ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·ã«ã«ã«
ããžã€ãããçšããŠã¢ã·ãåãè¡ãªãããšã§ãã·
ãªã«åå€ã補é ãããåæ§ã«ããŠã¬ã©ã¹æ¿ãã·ãª
ã«åãããã®ã¬ã©ã¹æ¿ã§æ··å液æ¶ããµã³ãã€ãã
ããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ãããšã
ããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€åãèªã
ãããã
ã®ä»£ããã«ãïŒâã¢ããããã«ããªãšããã·ã·ã©
ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·ã«ã«ã«
ããžã€ãããçšããŠã¢ã·ãåãè¡ãªãããšã§ãã·
ãªã«åå€ã補é ãããåæ§ã«ããŠã¬ã©ã¹æ¿ãã·ãª
ã«åãããã®ã¬ã©ã¹æ¿ã§æ··å液æ¶ããµã³ãã€ãã
ããã»ã«ã«çŽ«å€ç·ãšå¯èŠå ã亀äºã«ç §å°ãããšã
ããçŽäº€ãã³ã«äžã§å¯éçãªééå éå€åãèªã
ãããã
å®æœäŸ 17
å®æœäŸïŒã®ããªãšããã·ã¢ãããããã«ã·ã©ã³
ã®ä»£ããã«ãïŒâã¢ããããã«ãžã¡ãã«ã¡ããã·
ã·ã©ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·ã«
ã«ã«ããžã€ãããçšããŠã¢ã·ãåãè¡ãªãããš
ã§ãã·ãªã«åå€ã補é ããããã®ã·ãªã«åå€ã§ã¬
ã©ã¹ãåŠçããæ··å液æ¶ããµã³ãã€ããããã»ã«
ãäœæããããã®ã»ã«ãçŽäº€ãã³ã«éã«çœ®ãã
HeâNeã¬ãŒã¶ãŒã§ééå éãã¢ãã¿ãŒããã玫
å€ç·ç §å°åã®ã»ã«ã¯çŽäº€ãã³ã«äžã§ééå éã¯40
ïŒ ïŒåå åãå¹³è¡ã«çœ®ããã»ã«ãå ¥ããªãæã®é
éå ã100ãšãããïŒã§ãã365nmã®çŽ«å€ç·ãç §å°
ãããšãã¢ãŸãã³ãŒã³ããã©ã³ã¹ããã·ã¹ãžãšå
ç°æ§åããã«ã€ãééå éã¯æžå°ããã次ã«
440nm以äžã®å¯èŠå ãç §å°ãããšããã©ã³ã¹ãžã®
å ç°æ§åãèµ·ãã«ã€ããŠééå éã¯åã³å¢å ã
ãããã®ééå éã¯ã玫å€ç·ãšå¯èŠå ã®äº€äºç §å°
ã«å¿ããŠå¯éçã«å€åããã
ã®ä»£ããã«ãïŒâã¢ããããã«ãžã¡ãã«ã¡ããã·
ã·ã©ã³ãçšããå¡©åã¡ãã¬ã³äžãžã·ã¯ãããã·ã«
ã«ã«ããžã€ãããçšããŠã¢ã·ãåãè¡ãªãããš
ã§ãã·ãªã«åå€ã補é ããããã®ã·ãªã«åå€ã§ã¬
ã©ã¹ãåŠçããæ··å液æ¶ããµã³ãã€ããããã»ã«
ãäœæããããã®ã»ã«ãçŽäº€ãã³ã«éã«çœ®ãã
HeâNeã¬ãŒã¶ãŒã§ééå éãã¢ãã¿ãŒããã玫
å€ç·ç §å°åã®ã»ã«ã¯çŽäº€ãã³ã«äžã§ééå éã¯40
ïŒ ïŒåå åãå¹³è¡ã«çœ®ããã»ã«ãå ¥ããªãæã®é
éå ã100ãšãããïŒã§ãã365nmã®çŽ«å€ç·ãç §å°
ãããšãã¢ãŸãã³ãŒã³ããã©ã³ã¹ããã·ã¹ãžãšå
ç°æ§åããã«ã€ãééå éã¯æžå°ããã次ã«
440nm以äžã®å¯èŠå ãç §å°ãããšããã©ã³ã¹ãžã®
å ç°æ§åãèµ·ãã«ã€ããŠééå éã¯åã³å¢å ã
ãããã®ééå éã¯ã玫å€ç·ãšå¯èŠå ã®äº€äºç §å°
ã«å¿ããŠå¯éçã«å€åããã
第ïŒå³ã¯æ¬çºæã®å
èšé²çŽ åã®æ§é ã®ïŒäŸã瀺
ãæé¢å³ã第ïŒå³ã¯å¥ã®äŸåã³ãã®å ç §å°ååŸã®
液æ¶ã®é åç¶æ ã瀺ãæé¢å³ã第ïŒå³ã¯ããã«å¥
ã®äŸåã³ãã®å ç §å°ååŸã®æ¶²æ¶ã®é åç¶æ ã瀺ã
æé¢å³ã§ããã å³äžã笊å·ïŒã¯åºæ¿ãïŒã¯å ã«ããå¯éçãªæ§
é å€åãèµ·ãååç©ã®ååå±€ãïŒã¯æ¶²æ¶å±€ãïŒã¯
ãã¢ãžãã¢ã¹é åå±€ã§ããã
ãæé¢å³ã第ïŒå³ã¯å¥ã®äŸåã³ãã®å ç §å°ååŸã®
液æ¶ã®é åç¶æ ã瀺ãæé¢å³ã第ïŒå³ã¯ããã«å¥
ã®äŸåã³ãã®å ç §å°ååŸã®æ¶²æ¶ã®é åç¶æ ã瀺ã
æé¢å³ã§ããã å³äžã笊å·ïŒã¯åºæ¿ãïŒã¯å ã«ããå¯éçãªæ§
é å€åãèµ·ãååç©ã®ååå±€ãïŒã¯æ¶²æ¶å±€ãïŒã¯
ãã¢ãžãã¢ã¹é åå±€ã§ããã
Claims (1)
- ïŒ éæåºæ¿äžã«ãå ã«ããå¯éçã«æ§é å€åã
èµ·ãååç©ã®ååå±€ãä»ããŠæ¶²æ¶å±€ãèšããŠãªã
å èšé²çŽ åã
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62217317A JPS6460833A (en) | 1987-08-31 | 1987-08-31 | Optical recording element |
| US07/238,398 US4963448A (en) | 1987-08-31 | 1988-08-31 | Photorecording element and liquid crystal cell comprising the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62217317A JPS6460833A (en) | 1987-08-31 | 1987-08-31 | Optical recording element |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6460833A JPS6460833A (en) | 1989-03-07 |
| JPH0444813B2 true JPH0444813B2 (ja) | 1992-07-22 |
Family
ID=16702273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62217317A Granted JPS6460833A (en) | 1987-08-31 | 1987-08-31 | Optical recording element |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6460833A (ja) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02281235A (ja) * | 1989-04-21 | 1990-11-16 | Agency Of Ind Science & Technol | å èšé²ææ |
| JPH0519260A (ja) * | 1991-07-09 | 1993-01-29 | Victor Co Of Japan Ltd | 液æ¶ã©ã€ããã«ã |
| KR0182876B1 (ko) | 1996-01-09 | 1999-05-01 | 구ìí | ì¡ì ì ì í늬ížížë°©í¥ ì ìŽë°©ë² |
| US6191836B1 (en) | 1996-11-07 | 2001-02-20 | Lg Philips Lcd, Co., Ltd. | Method for fabricating a liquid crystal cell |
| US6292296B1 (en) | 1997-05-28 | 2001-09-18 | Lg. Philips Lcd Co., Ltd. | Large scale polarizer and polarizer system employing it |
| KR100259258B1 (ko) | 1997-11-21 | 2000-06-15 | êµ¬ë³žì€ | ì¡ì íììì |
| KR100301853B1 (ko) | 1999-03-25 | 2001-09-26 | 구볞ì€, ë¡ ìëŒíëëœì¬ | ì¡ì íìììì© ë°°í¥ë§ |
| KR100357214B1 (ko) | 1999-04-21 | 2002-10-18 | ìì§.íëŠœì€ ììë 죌ìíì¬ | ì¡ì íììì |
| KR100475107B1 (ko) | 1999-10-14 | 2005-03-09 | ìì§.íëŠœì€ ììë 죌ìíì¬ | ë©í°ëë©ìž ì¡ì ì ì ì ì¡°ë°©ë² |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS625293A (ja) * | 1985-07-01 | 1987-01-12 | ã«ã·ãªèšç®æ©æ ªåŒäŒç€Ÿ | ãŠã€ã³ããŠè¡šç€ºå¶åŸ¡è£ 眮 |
-
1987
- 1987-08-31 JP JP62217317A patent/JPS6460833A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS625293A (ja) * | 1985-07-01 | 1987-01-12 | ã«ã·ãªèšç®æ©æ ªåŒäŒç€Ÿ | ãŠã€ã³ããŠè¡šç€ºå¶åŸ¡è£ 眮 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6460833A (en) | 1989-03-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4963448A (en) | Photorecording element and liquid crystal cell comprising the same | |
| Ichimura | Photoalignment of liquid-crystal systems | |
| JPH0419615B2 (ja) | ||
| JPH0419614B2 (ja) | ||
| JP2000514468A (ja) | é«åºŠã«èªçºæ§ã®è€å±æã瀺ãå ã¢ãã¬ã¹æå®å¯èœåºè³ªããã³å ã¢ãã¬ã¹æå®å¯èœåŽåºããªããŒé¡ | |
| JPH0444813B2 (ja) | ||
| JP4183950B2 (ja) | å å¿çæ§æ¶²æ¶çµæç©ãæ å ±èšé²åªäœããã³æ å ±èšé²æ¹æ³ | |
| Akiyama et al. | Surface-selective modification of poly (vinyl alcohol) films with azobenzenes for in-plane alignment photocontrol of nematic liquid crystals | |
| JPH047520A (ja) | 液æ¶ææã®é åæ¹æ³ | |
| JPH04284421A (ja) | æãå ã«ãã液æ¶é åæ³ | |
| Natarajan et al. | Liquid crystalline siloxanes containing spiropyran chromophores as reversible optical data storage materials | |
| JPH05241151A (ja) | 液æ¶é åæ¹æ³ãšæ¶²æ¶å åŠçŽ å | |
| JP3141433B2 (ja) | 匷èªé»æ§æ¶²æ¶çµæç©åã³ãããçšãã液æ¶å åŠçŽ å | |
| JP2003073562A (ja) | 液æ¶é åçšå é åæš¹èçµæç©ã液æ¶å é åæš¹èèãããã³æ¶²æ¶å é åæš¹èèãçšãã液æ¶å åŠçŽ å | |
| JPS5994733A (ja) | å èšé²çšåªäœ | |
| JPH0419616B2 (ja) | ||
| Ichimura | Photoregulation of liquid crystal alignment by photochromic molecules and polymeric thin films | |
| JP2600089B2 (ja) | äžå®å®å å¶åŸ¡å åŠçŽ å | |
| JPH04284445A (ja) | å åŠçŽ å | |
| JPH02281235A (ja) | å èšé²ææ | |
| JP4051445B2 (ja) | 液æ¶èšé²åªäœã®è£œé æ¹æ³ | |
| JP2000047270A (ja) | å æ©èœçŽ å | |
| JPS6398852A (ja) | å åŠåŒæ å ±èšé²æ¹æ³ | |
| JP2950904B2 (ja) | å èšé²åªäœ | |
| JP2696697B2 (ja) | æ å ±èšé²åªäœ |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |