JPH04224128A - Glass cutting blade - Google Patents

Glass cutting blade

Info

Publication number
JPH04224128A
JPH04224128A JP41178590A JP41178590A JPH04224128A JP H04224128 A JPH04224128 A JP H04224128A JP 41178590 A JP41178590 A JP 41178590A JP 41178590 A JP41178590 A JP 41178590A JP H04224128 A JPH04224128 A JP H04224128A
Authority
JP
Japan
Prior art keywords
glass
cutting blade
glass cutting
cutting
blade
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP41178590A
Other languages
Japanese (ja)
Inventor
Atsuhiko Masuda
増田 敦彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Petrochemical Co Ltd
Original Assignee
Idemitsu Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co Ltd filed Critical Idemitsu Petrochemical Co Ltd
Priority to JP41178590A priority Critical patent/JPH04224128A/en
Publication of JPH04224128A publication Critical patent/JPH04224128A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00Severing cooled glass
    • C03B33/10Glass-cutting tools, e.g. scoring tools
    • C03B33/105Details of cutting or scoring means, e.g. tips
    • C03B33/107Wheel design, e.g. materials, construction, shape

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nonmetal Cutting Devices (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Chemical Vapour Deposition (AREA)

Abstract

PURPOSE:To prolong the service life of a glass cutting blade, to form a sharp V-shaped groove on a glass surface in the case of cutting of the glass, to be obtain an excellent cutting property and to obtain a smooth cut face. CONSTITUTION:The cross sectional shape of an edge part 4 of the cutting blade is made into V-shape. The surface of this V-shaped blade edge 4a is coated with diamond. Edge part 4 is formed by ceramics compatible with diamond such as silicon nitride (Si3N4). Diamond film applied to the surface of the blade edge is shaped by a surface grinding treatment.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明はガラス切断用刃に関し、
特に刃の寿命が長く、かつガラスの切断面を平滑にでき
るガラス切断用刃に関する。
[Industrial Application Field] The present invention relates to a glass cutting blade.
In particular, the present invention relates to a glass cutting blade that has a long blade life and is capable of smoothing the cut surface of glass.

【0002】0002

【従来の技術】近年、ガラス基板は用途に応じてさまざ
まな大きさ、厚さ、材料のものが各種産業分野で利用さ
れている。例えば、ディスプレイパネル、液晶表示板、
カラーフィルター等の構成要素としてガラス基板が用い
られており、所望の大きさ、形状に切断して使用されて
いる。
2. Description of the Related Art In recent years, glass substrates of various sizes, thicknesses, and materials have been used in various industrial fields depending on the purpose. For example, display panels, liquid crystal display boards,
Glass substrates are used as components of color filters and the like, and are cut into desired sizes and shapes.

【0003】従来、ガラス切断用の切断刃としては、ダ
イヤモンド粒子を金属中に埋め込んだ切断刃や、超硬合
金製の切断刃が硬度の点で優れているため一般に使用さ
れている。しかし、上記切断刃は寿命の点で十分ではな
く、この点を改良するため各種の技術が提案されている
[0003] Conventionally, as cutting blades for cutting glass, cutting blades in which diamond particles are embedded in metal and cutting blades made of cemented carbide are generally used because of their excellent hardness. However, the above-mentioned cutting blade does not have a sufficient lifespan, and various techniques have been proposed to improve this point.

【0004】例えば、刃先をセラミックで形成する技術
としては、特開昭55−104969号、実開昭59−
189840号、特開昭62−158129号等が知ら
れている。すなわち、特開昭55−104969号には
、酸化アルミニウム(Al2O3) を主成分とし、炭
化チタニウム(TiC) および/または窒化チタニウ
ム(TiN) を成分組成として含むガラス切断用セラ
ミックが開示されている。実開昭59−189840号
には、窒化ケイ素または炭化ケイ素を主成分とするセラ
ミック焼結体からなるガラス切断刃が開示されている。 特開昭62−158129号には、ホイールの少なくと
も刃先をジルコニア,アルミナ,炭化ケイ素質,窒化ケ
イ素質などのセラミック材で構成したガラス切断用ホイ
ールカッタが開示されている。
[0004] For example, as a technique for forming the cutting edge with ceramic, Japanese Patent Laid-Open No. 55-104969 and Utility Model Laid-open No. 59-
No. 189840, JP-A-62-158129, etc. are known. That is, JP-A-55-104969 discloses a ceramic for glass cutting which contains aluminum oxide (Al2O3) as a main component and titanium carbide (TiC) and/or titanium nitride (TiN) as a component composition. Japanese Utility Model Application No. 59-189840 discloses a glass cutting blade made of a ceramic sintered body containing silicon nitride or silicon carbide as a main component. JP-A-62-158129 discloses a wheel cutter for cutting glass in which at least the cutting edge of the wheel is made of a ceramic material such as zirconia, alumina, silicon carbide, or silicon nitride.

【0005】また、実開昭59−61246号には、多
結晶ダイヤおよび/または窒化ホウ素の焼結体からなる
薄い円板状の刃の両面に、補強のため、超硬合金製の円
板を固着したガラス切断刃が開示されている。さらに、
実公昭61−42820号には、金属あるいはサーナッ
ト製のホイールの周縁部に、ダイヤモンドおよび/また
は高圧相窒化ホウ素を含有する環状焼結体を配したガラ
ス切断刃が開示されている。
Furthermore, in Japanese Utility Model Application Publication No. 59-61246, cemented carbide disks are installed on both sides of a thin disk-shaped blade made of a sintered body of polycrystalline diamond and/or boron nitride for reinforcement. A glass cutting blade having a bonded thereon is disclosed. moreover,
Japanese Utility Model Publication No. 61-42820 discloses a glass cutting blade in which an annular sintered body containing diamond and/or high-pressure phase boron nitride is arranged around the peripheral edge of a wheel made of metal or Cernat.

【0006】[0006]

【発明が解決しようとする課題】しかしながら、上述し
たガラス切断刃は、いずれも石英等の高硬度ガラスの切
断に用いた場合、切れ味が悪く、寿命も短いという問題
がある。また、電子工業等の分野においては、切断面の
精度の向上が必要となってきており、切断面が平滑とな
るようにガラスを切断することが要求されているが、従
来のガラス切断刃で高硬度ガラスを切断すると、平滑で
きれいな切断面を得られないという問題がある。さらに
、上述したガラス切断刃のうちダイヤモンド焼結体を利
用したものは、ダイヤモンド粒子の剥落等のため寿命が
短く、さらに長時間にわたって高精度の刃を維持するこ
とが難しいという問題がある。また、図6に示すように
使用時間とともにガラス切断時にガラス7表面に形成さ
れる溝8が丸くなり、かつガラス切断刃1によるガラス
の押圧点から多数の不規則なひび(ランダムクラック)
9がはいるため切断面の精度が悪いという問題がある。 本発明は上述した問題点にかんがみてなされたもので、
寿命が長く、かつ平滑な切断面が得られる切断精度の高
いガラス切断用刃の提供を目的とする。
[Problems to be Solved by the Invention] However, the above-mentioned glass cutting blades all have problems in that they are not sharp and have a short lifespan when used to cut high hardness glass such as quartz. In addition, in fields such as the electronics industry, it is becoming necessary to improve the precision of cutting surfaces, and it is required to cut glass so that the cut surface is smooth, but conventional glass cutting blades are insufficient. When cutting high-hardness glass, there is a problem in that a smooth and clean cut surface cannot be obtained. Furthermore, among the above-mentioned glass cutting blades, those using diamond sintered bodies have a short lifespan due to exfoliation of diamond particles, etc., and furthermore, there is a problem that it is difficult to maintain a highly accurate blade for a long period of time. In addition, as shown in FIG. 6, the grooves 8 formed on the surface of the glass 7 during glass cutting become rounded with time of use, and a large number of irregular cracks (random cracks) occur from the pressing point of the glass by the glass cutting blade 1.
There is a problem that the accuracy of the cut surface is poor because 9 is included. The present invention has been made in view of the above-mentioned problems.
The purpose of the present invention is to provide a glass cutting blade that has a long life and has high cutting accuracy that allows a smooth cutting surface to be obtained.

【0008】[0008]

【課題を解決するための手段】上記目的を達成するため
に本発明者は鋭意研究を重ねた結果、ガラス切断用刃の
刃先をダイヤモンド膜で被覆されたセラミックで形成し
、かつ刃先の断面形状をV字形状とすると、ガラス切断
時に、ガラス表面にV字形状のシャープな溝が入るとと
もに、ガラスの押圧方向(ガラス板に垂直な方向)にク
ラックが入るので、切れ味がよく、平滑な切断面が得ら
れ切断精度の向上を図れることを見い出し、本発明を完
成するに至った。
[Means for Solving the Problems] In order to achieve the above object, the inventor of the present invention has made extensive research, and as a result, the cutting edge of a glass cutting blade is made of ceramic coated with a diamond film, and the cross-sectional shape of the cutting edge is If the glass is cut into a V-shape, a sharp V-shaped groove will be created on the glass surface and cracks will appear in the pressing direction of the glass (perpendicular to the glass plate), resulting in a sharp and smooth cut. It was discovered that a surface can be obtained and cutting accuracy can be improved, and the present invention has been completed.

【0009】すなわち、本発明のガラス切断用刃は、ガ
ラス切断用刃の刃先をダイヤモンド膜で被覆されたセラ
ミックで形成し、かつ、刃先の断面形状をV字形状とし
た構成とし、好ましくは、セラミックの表面に被覆され
たダイヤモンド膜を表面研磨処理した構成としてあり、
必要に応じ、ガラス切断用刃を回転式または固定式のも
のとしてある。
That is, the glass cutting blade of the present invention has a structure in which the cutting edge of the glass cutting blade is made of ceramic coated with a diamond film, and the cross-sectional shape of the cutting edge is V-shaped. It has a structure in which the surface of the ceramic is coated with a diamond film that has been surface-polished.
Depending on the need, the glass cutting blade can be either rotary or fixed.

【0010】以下、本発明を詳細に説明する。本発明の
ガラス切断用刃は刃先の断面形状をV字形状としてある
。刃先以外の部分は任意の形状としてよい。ここで、ガ
ラス切断用刃の全体の形状、構造は、ガラス切断用刃が
回転式のものであるか、あるいは固定式のものであるか
によって異なる。
The present invention will be explained in detail below. The glass cutting blade of the present invention has a cutting edge having a V-shaped cross section. The parts other than the cutting edge may have any shape. Here, the overall shape and structure of the glass cutting blade differ depending on whether the glass cutting blade is a rotary type or a fixed type.

【0011】回転式のガラス切断用刃の場合には、例え
ば図1(a)および(b)に示すように、ホイール状を
したガラス切断用刃1の中心部に、ホイール(刃体)2
を回転自在に支承する軸(図示せず)を貫通させるため
の貫通孔3を設け、かつホイール2の外周に、断面形状
がV字形状をなす刃先4を形成した構造としてある。そ
して、断面形状がV字形状をなす刃先4の表面にはダイ
ヤモンド膜5が被覆してある。
In the case of a rotary glass cutting blade, for example, as shown in FIGS. 1(a) and 1(b), a wheel (blade body) 2 is installed at the center of a wheel-shaped glass cutting blade 1.
A through hole 3 is provided for passing a shaft (not shown) that rotatably supports the wheel 2, and a cutting edge 4 having a V-shaped cross section is formed on the outer periphery of the wheel 2. The surface of the cutting edge 4, which has a V-shaped cross section, is coated with a diamond film 5.

【0012】また、固定式のガラス切断用刃の場合には
、例えば、図2(a)および(b)に示すように、半円
状のガラス切断用刃1をホルダー6に固着し、半円の外
周に断面形状がV字形状をなす刃先4を形成した構造と
してある。なお、固定式の場合は、ガラス切断用刃1を
半円状に形成する必要はなく、図3(a)および(b)
に示すように非対称な凸形状としてもよく、あるいは円
を切断して得られる部分円等任意の形状に形成してもよ
い。  この固定式のガラス切断用刃の場合にも、刃先
4の表面にはダイヤモンド膜5が被覆してある。
In the case of a fixed type glass cutting blade, for example, as shown in FIGS. 2(a) and 2(b), a semicircular glass cutting blade 1 is fixed to a holder 6, and the semicircular glass cutting blade 1 is It has a structure in which a cutting edge 4 having a V-shaped cross section is formed on the outer periphery of a circle. In addition, in the case of a fixed type, it is not necessary to form the glass cutting blade 1 in a semicircular shape, as shown in FIGS. 3(a) and (b).
It may be formed into an asymmetrical convex shape as shown in FIG. 2, or may be formed into any shape such as a partial circle obtained by cutting a circle. In the case of this fixed type glass cutting blade as well, the surface of the cutting edge 4 is coated with a diamond film 5.

【0013】回転式および固定式のいずれかの場合にお
いても刃先4の断面形状はV字形状としてある。これは
V字形状をしたダイヤモンド刃を形成するためである。 ダイヤモンド膜5を被覆した刃先の角度αは、好ましく
は60〜160°とし、特に好ましくは100〜140
°とする。刃先の角度αが小さすぎると刃が欠けやすく
なり、大きすぎると切れ味が悪くなるので好ましくない
。なお、刃先4の形状は完全なV字形状でなくてもよく
、刃の外側あるいは内側に丸味をもたせるようにしても
よい。また、図4に示すように二段落し角α、α’ を
有するように刃先を形成してもよい。
[0013] In either the rotary type or the fixed type, the cross-sectional shape of the cutting edge 4 is V-shaped. This is to form a V-shaped diamond blade. The angle α of the cutting edge coated with the diamond film 5 is preferably 60 to 160°, particularly preferably 100 to 140°.
°. If the angle α of the cutting edge is too small, the blade will easily chip, and if it is too large, the cutting quality will deteriorate, which is undesirable. Note that the shape of the cutting edge 4 does not have to be a perfect V-shape, and may be rounded on the outside or inside of the blade. Further, as shown in FIG. 4, the cutting edge may be formed to have two stroke angles α and α'.

【0014】ガラス切断用刃1の刃先部分の形成材料と
しては、ダイヤモンドの付着強度を高めるために、ダイ
ヤモンドと相性の良い低膨張のセラミックであって、か
つ、これらセラミックの中でもダイヤモンドを被覆する
基材として十分な強度、硬度および靱性を有するセラミ
ックが好ましい。このような性状を有するセラミックと
しては、例えば、窒化ケイ素(Si3N4など) 、炭
化ケイ素(SiC) 、あるいはこれらの混合物を主成
分とするもの、サイアロン、ダイヤモンド焼結体、c−
BN焼結体等が挙げられる。なお、ガラス切断用刃1の
うちダイヤモンドが被覆される刃先部4以外の部分は上
記セラミック以外の他の材料で形成してもよいが、ガラ
ス切断用刃1全体を上記セラミックのうちから選ばれる
一種の材料で形成するのが望ましい。
The material for forming the cutting edge portion of the glass cutting blade 1 is a low-expansion ceramic that is compatible with diamond in order to increase the adhesion strength of diamond. Ceramic material having sufficient strength, hardness and toughness is preferred. Ceramics with such properties include, for example, silicon nitride (Si3N4, etc.), silicon carbide (SiC), or those whose main components are mixtures thereof, sialon, diamond sintered bodies, c-
Examples include BN sintered body. Note that the parts of the glass cutting blade 1 other than the cutting edge portion 4 coated with diamond may be formed of other materials other than the above-mentioned ceramics, but the glass cutting blade 1 as a whole may be formed of materials selected from the above ceramics. Preferably, it is made of one type of material.

【0015】本発明のガラス切断用刃は、上述したガラ
ス切断用刃のセラミックで形成されたV字形状をなす刃
先表面をダイヤモンド膜で被覆した構成としてある。ダ
イヤモンド膜の形成方法、ダイヤモンド膜の性状および
合成条件等に関しては後述する。ダイヤモンド膜の厚さ
は、適宜選択される。固定式の場合は、回転式の刃に比
べ、ダイヤモンド膜の耐摩耗性が要求されるため、膜厚
を厚くする必要があり、例えば、10〜100μm程度
の膜厚とする。
The glass cutting blade of the present invention has a structure in which the surface of the V-shaped blade edge made of ceramic of the above-mentioned glass cutting blade is coated with a diamond film. The method for forming the diamond film, the properties of the diamond film, the synthesis conditions, etc. will be described later. The thickness of the diamond film is selected appropriately. In the case of a fixed type blade, since the diamond film is required to have higher wear resistance than a rotary type blade, the film thickness needs to be thicker, for example, about 10 to 100 μm.

【0016】なお、回転式のガラス切断用刃の場合には
、図5に示すように、ホイール2の側部2a,2b、お
よび貫通孔3へのダイヤモンド膜の付着を避けるため、
図に示すような治具を用いてダイヤモンド膜の被覆(コ
ート)を行なう。治具を用いるのは、ホイール2の側部
2a,2bや貫通孔3にダイヤモンドがコートされると
、ホイールを軸承する軸や、ホイール側部と摺接する金
具が損傷を受けたり、精度よく取付けられないなど好ま
しくないからである。治具は、貫通孔と係合する軸10
および押え部材11a,11bからなり、軸10で貫通
孔3を遮蔽(マスキング)する。また、押え部材11a
,11bでホイールの側部を押えつけてホイール2の側
部2a,2bを遮蔽するとともに、ホイール2を支持す
る。この治具を用いることにより、容易に刃先表面4の
みをダイヤモンドでコートできる。
In the case of a rotary glass cutting blade, as shown in FIG.
A diamond film is coated using a jig as shown in the figure. The reason for using a jig is that if the sides 2a and 2b of the wheel 2 and the through hole 3 are coated with diamond, the shaft that supports the wheel and the metal fittings that slide on the side of the wheel may be damaged, and it may be difficult to mount the jig accurately. This is because it is not desirable to be unable to do so. The jig includes a shaft 10 that engages with the through hole.
and press members 11a and 11b, and the shaft 10 shields (masks) the through hole 3. In addition, the pressing member 11a
, 11b press the side portions of the wheel to shield the side portions 2a, 2b of the wheel 2, and support the wheel 2. By using this jig, only the cutting edge surface 4 can be easily coated with diamond.

【0017】ダイヤモンド膜の合成方法としては、気相
法により原料となるガスを励起してダイヤモンド膜を形
成することのできる方法であれば、特に制限はなく、例
えば直流または交流アーク放電によるプラズマを利用す
る方法、高周波誘電放電によるプラズマを利用する方法
、マイクロ波放電によるプラズマを利用する方法(有磁
場−CVD 法, ECR法を含む)、光エネルギーを
利用する方法(光CVD 法,レーザー誘起CVD 法
を含む)あるいは、熱フィラメントによる加熱により熱
分解する熱分解法(EACVD 法を含む)、さらに燃
焼炎法、スパッタリング法、イオンプレーティング法な
どのいずれかをも採用することができる。特に原料ガス
を直流または交流アーク放電によりプラズマ分解する方
法、原料ガスにマイクロ波を照射し、プラズマを形成さ
せることにより活性化されたガスを、基材に接触させて
ダイヤモンド膜を生成させるマイクロ波プラズマCVD
法(有磁場法を含む)、熱フィラメント法が好ましい。 ダイヤモンド膜の性状は、結晶質ダイヤモンドが最も好
ましいが、非晶質炭素薄膜(ダイヤモンド状炭素薄膜)
であってもよい。 これは、ダイヤモンド状炭素膜はダイヤモンドに近い硬
度を持っているためである。原料ガス、反応圧力、基体
温度等のダイヤモンド膜の合成条件は、採用するダイヤ
モンド膜の形成方法や、所望するダイヤモンド膜の性状
等に応じ適宜選択される。
The method for synthesizing the diamond film is not particularly limited as long as it can form a diamond film by exciting the raw material gas using a vapor phase method. For example, plasma using direct current or alternating current arc discharge may be used. Methods using plasma from high-frequency dielectric discharge, Methods using plasma from microwave discharge (including magnetic field-CVD method and ECR method), Methods using light energy (photoCVD method, laser-induced CVD method) Alternatively, any one of a thermal decomposition method (including an EACVD method) in which thermal decomposition is performed by heating with a hot filament, a combustion flame method, a sputtering method, an ion plating method, etc. can be adopted. In particular, a method in which raw material gas is plasma decomposed by direct current or alternating current arc discharge, and a microwave method in which raw material gas is irradiated with microwaves and activated gas is brought into contact with a base material to form plasma to form a diamond film. plasma CVD
(including magnetic field method) and hot filament method are preferred. Regarding the properties of the diamond film, crystalline diamond is the most preferable, but amorphous carbon thin film (diamond-like carbon thin film)
It may be. This is because the diamond-like carbon film has a hardness close to that of diamond. The conditions for synthesizing the diamond film, such as the raw material gas, reaction pressure, and substrate temperature, are appropriately selected depending on the diamond film formation method employed, the desired properties of the diamond film, and the like.

【0018】本発明においては、上記で得られたガラス
切断用刃の刃先表面に被覆されたダイヤモンド膜を、表
面研磨処理して整形することが好ましい。表面研磨処理
はダイヤモンド砥粒等を用いて行なわれる。このように
ダイヤモンド膜の表面を研磨処理すると、さらに切れ味
がよくなり、平滑な切断面が得られるようになる。
In the present invention, it is preferable that the diamond film coated on the edge surface of the glass cutting blade obtained above is shaped by surface polishing. The surface polishing treatment is performed using diamond abrasive grains or the like. By polishing the surface of the diamond film in this way, it becomes even sharper and a smoother cut surface can be obtained.

【0019】なお、上述した本発明のガラス切断用刃は
、適宜変形して実施することができる。例えば、ガラス
切断用セラミック刃1の両側面に円板状の補強板を取り
付けるようにしてもよい。また、刃の寿命を長くするた
め固定式のガラス切断用刃の取付部分に角度変更穴を設
け、ガラスに当接する刃の部分を変えて使用できるよう
にしてもよい。
The glass cutting blade of the present invention described above can be modified as appropriate. For example, disk-shaped reinforcing plates may be attached to both sides of the ceramic blade 1 for cutting glass. Further, in order to extend the life of the blade, an angle changing hole may be provided in the mounting portion of the fixed type glass cutting blade so that the portion of the blade that contacts the glass can be changed for use.

【0020】[0020]

【実施例】以下、実施例により本発明をさらに具体的に
説明する。
[Examples] The present invention will be explained in more detail with reference to Examples below.

【0021】実施例1 直径(長径)3mmφ、厚さ1mm、刃先角(α)12
5°の窒化ケイ素(Si3N4)製セラミックホイール
の刃先部分に、マイクロ波プラズマCVD法によってダ
イヤモンド膜を20μm の厚さで被覆(コート)して
回転式のガラス切断用刃を作製した。マイクロ波プラズ
マCVD法によるダイヤモンド膜の合成は、原料ガスと
してCO15vol %,H285vol %の混合ガ
ス(流量200sccm )を用い、合成時間10時間
、ホイール(基体)の温度960°Cの条件で行なった
。上記のようにして得られた回転式ガラス切断用刃を用
いてガラスの切断テストを行なった。ガラスとしては石
英ガラスを使用した。その結果、10Kmの長さにわた
って溝入れしても、溝がやや浅くなるだけで、溝の形状
はきれいなV字形状をなしており、これを切断した場合
のガラスの切断面は平滑できれいであった。以上の条件
および結果を表1に示す。
Example 1 Diameter (major axis) 3 mmφ, thickness 1 mm, cutting edge angle (α) 12
A rotary glass cutting blade was prepared by coating the cutting edge of a 5° ceramic wheel made of silicon nitride (Si3N4) with a diamond film to a thickness of 20 μm by microwave plasma CVD. The diamond film was synthesized by the microwave plasma CVD method using a mixed gas of 15 vol % CO and 85 vol % H (flow rate 200 sccm) as a raw material gas, a synthesis time of 10 hours, and a wheel (substrate) temperature of 960°C. A glass cutting test was conducted using the rotary glass cutting blade obtained as described above. Quartz glass was used as the glass. As a result, even after grooving over a length of 10 km, the groove only becomes slightly shallower, and the groove has a beautiful V-shape, and the cut surface of the glass when this is cut is smooth and clean. there were. The above conditions and results are shown in Table 1.

【0022】実施例2 刃先部分にコートしたダイヤモンド膜の表面を、#20
00のダイヤモンド砥粒で研磨処理した以外は実施例1
と同様にして回転式ガラス切断用刃を作成し、ガラスの
切断テストを行なった。その結果、10Kmの長さにわ
たって溝入れしても、溝の深さは変わらず、かつ、溝の
形状はきれいなV字形状を保っていた。また、ガラスを
切断したときの切断面は平滑できれいであった。上記の
条件および結果を表1に示す。
Example 2 The surface of the diamond film coated on the cutting edge was coated with #20
Example 1 except that it was polished with 00 diamond abrasive grains.
A rotary glass cutting blade was created in the same manner as above, and a glass cutting test was conducted. As a result, even after grooving over a length of 10 km, the depth of the groove remained unchanged and the groove maintained a clean V-shape. Furthermore, the cut surface when cutting the glass was smooth and clean. The above conditions and results are shown in Table 1.

【0023】比較例1 ダイヤモンドをコートせず、セラミックホイールをその
ままガラス切断用刃として使用した以外は実施例1と同
様にしてガラスの切断テストを行なった。その結果、1
Km程度の長さにわたって溝入れをしただけで溝が浅く
なり、溝の形状も崩れたものとなった。また、ガラスを
切断したときの切断面は汚く、切断不良も発生した。上
記の条件および結果を表1に示す。
Comparative Example 1 A glass cutting test was carried out in the same manner as in Example 1 except that the ceramic wheel was used as a glass cutting blade without being coated with diamond. As a result, 1
Even after grooving over a length of about Km, the groove became shallow and its shape became distorted. Furthermore, when cutting the glass, the cut surface was dirty and some cutting defects occurred. The above conditions and results are shown in Table 1.

【0024】比較例2 実施例1と同一寸法、形状の超硬合金製ホイールカッタ
ーをガラス切断用刃として使用した以外は実施例1と同
様にしてガラスの切断テストを行なった。その結果3K
m程度の長さにわたって溝入れをしただけで溝が浅くな
り、溝の形状も崩れたものとなった。また、ガラスを切
断したときの切断面は汚く、切断不良も発生した。上記
の条件および結果を表1に示す。
Comparative Example 2 A glass cutting test was conducted in the same manner as in Example 1 except that a cemented carbide wheel cutter having the same dimensions and shape as in Example 1 was used as the glass cutting blade. The result was 3K
Even after grooving over a length of approximately m, the groove became shallow and the shape of the groove became distorted. Furthermore, when cutting the glass, the cut surface was dirty and some cutting defects occurred. The above conditions and results are shown in Table 1.

【0025】[0025]

【表1】[Table 1]

【0026】実施例1〜2および比較例1〜2から明ら
かなように、ダイヤモンドをコートした本発明のガラス
切断用刃は従来品に比べ寿命が三倍以上長く、かつ切断
面の状態も良好であることが判る。
As is clear from Examples 1 and 2 and Comparative Examples 1 and 2, the life of the diamond-coated glass cutting blade of the present invention is more than three times longer than that of conventional products, and the cutting surface is in good condition. It turns out that.

【0027】実施例3 半径3mmφ、厚さ1mm、刃先角125°の半円状の
窒化ケイ素(Si3N4)製ガラス切断用(セラミック
)刃の刃先部分にマイクロ刃プラズマCVD法によって
ダイヤモンド膜を厚さ20μm の厚さでコートして、
固定式のガラス切断用刃を作製した。なお、マイクロ刃
プラズマCVD法によるダイヤモンド膜の合成条件は実
施例1と同様とした。上記のようにして得られた固定式
ガラス切断用刃を用いてガラスの切断テストを行なった
。ガラスとしては石英ガラスを使用した。その結果、1
0Kmの長さにわたって溝入れしても溝がやや浅くなる
だけで、溝の形状はきれいなV字形状をなしており、こ
れを切断した場合の切断面は平滑できれいであった。以
上の条件および結果を表2に示す。
Example 3 A diamond film was deposited thickly on the cutting edge of a semicircular silicon nitride (Si3N4) glass cutting (ceramic) blade with a radius of 3 mmφ, a thickness of 1 mm, and a cutting edge angle of 125° using the micro-blade plasma CVD method. Coat with a thickness of 20 μm,
We created a fixed type glass cutting blade. Note that the conditions for synthesizing the diamond film by the micro-blade plasma CVD method were the same as in Example 1. A glass cutting test was conducted using the fixed glass cutting blade obtained as described above. Quartz glass was used as the glass. As a result, 1
Even after grooving over a length of 0 km, the groove was only slightly shallower, and the groove had a clean V-shape, and the cut surface was smooth and clean. The above conditions and results are shown in Table 2.

【0028】実施例4 刃先部分にコートしたダイヤモンド膜の表面を#200
0のダイヤモンド砥粒で研磨処理した以外は実施例3と
同様にして固定式ガラス切断用刃を作成し、ガラスの切
断テストを行なった。その結果、10Kmにわたって溝
入れしても溝の深さは変わらず、また、溝の形状はきれ
いなV字形状を保っていた。また、ガラスを切断したと
きの切断面は平滑できれいであった。上記の条件および
結果を表2に示す。
Example 4 The surface of the diamond film coated on the cutting edge was #200.
A fixed type glass cutting blade was prepared in the same manner as in Example 3 except that it was polished with 0 diamond abrasive grains, and a glass cutting test was conducted. As a result, even after grooving for 10 km, the depth of the groove did not change, and the groove maintained a clean V-shape. Furthermore, the cut surface when cutting the glass was smooth and clean. The above conditions and results are shown in Table 2.

【0029】比較例3 ダイヤモンドをコートせず、半円状のガラス切断用セラ
ミック刃をそのままガラス切断用刃とした以外は実施例
3と同様にしてガラスの切断テストを行なった。その結
果、300m 程度の長さにわたって溝入れをしただけ
で溝が浅くなり、溝の形状も崩れたものとなった。また
、ガラスを切断したときの切断面は汚く、切断不良も発
生した。 比較例4 実施例3と同一寸法、形状の半円状の超硬合金製カッタ
ーをガラス切断用刃として使用した以外は実施例3と同
様にしてガラスの切断テストを行なった。その結果、3
Km程度の長さにわたって溝入れしただけで溝が浅くな
り、溝の形状も崩れたものとなった。また、ガラスを切
断したときの切断面は汚く、切断不良も発生した上記の
条件および結果を表2に示す。
Comparative Example 3 A glass cutting test was carried out in the same manner as in Example 3, except that the glass cutting blade was not coated with diamond and the semicircular glass cutting ceramic blade was used as the glass cutting blade. As a result, even after grooving over a length of approximately 300 m, the groove became shallow and its shape became distorted. Furthermore, when cutting the glass, the cut surface was dirty and some cutting defects occurred. Comparative Example 4 A glass cutting test was conducted in the same manner as in Example 3, except that a semicircular cemented carbide cutter having the same dimensions and shape as in Example 3 was used as the glass cutting blade. As a result, 3
Even after grooving over a length of approximately Km, the groove became shallow and the shape of the groove became distorted. Furthermore, when cutting the glass, the cut surface was dirty and poor cutting occurred. The above conditions and results are shown in Table 2.

【0030】[0030]

【表2】[Table 2]

【0031】実施例3〜4および比較例3〜4から明ら
かなようにダイヤモンドをコートした本発明のガラス切
断用刃は従来品に比べ寿命が三倍以上長くかつ切断面の
状態も良好であることが判る。また、固定式であっても
回転式と同等の性能を示すことも判る。
As is clear from Examples 3 and 4 and Comparative Examples 3 and 4, the life of the diamond-coated glass cutting blade of the present invention is more than three times longer than that of conventional products, and the cutting surface is in good condition. I understand that. Furthermore, it can be seen that even the fixed type shows the same performance as the rotary type.

【発明の効果】以上説明したように本発明のガラス切断
用刃によれば、従来品に比べ刃の寿命が長く、かつ切断
面が平滑となるように高硬度ガラスを切断できる。
As explained above, according to the glass cutting blade of the present invention, the life of the blade is longer than that of conventional products, and high hardness glass can be cut with a smooth cut surface.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の回転式ガラス切断刃の一例を示す。 (a)は縦断面図、(b)は横断面図である。FIG. 1 shows an example of a rotary glass cutting blade of the present invention. (a) is a longitudinal cross-sectional view, and (b) is a cross-sectional view.

【図2】本発明の固定式ガラス切断刃の一例を示す。 (a)は一部裁断正面図、(b)は側面図である。FIG. 2 shows an example of a fixed glass cutting blade of the present invention. (a) is a partially cutaway front view, and (b) is a side view.

【図3】本発明の固定式ガラス切断刃の他の例を示す。 (a)は正面図、(b)は側面図である。FIG. 3 shows another example of the fixed glass cutting blade of the present invention. (a) is a front view, and (b) is a side view.

【図4】本発明のガラス切断刃の刃先の断面形状の他の
例を示す部分断面図である。
FIG. 4 is a partial sectional view showing another example of the cross-sectional shape of the cutting edge of the glass cutting blade of the present invention.

【図5】ダイヤモンド膜をコートする際に使用する治具
を示す正面図である。
FIG. 5 is a front view showing a jig used when coating a diamond film.

【図6】従来のガラス切断刃による切断状況を示す。 (a)は正面図、(b)は断面図である。FIG. 6 shows a cutting situation using a conventional glass cutting blade. (a) is a front view, and (b) is a sectional view.

【符号の説明】[Explanation of symbols]

1  ガラス切断用刃 4  刃先 5  ダイヤモンド膜 1 Glass cutting blade 4 Cutting edge 5 Diamond film

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】  ガラス切断用刃の刃先をダイヤモンド
膜で被覆されたセラミックで形成し、かつ、刃先の断面
形状をV字形状としたことを特徴とするガラス切断用刃
1. A glass cutting blade characterized in that the cutting edge of the glass cutting blade is made of ceramic coated with a diamond film and has a V-shaped cross section.
【請求項2】  セラミックの表面に被覆されたダイヤ
モンド膜を表面研磨処理したことを特徴とする請求項1
記載のガラス切断用刃。
[Claim 2] Claim 1, characterized in that the diamond film coated on the surface of the ceramic is subjected to surface polishing treatment.
Glass cutting blade as described.
【請求項3】  ガラス切断用刃が回転式のものである
請求項1または2記載のガラス切断用刃。
3. The glass cutting blade according to claim 1 or 2, wherein the glass cutting blade is of a rotary type.
【請求項4】  ガラス切断用刃が固定式のものである
請求項1または2記載のガラス切断用刃。
4. The glass cutting blade according to claim 1 or 2, wherein the glass cutting blade is of a fixed type.
JP41178590A 1990-12-20 1990-12-20 Glass cutting blade Pending JPH04224128A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP41178590A JPH04224128A (en) 1990-12-20 1990-12-20 Glass cutting blade

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP41178590A JPH04224128A (en) 1990-12-20 1990-12-20 Glass cutting blade

Publications (1)

Publication Number Publication Date
JPH04224128A true JPH04224128A (en) 1992-08-13

Family

ID=18520725

Family Applications (1)

Application Number Title Priority Date Filing Date
JP41178590A Pending JPH04224128A (en) 1990-12-20 1990-12-20 Glass cutting blade

Country Status (1)

Country Link
JP (1) JPH04224128A (en)

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0773194A1 (en) * 1995-11-06 1997-05-14 Mitsuboshi Diamond Industrial Co., Ltd. Glass cutting disc
JP2011213589A (en) * 2004-02-02 2011-10-27 Mitsuboshi Diamond Industrial Co Ltd Cutter wheel for scribing fragile material substrate and method of manufacturing the same
JP2012011475A (en) * 2010-06-29 2012-01-19 Tokyo Univ Of Science Diamond-coated tool, and method for manufacturing the same
EP2532501A1 (en) * 2011-06-08 2012-12-12 Mitsuboshi Diamond Industrial Co., Ltd. Scribing wheel, method for manufacturing the scribing wheel, and scribing method
JP2012250352A (en) * 2011-05-31 2012-12-20 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and scribing apparatus
WO2013133030A1 (en) 2012-03-08 2013-09-12 三星ダイヤモンド工業株式会社 Scribing wheel and method for manufacturing same
JP2013184388A (en) * 2012-03-08 2013-09-19 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method for manufacturing the same
JP2013202975A (en) * 2012-03-29 2013-10-07 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel, and method for manufacturing same
JP2013220554A (en) * 2012-04-13 2013-10-28 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method of manufacturing the same
JP2013233793A (en) * 2012-04-13 2013-11-21 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method of manufacturing the same
JP2013248746A (en) * 2012-05-30 2013-12-12 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method for manufacturing the same
CN104261667A (en) * 2012-10-31 2015-01-07 三星钻石工业股份有限公司 Scribing Wheel And Manufacturing Method Thereof
KR20160000406A (en) 2014-06-24 2016-01-04 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and manufacturing method thereof
JP2016013707A (en) * 2015-10-28 2016-01-28 三星ダイヤモンド工業株式会社 Scribing wheel
JP2016106046A (en) * 2015-12-28 2016-06-16 三星ダイヤモンド工業株式会社 Producing method of scribing wheel
JP2016117293A (en) * 2016-03-31 2016-06-30 三星ダイヤモンド工業株式会社 Scribing wheel and method of manufacturing the same
JP2017052281A (en) * 2016-10-31 2017-03-16 三星ダイヤモンド工業株式会社 Scribing wheel
JP2017074788A (en) * 2016-11-30 2017-04-20 三星ダイヤモンド工業株式会社 Method of manufacturing scribing wheel
JP2017213866A (en) * 2016-05-30 2017-12-07 三星ダイヤモンド工業株式会社 Scribing wheel and method for manufacturing the same
TWI641568B (en) * 2014-03-13 2018-11-21 大陸地區‧北京沃爾德金剛石工具股份有限公司 Double-edged scribing wheel for cutting coated glass
US10252480B2 (en) * 2012-04-06 2019-04-09 Svv Technology Innovations, Inc. Method and apparatus for making reflective surfaces within optically transmissive materials

Cited By (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5836229A (en) * 1995-11-06 1998-11-17 Mitsuboshi Diamond Industrial Co., Ltd. Glass scribing disc
EP1092686A2 (en) * 1995-11-06 2001-04-18 Mitsuboshi Diamond Industrial Co., Ltd. Glass cutting disc
EP1092686A3 (en) * 1995-11-06 2001-05-16 Mitsuboshi Diamond Industrial Co., Ltd. Glass cutting disc
EP2133316A3 (en) * 1995-11-06 2010-02-10 Mitsuboshi Diamond Industrial Co., Ltd. A method of forming a scribed line
EP2135848A3 (en) * 1995-11-06 2010-02-17 Mitsuboshi Diamond Industrial Co., Ltd. Glass cutting disc
EP0773194A1 (en) * 1995-11-06 1997-05-14 Mitsuboshi Diamond Industrial Co., Ltd. Glass cutting disc
JP2011213589A (en) * 2004-02-02 2011-10-27 Mitsuboshi Diamond Industrial Co Ltd Cutter wheel for scribing fragile material substrate and method of manufacturing the same
JP2013199131A (en) * 2004-02-02 2013-10-03 Mitsuboshi Diamond Industrial Co Ltd Cutter wheel for cross-scribing fragile material substrate, scribing method of the fragile material substrate, cutting method for the fragile material substrate, and method of manufacturing cutter wheel
JP2012011475A (en) * 2010-06-29 2012-01-19 Tokyo Univ Of Science Diamond-coated tool, and method for manufacturing the same
JP2012250352A (en) * 2011-05-31 2012-12-20 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and scribing apparatus
CN104608263B (en) * 2011-06-08 2016-11-23 三星钻石工业股份有限公司 Stitch marker, its manufacture method and scribble method
KR101529941B1 (en) * 2011-06-08 2015-06-29 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and scribing method
JP2016190497A (en) * 2011-06-08 2016-11-10 三星ダイヤモンド工業株式会社 Scribing wheel and scribing method
JP2016175421A (en) * 2011-06-08 2016-10-06 三星ダイヤモンド工業株式会社 Scribing wheel
CN102814870A (en) * 2011-06-08 2012-12-12 三星钻石工业股份有限公司 Scribing wheel, method for manufacturing the scribing wheel, and scribing method
CN104608261B (en) * 2011-06-08 2016-10-05 三星钻石工业股份有限公司 Stitch marker, its manufacture method and scribble method
TWI665067B (en) * 2011-06-08 2019-07-11 日商三星鑽石工業股份有限公司 Scribing wheel and manufacturing method thereof
TWI665066B (en) * 2011-06-08 2019-07-11 日商三星鑽石工業股份有限公司 Scribing wheel and scribing method
TWI665065B (en) * 2011-06-08 2019-07-11 日商三星鑽石工業股份有限公司 Scribing wheel and scribing method
KR101450127B1 (en) * 2011-06-08 2014-10-13 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel, method for manufacturing the same, and scribing method
TWI548503B (en) * 2011-06-08 2016-09-11 Mitsuboshi Diamond Ind Co Ltd Scribing wheel, its manufacturing method and crossed method
CN104608262B (en) * 2011-06-08 2017-01-04 三星钻石工业股份有限公司 Scribing wheel, manufacturing method thereof and scribing method
CN104193162A (en) * 2011-06-08 2014-12-10 三星钻石工业股份有限公司 Scribing wheel, method for manufacturing the scribing wheel, and scribing method
JP2016104577A (en) * 2011-06-08 2016-06-09 三星ダイヤモンド工業株式会社 Scribing wheel and manufacturing method thereof
CN104608263A (en) * 2011-06-08 2015-05-13 三星钻石工业股份有限公司 Scribing wheel, method for manufacturing the scribing wheel, and scribing method
CN104608261A (en) * 2011-06-08 2015-05-13 三星钻石工业股份有限公司 Scribing wheel, method for manufacturing the scribing wheel, and scribing method
CN104608262A (en) * 2011-06-08 2015-05-13 三星钻石工业股份有限公司 Scribing wheel, method for manufacturing the scribing wheel, and scribing method
EP2532501A1 (en) * 2011-06-08 2012-12-12 Mitsuboshi Diamond Industrial Co., Ltd. Scribing wheel, method for manufacturing the scribing wheel, and scribing method
JP2015157489A (en) * 2011-06-08 2015-09-03 三星ダイヤモンド工業株式会社 Scribing wheel, method for manufacturing the same, and scribing method
US9149953B2 (en) 2011-06-08 2015-10-06 Mitsuboshi Diamond Industrial Co., Ltd. Scribing wheel, method for manufacturing the scribing wheel, and scribing method
JP2015180548A (en) * 2011-06-08 2015-10-15 三星ダイヤモンド工業株式会社 Scribing wheel, and scribing method
JP2013014129A (en) * 2011-06-08 2013-01-24 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel, method for manufacturing the same, and scribing method
JP2016013706A (en) * 2011-06-08 2016-01-28 三星ダイヤモンド工業株式会社 Method for manufacturing scribing wheel
TWI595983B (en) * 2011-06-08 2017-08-21 Mitsuboshi Diamond Ind Co Ltd Cricketers and crossed lines
TWI613035B (en) * 2012-03-08 2018-02-01 Mitsuboshi Diamond Ind Co Ltd Scribing wheel and manufacturing method thereof
KR20160040726A (en) 2012-03-08 2016-04-14 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and method for manufacturing same
CN106113293B (en) * 2012-03-08 2018-08-03 三星钻石工业股份有限公司 Stitch marker and its manufacturing method
TWI565556B (en) * 2012-03-08 2017-01-11 三星鑽石工業股份有限公司 Scribing wheel and its manufacturing method
CN104136182A (en) * 2012-03-08 2014-11-05 三星钻石工业股份有限公司 Scribing wheel and method for manufacturing same
CN104136182B (en) * 2012-03-08 2016-09-07 三星钻石工业股份有限公司 Stitch marker and manufacture method thereof
KR20140125838A (en) 2012-03-08 2014-10-29 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and method for manufacturing same
JP2013184388A (en) * 2012-03-08 2013-09-19 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method for manufacturing the same
WO2013133030A1 (en) 2012-03-08 2013-09-12 三星ダイヤモンド工業株式会社 Scribing wheel and method for manufacturing same
CN106113293A (en) * 2012-03-08 2016-11-16 三星钻石工业股份有限公司 Stitch marker and manufacture method thereof
JP2013202975A (en) * 2012-03-29 2013-10-07 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel, and method for manufacturing same
US10252480B2 (en) * 2012-04-06 2019-04-09 Svv Technology Innovations, Inc. Method and apparatus for making reflective surfaces within optically transmissive materials
JP2016101756A (en) * 2012-04-13 2016-06-02 三星ダイヤモンド工業株式会社 Scribing wheel
JP2017074789A (en) * 2012-04-13 2017-04-20 三星ダイヤモンド工業株式会社 Scribing wheel
JP2013220554A (en) * 2012-04-13 2013-10-28 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method of manufacturing the same
JP2013233793A (en) * 2012-04-13 2013-11-21 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method of manufacturing the same
JP2013248746A (en) * 2012-05-30 2013-12-12 Mitsuboshi Diamond Industrial Co Ltd Scribing wheel and method for manufacturing the same
CN104261667A (en) * 2012-10-31 2015-01-07 三星钻石工业股份有限公司 Scribing Wheel And Manufacturing Method Thereof
TWI641568B (en) * 2014-03-13 2018-11-21 大陸地區‧北京沃爾德金剛石工具股份有限公司 Double-edged scribing wheel for cutting coated glass
CN105291271A (en) * 2014-06-24 2016-02-03 三星钻石工业股份有限公司 Scribing wheel and method for manufacturing the scribing wheel
KR20160000406A (en) 2014-06-24 2016-01-04 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and manufacturing method thereof
JP2016013707A (en) * 2015-10-28 2016-01-28 三星ダイヤモンド工業株式会社 Scribing wheel
JP2016106046A (en) * 2015-12-28 2016-06-16 三星ダイヤモンド工業株式会社 Producing method of scribing wheel
JP2016117293A (en) * 2016-03-31 2016-06-30 三星ダイヤモンド工業株式会社 Scribing wheel and method of manufacturing the same
JP2017213866A (en) * 2016-05-30 2017-12-07 三星ダイヤモンド工業株式会社 Scribing wheel and method for manufacturing the same
KR20170135717A (en) 2016-05-30 2017-12-08 미쓰보시 다이야몬도 고교 가부시키가이샤 Scribing wheel and method for manufacturing the same
CN107443592A (en) * 2016-05-30 2017-12-08 三星钻石工业股份有限公司 Stitch marker and its manufacture method
JP2017052281A (en) * 2016-10-31 2017-03-16 三星ダイヤモンド工業株式会社 Scribing wheel
JP2017074788A (en) * 2016-11-30 2017-04-20 三星ダイヤモンド工業株式会社 Method of manufacturing scribing wheel

Similar Documents

Publication Publication Date Title
JPH04224128A (en) Glass cutting blade
RU2111846C1 (en) Diamond-plated tool and method of its manufacture
CA2061944C (en) A diamond and/or diamond-like carbon-coated hard material
JPH01153228A (en) Vapor phase composite method for producing diamond tool
WO2005116146A2 (en) Abrasive composite tools having compositional gradients and associated methods
JP2002179493A (en) Diamond-clad member and producing method thereof
JPH02109608A (en) Cemented carbide cutter tip and manufacture thereof
EP1616974B1 (en) Method for preparing an alpha alumina coating
JP3448884B2 (en) Artificial diamond coating
JPH0621360B2 (en) Diamond-coated sintered bond excellent in peel resistance and method for producing the same
JPS61291493A (en) Diamond coated hard material
JPH08300265A (en) Cutting grinding wheel
JP7360202B2 (en) Manufacturing method of diamond coated silicon nitride ceramic whole tool
KR101243686B1 (en) Scriber cutter wheel and method for manufacturing the same
JPH0710443B2 (en) Cutting tip
JPH04280974A (en) Boron nitride coated hard material
JP3520098B2 (en) Diamond coated cutting tool
JPS63306805A (en) Diamond coated cutting tool
JPH06262525A (en) Grinding wheel and its manufacture
JP2831396B2 (en) Diamond coated cutting tool
JPH01259171A (en) Cutting tool member coated with hard film
JPS61270373A (en) Diamond coated sintered hard alloy
JPH0197570A (en) Diamond grinding material for metal bond grinding stone
JPH05125542A (en) Manufacture of thin diamond film tool
JPS59166673A (en) Surface-coated tool member excellent in wear resistance