JPH04143558A - Adsorption heat exchanger and manufacture thereof - Google Patents
Adsorption heat exchanger and manufacture thereofInfo
- Publication number
- JPH04143558A JPH04143558A JP26558490A JP26558490A JPH04143558A JP H04143558 A JPH04143558 A JP H04143558A JP 26558490 A JP26558490 A JP 26558490A JP 26558490 A JP26558490 A JP 26558490A JP H04143558 A JPH04143558 A JP H04143558A
- Authority
- JP
- Japan
- Prior art keywords
- heat transfer
- adsorbent
- heat
- adsorption
- heat exchanger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000001179 sorption measurement Methods 0.000 title claims description 76
- 239000003463 adsorbent Substances 0.000 claims abstract description 86
- 238000005245 sintering Methods 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 13
- 238000011049 filling Methods 0.000 claims description 4
- 239000004020 conductor Substances 0.000 claims description 3
- 230000002093 peripheral effect Effects 0.000 claims 2
- 238000000465 moulding Methods 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000010438 heat treatment Methods 0.000 description 12
- 238000001816 cooling Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 230000008929 regeneration Effects 0.000 description 8
- 238000011069 regeneration method Methods 0.000 description 8
- 238000004378 air conditioning Methods 0.000 description 5
- 230000001737 promoting effect Effects 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000012809 cooling fluid Substances 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 230000008016 vaporization Effects 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Landscapes
- Sorption Type Refrigeration Machines (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本願発明は液相と気相の間で相変化する熱媒の脱着を通
じて熱交換作用を行う吸着熱交換器並びにその製造方法
に関するものである。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to an adsorption heat exchanger that performs heat exchange through desorption of a heat medium that changes phase between a liquid phase and a gas phase, and a method for manufacturing the same. .
第８図には、このような吸着熱交換器を組込んだシステ
ムの一例が示されている。FIG. 8 shows an example of a system incorporating such an adsorption heat exchanger.
このシステムは空調用のもので、特開昭６２−９１７６
３号公報に記載されているものである。以下、吸着熱交
換器の作用をこの第８図のシステム例を参照しながら説
明すると、吸着熱交換器は、液相と気相の間で相変化す
る熱媒（冷媒）を有する雰囲気１０中に設置され、該吸
着熱交換器を構成する吸着熱交換エレメント中の吸着剤
か当該熱媒９蒸気Ｃを吸着又は放出することによってそ
の機能を果すものである。This system is for air conditioning and is published in Japanese Patent Publication No. 62-9176.
This is described in Publication No. 3. Hereinafter, the operation of the adsorption heat exchanger will be explained with reference to the system example shown in FIG. 8. The adsorbent in the adsorption heat exchange element constituting the adsorption heat exchanger performs its function by adsorbing or releasing the heat medium 9 vapor C.
すなわち、上記吸着熱交換器中の吸着剤は、これを冷却
することによって上記熱媒蒸気Ｃを吸着しく但し飽和状
態となるまで）、加熱することによって同熱媒蒸気Ｃを
放出する（吸着剤の再生）。That is, the adsorbent in the adsorption heat exchanger adsorbs the heat medium vapor C by cooling it (until it becomes saturated), and releases the heat medium vapor C by heating it (the adsorbent (playback).
この熱媒蒸気Ｃの吸着時に該熱媒の蒸発作用が生じ、そ
の蒸発潜熱により、当該熱媒が付着していた同雰囲気１
０中の他系統の熱交換器（利用側熱交換エレメント）２
を冷却する。吸着剤に熱媒蒸気Ｃの吸着作用を生じさせ
るには吸着熱交換エレメント１中の伝熱管に冷水等の冷
却用流体を流通させ、これに対して吸着剤から熱媒を放
出させる（吸着剤の再生）には同伝熱管にホイラ廃水あ
るいは太陽軌温水等の比較的低温の再生用流体を流通さ
せる。At the time of adsorption of this heating medium vapor C, an evaporation effect of the heating medium occurs, and due to the latent heat of vaporization, the same atmosphere 1 to which the heating medium was attached
Heat exchanger of other system in 0 (user side heat exchange element) 2
to cool down. In order to cause the adsorbent to adsorb heat medium vapor C, a cooling fluid such as cold water is passed through the heat transfer tube in the adsorption heat exchange element 1, and the heat medium is released from the adsorbent. (regeneration), a relatively low-temperature regeneration fluid such as Hoira wastewater or solar orbit hot water is passed through the heat exchanger tube.
これを第８図のノステム例についていえば、同図におい
て符号２６はホイラ廃水槽や太陽軌温水器等の比較的低
温の加熱用流体を供給する加熱用軌源体て之り、２７は
クーリングタワー等の冷却用熱源体である。又、符号２
８は利用側熱交換エレメント２て冷却生成された冷水を
貯えておく１こめの冷水貯槽、３４は冷水貯槽２８内の
冷水を利用して冷房を行わしめるための空調用の熱交換
器である。Referring to the Nostem example shown in Fig. 8, in the same figure, numeral 26 is a heating orbital source body that supplies relatively low-temperature heating fluid such as a houla wastewater tank or a solar orbital water heater, and 27 is a cooling tower. It is a heat source for cooling. Also, code 2
Reference numeral 8 designates a cold water storage tank for storing the cold water generated by cooling the user-side heat exchange element 2, and 34 designates an air conditioning heat exchanger for performing cooling using the cold water in the cold water storage tank 28. .
先ず、上記システムにおいて、吸着熱交換エレメントｌ
が熱媒蒸気を吸着する吸着行程について説明すると、こ
の場合は、バルブＶ 、、Ｖ 、の切替により吸着熱交
換エレメント１用の配管し１をクーリングタワー２７側
配管Ｌ ２７に接続させる。又、利用側熱交換エレメン
ト２用の配管り、はバルブＶ３．Ｖ、の切替によりこれ
を冷水貯１１Ｆ２８側の配管Ｌ ２Ｂに接続させる。そ
してクーリンクタワー２７及び配管Ｌ２７中のポンプＰ
、７、配管Ｌ ２ｇ中のポンプＰ２１１を運転すると、
吸着熱交換エレメントｌｌには実線矢印Ａで示すように
クーリンクタワ２７から冷却用流体が供給される。この
冷却用流体は、吸着熱交換エレメント１．１に供給され
、該吸着熱交換エレメント１．１中の吸着剤を冷却する
。First, in the above system, the adsorption heat exchange element l
In this case, the pipe 1 for the adsorption heat exchange element 1 is connected to the cooling tower 27 side pipe L 27 by switching the valves V 1 , , V 2 . Also, the piping for the heat exchange element 2 on the user side is valve V3. By switching V, this is connected to the pipe L2B on the cold water storage 11F28 side. And pump P in cooling link tower 27 and piping L27
, 7. When pump P211 in pipe L 2g is operated,
Cooling fluid is supplied from the cooling tower 27 to the adsorption heat exchange element 11 as indicated by the solid arrow A. This cooling fluid is supplied to the adsorption heat exchange element 1.1 and cools the adsorbent in the adsorption heat exchange element 1.1.
吸着剤の温度か低下すると、該吸着剤は雰囲気１０中に
充満している熱媒の蒸気Ｃを吸着する。When the temperature of the adsorbent decreases, the adsorbent adsorbs the vapor C of the heating medium filling the atmosphere 10.
そして該熱媒蒸気Ｃの連続的吸着作用により雰囲気１０
中の蒸気圧力が低下すると、次は利用側熱交換エレメン
ト２の表面に付着している液状の熱媒か気化するように
なり、その気化熱により利用側熱交換エレメント２を冷
却する。そのようにして冷却された利用側熱交換エレメ
ント２に対して実線矢印Ｂで示すように、ポンプＰ２８
により冷水貯槽２８内の水Ｗを供給すれば該水Ｗは冷却
されて冷水となって冷水貯槽２８に蓄積される。そして
ポンプＰ３４を運転してこの冷水を空調用熱交換器３４
に供給すれば冷房熱源とすることかできる。Then, due to the continuous adsorption action of the heat medium vapor C, the atmosphere 10
When the pressure of the steam inside decreases, the liquid heat medium adhering to the surface of the heat exchange element 2 on the user side begins to vaporize, and the heat of vaporization cools the heat exchange element 2 on the user side. As shown by the solid line arrow B, the pump P28
When the water W in the cold water storage tank 28 is supplied, the water W is cooled to become cold water and stored in the cold water storage tank 28. Then, the pump P34 is operated to transfer this cold water to the air conditioning heat exchanger 34.
It can be used as a heat source for air conditioning.
このようにして一定時間吸着熱交換エレメント１．１を
冷却するとやがて吸着剤が飽和状態に達し熱媒蒸気の吸
着作用か鈍化又は停止するので、次には吸着熱交換エレ
メント１の吸着剤がら熱媒蒸気を放出させるための再生
行程に転換させる。When the adsorption heat exchange element 1.1 is cooled for a certain period of time in this way, the adsorbent will eventually reach a saturated state and the adsorption effect of the heat medium vapor will slow down or stop. The process is changed to a regeneration process to release the medium vapor.
吸着熱交換エレメント１の吸着剤を再生する場合には、
バルブＶ、、Ｖ、を切替えて吸着熱交換エレメント１用
の配管し１を熱源体２６側の配管し。When regenerating the adsorbent of adsorption heat exchange element 1,
Switch the valves V, , V, and connect the piping for the adsorption heat exchange element 1, and connect the piping 1 to the heat source 26 side.
８に接続させ、さらにバルブＶ３．Ｖ４を切替えて利用
側熱交換エレメント２側の配管し、をクーリングタワー
２７の配管り３．に接続させる。8 and further connect valve V3. Switch V4 and connect the piping to the heat exchange element 2 on the user side, and connect the piping to the cooling tower 27.3. Connect to.
上記のような配管の接続状態において配管Ｌ ｗｅ中の
ポンプＰｔｅ及び配管Ｌ２．中のポンプＰｔ７を運転す
ると、吸着熱交換エレメントｌには破線矢印Ｃて示すよ
うに熱源体２６から加熱用流体が供給される。この加熱
用流体により吸着熱交換エレメント１．１の吸着剤が加
熱されると、吸着剤中に吸着されている熱媒か分離放出
され、雰囲気１０中における熱媒蒸気Ｃの濃度か高くな
る。In the connection state of the pipes as described above, the pump Pte in the pipe Lwe and the pipe L2. When the pump Pt7 inside is operated, heating fluid is supplied from the heat source 26 to the adsorption heat exchange element 1 as shown by the broken arrow C. When the adsorbent of the adsorption heat exchange element 1.1 is heated by this heating fluid, the heating medium adsorbed in the adsorbent is separated and released, and the concentration of the heating medium vapor C in the atmosphere 10 increases.
方、ポツプＰ２１の運転により利用側熱交換エレメント
２には破線矢印りて示すようにクーリンクタワー２７か
ら冷却用の流体か供給され、これによって利用側熱交換
エレメント２が冷却されることにより雰囲気ＩＯ中の熱
媒蒸気Ｃは凝縮液化して利用側熱交換エレメント２の表
面に付着する。On the other hand, due to the operation of the pop P21, cooling fluid is supplied from the cooling link tower 27 to the heat exchange element 2 on the user side as shown by the broken line arrow, and as a result, the heat exchange element 2 on the user side is cooled, thereby reducing the atmosphere. The heat medium vapor C in the IO is condensed and liquefied, and adheres to the surface of the utilization side heat exchange element 2.
この吸着熱交換エレメント１からの熱媒の放出（吸着剤
の再生）は、該吸着剤からの鴫媒の放出速度が鈍化する
かあるいは停止状態となるに及んで中止され、次の吸着
行程に切替えられる。なお、この再生行程の間は冷水貯
槽２８用の配管し２＠中にあるポンプＰ２８は休止して
いるが、冷水貯槽２８には必要量の冷水が貯留されてい
るので空調用熱交換器３４への冷水供給は中断すること
なく継続することができる。The release of the heat medium from the adsorption heat exchange element 1 (regeneration of the adsorbent) is stopped when the release rate of the adsorbent from the adsorbent slows down or comes to a halt, and the next adsorption process is started. Can be switched. Note that during this regeneration process, the pump P28 in the piping 2 for the cold water storage tank 28 is inactive, but since the necessary amount of cold water is stored in the cold water storage tank 28, the air conditioning heat exchanger 34 The cold water supply to can continue without interruption.
以上のような吸着行程及び再生行程を交互に繰返すこと
により、比較的低温の加熱用熱媒を利用した冷凍運転を
行うことができるものである。By alternately repeating the adsorption process and the regeneration process as described above, it is possible to perform a refrigeration operation using a relatively low-temperature heating medium.
（従来の技術）
ところで、この種の吸着熱交換器の従来例としてはたと
えば第９図（前述の特開昭６２−９１７６３号公報の第
３図）に記載される如きものがある。(Prior Art) By the way, as a conventional example of this type of adsorption heat exchanger, there is one as shown in FIG. 9 (FIG. 3 of the above-mentioned Japanese Patent Laid-Open No. 62-91763).
この従来例のものは、伝熱管５１に一定の間隔てフィン
５２を装着した伝熱芯管の各フィン５２５２・・の間に
粒状の吸着剤５３を詰め込み、その外側を金網５４で被
覆して構成されている。In this conventional example, granular adsorbent 53 is packed between each fin 5252 of a heat transfer core tube in which fins 52 are attached to a heat transfer tube 51 at regular intervals, and the outside thereof is covered with a wire mesh 54. It is configured.
（発明か解決しようとする課題）
ところか、上記の従来構造の吸着熱交換器の如く、単に
粒状の吸着剤５３を詰め込んだものでは、伝熱管５１又
はフィン５２と吸着剤５３との間の接触が悪いことから
、この部分での接触熱抵抗の増加により十分な伝熱性能
か得られないという問題がある。又、その結果として、
吸着剤からの熱除去性能も劣り、該吸着剤の吸着及び再
生作用か不十分であるという問題をも有している。(Problem to be solved by the invention) However, in an adsorption heat exchanger of the above-mentioned conventional structure, which is simply filled with granular adsorbent 53, the gap between the heat transfer tubes 51 or fins 52 and the adsorbent 53 is Since the contact is poor, there is a problem in that sufficient heat transfer performance cannot be obtained due to an increase in contact thermal resistance at this portion. Also, as a result,
There are also problems in that the heat removal performance from the adsorbent is poor and the adsorption and regeneration effects of the adsorbent are insufficient.
さらに、熱交換器においては、複数の伝熱管を組み合わ
せて一つの熱交換ユニットを構成するのが通例であるか
、その場合に各伝熱管か上記従来例の如き構成であると
、熱交換器全体としてみた場合に上記問題点はより顕著
となるに止どまらず、各伝熱管にそれぞれ個別に吸着剤
５３を詰ぬ込まなければならないことからその作業性か
低劣となり、また各伝熱管の組付状態においては該各伝
軌管５１のフィン５２相互間か非連続となり十分な伝熱
面積か確保しに＜シ）等の新たな問題か生しることにも
なる。Furthermore, in a heat exchanger, it is customary to combine a plurality of heat exchanger tubes to form one heat exchange unit, and in that case, if each heat exchanger tube has a configuration like the above conventional example, the heat exchanger When viewed as a whole, the above-mentioned problems not only become more prominent, but also the workability is poor because each heat exchanger tube must be filled with adsorbent 53 individually, and each heat exchanger tube In the assembled state, the fins 52 of each of the transmission tubes 51 become discontinuous, leading to new problems such as difficulty in ensuring a sufficient heat transfer area.
そこで本願発明では、複数の伝熱管及びこれらに跨って
設けられる伝熱フィンの周囲に吸着剤を充填し且つこれ
を焼結成形して一体化するという独特な方法を採用する
ことにより、熱交換性能に優れ且つ製造時における作業
性の良好な吸着熱交換器及びその製造方法を提案せんと
してなされたものである。Therefore, in the present invention, by adopting a unique method of filling an adsorbent around a plurality of heat transfer tubes and heat transfer fins provided across these, and sintering and forming the adsorbent into one piece, heat exchange can be achieved. This paper was made with the aim of proposing an adsorption heat exchanger with excellent performance and good workability during manufacture, and a method for manufacturing the same.
（課題を解決するための手段）
本願発明は、従来の吸着熱交換器における上記の如き事
情に鑑み、その問題点を改善しようとしてなされたもの
で、
（１）請求項１記載の発明は、第１図〜第７図に例示す
るように、複数の伝熱管＋ １．１１．・・に跨がるよ
うにしてその外周面に伝熱フィン１２１２、・・を取り
付けるとともに、該各伝熱管１１、＋ １．・・と各伝
熱フィン＋ ２．１２．・・の周囲を、吸着剤を焼結成
形してなる吸着剤成形体１３によって伝熱接触可能に被
包して一体的に構成したことを特徴とし、
（ｎ） 請求項２記載の発明は、第１図〜第７図に例
示するように、請求項１記載の吸着熱交換器において、
各伝熱フィン＋ ２．１２．・・を網状フィン又は針状
フィン又はコイル状フィンで構成したことを特徴とし、
（ＩＩＩ） 請求項３記載の発明は、請求項１又は２
記載の吸着熱交換器において、吸着剤中に、伝熱性材質
からなる伝熱促進材を混入せしめたことを特徴とし、
（ＩＶ） 請求項４記載の発明は、吸着熱交換器の製
造に際して、複数の伝熱管１１．１１．・・に跨がるよ
うにしてその外周面に伝熱フィン＋ ２．１２・・を取
り付けてなる伝熱ユニット１０の周囲に、スラリー状の
吸着剤を充填し、然る後、該スラリー状吸着剤を焼結成
形することにより上記伝粍ユニノ）１０の周囲を吸着剤
成形体１３によって体的に被包するよにしたことを特徴
とする。(Means for Solving the Problems) The present invention has been made in view of the above-mentioned circumstances in conventional adsorption heat exchangers, and has been made in an attempt to improve the problems. (1) The invention as claimed in claim 1, As illustrated in FIGS. 1 to 7, a plurality of heat exchanger tubes + 1.11. The heat transfer fins 1212,... are attached to the outer circumferential surface of each heat transfer tube 11, +1. ...and each heat transfer fin + 2.12. (n) The invention according to claim 2 is characterized in that the periphery of the adsorbent is integrally surrounded by an adsorbent molded body 13 formed by sintering an adsorbent so as to be able to contact with heat transfer. , As illustrated in FIGS. 1 to 7, in the adsorption heat exchanger according to claim 1,
Each heat transfer fin + 2.12. (III) The invention according to claim 3 is characterized in that it is composed of net-like fins, needle-like fins, or coil-like fins.
The adsorption heat exchanger described above is characterized in that a heat transfer accelerator made of a heat conductive material is mixed into the adsorbent; Multiple heat transfer tubes 11.11. A slurry-like adsorbent is filled around the heat transfer unit 10, which has heat transfer fins +2. It is characterized in that the adsorbent is sintered and formed so that the periphery of the above-mentioned transfer unit 10 is physically covered with the adsorbent molded body 13.
（作 用）
（１）請求項１及び２記載の吸着熱交換器では、吸着剤
を、複数の伝熱管＋ １．１１．・・及びこれらに跨っ
て設けらねた伝熱フィン１２＋２．・・の周囲に充填せ
しめた状態でこれを焼結成形して吸着剤成形体１３を構
成しているにめ、吸着剤と各伝熱管１１．＋１．・・あ
るいは吸着剤と伝熱フィン＋２ １２ ・・との間の
伝熱性に優れており、したがって、吸着剤成形体１３の
冷却又は加熱が速やかに行われ、該吸着剤成形体１３へ
の熱媒蒸気の吸着又は吸着剤成形体１３からの熱媒の放
出（吸着剤の再生）時間が短縮される。(Function) (1) In the adsorption heat exchanger according to claims 1 and 2, the adsorbent is combined with a plurality of heat exchanger tubes + 1.11. ...and heat transfer fins 12+2 provided across these. The adsorbent molded body 13 is constructed by sintering and sintering the periphery of the adsorbent and each heat transfer tube 11. +1. ...or the heat transfer between the adsorbent and the heat transfer fins is excellent, so that the adsorbent molded body 13 is quickly cooled or heated, and the heat transfer to the adsorbent molded body 13 is excellent. The time for adsorption of the medium vapor or release of the heat medium from the adsorbent molded body 13 (regeneration of the adsorbent) is shortened.
（ｌ］） さらに、請求項３記載の吸着熱交換器では
、上記（））記載の作用に加えて、吸着剤成形体１３を
構成する吸着剤中に伝熱促進材が混入されてし）るため
、該伝熱促進材による伝熱促進作用により、吸着剤成形
体１３の冷却又は加熱かより一層速やかに行なわれる。(l]) Furthermore, in the adsorption heat exchanger according to claim 3, in addition to the effect described in ()) above, a heat transfer accelerator is mixed into the adsorbent constituting the adsorbent molded body 13). Therefore, the adsorbent molded body 13 is cooled or heated more quickly due to the heat transfer promoting effect of the heat transfer promoting material.
（ｉｉｉ） また、請求項４記載の吸着熱交換器の製
造方法においては、予しめスラリー状とした吸着剤を複
数の伝熱ｉ＋ ＋、＋ １．・・及びこれらに跨ってそ
の外周面に設けられた伝熱フィンｌ ２，１２・・の周
囲に充填し、この状態で該吸着剤を焼結成形して吸着剤
成形体１３を得るものである１こめ、該吸着剤と伝熱管
＋ １．１１．・・及び伝熱フィン１２．１２．・・と
の間の密着性か向上し、ニア′″、ら相互間の接触軌抵
抗が可及的に減少する。(iii) In the method for manufacturing an adsorption heat exchanger according to claim 4, the adsorbent, which has been made into a slurry in advance, is used for a plurality of heat transfers i+ +, +1. ... and the heat transfer fins 12, 12, which are provided on the outer circumferential surface of the adsorbent straddling these, are filled, and the adsorbent is sintered in this state to obtain the adsorbent molded body 13. For a certain reason, the adsorbent and heat transfer tube + 1.11. ...and heat transfer fins 12.12. ... is improved, and the contact resistance between the near ′'' and the near ′'' is reduced as much as possible.
（発明の効果）
従って、請求項１又は２記載の吸着熱交換器によれば、
■吸着剤と各伝熱管１１．１１．・・及び各フィン・］
２．１２．・・相互間の接触熱抵抗が可及的に低減さ
れることから、該吸着剤に対する熱媒の脱着が速やかに
行われ、その結果、熱交換効率のより一層の向上が図れ
る、
■このように熱交換効率か向上する結果、吸着熱交換器
のより一層の小型化が促進される。(Effect of the invention) Therefore, according to the adsorption heat exchanger according to claim 1 or 2, (1) the adsorbent and each heat exchanger tube 11.11. ...and each fin]
2.12. ...Since the contact thermal resistance between them is reduced as much as possible, the heat medium can be quickly desorbed from the adsorbent, and as a result, the heat exchange efficiency can be further improved. As a result of the improved heat exchange efficiency, further downsizing of the adsorption heat exchanger is promoted.
■各フィンｌ ２．１２．・・か各伝熱管１１．１１・
・相互間に跨って配置されていることから、例えば上掲
公知例の如き構成の伝熱管を複数本配置する場合に比し
て、伝熱面積の確保か容易であり、より高い伝熱性能か
得らイする、
■複数の伝熱管ＩＩ、１１．・・と複数のフィン１２、
＋ ２．・・とか焼結成形された比較的強度の高い吸着
剤によって被包されることにより一体化（ユニット化）
されているため、熱交換器の製作に際しては、この複数
の伝熱管１１．１１．・・か一体化されたユニットを順
次積層配置することにより伝熱管を一度に複数本つつ組
付けることかでき、例えば従来構造のような単体構成の
伝熱管を順次−本づつ組付けるような場合に比して、熱
交換器製作上における作業性が向上せしめられる、等の
効果か得られる。■Each fin 2.12. ...or each heat transfer tube 11.11.
-Since they are arranged across each other, it is easier to secure the heat transfer area and higher heat transfer performance compared to, for example, the case where multiple heat transfer tubes are arranged as in the above-mentioned known example. ■Multiple heat exchanger tubes II, 11. ... and a plurality of fins 12,
+2.・It is integrated by being encapsulated by a relatively strong adsorbent formed by sintering (unitization).
Therefore, when manufacturing a heat exchanger, the plurality of heat exchanger tubes 11.11. ...By sequentially stacking integrated units, it is possible to assemble multiple heat exchanger tubes at once; for example, when heat exchanger tubes with a single structure like the conventional structure are assembled one after another. Compared to the above, effects such as improved workability in manufacturing the heat exchanger can be obtained.
又、請求項３記載の吸着熱交換器では、上記各効果に加
えて、伝熱促進材の伝熱促進作用により、熱交換効率の
より一層の向上か図れるという効果か得られる。In addition to the above-mentioned effects, the adsorption heat exchanger according to the third aspect of the present invention has the effect that the heat exchange efficiency can be further improved due to the heat transfer promoting action of the heat transfer promoting material.
さらに、請求項４記載の吸着熱交換器の製造方法によれ
ば、複数の伝熱管］ １．１１．・・及びこれら相互間
に跨って配置される伝熱フィン１２１２、・・と吸着剤
成形体１３の吸着剤との間の密着性の向上を、より簡易
な方法でしかも確実に実現することかできるものであり
、低コス）・でしかも熱交換性能の高い吸着熱交換器の
提供か可能となる。Furthermore, according to the method for manufacturing an adsorption heat exchanger according to claim 4, a plurality of heat exchanger tubes] 1.11. ... and the heat transfer fins 1212 disposed straddling these mutually, and the adhesion between them and the adsorbent of the adsorbent molded body 13 can be achieved in a simpler and more reliable manner. This makes it possible to provide an adsorption heat exchanger with high heat exchange performance and low cost.
（実施例）
以下、添付図面を参照して本願各発明の好適な実施例を
説明する。(Embodiments) Hereinafter, preferred embodiments of each invention of the present application will be described with reference to the accompanying drawings.
第１実施例
第１図には、本願の請求項１及び２記載の発明の実施例
にかかる吸着熱交換器を構成するための吸着熱交換エレ
メントが示されており、同図において符号ｌは吸着熱交
換エレメント全体、１１は伝熱管、１２は網状フィンで
構成される伝熱フィン、１３は後述のように請求項６記
載の製造方法によって吸着剤を焼結して成形された吸着
剤成形体１３をそれぞれ示している。FIRST EMBODIMENT FIG. 1 shows an adsorption heat exchange element for configuring an adsorption heat exchanger according to an embodiment of the invention as claimed in claims 1 and 2 of the present application, and in the figure, the reference numeral l is The entire adsorption heat exchange element, 11 is a heat transfer tube, 12 is a heat transfer fin constituted by a mesh fin, and 13 is an adsorbent molded by sintering the adsorbent by the manufacturing method according to claim 6 as described below. The body 13 is shown respectively.
伝熱管１１は銅、アルミニウム等の高伝熱性の材料から
なる円筒管で構成されている。The heat exchanger tube 11 is a cylindrical tube made of a highly heat conductive material such as copper or aluminum.
伝熱フィン１２は、伝熱管１１と同様に銅、アルミニウ
ム等の高伝熱性の金属材料で作られており、所定の間隔
をもって平行配置されｆニ二本の伝熱管１１．１１相互
間に跨がるようにして該伝熱管１１．１１に対して、上
下方向に所定間隔をもって三枚重ね状に取付けられてし
ｌる。そして、二の伝熱管＋１．Ｉ＋とこれに固着され
た伝熱フィン＋ ２．１２．・・とて伝熱ユニット１０
が形成されている。Like the heat exchanger tubes 11, the heat transfer fins 12 are made of a highly heat conductive metal material such as copper or aluminum, and are arranged in parallel with a predetermined interval between the two heat exchanger tubes 11 and 11. The heat transfer tubes 11 and 11 are attached to the heat transfer tubes 11 and 11 in a stacked manner with a predetermined interval in the vertical direction. And the second heat exchanger tube +1. I+ and heat transfer fins+ fixed thereto 2.12. ...Tote heat transfer unit 10
is formed.
さらに、この伝熱ユニット１０は、後述の吸着剤成形体
１３によってその内部に被包され該吸着剤成形体１３と
一体化されることにより、吸着熱交換エレメント１を構
成する。Furthermore, this heat transfer unit 10 is encapsulated and integrated with an adsorbent molded body 13, which will be described later, thereby forming the adsorption heat exchange element 1.
ここで、この吸着剤成形体１３の成形方法を説明すると
、先ず最初に、上記伝熱ユニット１０を成形型（図示省
略）内にセットする。次に、例えば、七オライド、ノリ
力ゲル等の吸着剤に、伝熱性に優れた銅粉あるいは銅繊
維等からなる伝熱促進材を所定混合比で混ぜ合せ、且つ
これをスラリー状とする。そして、この伝熱促進材が混
合されたスラリー状の吸着剤を上記成形型内に投入し、
且つこれを該伝軌ユニッ）１０の各部に隙間なく充填す
る。Here, to explain the method of molding this adsorbent molded body 13, first, the heat transfer unit 10 is set in a mold (not shown). Next, for example, an adsorbent such as heptaolide or glue gel is mixed with a heat transfer accelerator such as copper powder or copper fibers having excellent heat transfer properties at a predetermined mixing ratio, and the mixture is made into a slurry. Then, a slurry-like adsorbent mixed with this heat transfer promoter is put into the mold,
Then, each part of the track transmission unit 10 is filled with the same without any gaps.
然る後、成形型を閉じ、加圧しながら上記吸着剤を焼結
させ、略板状の吸着剤成形体１３を得るものである。Thereafter, the mold is closed and the adsorbent is sintered under pressure to obtain a substantially plate-shaped adsorbent molded body 13.
従って、吸着剤成形体１３の焼結成形状態においては、
上記伝軌ユニット１０は該吸着剤成形体１３内に被包さ
れ１こ状態て一体化される。そして、この場合、吸着剤
成形体１３と、伝熱ユニット１０との間の密着性は、焼
結前における吸着剤の充填作用と、焼結成形時における
加圧作用との相乗的効果により、極めて高水準に維持さ
れている。Therefore, in the sintered state of the adsorbent molded body 13,
The transmission unit 10 is encapsulated within the adsorbent molded body 13 and integrated therewith. In this case, the adhesion between the adsorbent molded body 13 and the heat transfer unit 10 is due to the synergistic effect of the filling action of the adsorbent before sintering and the pressurizing action during sintering. Maintained at an extremely high standard.
このように構成された吸着熱交換エレメントｌを備えた
吸着熱交換器においては、先ず、上述のように伝熱ユニ
ット１０と吸着剤成形体１３との密着性か極めて高くこ
れらの間の接触熱抵抗が可及的に低減されその伝熱性か
良好ならしめられていること、及び吸着剤成形体１３を
構成する吸着剤に伝熱促進材か混入され該吸着剤成形体
１３そのものの伝熱性か該吸着剤のみの場合よりもさら
こ高められていること、さらに各フィン１２，１２、・
・か各伝熱管＋ １．１１．・・相互間に跨かっ１こ状
態で配置されておりその伝軌面積を十分にくよできるこ
とから、より高水準の熱交換性能を８″？−有すること
となる。In the adsorption heat exchanger equipped with the adsorption heat exchange element 1 configured in this way, first, as described above, the adhesion between the heat transfer unit 10 and the adsorbent molded body 13 is extremely high, and the contact heat between them is extremely high. The resistance is reduced as much as possible and its heat conductivity is good, and the adsorbent constituting the adsorbent molded body 13 is mixed with a heat transfer promoter, and the adsorbent molded body 13 itself has good heat conductivity. In addition, each fin 12, 12, .
・Each heat transfer tube + 1.11. ...Since they are arranged in a bracket between each other and the track transmission area can be sufficiently covered, it has a higher level of heat exchange performance of 8"?-.
尚、吸着剤に混合される伝熱促進材として、例えば粉体
状のものを使用した場合には、該伝熱促進材と吸着剤と
の混合状態の均一化か図り易く、このため吸着熱交換エ
レメント１の全域における伝熱性の管理が容易になると
いう利点か在る。また、繊維状のものを使用した場合に
は、繊維状ものに特有の拘束作用によって吸着剤成形体
１３の強度アップが図れ、結果的に該吸着剤成形体Ｉ３
の薄肉化の促進によりその伝熱性のより一層の向上が図
れるという利点が有る。In addition, when a powdered material is used as the heat transfer accelerator mixed with the adsorbent, it is easier to uniformize the mixing state of the heat transfer accelerator and the adsorbent, and therefore the heat of adsorption is reduced. There is an advantage that the heat transfer properties in the entire area of the exchange element 1 can be easily managed. In addition, when a fibrous material is used, the strength of the adsorbent molded body 13 can be increased due to the constraining action specific to the fibrous material, and as a result, the adsorbent molded body I3
There is an advantage that the heat transfer properties can be further improved by promoting the thinning of the .
また、この吸着熱交換エレメントｌを複数枚組み合わせ
て所定本数の伝熱管１１．１１．・・を有する熱交換器
を製造する場合には、該吸着熱交換エレメント１を順次
積層配置することによって度に複数本（この実施例にお
いては２本）つり伝熱管１１．１１．・・を組み付ける
ことかでき、例えばこの伝熱管を一本っつ組み付１号る
場合に比して、その製造上の作業性か良好となる。In addition, a predetermined number of heat transfer tubes 11.11. by combining a plurality of adsorption heat exchange elements l. When manufacturing a heat exchanger having 11. ... can be assembled, and the manufacturing workability is improved compared to, for example, the case where the heat exchanger tubes are assembled one by one.
さらに、この吸着熱交換エレメント１の組付けに際して
は、これが比較的強度の高い吸着剤成形体３によって被
包されていることから、その取扱いか容易であり、これ
によっても作業性の向上か図られるものである。Furthermore, when assembling the adsorption heat exchange element 1, it is easy to handle because it is covered with a relatively strong adsorbent molded body 3, and this also improves work efficiency. It is something that can be done.
ｌ素大滝号
第２図および第３図には、本願発明の第２実施例にかか
る吸着熱交換器に適用される吸着熱交換エレメントＩか
示されている。この吸着熱交換エレメント１は、上記第
１実施例で示した吸着熱交換エレメント１の変形例とも
言うべきものであって、上記第１実施例のしのが伝熱フ
ィン１２として網状フィンのみを使用していたのに対し
て、この第２実施例のものは、網状フィンに加えて、伝
熱管１１．１１の外周に放射状に針状フィンを設す、こ
の両者て伝熱フィン１２を構成したものである。Figures 2 and 3 show an adsorption heat exchange element I applied to an adsorption heat exchanger according to a second embodiment of the present invention. This adsorption heat exchange element 1 can also be called a modification of the adsorption heat exchange element 1 shown in the first embodiment, and the first embodiment uses only mesh fins as the heat transfer fins 12. In contrast, in the second embodiment, needle-shaped fins are provided radially around the outer periphery of the heat transfer tubes 11 and 11 in addition to the net-like fins, and both constitute the heat transfer fins 12. This is what I did.
従って、この実施例のものにおし１では、剣状フィンを
持１こなＬ・第１実施例ε二）吸着熱交換ニレメツ）・
Ｉよりもさらに高い伝熱性能を確保することかできるも
のである。Therefore, in the case of this example, the knife 1 has sword-like fins.
It is possible to ensure even higher heat transfer performance than I.
第３実施例
第４図及び第５図には、本願発明の第３実施例にかかる
吸着熱交換器に適用される吸着軌交換エレメントｌか示
されている。この吸着熱交換エレメントｌは、伝熱ユニ
ットＩＯを、伝熱管１１゜１１と、これら相互間に跨が
るようにして固着された多数の針状フィン及び該伝熱管
１１．１１の外周面に放射状に固着した多数の針状フィ
ンとからなる伝熱フィン１２．１２．・・とて構成した
ものである。尚、吸着剤成形体１３は、上記第１実施例
の場合と同様構成とされている。Third Embodiment FIGS. 4 and 5 show an adsorption locus exchange element 1 applied to an adsorption heat exchanger according to a third embodiment of the present invention. This adsorption heat exchange element 1 connects the heat transfer unit IO to the heat transfer tubes 11. Heat transfer fins consisting of a large number of needle-like fins fixed in a radial manner 12.12. ...It was constructed as follows. The adsorbent molded body 13 has the same structure as in the first embodiment.
この実施例の吸着熱交換エレメント１においても、上記
第１実施例と同様の作用効果か得られるものである。The adsorption heat exchange element 1 of this embodiment also provides the same effects as those of the first embodiment.
第４実施例
第６図及び第７図には、本願発明の第４実施例にかかる
吸着熱交換器に適用される吸着熱交換エレメントｌが示
されている。この吸着軌交換エレメントｌは、伝熱ユニ
ット１０を、伝熱管ｌｌ１１と、これら相互間に跨がる
ようにして所定間隔で平行配置された複数本のコイル状
フィンからなる伝熱フィンｌ ２．＋ ２．・・とて構
成しにものである。尚、吸着剤成形体１３は、上記第１
実施例の場合と同様構成とされている。Fourth Embodiment FIGS. 6 and 7 show an adsorption heat exchange element 1 applied to an adsorption heat exchanger according to a fourth embodiment of the present invention. This adsorption track exchange element 1 includes a heat transfer unit 10, a heat transfer tube 111, and a plurality of coiled fins arranged in parallel at predetermined intervals so as to straddle the heat transfer fins 2. +2. ...It's quite a composition. In addition, the adsorbent molded body 13 is
The configuration is similar to that of the embodiment.
この実施例の吸着熱交換エレメントｌにおいても、上記
第１実施例と同様の作用効果が得られるものである。The adsorption heat exchange element 1 of this embodiment also provides the same effects as those of the first embodiment.
第１図は本願発明の第１実施例の吸着熱交換器に使用さ
れる吸着熱交換エレメントの斜視図、第２図は第２実施
例の吸着熱交換器に使用される吸着熱交換エレメントの
平面図、第３図は第２図の■−■断面図、第４図は第３
実施例の吸着熱交換器に使用される吸着執交換エレメン
トの平面図、第５図は第４図のｖ−■断面図、第６図は
第４実施例の吸着熱交換器に使用される吸着熱交換エレ
メントの平面図、第７図は第６図の■−■断面図、第８
図は吸着熱交換器を使用したノステム例の説明図、第９
図は従来の吸着熱交換器に使用されている吸着熱交換エ
レメントの一部拡大図である。
ｌ・・・・・吸着熱交換エレメント
１１・・・・伝熱管
１２・・・・伝熱フィン
１３・・・・吸着剤成形体
出
代
願
理
人
人
ダイキン工業株式会社FIG. 1 is a perspective view of an adsorption heat exchange element used in an adsorption heat exchanger according to a first embodiment of the present invention, and FIG. 2 is a perspective view of an adsorption heat exchange element used in an adsorption heat exchanger according to a second embodiment of the present invention. The plan view, Figure 3 is a sectional view taken from ■-■ in Figure 2, and Figure 4 is the
A plan view of the adsorption exchange element used in the adsorption heat exchanger of the embodiment, FIG. 5 is a sectional view taken along the line v-■ in FIG. 4, and FIG. A plan view of the adsorption heat exchange element, Fig. 7 is a sectional view taken along ■-■ of Fig. 6, and Fig. 8
The figure is an explanatory diagram of an example of Nostem using an adsorption heat exchanger, No. 9
The figure is a partially enlarged view of an adsorption heat exchange element used in a conventional adsorption heat exchanger. l...Adsorption heat exchange element 11...Heat transfer tube 12...Heat transfer fin 13...Applicant for application for adsorbent molded body Daikin Industries, Ltd.
Claims (1)
うにしてその外周面に伝熱フィン（１２、１２、・・）
を取り付けるとともに、該各伝熱管（１１、１１、・・
）と各伝熱フィン（１２、１２、・・）の周囲を、吸着
剤を焼結成形してなる吸着剤成形体（１３）によって伝
熱接触可能に被包して一体的に構成したことを特徴とす
る吸着熱交換器。 ２、伝熱フィン（１２、１２、・・）が網状フィン又は
針状フィン又はコイル状フィンで構成されていることを
特徴とする請求項１記載の吸着熱交換器。 ３、吸着剤中に、伝熱性材質からなる伝熱促進材が混入
せしめられていることを特徴とする請求項１又は２記載
の吸着熱交換器。 ４、複数の伝熱管（１１、１１、・・）に跨がるように
してその外周面に伝熱フィン（１２、１２、・・）を取
り付けてなる伝熱ユニット（１０）の周囲に、スラリー
状の吸着剤を充填し、然る後、該スラリー状吸着剤を焼
結成形することにより上記伝熱ユニット（１０）の周囲
を吸着剤成形体（１３）によって一体的に被包すること
を特徴とする吸着熱交換器の製造方法。[Claims] 1. A plurality of heat transfer tubes (11, 11, . . . ) with heat transfer fins (12, 12, . . . ) on their outer peripheral surfaces so as to straddle each other.
At the same time, attach each heat transfer tube (11, 11,...
) and each of the heat transfer fins (12, 12, . . . ) are integrally constructed by enclosing and enabling heat transfer contact with an adsorbent molded body (13) formed by sintering an adsorbent. An adsorption heat exchanger featuring: 2. The adsorption heat exchanger according to claim 1, wherein the heat transfer fins (12, 12, . . . ) are composed of net-like fins, needle-like fins, or coil-like fins. 3. The adsorption heat exchanger according to claim 1 or 2, wherein the adsorbent contains a heat transfer accelerator made of a heat conductive material. 4. Around the heat transfer unit (10) formed by attaching heat transfer fins (12, 12,...) to the outer peripheral surface of the heat transfer tubes (11, 11, . . . ) so as to straddle a plurality of heat transfer tubes (11, 11, . The periphery of the heat transfer unit (10) is integrally covered with the adsorbent molded body (13) by filling a slurry-like adsorbent and then sintering the slurry-like adsorbent. A method for manufacturing an adsorption heat exchanger characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2265584A JP2550768B2 (en) | 1990-10-02 | 1990-10-02 | Adsorption heat exchanger |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2265584A JP2550768B2 (en) | 1990-10-02 | 1990-10-02 | Adsorption heat exchanger |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04143558A true JPH04143558A (en) | 1992-05-18 |
| JP2550768B2 JP2550768B2 (en) | 1996-11-06 |
Family
ID=17419153
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2265584A Expired - Fee Related JP2550768B2 (en) | 1990-10-02 | 1990-10-02 | Adsorption heat exchanger |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2550768B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007247928A (en) * | 2006-03-14 | 2007-09-27 | Osaka Gas Co Ltd | Method of manufacturing heat exchange-type reactor, and heat exchange-type reactor |
| JP2008121912A (en) * | 2006-11-08 | 2008-05-29 | Denso Corp | Adsorption module and manufacturing method of adsorption module |
| JP2008157536A (en) * | 2006-12-22 | 2008-07-10 | Denso Corp | Adsorber, and manufacturing method of adsorber |
| JP2009097733A (en) * | 2007-10-12 | 2009-05-07 | Denso Corp | Adsorption heat exchanger and its manufacturing method |
| JP2009198146A (en) * | 2008-02-25 | 2009-09-03 | Denso Corp | Adsorption module and adsorption heat exchanger |
| JP2014181863A (en) * | 2013-03-19 | 2014-09-29 | Toyota Central R&D Labs Inc | Heat exchange type reactor and adsorption type heat pump |
| JP2014224668A (en) * | 2013-04-15 | 2014-12-04 | 株式会社リコー | Reactive material molded body and heat accumulating-radiating unit |
| WO2015079770A1 (en) * | 2013-11-26 | 2015-06-04 | 株式会社村田製作所 | Heat storage device |
| JP2017525933A (en) * | 2014-08-22 | 2017-09-07 | 中盈▲長▼江国▲際▼新能源投▲資▼有限公司 | Solar energy water heating auxiliary heat storage device and power plant boiler solar energy water heating supply system formed from solar energy water heating auxiliary heat storage device |
| JP2019203611A (en) * | 2018-05-21 | 2019-11-28 | 株式会社デンソー | Adsorber and manufacturing method of adsorber |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60232242A (en) * | 1983-12-30 | 1985-11-18 | ペ−タ− マイヤ− ―ラツクス フ−バ− | High-temperature conductive zeolite semi-molded shape and manufacture thereof |
| JPS61205758A (en) * | 1985-03-09 | 1986-09-11 | 株式会社日本製鋼所 | Chemical heat accumulator |
| JPS63185446A (en) * | 1987-01-26 | 1988-08-01 | Nishiyodo Kuuchiyouki Kk | Production of solid adsorbent |
| JPS63142659U (en) * | 1987-03-11 | 1988-09-20 |
-
1990
- 1990-10-02 JP JP2265584A patent/JP2550768B2/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60232242A (en) * | 1983-12-30 | 1985-11-18 | ペ−タ− マイヤ− ―ラツクス フ−バ− | High-temperature conductive zeolite semi-molded shape and manufacture thereof |
| JPS61205758A (en) * | 1985-03-09 | 1986-09-11 | 株式会社日本製鋼所 | Chemical heat accumulator |
| JPS63185446A (en) * | 1987-01-26 | 1988-08-01 | Nishiyodo Kuuchiyouki Kk | Production of solid adsorbent |
| JPS63142659U (en) * | 1987-03-11 | 1988-09-20 |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007247928A (en) * | 2006-03-14 | 2007-09-27 | Osaka Gas Co Ltd | Method of manufacturing heat exchange-type reactor, and heat exchange-type reactor |
| JP2008121912A (en) * | 2006-11-08 | 2008-05-29 | Denso Corp | Adsorption module and manufacturing method of adsorption module |
| JP2008157536A (en) * | 2006-12-22 | 2008-07-10 | Denso Corp | Adsorber, and manufacturing method of adsorber |
| JP2009097733A (en) * | 2007-10-12 | 2009-05-07 | Denso Corp | Adsorption heat exchanger and its manufacturing method |
| JP2009198146A (en) * | 2008-02-25 | 2009-09-03 | Denso Corp | Adsorption module and adsorption heat exchanger |
| JP2014181863A (en) * | 2013-03-19 | 2014-09-29 | Toyota Central R&D Labs Inc | Heat exchange type reactor and adsorption type heat pump |
| US9464824B2 (en) | 2013-03-19 | 2016-10-11 | Kabushiki Kaisha Toyota Chuo Kenkyusho | Heat exchange reactor and adsorption heat pump |
| JP2014224668A (en) * | 2013-04-15 | 2014-12-04 | 株式会社リコー | Reactive material molded body and heat accumulating-radiating unit |
| WO2015079770A1 (en) * | 2013-11-26 | 2015-06-04 | 株式会社村田製作所 | Heat storage device |
| JP2017525933A (en) * | 2014-08-22 | 2017-09-07 | 中盈▲長▼江国▲際▼新能源投▲資▼有限公司 | Solar energy water heating auxiliary heat storage device and power plant boiler solar energy water heating supply system formed from solar energy water heating auxiliary heat storage device |
| JP2019203611A (en) * | 2018-05-21 | 2019-11-28 | 株式会社デンソー | Adsorber and manufacturing method of adsorber |
| WO2019225383A1 (en) * | 2018-05-21 | 2019-11-28 | 株式会社デンソー | Adsorber, and method for manufacturing adsorber |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2550768B2 (en) | 1996-11-06 |
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