JPH06246513A - Cutting tool made of surface coating silicon-nitride group ceramics with excellent adhesion of hard coating layer - Google Patents

Cutting tool made of surface coating silicon-nitride group ceramics with excellent adhesion of hard coating layer

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Publication number
JPH06246513A
JPH06246513A JP5063431A JP6343193A JPH06246513A JP H06246513 A JPH06246513 A JP H06246513A JP 5063431 A JP5063431 A JP 5063431A JP 6343193 A JP6343193 A JP 6343193A JP H06246513 A JPH06246513 A JP H06246513A
Authority
JP
Japan
Prior art keywords
layer
hard coating
cutting
coating layer
cutting tool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP5063431A
Other languages
Japanese (ja)
Other versions
JP3087504B2 (en
Inventor
Takashi Koyama
孝 小山
Takashi Fujisawa
隆史 藤沢
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
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Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP05063431A priority Critical patent/JP3087504B2/en
Publication of JPH06246513A publication Critical patent/JPH06246513A/en
Application granted granted Critical
Publication of JP3087504B2 publication Critical patent/JP3087504B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Chemical Vapour Deposition (AREA)
  • Cutting Tools, Boring Holders, And Turrets (AREA)
  • Ceramic Products (AREA)

Abstract

PURPOSE:To provide a cutting tool made of a surface coating WC-group cemented carbide with excellent abrasion resistance and defect resistance. CONSTITUTION:On the surface of a WC-group cemented carbide base body which contains a metallic bond layer whose main components are Co and/or Ni: 5-20weight% and the rest formed of a hard layer mainly consisting of WC, a hard coating layer composed of one kind of single layer or multiple layers of two or more kinds of TiC, TiN, TiCN, TiCO, TiNO, TiCNO and Al2O3 is formed with average layer thickness of 1-15mum. The lower part on base body side of the hard coating layer is made a shot peening formed crack distributed layer.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、すぐれた耐摩耗性と
耐欠損性を有し、特に耐欠損性が要求される、例えば鋼
の高送り切削や高切込み切削などの重切削において、こ
れの高速切削に用いた場合にすぐれた耐摩耗性を発揮す
る表面被覆炭化タングステン(以下、WCで示す)基超
硬合金製切削工具に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention has excellent wear resistance and fracture resistance, and is particularly suitable for heavy cutting such as high feed cutting and high depth cutting of steel which requires fracture resistance. The present invention relates to a surface-coated tungsten carbide (hereinafter referred to as WC) based cemented carbide cutting tool that exhibits excellent wear resistance when used for high speed cutting.

【0002】[0002]

【従来の技術】従来、一般に、例えば鋼の通常条件での
連続切削や断続切削に、重量%で(以下、%は重量%を
示す)、Coおよび/またはNiを主体とする金属結合
相:5〜20%を含有し、残りがWCを主体とする硬質
相からなるWC基超硬合金基体の表面に、化学蒸着法を
用いて、Tiの炭化物、窒化物、炭窒化物、炭酸化物、
窒酸化物、および炭窒酸化物、並びに酸化アルミニウム
(以下、それぞれTiC、TiN、TiCN、TiC
O、TiNO、およびTiCNO、並びにAl2 3
示す)のうちの1種の単層または2種以上の複層からな
る硬質被覆層を1〜15μmの平均層厚で形成してなる
表面被覆WC基超硬合金製切削工具が用いられているこ
とは良く知られるところである。また、例えば特開平2
−254144号公報に記載されるように、耐欠損性を
向上させ、もって例えば鋼の高送り切削や高切込み切削
などの重切削での耐摩耗性を向上させる目的で、上記の
表面被覆WC基超硬合金製切削工具の表面にショットピ
ーニングを施して、これを構成する硬質被覆層中にクラ
ックを積極的に一様に形成してなる表面被覆WC基超硬
合金製切削工具も知られている。
2. Description of the Related Art Conventionally, for example, in continuous cutting or interrupted cutting of steel under normal conditions, a metallic binder phase mainly composed of Co and / or Ni in weight% (hereinafter,% means weight%): On the surface of a WC-based cemented carbide substrate containing 5 to 20% and the rest consisting of a hard phase mainly composed of WC, a Ti carbide, a nitride, a carbonitride, or a carbonate of Ti is formed by a chemical vapor deposition method.
Nitride oxide, carbonitride oxide, and aluminum oxide (hereinafter, TiC, TiN, TiCN, TiC, respectively)
O, TiNO, and TiCNO, and Al 2 O 3 ), a surface coating formed by forming a hard coating layer composed of one single layer or two or more multiple layers with an average layer thickness of 1 to 15 μm. It is well known that WC-based cemented carbide cutting tools are used. Also, for example, Japanese Patent Laid-Open No.
As described in JP-A-254144, for the purpose of improving fracture resistance, and thus improving wear resistance in heavy cutting such as high feed cutting and high depth cutting of steel, the above surface-coated WC group is used. A surface-coated WC-based cemented carbide cutting tool is also known in which shot peening is performed on the surface of the cemented carbide cutting tool, and cracks are positively and uniformly formed in the hard coating layer constituting the cutting tool. There is.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の切削加工
のFA化および省力化はめざましく、これに伴ない、切
削工具にも切削条件に影響を受けにくい汎用性が強く望
まれているが、上記の硬質被覆層にショットピーニング
形成クラックが一様に存在する従来表面被覆WC基超硬
合金製切削工具は、通常の条件での重切削ではすぐれた
耐摩耗性を示すものの、これを高速化した場合、摩耗進
行が著しく速くなり、比較的短時間で使用寿命に至るの
が現状である。
On the other hand, in recent years FA cutting and labor saving in cutting processing have been remarkable, and along with this, there is a strong demand for versatility of cutting tools that is not easily affected by cutting conditions. The conventional surface-coated WC-based cemented carbide cutting tool in which shot peening-forming cracks are uniformly present in the above hard coating layer has excellent wear resistance in heavy cutting under normal conditions, but has a high speed. In such a case, the progress of wear becomes extremely fast, and the service life is reached in a relatively short time.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、上記の硬質被覆層にショットピ
ーニング形成クラックが一様に分布する従来表面被覆W
C基超硬合金製切削工具のもつ問題点を解決すべく研究
を行なった結果、上記の表面被覆WC基超硬合金製切削
工具において、これを構成する硬質被覆層の基体側下方
部分に、望ましくは硬質被覆層の全層厚に対する割合で
20〜80%の層厚でショットピーニングにより形成し
たクラックを分布させてやると、この結果の表面被覆W
C基超硬合金製切削工具は、硬質被覆層における前記基
体側下方部分のショットピーニング形成クラック分布層
によってすぐれた耐欠損性が確保され、一方残りの表面
側上方部分によってすぐれた耐摩耗性が確保されること
から、耐欠損性が要求される、例えば鋼の重切削を高速
で行なっても切刃に欠損やチッピングの発生なく、摩耗
進行が著しく抑制されるようになり、長期に亘ってすぐ
れた切削性能を発揮するという研究結果を得たのであ
る。
Therefore, the present inventors have
From the viewpoint as described above, the conventional surface coating W in which the shot peening formation cracks are uniformly distributed in the hard coating layer described above.
As a result of research to solve the problems of the C-based cemented carbide cutting tool, in the above-described surface-coated WC-based cemented carbide cutting tool, the hard coating layer constituting the surface-coated lower portion of the base side is Desirably, cracks formed by shot peening are distributed in a layer thickness of 20 to 80% with respect to the total layer thickness of the hard coating layer.
In the C-based cemented carbide cutting tool, excellent fracture resistance is secured by the shot peening formation crack distribution layer in the lower portion on the substrate side of the hard coating layer, while excellent wear resistance is obtained by the remaining upper portion on the surface side. Since it is ensured that fracture resistance is required, for example, even if heavy cutting of steel is performed at high speed, the cutting edge will not be chipped or chipped, and the progress of wear will be significantly suppressed, and for a long time We obtained the research results that show excellent cutting performance.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、Coおよび/またはNiを主体
とする金属結合相:5〜20%を含有し、残りがWCを
主体とする硬質相からなるWC基超硬合金基体の表面
に、TiC、TiN、TiCN、TiCO、TiNO、
TiCNO、およびAl2 3 のうちの1種の単層また
は2種以上の複層からなる硬質被覆層を1〜15μmの
平均層厚で形成してなる表面被覆WC基超硬合金製切削
工具において、上記硬質被覆層の基体側下方部分をショ
ットピーニング形成クラック分布層とすることにより耐
摩耗性と耐欠損性の向上をはかった点に特徴を有するも
のである。
The present invention has been made based on the above-mentioned research results, and contains a metal binder phase containing Co and / or Ni as a main component: 5 to 20%, and the rest containing WC as a main component. TiC, TiN, TiCN, TiCO, TiNO, on the surface of the WC-based cemented carbide substrate composed of phases,
A surface-coated WC-based cemented carbide cutting tool formed by forming a hard coating layer consisting of one single layer or two or more multiple layers of TiCNO and Al 2 O 3 with an average layer thickness of 1 to 15 μm. In the second aspect, the lower portion of the hard coating layer on the substrate side is a shot peening formation crack distribution layer, which is characterized in that abrasion resistance and fracture resistance are improved.

【0006】なお、この発明の切削工具において、これ
を構成する基体の金属結合相の含有量を5〜20%とし
たのは、その含有量が5%未満では焼結性が低下し、基
体に十分な強度を確保することができず、一方その含有
量が20%を越えると硬さが低下し、基体自体の摩耗進
行が急激に加速されるようになるという理由によるもの
である。また、この発明の切削工具を構成する硬質被覆
層の平均層厚を1〜15μmと限定したのは、その平均
層厚が1μm未満では所望の耐摩耗性向上効果が得られ
ず、一方その平均層厚が15μmを越えると、切刃に欠
損やチッピング(微小欠け)が発生するようになるとい
う理由にもとづくものである。
In the cutting tool of the present invention, the content of the metallic binder phase in the base material constituting the cutting tool is set to 5 to 20%. If the content is less than 5%, the sinterability is lowered and the base material is However, if the content exceeds 20%, the hardness decreases, and the progress of wear of the substrate itself is rapidly accelerated. Moreover, the average layer thickness of the hard coating layer constituting the cutting tool of the present invention is limited to 1 to 15 μm because the desired wear resistance improving effect cannot be obtained when the average layer thickness is less than 1 μm, while the average value This is based on the reason that when the layer thickness exceeds 15 μm, chipping or chipping (fine chipping) occurs in the cutting edge.

【0007】[0007]

【実施例】つぎに、この発明の表面被覆WC基超硬合金
製切削工具を実施例により具体的に説明する。原料粉末
として、いずれも1〜6μmの範囲内の所定の平均粒径
を有するWC粉末、TiC粉末、TiN粉末、TaC粉
末、NbC粉末、Cr3 2 粉末、VC粉末、Co粉
末、およびNi粉末を用意し、これら原料粉末を表1に
示される配合組成に配合し、ボールミルで72時間湿式
混合した後、1ton /cm2 の圧力で圧粉体にプレス成形
し、この圧粉体を、10〜100torrの範囲内の所定の
2 分圧の窒素雰囲気中、1380〜1430℃の範囲
内の所定温度に1時間保持の条件で焼結してISO規格
SNMN432のスローアウェイチップ形状を有するW
C基超硬合金基体A〜Iを形成した。
EXAMPLES Next, the surface-coated WC-based cemented carbide of the present invention
The manufacturing tool will be specifically described by way of examples. Raw powder
As a predetermined average particle size within the range of 1 to 6 μm
WC powder, TiC powder, TiN powder, TaC powder having
Powder, NbC powder, Cr3C2Powder, VC powder, Co powder
Powder and Ni powder were prepared, and these raw material powders are shown in Table 1.
Formulated in the composition shown and wet in a ball mill for 72 hours
After mixing, 1ton / cm2Press forming into green compact with pressure
Then, apply the green compact to a predetermined amount within the range of 10 to 100 torr.
N 2Range of 1380 to 1430 ° C. in partial pressure nitrogen atmosphere
ISO standard by sintering at a predetermined temperature for 1 hour
W with throwaway tip shape of SNMN432
C-based cemented carbide substrates A to I were formed.

【0008】ついで、上記基体A〜Iの表面に、通常の
化学蒸着装置を用い、表2に※印を付した組成および平
均層厚の単層または複層の硬質被覆層を形成し、これ
に、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:60m/sec 、 投射時間:3分、 の条件でショットピーニングを施して、これをショット
ピーニング形成クラック分布層とし、引続いて、これの
上に同じく表2に示される組成および平均層厚の単層ま
たは複層の硬質被覆層を形成することにより、それぞれ
クラック分布密度は異るが、硬質被覆層の基体側下方部
分をショットピーニング形成クラック分布層とした本発
明表面被覆WC基超硬合金製切削工具(以下、本発明被
覆切削工具という)1〜13を製造した。
Then, a single or multiple hard coating layer having the composition and average layer thickness marked with "*" in Table 2 is formed on the surface of each of the substrates A to I by using a normal chemical vapor deposition apparatus. , Shot: cast iron spheres having an average particle size of 0.4 mm, shot speed: 60 m / sec, shot time: 3 minutes, and shot peening was performed as a shot peening formation crack distribution layer. Then, by forming a single-layer or multiple-layer hard coating layer having the same composition and average layer thickness as shown in Table 2 above, the crack distribution densities differ, but the lower portion of the hard coating layer on the substrate side. The surface-coated WC-based cemented carbide cutting tools of the present invention (hereinafter referred to as the present coated cutting tools) 1 to 13 were manufactured by using as a shot peening formation crack distribution layer.

【0009】また、比較の目的で、上記の基体A〜Iの
表面に、同じ化学蒸着装置を用い、上記本発明被覆切削
工具1〜13のそれぞれに対応した組成および平均層厚
の硬質被覆層を形成した後、 ショット:0.4mmの平均粒径を有する鋳鉄球、 投射速度:60m/sec 、 投射時間:3分、 の条件でショットピーニングを施して、硬質被覆層に一
様なクラック分布密度のショットピーニング形成クラッ
クを形成することにより従来表面被覆WC基超硬合金製
切削工具(以下、従来被覆切削工具という)1〜13を
それぞれ製造した。
For the purpose of comparison, the same chemical vapor deposition apparatus is used on the surfaces of the above-mentioned substrates A to I, and a hard coating layer having a composition and an average layer thickness corresponding to each of the coated cutting tools 1 to 13 of the present invention. After forming, shot: peening iron balls having an average particle size of 0.4 mm, projection speed: 60 m / sec, projection time: 3 minutes, shot peening was performed, and a uniform crack distribution in the hard coating layer. Conventional surface-coated WC-based cemented carbide cutting tools (hereinafter referred to as conventional coated cutting tools) 1 to 13 were manufactured by forming shot peening formation cracks of high density.

【0010】つぎに、この結果得られた各種の被覆切削
工具について、クラック分布密度を検討するために、そ
の硬質被覆層の縦断面を顕微鏡観察し、これの基体界面
と最表面における長さ:1mm内に存在するクラック本数
を任意5個所について目視測定した。この測定結果を平
均値として表3,4に示した。
Next, in order to examine the crack distribution density of the various coated cutting tools obtained as a result, the longitudinal section of the hard coating layer was observed under a microscope, and the lengths at the substrate interface and the outermost surface were: The number of cracks existing within 1 mm was visually measured at arbitrary 5 points. The results of this measurement are shown in Tables 3 and 4 as average values.

【0011】また、上記の各種被覆切削工具について、 被削材:SNCM439(硬さ:HB 260)の丸棒、 切削速度:230m/min 、 切込み:4mm、 送り:0.25mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み高速切削試験、並びに、 被削材:SNCM439(硬さ:HB 260)の丸棒、 切削速度:150m/min 、 切込み:4mm、 送り:0.25mm/rev.、 切削時間:30分、 の条件での鋼の連続高切込み切削試験を行ない、いずれ
の試験でも切刃の逃げ面摩耗幅を測定した。これらの測
定結果も表3,4に示した。
Regarding the above various coated cutting tools, the work material: a round bar of SNCM439 (hardness: H B 260), cutting speed: 230 m / min, depth of cut: 4 mm, feed: 0.25 mm / rev., cutting time: 30 min, continuous high cut speed cutting test of the steel under the condition of, and, workpiece: SNCM439 (hardness: H B 260) round bar, cutting speed: 150 meters / min, cut: 4 mm, feed : 0.25 mm / rev., Cutting time: 30 minutes, a continuous high cutting depth cutting test of steel was performed, and the flank wear width of the cutting edge was measured in each test. The results of these measurements are also shown in Tables 3 and 4.

【0012】[0012]

【表1】 [Table 1]

【0013】[0013]

【表2】 [Table 2]

【0014】[0014]

【表3】 [Table 3]

【0015】[0015]

【表4】 [Table 4]

【0016】[0016]

【発明の効果】表1〜4に示される結果から、いずれの
被覆切削工具も耐欠損性にすぐれているので、耐欠損性
が要求される鋼の高切込み切削試験を行なっても切削速
度が150m/min の通常の切削条件では切刃に欠損や
チッピングが発生することはないが、切削速度が230
m/min の高速切削になると硬質被覆層の基体側下方部
分だけをショットピーニング形成クラック分布層とした
本発明被覆切削工具1〜13の方が、硬質被覆層全体を
ショットピーニング形成クラック分布層とした従来被覆
切削工具1〜13に比して一段とすぐれた耐摩耗性を示
すことが明らかである。上述のように、この発明の表面
被覆WC基超硬合金製切削工具は、すぐれた耐摩耗性と
耐欠損性を有するので、特に耐欠損性が要求される、例
えば鋼の重切削に用いた場合に、これを高速切削で行な
っても摩耗進行が著しく抑制されることから、長期に亘
ってすぐれた切削性能を発揮するのである。
From the results shown in Tables 1 to 4, since all of the coated cutting tools have excellent fracture resistance, the cutting speed is high even if a high-cut cutting test for steel requiring fracture resistance is performed. Under normal cutting conditions of 150 m / min, the cutting edge will not be chipped or chipped, but the cutting speed is 230
In the case of high-speed cutting of m / min, the coated cutting tools 1 to 13 of the present invention, in which only the lower portion of the hard coating layer on the substrate side is a shot peening formation crack distribution layer, the whole hard coating layer is a shot peening formation crack distribution layer. It is obvious that the coated cutting tools 1 to 13 have excellent wear resistance. As described above, since the surface-coated WC-based cemented carbide cutting tool of the present invention has excellent wear resistance and fracture resistance, it was used for heavy cutting of steel for which fracture resistance is particularly required. In this case, even if this is performed by high-speed cutting, the progress of wear is significantly suppressed, so that excellent cutting performance is exhibited over a long period of time.

フロントページの続き (51)Int.Cl.5 識別記号 庁内整理番号 FI 技術表示箇所 // B24C 1/10 A 7411−3C Continuation of front page (51) Int.Cl. 5 Identification number Office reference number FI technical display location // B24C 1/10 A 7411-3C

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 Coおよび/またはNiを主体とする金
属結合相:5〜20重量%を含有し、残りが炭化タング
ステンを主体とする硬質相からなる炭化タングステン基
超硬合金基体の表面に、Tiの炭化物、窒化物、炭窒化
物、炭酸化物、窒酸化物、および炭窒酸化物、並びに酸
化アルミニウムのうちの1種の単層または2種以上の複
層からなる硬質被覆層を1〜15μmの平均層厚で形成
してなる表面被覆炭化タングステン基超硬合金製切削工
具において、 上記硬質被覆層の基体側下方部分を、ショットピーニン
グ形成クラック分布層としたことを特徴とする耐摩耗性
および耐欠損性のすぐれた表面被覆炭化タングステン基
超硬合金製切削工具。
1. A metal-bonded phase mainly composed of Co and / or Ni: 5 to 20% by weight, and the balance consisting of a hard phase mainly composed of tungsten carbide on the surface of a tungsten carbide-based cemented carbide substrate, 1 to 1 of a hard coating layer composed of a single layer or two or more multi-layers of Ti carbide, nitride, carbonitride, carbon oxide, oxynitride, and oxycarbonitride, and aluminum oxide. A surface-coated tungsten carbide based cemented carbide cutting tool formed with an average layer thickness of 15 μm, characterized in that the lower part of the hard coating layer on the substrate side is a shot peening formation crack distribution layer. And surface-coated tungsten carbide based cemented carbide cutting tool with excellent fracture resistance.
JP05063431A 1993-02-26 1993-02-26 Manufacturing method of surface-coated tungsten carbide based cemented carbide cutting tools with excellent wear and fracture resistance Expired - Fee Related JP3087504B2 (en)

Priority Applications (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19652872A1 (en) * 1996-12-18 1998-07-02 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
WO1999024198A1 (en) * 1997-11-06 1999-05-20 Sumitomo Electric Industries, Ltd. Coated tool of cemented carbide
JPH11158599A (en) * 1997-10-02 1999-06-15 Mtu Motoren & Turbinen Union Muenchen Gmbh Heat insulating layer and its production
US20130101365A1 (en) * 2011-05-10 2013-04-25 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
US20140227052A1 (en) * 2011-09-22 2014-08-14 Tungaloy Corporation Coated cutting tool
US20160263659A1 (en) * 2013-11-08 2016-09-15 Tungaloy Corporation Coated cutting tool

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19652872A1 (en) * 1996-12-18 1998-07-02 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
DE19652872C2 (en) * 1996-12-18 2000-07-06 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
JPH11158599A (en) * 1997-10-02 1999-06-15 Mtu Motoren & Turbinen Union Muenchen Gmbh Heat insulating layer and its production
WO1999024198A1 (en) * 1997-11-06 1999-05-20 Sumitomo Electric Industries, Ltd. Coated tool of cemented carbide
US6187421B1 (en) 1997-11-06 2001-02-13 Sumitomo Electric Industries, Ltd. Coated tool of cemented carbide
US20130101365A1 (en) * 2011-05-10 2013-04-25 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
US8945707B2 (en) * 2011-05-10 2015-02-03 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool
US20140227052A1 (en) * 2011-09-22 2014-08-14 Tungaloy Corporation Coated cutting tool
US9566649B2 (en) * 2011-09-22 2017-02-14 Tungaloy Corporation Coated cutting tool
US20160263659A1 (en) * 2013-11-08 2016-09-15 Tungaloy Corporation Coated cutting tool
US9993878B2 (en) * 2013-11-08 2018-06-12 Tungaloy Corporation Coated cutting tool

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