JPH04201002A - Cutting tool made of surface-coated thermet - Google Patents

Cutting tool made of surface-coated thermet

Info

Publication number
JPH04201002A
JPH04201002A JP32825390A JP32825390A JPH04201002A JP H04201002 A JPH04201002 A JP H04201002A JP 32825390 A JP32825390 A JP 32825390A JP 32825390 A JP32825390 A JP 32825390A JP H04201002 A JPH04201002 A JP H04201002A
Authority
JP
Japan
Prior art keywords
coating layer
cutting
vapor deposition
physical vapor
coated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32825390A
Other languages
Japanese (ja)
Other versions
JP2560541B2 (en
Inventor
Munenori Kato
加藤 宗則
Hironori Yoshimura
吉村 寛範
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP2328253A priority Critical patent/JP2560541B2/en
Publication of JPH04201002A publication Critical patent/JPH04201002A/en
Application granted granted Critical
Publication of JP2560541B2 publication Critical patent/JP2560541B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To improve airtightness by forming an anti-friction physical deposition coated layer of (Ti, Al)N, on the surface of a base made of WC-base ultra-high alloy or of TiCN-base thermet, through an airtight physical deposition coated layer made of TiN. CONSTITUTION:An airtight physical deposition coated layer of TiN of average film thickness of 0.1-1mum is formed on the surface of a base made of WC-base ultra-high alloy or of TiCN-base thermet. An anti-frictional physical deposition coated layer made of (Ti, Al)N of average film thickness of 0.5-5mum is coated and formed on the coated layer. An anti-defective physical deposition coated layer made of TiN of average film thickness of 0.1-3mum is formed, if necessary, thereupon, and a cutting tool is thus formed. The airtightness is improved, and peeling is inhibited, while anti-frictional characteristic is improved. and anti-defectiveness is also improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、炭化タングステン(以下wcて示す)超超
硬合金または炭窒化チタン(以下TiCNて示す)基サ
ーメットからなる基体の表面に、物理蒸着法にて形成さ
れた耐摩耗性のすぐれたTi とAlの複合窒化物〔以
下、(Ti゜AA’)Nで示す〕被覆層の前記基体表面
に対する密着性のすぐれた表面被覆サーメット製切削工
具に関するものである。
Detailed Description of the Invention [Industrial Field of Application] This invention provides a method for applying a physical Composite nitride of Ti and Al with excellent wear resistance formed by vapor deposition method [hereinafter referred to as (Ti゜AA')N] Surface-coated cermet cutting with excellent adhesion to the substrate surface of the coating layer It's about tools.

〔従来の技術〕[Conventional technology]

従来、例えば特開昭62−56565号公報に記載され
る通り、WCC超超硬合金高速度工具鋼なとで構成され
た基体の表面に、物理蒸着法を用いて、耐摩耗性のすく
れたTIとAlの複合窒化物〔以下、(Ti、AA’)
Nで示す〕からなる硬質被覆層を形成してなる表面被覆
切削工具が提案されている。
Conventionally, as described in, for example, JP-A-62-56565, wear-resistant undercuts have been applied to the surface of a base made of WCC cemented carbide high-speed tool steel using a physical vapor deposition method. Composite nitride of TI and Al [hereinafter referred to as (Ti, AA')]
A surface-coated cutting tool has been proposed in which a hard coating layer is formed.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

一方、近年の切削機械の高性能化はめざましく、これに
伴ない、より速い速度での切削や、より一段の高切込み
あるいは高送りなどの重切削が行なわれる状況にあるか
、このような苛酷な切削条件下では、上記の従来表面被
覆切削工具においては、(Ti、Al)N被覆層の基体
表面に対する密着性が十分てないために、これに満足に
対応することができないのが現状である。
On the other hand, the performance of cutting machines has improved dramatically in recent years, and as a result, heavy cutting such as faster cutting speeds, higher depths of cut, and higher feed rates are being carried out, and such harsh cutting conditions are becoming more difficult. Under such cutting conditions, the conventional surface-coated cutting tools described above cannot satisfactorily cope with these conditions because the adhesion of the (Ti, Al)N coating layer to the substrate surface is insufficient. be.

〔課題を解決するための手段〕[Means to solve the problem]

そこで、本発明者等は、上述のような観点から、上記の
従来表面被覆切削工具に着目し、(Ti゜Al)N被覆
層の基体表面に対する密着性を向上せしめるべく研究を
行なった結果、基体をWCC超超硬合金よびTiCN基
サーメットに特定した上で、この基体の表面に、物理蒸
着法にて形成した窒化チタン(以下TiNで示す)被覆
層を介して、上記の耐摩耗性のすぐれた(Ti、AA’
)N被覆層を形成すると、前記TiN被覆層の前記基体
および(Ti、Al )N被覆層に対する密着性が著し
く高いものであることから、苛酷な条件での切削に供し
ても(Ti、AA’)N被覆層に剥離の発生がなく、す
ぐれた切削性能を長期に亘って発揮するようになり、さ
らにこの上に同じく物理蒸着法を用いてTiNを被覆す
ると、耐欠損性が一段と向上するようになるという研究
結果を得たのである。
Therefore, from the above-mentioned viewpoint, the present inventors focused on the above-mentioned conventional surface-coated cutting tools and conducted research to improve the adhesion of the (Ti゜Al)N coating layer to the substrate surface. After specifying the base material as WCC cemented carbide or TiCN-based cermet, the above-mentioned wear-resistant material is coated on the surface of the base material with a titanium nitride (hereinafter referred to as TiN) coating layer formed by physical vapor deposition. Excellent (Ti, AA'
)N coating layer is formed, the adhesion of the TiN coating layer to the substrate and the (Ti, Al)N coating layer is extremely high. ') The N coating layer does not peel off and exhibits excellent cutting performance over a long period of time, and if TiN is coated on top using the same physical vapor deposition method, fracture resistance is further improved. The research results showed that.

この発明は、上記の研究結果にもとづいてなされたもの
であって、 WCC超超硬合金たはTiCN基サーメットからなる基
体の表面に、 平均層厚で01〜1μmのTiNからなる密着性物理蒸
着被覆層を介して、 平均層厚で05〜5μmの(Ti、Ajl’)Nからな
る耐摩耗性物理蒸着被覆層を形成し、 さらに、必要に応じて、その上に同じく平均層厚で0.
1〜3μ口のTiNからなる耐欠損性物理蒸着被覆層を
形成してなる表面被覆サーメット製切削工具に特徴を有
するものである。
This invention was made based on the above research results, and includes adhesive physical vapor deposition of TiN with an average layer thickness of 01 to 1 μm on the surface of a base made of WCC cemented carbide or TiCN-based cermet. A wear-resistant physical vapor deposition coating layer made of (Ti, Ajl')N with an average layer thickness of 0.5 to 5 μm is formed via the coating layer, and if necessary, a wear-resistant physical vapor deposition coating layer of (Ti, Ajl')N with an average layer thickness of ..
The cutting tool is characterized by a surface-coated cermet cutting tool formed by forming a chipping-resistant physical vapor deposition coating layer of TiN with a diameter of 1 to 3 μm.

つぎに、この発明の切削工具において、これを構成する
被覆層の平均層厚を上記の通りに限定した理由を説明す
る。
Next, in the cutting tool of the present invention, the reason why the average layer thickness of the coating layer constituting the cutting tool is limited as described above will be explained.

(a)  密着性物理蒸着被覆層 このTiN被覆層には、上記の通り基体および(Ti、
A7りN被覆層に対して強固に接合し、苛酷な切削条件
下でも(Ti、A7りN被覆層の剥離を防止する作用が
あるが、その平均層厚が0.1μm未満では前記作用に
所望の効果が得られず、一方その平均層厚が1μmを越
えても前記作用により一層の向上効果が得られないこと
から、経済性も考慮して、その平均層厚を01〜1μm
と定めた。
(a) Adhesive Physical Vapor Deposition Coating Layer This TiN coating layer includes a substrate and (Ti,
It firmly bonds to the A7-N coating layer and has the effect of preventing the peeling of the A7-N coating layer even under severe cutting conditions (Ti, A7-N coating layer, but if the average layer thickness is less than 0.1 μm, the above effect will not occur). The desired effect cannot be obtained, and on the other hand, even if the average layer thickness exceeds 1 μm, further improvement effects cannot be obtained due to the above action.
It was determined that

(b)  耐摩耗性物理蒸着被覆層 この(Ti、Al)N被覆層は、きわめて硬質であり、
これの形成によって耐摩耗性か著しく向上するようにな
るが、その平均層厚が05μm未満ては所望のすぐれた
耐摩耗性を確保することができず、一方その平均層厚が
5μmを越えると、チッピング(微小欠け)が発生し易
くなることから、その平均層厚を05〜5μmと定めた
(b) Abrasion-resistant physical vapor deposition coating layer This (Ti, Al)N coating layer is extremely hard;
The formation of this layer significantly improves wear resistance, but if the average layer thickness is less than 0.5 μm, the desired excellent wear resistance cannot be achieved, whereas if the average layer thickness exceeds 5 μm, Since chipping (micro-chips) is likely to occur, the average layer thickness was set at 0.5 to 5 μm.

なお、(Ti、Al)Nを組成式・ (T + XA 
l + −X ) Nて現わした場合、Xの値を025
〜095とするのがよく、これは、Xの値が025未満
になると被覆層に急激な硬さ低下が起り、十分な耐摩耗
性を得ることができなくなり、一方Xの値が0.95を
越えると高温耐酸化性が低下し、特に切刃の逃げ面摩耗
か進行するようになるという理由によるものである。
In addition, (Ti, Al)N is represented by the composition formula: (T + XA
l + −X ) N, the value of X is 025
The value of X is preferably 0.95 to 0.95, because if the value of This is because if the temperature exceeds 100%, the high-temperature oxidation resistance decreases, and especially the flank wear of the cutting edge progresses.

(c)  耐欠損性物理蒸着被覆層 最外層に形成されるTiN被覆層には切刃の耐欠損性を
改善する作用かあるので必要に応じて形成されるが、そ
の平均層厚が01μm未満では所望の耐欠損性向上効果
は得られず、一方その平均層厚が3μmを越えても耐欠
損性により一層の向上効果が現われないことから、その
平均層厚を0.1〜3μmと定めた。
(c) Fracture-resistant physical vapor deposition coating layer The TiN coating layer formed as the outermost layer has the effect of improving the fracture resistance of the cutting edge, so it is formed as necessary, but the average layer thickness is less than 0.1 μm. However, even if the average layer thickness exceeds 3 μm, the effect of further improving the fracture resistance does not appear. Therefore, the average layer thickness is set at 0.1 to 3 μm. Ta.

〔実 施 例〕〔Example〕

つぎに、この発明の表面被覆サーメット製切削工具を実
施例により具体的に説明する。
Next, the surface-coated cermet cutting tool of the present invention will be specifically explained with reference to Examples.

いずれも通常の粉末冶金法で製造され、かつそれぞれ第
1表に示される成分組成をもったWCC超超硬合金基体
よびTiCN基サーメット基体を用意し、これら基体を
、物理蒸着装置の1種であるアーク放電型イオンブレー
ティング装置の基板上に載置し、まず、 陰    極  :純Ti。
A WCC cemented carbide substrate and a TiCN-based cermet substrate, both of which are manufactured by a normal powder metallurgy method and each have the composition shown in Table 1, are prepared, and these substrates are coated with a type of physical vapor deposition equipment. First, the cathode: pure Ti was placed on the substrate of an arc discharge type ion blating device.

反応雰囲気: I XIO(or+のN2、基板印加電
圧・−400V、 陰極電流: ll0A。
Reaction atmosphere: IXIO (or+N2, substrate applied voltage -400V, cathode current: 110A.

の条件でTiNの物理蒸着を行ない、反応時間にて層厚
を調節して、それぞれ第1表に示される平均層厚の密着
性物理蒸着被覆層(TiN被覆層)を形成し、 ついで、陰極として、Al含有量を5〜75重量%の範
囲内で種々変化させた各種のTi−AA’合金を用いる
以外は同一の条件で、(Ti、Al)Nの物理蒸着を行
ない、同様に反応時間にて層厚を調整し、かつTi−A
A’合金中のAl含有量にてTiとAlの割合を変化さ
せて、それぞれ第1表に示される組成および平均層厚の
耐摩耗性物理蒸着被覆層〔(Ti、Al)N被覆層〕を
形成し、さらに必要に応して、再び陰極として純Tiを
用い、上記の条件と同し条件てTiNの物理蒸着を行な
い、それぞれ第1表に示される平均層厚の耐欠損性物理
蒸着被覆層(TiN被覆層)を形成することにより、I
SO規格S P G N 1204Hまたは同5EEN
1203G8AFTNのチップ形状をもった本発明表面
被覆サーメット製切削工具(以下本発明被覆切削工具と
いう)1〜35をそれぞれ製造した。
Physical vapor deposition of TiN was carried out under the following conditions, and the layer thickness was adjusted by the reaction time to form an adhesive physical vapor deposition coating layer (TiN coating layer) with the average layer thickness shown in Table 1. Physical vapor deposition of (Ti, Al)N was carried out under the same conditions except that various Ti-AA' alloys with varying Al contents in the range of 5 to 75% by weight were used, and the reaction was carried out in the same manner. Adjust the layer thickness with time, and Ti-A
A wear-resistant physical vapor deposition coating layer [(Ti, Al)N coating layer] with the composition and average layer thickness shown in Table 1 by changing the ratio of Ti and Al depending on the Al content in the A' alloy. If necessary, physical vapor deposition of TiN is performed again using pure Ti as a cathode under the same conditions as above to obtain defect-resistant physical vapor deposition with the average layer thickness shown in Table 1. By forming a coating layer (TiN coating layer), I
SO standard SP GN 1204H or 5EEN
Cutting tools 1 to 35 made of surface-coated cermet of the present invention (hereinafter referred to as the coated cutting tool of the present invention) each having a tip shape of 1203G8AFTN were manufactured.

また、比較の目的で、上記の密着性物理蒸着被覆層およ
び耐欠損性物理蒸着被覆層の形成を行なわない以外は、
同一の条件で同じく第1表に示される組成および平均層
厚の耐摩耗性物理蒸着被覆層((Ti、AA )N被覆
層〕だけを形成することにより従来表面被覆サーメット
製切削工具(以下従来被覆切削工具という)1〜12を
製造した。
In addition, for comparison purposes, except that the above-mentioned adhesive physical vapor deposition coating layer and chipping-resistant physical vapor deposition coating layer were not formed,
By forming only a wear-resistant physical vapor deposition coating layer ((Ti, AA)N coating layer) with the composition and average layer thickness shown in Table 1 under the same conditions, conventional 1 to 12 (referred to as coated cutting tools) were manufactured.

つぎに、この結果得られた各種の切削工具について、 A、チップ形状・S P G N 120408被削材
: SNCM439(Ni −Ct −MO鋼)の丸棒
、 切削速度:180m/min。
Next, regarding the various cutting tools obtained as a result, A. Chip shape/SPG N 120408 Work material: SNCM439 (Ni-Ct-MO steel) round bar, Cutting speed: 180 m/min.

送   リ + 0.4mm/ +ev、、切込み:2
vm。
Feed +0.4mm/+ev,, depth of cut: 2
vm.

切削時間:20分、 の条件(切削条件Aという)での鋼の高送り湿式%式% 切込み3InI111 の条件(切削条件Bという)での鋼の高送り乾式正面フ
ライス切削試験、 C,チップ形状・S P G N !20408、被削
材 Fe12(鋳鉄)の丸棒、 切削速度 280 m / m i n、送   リ:
 0.35mm/ +ev、 。
Cutting time: 20 minutes, High feed dry face milling test of steel under conditions (referred to as cutting conditions A), High feed dry type face milling test of steel under conditions of depth of cut 3InI111 (referred to as cutting conditions B), C, Chip shape・SPGN! 20408, Work material: Fe12 (cast iron) round bar, Cutting speed: 280 m/min, Feed rate:
0.35mm/+ev, .

切込み21+1111゜ 切削時間=60分、 の条件(切削条件Cという)での鋳鉄の高速乾式%式% D、チップ形状・S P G N 120408被削材
:5S41の丸棒、 切削速度:210m/min、 送     リ   0. 3mm/ +ev、。
Depth of cut 21 + 1111°, cutting time = 60 minutes, high-speed dry % formula for cast iron under the following conditions (referred to as cutting conditions C): D, chip shape/SP GN 120408 Work material: 5S41 round bar, cutting speed: 210 m/ min, sending 0. 3mm/+ev.

切込み・3.5mm。Depth of cut: 3.5mm.

切削時間、100分、 の条件(切削条件りという)での鋼の高切込み乾式連続
切削試験、 E、チップ形状: S P G N 120408、被
削材・円筒状支持台の長さ方向両側2ケ所に取付けた断
面扇形のS N−CM 439製角材、切削速度 14
0m/min、 送   リ ・0,3祁/+ev、。
Cutting time: 100 minutes, high depth of cut dry continuous cutting test on steel under the conditions (referred to as cutting conditions), E, Chip shape: SP GN 120408, Work material/Both sides in the length direction of the cylindrical support base 2 S N-CM 439 square timber with fan-shaped cross section attached at two points, cutting speed 14
0m/min, feed re-0.3m/+ev.

切込み・3mm。Depth of cut: 3mm.

切削時間 10分、 の条件(切削条件Eという)での鋼の高切込み乾式連続
切削試験、 以上A−Hの苛酷な条件での切削試験のうちの少なくと
もいずれかの切削試験を行ない、切削条件A、  C,
およびDでは切刃の逃げ面摩耗幅とすくい面摩耗深さ(
切削条件Cては省略)を測定し、さらに切削条件Bでは
切刃の逃げ面摩耗幅が0.30に至るまでの切削時間、
切削条件Eでは20個の試験切刃のうちの欠は発生数を
それぞれ測定した。
Cutting time: 10 minutes, high depth of cut dry continuous cutting test on steel under the conditions (referred to as cutting conditions E), and cutting tests under severe conditions A-H. A, C,
and D, the width of flank wear of the cutting edge and the wear depth of the rake face (
Furthermore, under cutting condition B, the cutting time until the flank wear width of the cutting edge reached 0.30,
Under cutting condition E, the number of chips that occurred among the 20 test cutting edges was measured.

これらの測定結果を第1表に示した。The results of these measurements are shown in Table 1.

〔発明の効果〕〔Effect of the invention〕

第1表に示される結果から、本発明被覆切削工具1〜3
5は、いずれも密着性物理蒸着被覆層であるTiN層の
介在によって(Ti、AA’)N被覆層の基体表面に対
する密着性が著しく向上したものになっているので、上
記の通りの苛酷な条件下での切削にも(Ti、AA’)
N被覆層が剥離することなく、(Ti、Al )N被覆
層のもつすぐれた耐摩耗性を十分に発揮するのに対して
、TiN被覆層の形成がない従来被覆切削工具1〜12
は、(Ti。
From the results shown in Table 1, the coated cutting tools 1 to 3 of the present invention
5, the adhesion of the (Ti, AA')N coating layer to the substrate surface is significantly improved due to the presence of the TiN layer, which is an adhesive physical vapor deposition coating layer, and therefore Also suitable for cutting under conditions (Ti, AA')
While the N coating layer does not peel off and fully exhibits the excellent wear resistance of the (Ti, Al)N coating layer, conventional coated cutting tools 1 to 12 without the formation of a TiN coating layer
(Ti.

Al)N被覆層の基体表面に対する密着性が不十分なた
めに、上記の苛酷な条件での切削では、切削開始後、短
時間で剥離か生し、使用寿命に至ることが明らかです。
It is clear that due to insufficient adhesion of the Al)N coating layer to the substrate surface, when cutting under the above harsh conditions, it will peel off within a short time after cutting starts, and the service life will be reached.

上述のように、この発明の表面被覆サーメット製切削工
具は、これを構成する硬質の(Ti、Al)N被覆層の
WCC超超硬合金基体よびTiCN基サーメット基体の
表面に対する密着性が著しく高く、苛酷な条件下での切
削にも剥離することかないので、切削機械の高性能化に
も満足して対応することができ、かつ実用に際してすぐ
れた切削性能を長期に亘って発揮するのである。
As mentioned above, the surface-coated cermet cutting tool of the present invention has extremely high adhesion of the hard (Ti, Al)N coating layer constituting the tool to the surfaces of the WCC cemented carbide substrate and the TiCN-based cermet substrate. Since it does not peel off even when cutting under severe conditions, it can satisfactorily respond to higher performance cutting machines and exhibits excellent cutting performance over a long period of time in practical use.

Claims (2)

【特許請求の範囲】[Claims] (1)炭化タングステン基超硬合金または炭窒化チタン
基サーメットからなる基体の表面に、 平均層厚で0.1〜1μmの窒化チタンからなる密着性
物理蒸着被覆層を介して、 平均層厚で0.5〜5μmのTiとAlの複合窒化物か
らなる耐摩耗性物理蒸着被覆層、 を形成してなる表面被覆サーメット製切削工具。
(1) On the surface of a substrate made of tungsten carbide-based cemented carbide or titanium carbonitride-based cermet, an adhesive physical vapor deposition coating layer made of titanium nitride with an average layer thickness of 0.1 to 1 μm is applied. A surface-coated cermet cutting tool formed with a wear-resistant physical vapor deposition coating layer of 0.5 to 5 μm of composite nitride of Ti and Al.
(2)炭化タングステン基超硬合金または炭窒化チタン
基サーメットからなる基体の表面に、 平均層厚で0.1〜1μmの窒化チタンからなる密着性
物理蒸着被覆層を介して、 平均層厚で0.5〜5μmのTiとAlの複合窒化物か
らなる耐摩耗性物理蒸着被覆層を形成し、さらに、その
上に同じく平均層厚で0.1〜3μmの窒化チタンから
なる耐欠損性物理蒸着被覆層、を形成してなる表面被覆
サーメット製切削工具。
(2) On the surface of a substrate made of tungsten carbide-based cemented carbide or titanium carbonitride-based cermet, an adhesive physical vapor deposition coating layer made of titanium nitride with an average layer thickness of 0.1 to 1 μm is applied. A wear-resistant physical vapor deposition coating layer made of composite nitride of Ti and Al with a thickness of 0.5 to 5 μm is formed, and a chipping-resistant physical coating layer made of titanium nitride with an average layer thickness of 0.1 to 3 μm is further formed thereon. A surface-coated cermet cutting tool formed with a vapor-deposited coating layer.
JP2328253A 1990-11-28 1990-11-28 Surface coated cermet cutting tool Expired - Lifetime JP2560541B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2328253A JP2560541B2 (en) 1990-11-28 1990-11-28 Surface coated cermet cutting tool

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2328253A JP2560541B2 (en) 1990-11-28 1990-11-28 Surface coated cermet cutting tool

Publications (2)

Publication Number Publication Date
JPH04201002A true JPH04201002A (en) 1992-07-22
JP2560541B2 JP2560541B2 (en) 1996-12-04

Family

ID=18208154

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2328253A Expired - Lifetime JP2560541B2 (en) 1990-11-28 1990-11-28 Surface coated cermet cutting tool

Country Status (1)

Country Link
JP (1) JP2560541B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007031779A (en) * 2005-07-27 2007-02-08 Tungaloy Corp Film-coated sintered alloy

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4966513A (en) * 1972-08-18 1974-06-27
JPH0317251A (en) * 1989-06-14 1991-01-25 Kobe Steel Ltd Wear resistant film
JPH03120352A (en) * 1989-09-29 1991-05-22 Sumitomo Electric Ind Ltd Surface coated super hard member for cutting or wear resistant tool

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4966513A (en) * 1972-08-18 1974-06-27
JPH0317251A (en) * 1989-06-14 1991-01-25 Kobe Steel Ltd Wear resistant film
JPH03120352A (en) * 1989-09-29 1991-05-22 Sumitomo Electric Ind Ltd Surface coated super hard member for cutting or wear resistant tool

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007031779A (en) * 2005-07-27 2007-02-08 Tungaloy Corp Film-coated sintered alloy

Also Published As

Publication number Publication date
JP2560541B2 (en) 1996-12-04

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