JPH04201003A - Cutting tool made of surface-coated ceramic - Google Patents
Cutting tool made of surface-coated ceramicInfo
- Publication number
- JPH04201003A JPH04201003A JP32825490A JP32825490A JPH04201003A JP H04201003 A JPH04201003 A JP H04201003A JP 32825490 A JP32825490 A JP 32825490A JP 32825490 A JP32825490 A JP 32825490A JP H04201003 A JPH04201003 A JP H04201003A
- Authority
- JP
- Japan
- Prior art keywords
- coating layer
- cutting
- vapor deposition
- physical vapor
- coated layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 22
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 17
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 7
- 239000011247 coating layer Substances 0.000 claims description 40
- 239000010410 layer Substances 0.000 claims description 29
- 238000005240 physical vapour deposition Methods 0.000 claims description 24
- 239000010936 titanium Substances 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 18
- 239000000853 adhesive Substances 0.000 claims description 7
- 230000001070 adhesive effect Effects 0.000 claims description 7
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 239000011224 oxide ceramic Substances 0.000 claims 2
- 229910052574 oxide ceramic Inorganic materials 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052593 corundum Inorganic materials 0.000 abstract description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract description 4
- 238000005289 physical deposition Methods 0.000 abstract 5
- 229910001018 Cast iron Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229910001315 Tool steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
Landscapes
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Physical Vapour Deposition (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、酸化アルミニウム(以下Al2O3で示す
)系セラミックスまたは窒化けい素(以下、S + 3
N 4で示す)系セラミックスからなる基体の表面に、
物理蒸着法にて形成された耐摩耗性のすぐれたT1とA
lの複合窒化物〔以下、(Ti、Al)Nで示す〕被覆
層の前記基体表面に対する密着性を向上させた表面被覆
セラミックス製切削工具に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention is directed to aluminum oxide (hereinafter referred to as Al2O3) based ceramics or silicon nitride (hereinafter referred to as S + 3
On the surface of a base made of ceramics (denoted as N4),
T1 and A with excellent wear resistance formed by physical vapor deposition
The present invention relates to a surface-coated ceramic cutting tool in which the adhesion of a coating layer of a composite nitride (hereinafter referred to as (Ti, Al)N) to the substrate surface is improved.
従来、例えば特開昭62−56565号公報に記載され
る通り、WCC超超硬合金高速度工具鋼などで構成され
た基体の表面に、物理蒸着法を用いて、耐摩耗性のすぐ
れたTiとAlの複合窒化物〔以下、(Ti、Al)N
て示す〕からなる硬質被覆層を形成してなる表面被覆切
削工具が提案されている。Conventionally, as described in JP-A No. 62-56565, for example, Ti, which has excellent wear resistance, has been deposited on the surface of a base made of WCC cemented carbide high speed tool steel using a physical vapor deposition method. and Al composite nitride [hereinafter referred to as (Ti, Al)N
A surface-coated cutting tool has been proposed in which a hard coating layer is formed.
一方、近年の切削機械の高性能化はめざましく、これに
伴ない、より速い速度での切削や、より一段の高切込み
あるいは高送りなどの重切削が行なわれる状況にあるか
、このような苛酷な切削条件下では、上記の従来表面被
覆切削工具においては、(Ti、Ajl’)N被覆層の
基体表面に対する密着性が十分でないために、これに満
足に対応することができないのが現状である。On the other hand, the performance of cutting machines has improved dramatically in recent years, and as a result, heavy cutting such as faster cutting speeds, higher depths of cut, and higher feed rates are being carried out, and such harsh cutting conditions are becoming more difficult. Under such cutting conditions, the above-mentioned conventional surface-coated cutting tools cannot satisfactorily cope with these conditions because the adhesion of the (Ti,Ajl')N coating layer to the substrate surface is insufficient. be.
そこで、本発明者等は、上述のような観点から、上記の
従来表面被覆切削工具に着目し、(T1゜Al)N被覆
層の基体表面に対する密着性を向上せしめるべく研究を
行なった結果、基体をAl2O3系セラミックスおよび
S】3N4系セラミツクスに特定した上で、この基体の
表面に、物理蒸着法にて形成した窒化チタン(以下Ti
Nて示す)被覆層を介して、上記の耐摩耗性のすくれた
(Ti、Al)N被覆層を形成すると、前記TiN被覆
層の前記基体および(Ti、Al)N被覆層に対する密
着性が著しく高いものであることから、苛酷な条件での
切削に供しても(Ti、Al)N被覆層に剥離の発生が
なく、かつ切刃に欠損の発生もなく、すぐれた切削性能
を長期に亘って発揮するようになり、さらにこの上に同
じく物理蒸着法を用いてTiNを被覆すると、耐欠損性
が一段と向上するようになるという研究結果を得たので
ある。Therefore, from the above-mentioned viewpoint, the present inventors focused on the above-mentioned conventional surface-coated cutting tools and conducted research to improve the adhesion of the (T1゜Al)N coating layer to the substrate surface. After specifying the substrate to be Al2O3 ceramics and S]3N4 ceramics, titanium nitride (hereinafter referred to as Ti) was formed on the surface of this substrate by physical vapor deposition.
When the wear-resistant (Ti, Al)N coating layer is formed through the coating layer (indicated by N), the adhesion of the TiN coating layer to the substrate and the (Ti, Al)N coating layer increases. Even when subjected to cutting under severe conditions, the (Ti, Al)N coating layer does not peel off, and the cutting edge does not suffer from damage, ensuring excellent cutting performance over a long period of time. The research results showed that if TiN was coated on top of this using the same physical vapor deposition method, the chipping resistance would be further improved.
この発明は、上記の研究結果にもとづいてなされたもの
であって、
A I 203系セラミツクスまたはSi3N4系セラ
ミックスからなる基体の表面に、
平均層厚で01〜1μmのTiNからなる密着性物理蒸
着被覆層を介して、
平均層厚で0.5〜5μmの(Ti、AA’ )Nから
なる耐摩耗性物理蒸着被覆層を形成し、
さらに、必要に応じて、その上に同じく平均層厚で01
〜3μmのTiNからなる耐欠損性物理蒸削工具に特徴
を有するものである。This invention was made based on the above research results, and includes an adhesive physical vapor deposition coating of TiN having an average layer thickness of 01 to 1 μm on the surface of a substrate made of AI 203 ceramics or Si3N4 ceramics. A wear-resistant physical vapor deposition coating layer of (Ti, AA')N with an average layer thickness of 0.5 to 5 μm is formed through the layer, and if necessary, a wear-resistant physical vapor deposition coating layer with the same average layer thickness is formed on top of the layer, if necessary. 01
It is characterized by a fracture-resistant physical steaming tool made of TiN with a thickness of ~3 μm.
つぎに、この発明の切削工具において、これを構成する
被覆層の平均層厚を上記の通りに限定した理由を説明す
る。Next, in the cutting tool of the present invention, the reason why the average layer thickness of the coating layer constituting the cutting tool is limited as described above will be explained.
fa) 密着性物理蒸着被覆層
このTiN被覆層には、上記の通り基体および(Ti、
AA’)N被覆層に対して強固に接合し、苛酷な切削条
件下でも(Ti、AA’)N被覆層の剥離を防止する作
用があるが、その平均層厚か0.1μm未満ては前記作
用に所望の効果か得られず、一方その平均層厚か1μm
を越えても前記作用により一層の向上効果が得られない
ことから、経済性も考慮して、その平均層厚を01〜1
μmと定めた。fa) Adhesive Physical Vapor Deposition Coating Layer This TiN coating layer includes a substrate and (Ti,
It has the effect of strongly bonding to the AA')N coating layer and preventing the peeling of the (Ti, AA')N coating layer even under severe cutting conditions, but if the average layer thickness is less than 0.1 μm. The desired effect was not obtained in the above action, and on the other hand, the average layer thickness was 1 μm.
Even if the average layer thickness exceeds 0.01 to 0.01, no further improvement effect can be obtained due to the above action.
It was determined as μm.
(b) 耐摩耗性物理蒸着被覆層
この(Ti、Al)N被覆層は、きわめて硬質であり、
これの形成によって耐摩耗性が著しく向上するようにな
るか、その平均層厚が05μm未満では所望のすぐれた
耐摩耗性を確保することができす、一方その平均層厚か
5μmを越えると、チッピング(微小欠け)か発生し易
くなることから、その平均層厚を05〜5μmと定めた
。(b) Abrasion-resistant physical vapor deposition coating layer This (Ti, Al)N coating layer is extremely hard;
If the average layer thickness is less than 0.5 μm, the desired excellent wear resistance can be achieved, but if the average layer thickness exceeds 5 μm, the wear resistance can be significantly improved. Since chipping (microscopic chipping) is likely to occur, the average layer thickness was set at 0.5 to 5 μm.
なお、(Ti、Al)Nを組成式: (Ti工i、−
X) Nて現わした場合、Xの値を025〜0.95と
するのかよく、これは、Xの値がl)、25未満になる
と被覆層に急激な硬さ低下か起り、十分な耐摩耗性を得
ることができなくなり、一方Xの値が095を越えると
高温耐酸化性が低下し、特に切刃の逃げ面摩耗が進行す
るようになるという理由によるものである。In addition, (Ti, Al)N has the composition formula: (Ti, Al)N, -
When expressed as X)N, the value of This is because it becomes impossible to obtain wear resistance, and on the other hand, if the value of
fc) 耐欠損性物理蒸着被覆層
最外層に形成されるTiN被覆層には切刃の耐欠損性を
改善する作用があるので必要に応して形成されるか、そ
の平均層厚か01μm未満では所望の耐欠損性向上効果
は得られず、一方その平均層厚か3μ口を越えても耐欠
損性により一層の向上効果が現われないことから、その
平均層厚を01〜3μmと定めた。fc) Fracture-resistant physical vapor deposition coating layer The TiN coating layer formed as the outermost layer has the effect of improving the fracture resistance of the cutting edge, so it may be formed as necessary, or its average layer thickness may be less than 0.1 μm. However, even if the average layer thickness exceeds 3 μm, further improvement in chip resistance does not appear, so the average layer thickness was set at 0.1 to 3 μm. .
工具を実施例により具体的に説明する。The tool will be specifically explained using examples.
いずれも通常の粉末冶金法で製造され、かつそれぞれ第
1表に示される成分組成をもったAl O系セラミッ
クス基体および813N4系セラミックス基体を用意し
、これら基体を、物理蒸着装置の1種であるアーク放電
型イオンブレーティング装置の基板上に載置し、まず、
陰 極 純T1、
反応雰囲気: l xlO+OILのN2、基板印加電
圧・−400■、
陰極電流: ll0A。An AlO-based ceramic substrate and an 813N4-based ceramic substrate, both of which are manufactured by a normal powder metallurgy method and each have the composition shown in Table 1, are prepared, and these substrates are processed using a type of physical vapor deposition apparatus. Place it on the board of the arc discharge type ion blating device, and
Cathode pure T1, reaction atmosphere: lxlO+OIL N2, substrate applied voltage -400■, cathode current: ll0A.
の条件でTiNの物理蒸着を行ない、反応時間にて層厚
を調節して、それぞれ第1表に示される平均層厚の密着
性物理蒸着被覆層(TiN被覆層)を形成し、
ついで、陰極として、Al含有量を5〜75重量%の範
囲内で種々変化させた各種のTi−AA’合金を用いる
以外は同一の条件で、(Ti、Al)Nの物理蒸着を行
ない、同様に反応時間にて層厚を調整し、かつTi−A
1合金中のAA含有量にて■1とAlの割合を変化させ
て、それぞれ第1表に示される組成および平均層厚の耐
摩耗性物理蒸着被覆層((Ti、Al)N被覆層〕を形
成し、さらに必要に応して、再び陰極として純Tiを用
い、上記の条件と同じ条件でTiNの物理蒸着を行ない
、それぞれ第1表に示される平均層厚の耐欠損性物理蒸
着被覆層(TiN被覆層)を形成することにより、いず
れもS P G N 12408のチップ形状をもった
本発明表面被覆セラミックス製切削工具(以下本発明被
覆切削工具という)1〜33をそれぞれ製造した。Physical vapor deposition of TiN was carried out under the following conditions, and the layer thickness was adjusted by the reaction time to form an adhesive physical vapor deposition coating layer (TiN coating layer) with the average layer thickness shown in Table 1. Physical vapor deposition of (Ti, Al)N was carried out under the same conditions except that various Ti-AA' alloys with varying Al contents in the range of 5 to 75% by weight were used, and the reaction was carried out in the same manner. Adjust the layer thickness with time, and Ti-A
(Ti, Al)N coating layer with the composition and average layer thickness shown in Table 1 by changing the ratio of 1 and Al according to the AA content in the alloy. If necessary, physical vapor deposition of TiN is performed again under the same conditions as above using pure Ti as a cathode to form a defect-resistant physical vapor deposited coating with the average layer thickness shown in Table 1. By forming a layer (TiN coating layer), cutting tools 1 to 33 made of the surface-coated ceramic of the present invention (hereinafter referred to as the coated cutting tool of the present invention) each having a chip shape of S P GN 12408 were manufactured.
また、比較の目的で、上記の密着性物理蒸着被覆層およ
び耐欠損性物理蒸着被覆層の形成を行なわない以外は、
同一の条件で同じく第1表に示される組成および平均層
厚の耐摩耗性物理蒸着被覆層((Ti、Al)N被覆層
〕たけを形成することにより従来表面被覆セラミックス
製切削工具(以下従来被覆切削工具という)1〜10を
製造した。In addition, for comparison purposes, except that the above-mentioned adhesive physical vapor deposition coating layer and chipping-resistant physical vapor deposition coating layer were not formed,
By forming a wear-resistant physical vapor deposition coating layer ((Ti, Al)N coating layer) with the composition and average layer thickness shown in Table 1 under the same conditions, conventional 1 to 10 (referred to as coated cutting tools) were manufactured.
つぎに、この結果得られた各種の切削工具について、
A、被削材:円周にそって等間隔て6本の切込み溝を放
射状に有する直径・250mmφのFe12(鋳鉄)製
置板材、
切削速度・310〜ll0m/田in(面外側−中心)
、送 リ : 0.6mm/ +cv、、切込み
IO職、
の条件(切削条件Aという)での鋳鉄片側面の高送り乾
式断続切削試験、
B、被削材:Fe12の丸棒、
切削速度 500m/min、
送 リ゛0.3mm / t e v、、切込み・
1.5mm。Next, regarding the various cutting tools obtained as a result, A. Workpiece material: Fe12 (cast iron) plate material with a diameter of 250 mmφ and having six cutting grooves radially spaced at equal intervals along the circumference; Speed: 310~ll0m/in (outside surface - center)
, Feed: 0.6mm/ +cv, , Depth of cut
IO job, high feed dry intermittent cutting test on the side surface of a cast iron piece under conditions (referred to as cutting conditions A), B. Work material: Fe12 round bar, cutting speed 500 m/min, feed rate 0.3 mm/te. v,, cut depth・
1.5mm.
切削時間 30分、
の条件(切削条件Bという)での鋳鉄の高速乾式%式%
C1被削材をFe12とする以外は切削条件Aと同し条
件(切削条件Cという)での鋳鉄片側面の高送り乾式断
続切削試験、
D、被削材をFe12とする以外は切削条件Bと同じ条
件(切削条件りという)での鋳鉄の高速乾式%式%
E、切込みを3.0+nmとする以外は切削条件Aと同
じ条件(切削条件Eという)での鋳鉄片側面の高送り高
切込み乾式断続切削試験、
F、被削材をFe12とする以外は切削条件Bと同し条
件(切削条件Fという)での鋳鉄の高速乾式%式%
以上A−Fのうち少なくともいずれかの切削条件で切削
試験を行ない、切削条件A、 C,およびEでは切刃
に欠損が発生するまでの面削り回数、切削条件Bおよび
Dては切刃の逃げ面摩耗幅、切削条件Fては切刃の逃げ
面摩耗幅か03画に至るまでの切削時間をそれぞれ測定
した。これらの測定結果を第1表に示した。Cutting time: 30 minutes, high-speed dry % formula for cast iron under the conditions (referred to as cutting conditions B) Side surface of a cast iron piece under the same conditions as cutting conditions A (referred to as cutting conditions C) except that the C1 work material is Fe12 High-speed dry interrupted cutting test of cast iron under the same conditions as cutting conditions B (referred to as cutting conditions) except that the work material is Fe12 (D), except that the work material is Fe12 is a high-feed, high-cut dry intermittent cutting test on the side surface of a cast iron piece under the same conditions as cutting condition A (referred to as cutting condition E); A cutting test was conducted under at least one of the cutting conditions A-F above, and under cutting conditions A, C, and E, the number of face millings until chipping occurred on the cutting edge was determined. Under cutting conditions B and D, the flank wear width of the cutting edge was measured, and under cutting condition F, the cutting time until the flank wear width of the cutting edge reached 03 strokes was measured. The results of these measurements are shown in Table 1.
第1表に示される結果から、本発明被覆切削工具1〜3
3は、いずれも密着性物理蒸着被覆層であるTiN層の
介在によって(Ti、Al)N被覆層の基体表面に対す
る密着性か著しく向上したものになっているので、上記
の通りの苛酷な条件下ての切削にも(Ti、AA)N被
覆層か剥離することなく、かつ切刃に欠損が発生するこ
となく、(Ti、AA’)N被覆層のもつすぐれた耐摩
耗性を十分に発揮するのに対して、TiN被覆層の形成
かない従来被覆切削工具1〜10は、(Ti、AA)N
被覆層の基体表面に対する密着性が不十分なために、上
記の苛酷な条件での切削では、切削開始後、短時間で欠
損や剥離が生し、使用寿命に至ることが明らかである。From the results shown in Table 1, the coated cutting tools 1 to 3 of the present invention
3, the adhesion of the (Ti, Al)N coating layer to the substrate surface is significantly improved due to the interposition of the TiN layer, which is an adhesive physical vapor deposition coating layer, so it can be used under the severe conditions described above. The excellent wear resistance of the (Ti, AA')N coating layer can be fully maintained even during lower cutting without peeling off the (Ti, AA)N coating layer or causing damage to the cutting edge. In contrast, the conventional coated cutting tools 1 to 10, which do not have a TiN coating layer, have (Ti, AA)N
It is clear that because the adhesion of the coating layer to the substrate surface is insufficient, when cutting under the above-mentioned severe conditions, chipping and peeling occur within a short period of time after the start of cutting, leading to the end of the service life.
上述のように、この発明の表面被覆セラミックス製切削
工具は、これを構成する硬質の(Ti。As mentioned above, the surface-coated ceramic cutting tool of the present invention is composed of hard (Ti).
AA’)N被覆層のA 1203系セラミックス基体お
よびSi3N4系セラミックス基体の表面に対する密着
性が著しく高く、苛酷な条件下での切削にも欠損や剥離
することがないので、切削機械の高性能化にも満足して
対応することかでき、かつ実用に際してずくれた切削性
能を長期に亘って発揮するのである。The adhesion of the AA')N coating layer to the surface of the A1203 ceramic substrate and the Si3N4 ceramic substrate is extremely high, and it will not break or peel off even when cutting under severe conditions, improving the performance of cutting machines. It can satisfactorily cope with various conditions and exhibits excellent cutting performance over a long period of time in practical use.
Claims (2)
素系セラミックスからなる基体の表面に、平均層厚で0
.1〜1μmの窒化チタンからなる密着性物理蒸着被覆
層を介して、平均層厚で0.5〜5μmのTiとAlの
複合窒化物からなる耐摩耗性物理蒸着被覆層、を形成し
てなる表面被覆セラミックス製切削工具。(1) On the surface of a substrate made of aluminum oxide ceramics or silicon nitride ceramics, the average layer thickness is 0.
.. A wear-resistant physical vapor deposition coating layer made of a composite nitride of Ti and Al having an average layer thickness of 0.5 to 5 μm is formed via an adhesive physical vapor deposition coating layer made of titanium nitride with a thickness of 1 to 1 μm. Cutting tools made of surface-coated ceramics.
素系セラミックスからなる基体の表面に、平均層厚で0
.1〜1μmの窒化チタンからなる密着性物理蒸着被覆
層を介して、平均層厚で0.5〜5μmのTiとAlの
複合窒化物からなる耐摩耗性物理蒸着被覆層を形成し、
さらに、その上に同じく平均層厚で0.1〜3μmの窒
化チタンからなる耐欠損性物理蒸着被覆層、を形成して
なる表面被覆セラミックス製切削工具。(2) On the surface of the substrate made of aluminum oxide ceramics or silicon nitride ceramics, the average layer thickness is 0.
.. Forming a wear-resistant physical vapor deposition coating layer made of a composite nitride of Ti and Al with an average layer thickness of 0.5 to 5 μm via an adhesive physical vapor deposition coating layer made of titanium nitride with a thickness of 1 to 1 μm,
Furthermore, a surface-coated ceramic cutting tool is formed by forming thereon a chipping-resistant physical vapor deposition coating layer of titanium nitride having an average layer thickness of 0.1 to 3 μm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2328254A JP2993116B2 (en) | 1990-11-28 | 1990-11-28 | Surface-coated ceramic cutting tool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2328254A JP2993116B2 (en) | 1990-11-28 | 1990-11-28 | Surface-coated ceramic cutting tool |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH04201003A true JPH04201003A (en) | 1992-07-22 |
JP2993116B2 JP2993116B2 (en) | 1999-12-20 |
Family
ID=18208166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2328254A Expired - Fee Related JP2993116B2 (en) | 1990-11-28 | 1990-11-28 | Surface-coated ceramic cutting tool |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2993116B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6313054B1 (en) * | 1997-12-26 | 2001-11-06 | Ngk Spark Plug Co., Ltd. | Silicon nitride sintered body, method for manufacturing the same, and cutting insert formed of the sintered body |
EP0709353B2 (en) † | 1994-10-27 | 2007-11-28 | Sumitomo Electric Industries, Limited | Hard composite material for tools |
-
1990
- 1990-11-28 JP JP2328254A patent/JP2993116B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0709353B2 (en) † | 1994-10-27 | 2007-11-28 | Sumitomo Electric Industries, Limited | Hard composite material for tools |
US6313054B1 (en) * | 1997-12-26 | 2001-11-06 | Ngk Spark Plug Co., Ltd. | Silicon nitride sintered body, method for manufacturing the same, and cutting insert formed of the sintered body |
Also Published As
Publication number | Publication date |
---|---|
JP2993116B2 (en) | 1999-12-20 |
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